Engineering Commons^™

Stabilizing Electrochemical Carbon Capture Membrane With Al2O3 Thin-Film Overcoating Synthesized By Chemical Vapor Deposition, Jingjing Tong, Fengzhan Si, Lingling Zhang, Jie Fang, Minfang Han, Kevin Huang

Faculty Publications

Development of high-efficiency and cost-effective carbon capture technology is a central element of our effort to battle the global warming and climate change. Here we report that the unique high-flux and high-selectivity of electrochemical silver-carbonate dual-phase membranes can be retained for an extended period of operation by overcoating the surfaces of porous silver matrix with a uniform layer of Al₂O₃ thin-film derived from chemical vapor deposition.

La0.7Sr0.3Fe0.7Ga0.3O3-Δ As Electrode Material For A Symmetrical Solid Oxide Fuel Cell, Zhibin Yang, Yu Chen, Chao Jin, Guoliang Xiao, Minfang Han, Fanglin Chen

Faculty Publications

In this research, La_0.7Sr_0.3Fe_0.7Ga_0.3O_3−δ (LSFG) perovskite oxide was successfully prepared using a microwave-assisted combustion method, and employed as both anode and cathode in symmetrical solid oxide fuel cells. A maximum power density of 489 mW cm⁻² was achieved at 800 °C with wet H₂ as the fuel and ambient air as the oxidant in a single cell with the configuration LSFG|La_0.8Sr_0.2Ga_0.83Mg_0.17O_3−δ|LSFG. Furthermore, the cells demonstrated good stability in H₂ and acceptable sulfur tolerance.

La0.6Sr1.4Mno4+Δ Layered Perovskite Oxide: Enhanced Catalytic Activity For The Oxygen Reduction Reaction, Yarong Wang, Zhibin Yang, Fanliang Liu, Chao Jin, Jiao Wu, Ming Shen, Ruizhi Yang, Fanglin Chen

Faculty Publications

Efficient electrocatalysts for the oxygen reduction reaction (ORR) is a critical factor to influence the performance of lithium–oxygen batteries. In this study, La_0.6Sr_1.4MnO_4+δ layered perovskite oxide as a highly active electrocatalyst for the ORR has been prepared, and a carbon-coating layer with thickness <5 nm has been successfully introduced to enhance the electronic conductivity of the as-prepared oxide. XRD, XPS, Raman, SEM and TEM measurements were carried out to characterize the crystalline structure and morphology of these samples. Rotating ring-disk electrode (RRDE) technique has been used to study catalytic activities of the as-prepared catalysts for the ORR in 0.1 M KOH media. RRDE results reveal that carbon-coated La_0.6Sr_1.4MnO_4+δ exhibits better catalytic activity for the ORR. For the carbon-coated La_0.6Sr_1.4MnO_4+δ, the ORR proceeds predominately via a direct four electron process, and a maximum cathodic current density of 6.70 mA cm⁻² at 2500 rpm has been obtained, …

Graphene Based Heterojunctions For Nano-Electronic And Sensing Applications, Md A. Uddin

Theses and Dissertations

Graphene, an atomically thin and semi-metallic two dimensional material, has been extensively researched over the past decade due to its superior intrinsic carrier velocity, electrical and chemically tunable work function, ability to form layered heterostructure with other materials, and relevant potential applications in electronics, sensing, optoelectronics, energy storage, etc. However, the confinement of charge carriers within one atomic layer results in an electrical transport that is extremely sensitive to the surrounding environment, which is beneficial for sensing applications, but at times unfavorable for electronic applications due to scattering from extrinsic impurities. In addition, due to its rather delicate structure, engineering …

Design, Fabrication, And Characterization Of Pseudomorphic And Quasi-Pseudomorphic Algan Based Deep Ultraviolet Light Emitting Diodes Over Sapphire, Fatima Asif

Theses and Dissertations

III-Nitride based deep ultraviolet (UV) light emitting diodes (LEDs) emitting below 280nm has the potential to replace mercury lamps currently used in the systems for water/air purification, germicidal and medical instruments sterilization applications. However, this potential has not yet been fully realized as the output power, quantum efficiency and lifetime of deep UV-LEDs have been limited by the large number of dislocations in the active region of the devices, arising from the lattice mismatched sapphire substrate, which has been the substrate of choice due to its high transparency to deep UV radiation. To reduce dislocations in the active region of …

