Structural Materials Commons^™

Comparative Study Of Cement-Rice Husk Ash Stabilized Bricks And Fired Clay Bricks, Daniel R. Samson, Emmanuel S. Leo

Tanzania Journal of Science

In some countries, fired clay bricks (FCBs) are widely used for construction, but their production is energy-intensive, relies largely on firewood, and contributes to deforestation and carbon emissions. This study explores unfired clay bricks stabilised with cement and rice husk ash (RHA) as a sustainable alternative, using Dakawa ward in the Morogoro Region, Tanzania, as a case study. The bricks, with a clay of plasticity index 17%, were stabilized with 6%, 10%, and 14% cement by mass, moulded into 40 mm cubes, and cured for 28 days. The compressive strengths achieved were 1.5, 3.6, and 4.1 MPa with water absorption …

Creation Of The 2-Way Cross Laminated Timber Subroutine For Computing Dynamic Analysis Parameters, Joseph Freitas

Architectural Engineering

This document will describe the inputs, methodology, and outputs for the CLT 2-way subroutine for cases with and without openings recently added to a proprietary structural analysis software. For the sake of simplicity, most of the discussion will be focused on cases without openings from here on out, as the verification process for a novel method for cases with openings is still in progress. The CLT 2-way module calculates multi-point resistance functions for panels without openings by automating the procedure outlined in an industry-standard structural design manual. The subroutine also finds the appropriate dynamic response factors, kinetic load multipliers, mass, …

Metal-Free Nitrogen-Enriched Graphitic Carbon Nitride Architectures For Advanced Supercapacitor Energy Storage: Design, Synthesis, And Electrochemical Performance Optimization, Loujain Gamal Mohamed

Theses and Dissertations

Abstract

This thesis addresses the urgent global requirement for efficient energy storage materials by developing and characterizing advanced graphitic carbon nitride (g-C3N4)-based electrode materials for supercapacitors. A facile, low-cost thermal polymerization method produces 2D nitrogen-rich GCN nanosheets exhibiting excellent electrochemical stability and wide voltage windows, enabling symmetric devices with 19.33 Wh/kg energy density and remarkable cycling stability over 21,000 cycles. To overcome intrinsic limitations of pristine GCN, a 3D/2D metal free composite with bio-derived carbon (Bio-Cx) is synthesized, delivering high capacitance, wide potential windows, and ultrahigh energy density of 53.72 Wh/kg in asymmetric configurations paired with mesoporous nitrogen-doped carbon (MPNDC). …

Development Of A Novel Innovative Umbrella Falsework System For Concrete Slabs, Abdelazem Hashim

Theses and Dissertations

Formwork is one of the major elements that contribute to the cost and duration of concrete building projects. This is why optimizing such an element can lead to huge savings to all parties involved in the construction projects. With contractors facing huge challenges in such a competitive industry and employers seeking the least price and least duration for their projects, contractors are constantly under the obligations of finding the best alternatives to deliver their projects in terms of both time and money. Therefore, the main aim of this research project is to develop a falsework system, where the falsework system …

Co-Calcination Of Limestone And Clay Enhances The Performance Of Limestone Calcined Clay Cement (Lc3), Oluwadamilare Charles Adesina, Sahil Surehali, Avinaya Tripathi, Kayla Lauren Lee, Bryan K. Aylas-Paredes, Aditya Kumar, Narayanan Neithalath

Materials Science and Engineering Faculty Research & Creative Works

Limestone-calcined clay cements (LC³) reduce the environmental impact of cement production and accelerate the industry transition toward carbon neutrality. While conventional LC³ with 50% clinker replacement (LC³-50) demonstrate long-term performance comparable to ordinary Portland cement (OPC) in concrete, early-age performance is generally compromised. This study explores for the first time, joint thermal treatment—that is, co-calcination—of limestone (LS) and bulk kaolinitic clay in mass ratios of 1:1 to 1:4 under a calcination regime specifically designed to ensure activation of the clay mineral. The co-calcination converts a small fraction of LS to metastable CaO, thus providing an …

Copper Metal Organic Framework-Based Nanomaterial For Non-Enzymatic Glucose Electrochemical Sensor, Sameha Mohamed Sadek

Theses and Dissertations

This thesis examines the development of non-enzymatic glucose sensors by engineering advanced electrode materials based on metal-organic frameworks (MOFs). Conventional enzymatic glucose sensors, although widely used, suffer from inherent limitations, including poor long-term stability, narrow operating conditions, and sensitivity to environmental factors, due to their reliance on biological enzymes. Non-enzymatic sensors offer a more robust alternative by enabling direct electrochemical oxidation of glucose on engineered electrode surfaces. MOFs represent a highly tunable class of hybrid materials with structural and chemical features that are ideal for sensor applications, including a high surface area, tailored porosity, and excellent thermal and chemical stability. …

Areosense, Josephine Turney

Williams Honors College, Honors Research Projects

The AeroSense growing system is designed to make indoor aeroponic gardening easy and accessible for everyone. By combining sensors, automation, and AI, the system can monitor and adjust humidity, lighting, and nutrient levels to help plants thrive without requiring expert knowledge. The goal is to create a self-regulating garden that takes the guesswork out of growing fresh herbs and vegetables at home. The project involves building a working aeroponic prototype equipped with misters, pumps, and environmental sensors, all managed by a Raspberry Pi. Using computer vision and machine learning, AeroSense will be able to assess plant health and respond automatically …

Data Set, R Scripts And Script Outputs For Manuscript: Manufacturing