Predictive Methods For End Of Life Prognosis In Composites, Vamsee Vadlamudi

Theses and Dissertations

The long-term properties of continuous fiber reinforced composite materials are increasingly important as applications in airplanes, cars, and other safety critical structures are growing rapidly. The mechanical, electrical, and thermal properties of composite materials are altered by the initiation and accumulation of discrete fracture events whose distribution and eventual interaction defines the limits of design, such as strength and life. There is a correlation that exists between the long term behavior of those materials under combined mechanical, thermal, and electrical fields, and the functional properties and characteristics of the composite materials that requires a fundamental understanding of the material state …

Investigation Of Modular Multilevel Converter Performance Under Non-Ideal Distribution System Conditions, Rostan Rodrigues

Theses and Dissertations

The Modular Multilevel Converter (MMC) is an emerging power converter technology that has caught widespread attention mainly because of several technical and economic benefits such as modular realization, easy scalability, low total harmonic distortion, fail-safe operations etc. The MMC is comprised of a series connection of sub-modules (SM). A sub-module is made by either a half-bridge or a full-bridge IGBT device and a capacitor as a source of energy connected across the bridge. This modular structure allows for the possibility to design high-voltage converters handling hundreds of kilo-volts without direct series connection of the power semiconductor devices.

Due to its …

Adaptivity For Meshfree Point Collocation Methods In Linear Elastic Solid Mechanics, Joshua Wayne Derrick

Theses and Dissertations

This study presents the behavior of local node adaptivity for point collocation meshfree numerical methods and its application to linear elastic solid mechanics. A bisection approach to meshfree adaptivity will be presented with numerical examples showing that convergence is achieved. A threshold value is required from the user and this value is an acceptable change in gradient for the problem. If the change in gradient between 2 nodes exceed this limit, a node is added at the mid-point between the two nodes. This process applies to all nodes in the model. Once the refinement is complete, the model is processed …

Experimental Study Of Longitudinal Sorting Of Particles Differing In Size And Density, Nabila Mahjabeen

Theses and Dissertations

Transport, deposition and erosion of sediment particles differing in size, shape and density may result in particle segregation, which in geosciences applications is generally referred to as sediment sorting. A thorough understanding of sediment sorting processes is important to describe and model a wide variety of natural processes such as the decrease in particle size and/or density in a fluvial system (downstream fining and/or lightening), the formation of economic placers, concentration of heavy minerals, chemical and metal pollutants etc. Sorting of sediment grains associated with sediment transport in the streamwise direction results in the development of longitudinal sorting patterns. Vertical …

Inn Nems And Heterojunction Devices For Sensing Applications, Alina Wilson

Theses and Dissertations

Recent research trends in chemical and biological sensing have been geared toward developing molecular sensor devices that are fast, inexpensive, miniaturized, have low power consumption and are portable. The performance of these devices can be dramatically improved by utilizing multimodal detection techniques, new materials and nanofabrication technologies. To develop such sensor devices, we utilized Indium Nitride (InN) nanowires (NWs) to fabricate nanoelectromechanical system (NEMS) based sensors and Graphene/InN NW heterojunctions, and InN thin films to fabricate Graphene/InN thin film heterojunction based sensors. InN NWs, which exhibit interesting properties including high carrier density, superior electron mobility, strong surface charge accumulation, and …

Material Considerations For Development Of 3d Printed Bronchial And Tracheal Stents, Nidah M. Hussain

Theses and Dissertations

Tracheobronchial malacia is a commonly under-diagnosed condition that results in difficulty breathing. The use of a tracheobronchial stent is the best course of treatment for patients whose quality of life has deteriorated due to malacia; unfortunately stents need replacing after issues with inflammation, migration, or eventual stent-breakdown resulting in fistula formation.

The purpose of this thesis is to use three-dimensional (3D) printing technology to improve on existing stents through designing and printing a bioresorbable/biodegradable tracheobronchial stent that can treat tracheobronchial malacia. This was undertaken by testing three biologically favorable materials, type I collagen, polycaprolactone (PCL), and thermoplastic polyurethane (TPU), with …

Design And Development Of A Ventilation Chamber For Testing Efficacy Of Tracheal Stents, Caroline N. Horton

Theses and Dissertations

Tracheobronchial malacia results in a weakening of the tracheal walls, leading to increased difficulty breathing. Stents are used to reopen the lumen of the trachea, however, current models are not personalized to each patient, leading to migration, inflammation, and breakage of the stents. In order to successfully test novel stent designs, a ventilation chamber is needed to recreate the breathing conditions of the body.

The following describes the iterative development of a ventilation chamber, which allows inflation and deflation of lungs via negative pressure ventilation, as representative of an actual body undergoing respiration. Previous work shows that lungs are not …

Design Of Experiments Analysis Of Non-Standard Inputs For The Optimization Of Friction Stir Welding, Ryan Widejko

Theses and Dissertations

The purpose of this study was to use non-standard Design of Experiments (DoE) inputs in Friction Stir Welding (FSW) to deduce relationships between various weld input and response variables. Typically, inputs for FSW DoE are tool rotational speed, welding speed and forge force. In this study, three different input factors were investigated: travel speed, thermal boundary conditions (TBC), and advance per revolution (APR). The experimental design included a full factorial with each factor at two levels plus two centerpoint runs. Response variables included weld temperature, microstructure, hardness, power, weld energy, and in plane forces.

An investigation of the effect of …

An Investigation Into Quasi-Tunable Rf Passive Circuit Design, Terry L. Moss

Theses and Dissertations

Modern wireless electronic circuit design is continually challenged by the needs to reduce circuit size, and to also function reliably with lower power levels. To that end, two aspects of RFIC circuit design and technology have gained great interest, i.e. RF MEMS switching technology, and RF MEMS passive component development. MEMS (Micro-Electromechanical Systems) technology, originally developed for the defense industry, has been in development since the 1970s, and today enjoys wide range of utilization, from the defense industry to the automotive industry. Spiral inductors used in RFIC circuits, e.g. silicon technology, are ubiquitous in wireless RFIC applications. The tradeoff with …

Brand Positioning Map And Analysis Using Web Scraping And Advertisement Analysis, Surya Bhatt

Theses and Dissertations

There’s a significant increase in online consumer forums. When customers set out to buy a product they use these forums to form an opinion. Our research focuses on comparing Brand positioning maps based on consumer reviews. We also analyse the impact of advertisements and expert reviews. Our goal is to show that combining consumer reviews with ads and electronic media will help us analyze the effectiveness of advertising on brand positioning maps. This approach shall also help us in making association graphs for a brand using words of perception/opinion associated with that brand/product. Which may in turn assist companies in …

Selective Synthesis And Characterization Of Single-Site Hy Zeolite-Supported Rhodium Complexes And Their Use As Catalysts For Ethylene Hydrogenation And Dimerization, Konstantin Khivantsev

Theses and Dissertations

Single-site Rh(CO)2, Rh(C2H4)2 and Rh(NO)2 complexes anchored on various dealuminated HY zeolites can be used as precursors for the selective surface mediated synthesis of well-defined site-isolated Rh(CO)(H)x complexes. DFT calculations and D2 isotope exchange experiments provide strong evidence for the formation of a family of site isolated mononuclear rhodium carbonyl hydride complexes (including the first examples of RhH complexes with undissociated H2 ligands): Rh(CO)(H2), Rh(CO)(H)2, and Rh(CO)(H). The fraction of each individual complex formed varies significantly with the Si/Al ratio of the zeolite and the nature of the precursor used.

HY zeolite-supported mononuclear Rh(CO)2 complexes are remarkably active in ethylene …

Fabrication And Characterization Of Graphene Based Biocompatible Ion-Sensitive Field Effect Transistor (Isfet), Rina Patel

Theses and Dissertations

Graphene, a two-dimensional material with a high surface to volume ratio, has drawn extensive research enthusiasm for applications in the field of electronic sensors. The special material properties that make graphene a highly promising material include its biocompatibility, very high mobility, low 1/f and thermal noise, modulation of carrier concentration and fermi level by electrical, optical, and chemical means. To exploit these properties for practical applications a large area high quality graphene, transferred on appropriate substrates, is required. In this work, high quality single monolayer graphene (determined from Raman spectroscopy) has been synthesized by chemical vapor deposition (CVD) technique for …

Technology Development And Characterization Of Aiinn/Gan Hemts For High Power Application, Mahbuba Sultana

Theses and Dissertations

AlInN has attracted much attention only recently as a material due to its unique and superior material properties, which is however known to be difficult to be grown among the III-nitride ternary compounds. The electrons confined at the heterointerface of coherently grown AlInN on GaN buffer layers determine crucial electronic properties. This dissertation has been designed targeting the lattice matched AlInN/GaN investigation with very detail to optimize the design, fabrication process, and electronic properties to realize AlInN/GaN HEMTs. Each single step of this process was optimized in order to improve device performance.

The work started with establishing the main features …

Engineered 3d Microenvironments To Direct Osteogenic Differentiation And Modulate Inflammation, Katherine Elizabeth Rutledge

Theses and Dissertations

Current methods of treating critical size bone defects (CSDs) include autografts and allografts, however both present major limitations including donor-site morbidity, risk of disease transmission, and immune-rejection. Tissue engineering provides a promising alternative to circumvent these shortcomings through the use of stem cells, three dimensional (3D) scaffolds, and growth factors. Cells receive signals from their microenvironment that determine cell phenotype, and a combination of physical cues and chemical factors is thought to have the most profound influence on stem cell behavior. A major focus of tissue engineering strategies is scaffold design to recapitulate in vivo microenvironmental architecture to direct stem …

Drilled Shaft Skin Resistance Design In The Cooper Marl, William J. Gieser

Theses and Dissertations

As drilled shafts have become a more popular foundation type in the Charleston, South Carolina area, there has been an ongoing goal of optimizing drilled shaft design while maintaining the structural integrity of the foundation. In the Charleston area, the primary bearing stratum for deep foundations is the Cooper Marl, a calcareous Oligocene formation. Research performed from 2002 to 2004 on load test data from drilled shafts constructed in the Cooper Marl and soil properties from three test sites for the Cooper River Bridge explored the relationship between the measured skin resistance and geotechnical properties. In the 15 years since …

Iii-V Nitride Based Microcantilever Heaters For Unique Multimodal Detection Of Volatile Organic Compounds At Low Temperature, Ifat Jahangir

Theses and Dissertations

Detection of volatile organic compounds (VOCs), which are widely used in industrial processes and household products, is very important due to significant health hazards associated with them. VOCs are commonly detected using photo-ionization detectors (PIDs), suspended hot bead pellistors, or heated metal oxide semiconductor functionalization layers. However, these techniques used for detecting VOCs often suffer from one or more of the following issues - high power consumption, limited selectivity, complicated functionalization technique and expensive characterization tools. On the other hand, microcantilevers offer excellent avenues for molecular sensing that arises out of their high sensitivity to various physical parameter changes induced …

Fabrication And Characterization Of Anode-Supported Micro-Tubular Solide Oxide Fuel Cell By Phase Inversion Method, Cong Ren

Theses and Dissertations

Nowadays, the micro-tubular solid oxide fuel cells (MT-SOFCs), especially the anode supported MT-SOFCs have been extensively developed to be applied for SOFC stacks designation, which can be potentially used for portable power sources and vehicle power supply. To prepare MT-SOFCs with high electrochemical performance, one of the main strategies is to optimize the microstructure of the anode support. Recently, a novel phase inversion method has been applied to prepare the anode support with a unique asymmetrical microstructure, which can improve the electrochemical performance of the MT-SOFCs. Since several process parameters of the phase inversion method can influence the pore formation …

Defect Characterization Of 4h-Sic By Deep Level Transient Spectroscopy (Dlts) And Influence Of Defects On Device Performance, Mohammad Abdul Mannan

Theses and Dissertations

Silicon carbide (SiC) is one of the key materials for high power opto-electronic devices due to its superior material properties over conventional semiconductors (e.g., Si, Ge, GaAs, etc). SiC is also very stable and a highly suitable material for radiation detection at room temperature and above. The availability of detector grade single crystalline bulk SiC is limited by the existing crystal growth techniques which introduce extended and microscopic crystallographic defects during the growth process. Recently, SiC based high-resolution semiconductor detectors for ionizing radiation have attracted world-wide attention due to the availability of high resistive, highly crystalline epitaxial layers with very …

Methods For Determining Grease Service Levels In An Ah-64d Intermediate Gearbox Using On-Board Sensors, Travis Steven Edwards

Theses and Dissertations

The intermediate gearbox (IGB) on the AH-64D was chosen as the subject for this study based on the persistent grease leaks that require grounding aircraft. The aircraft is not currently equipped with a method of detecting grease loss during flight, so techniques for analyzing the usefulness of old metrics and possible new techniques can be tested. The main objective of this study is to use the aircraft’s on-board sensors to develop a method of determining the lubrication level of the IGB. Currently, the most reliable method for detecting a fault on the aircraft is through the use of vibration-based condition …

Development Of Computer Simulation Model For Urban Region Using Xp-Swmm In Savannah, Georgia, Matthew Dale Ricks

Theses and Dissertations

The objective of this thesis was to determine if it is possible to create, calibrate, and validate a computer simulation model given a limited amount of measured data. In June 1999, significant flooding was experienced throughout the Casey Canal North drainage basin in Savannah, Georgia. Time-depth rainfall data from a single gage was recorded for this event, along with peak water surface elevations throughout the basin. The computer model chosen for this application was XP-SWMM, which was approved by the Federal Emergency Management Agency to simulate both one dimensional and two dimensional hydraulic models. XP-SWMM was chosen due to its …

Propagated Image Segmentation Using Edge-Weighted Centroidal Voronoi Tessellation Based Methods, Youjie Zhou

Theses and Dissertations

Propagated image segmentation is the problem of utilizing the existing segmentation of an image for obtaining a new segmentation of, either a neighboring image in a sequence, or the same image but in different scales. We name these two cases as the inter-image propagation and the intra-image propagation respectively. The inter-image propagation is particularly important to material science, where efficient and accurate segmentation of a sequence of 2D serial-sectioned images of 3D material samples is an essential step to understand the underlying micro-structure and related physical properties. For natural images with objects in different scales, the intra-image propagation, where segmentations …

Dual-Band Non-Stationary Channel Modeling For The Air-Ground Channel, Ruoyu Sun

Theses and Dissertations

Multiple air-to-ground (AG) radio propagation channels are experimentally characterized for two frequency bands, C-band and L-band. These characterizations are aimed to support the specification of the control and non-payload communication (CNPC) links being designed for civil unmanned aircraft systems (UAS). The use of UAS is expected to grow dramatically in the coming decades. In the United States, UAS will be monitored and guided in their operation within the national airspace system (NAS) via the CNPC link. The specifications of the CNPC link are being designed by government, industries, academia and standards bodies such as the Radio Technical Commission for Aeronautics …

A Reversible And Stable Flake-Like Licoo2 Cathode For Lithium Ion Batteries, Tao Wei, Rui Zeng, Yongming Sun, Yunhui Huang, Kevin Huang

Faculty Publications

A dense and thick flake-like cathode structure was demonstrated to have a preferential crystallographic orientation for Li+ migration and a better tolerance to cracking, both of which enable a reversible and stable capacity at moderate rates from 0.1 to 2 C.

Theoretical Investigation Of The Catalytic, Liquid-Phase Hydrodeoxygenation Of Organic Acids And Esters, Sina Behtash

Theses and Dissertations

With worldwide fossil fuel resources dwindling and greenhouse gas emissions rising, it is urgent to find renewable liquid fuel alternatives from e.g. biomass to meet the world’s growing energy demand. Lipid feedstocks and pyrolysis oils from woody biomass can be utilized for the production of second-generation biofuels via a catalytic hydrodeoxygenation (HDO) process. The conversion of fatty acids and esters plays an important role in the activity and selectivity of these processes. Understanding the HDO reaction mechanism of organic acids and esters on metal surfaces is a prerequisite for the rational design of new HDO catalysts specifically designed for upgrading …

Quantifying Individual Losses In A Direct Methanol Fuel Cell, Jennifer Rae Ruffing

Theses and Dissertations

The performance of a direct methanol fuel cell (DMFC) is complicated due to the complex interactions of kinetic and transport processes. As a result, changes in one aspect of the cell have consequences in other aspects, which are difficult to elucidate from the full-cell polarization (i.e. voltage vs. current) behavior that fuel cell researchers often use to characterize the performance of their systems. The objective of this work was to develop a strategy to use current and voltage relationships from anode half cells, cathode half-cells, and a hydrogen pump, coupled with methanol crossover data and a mathematical model, to quantify …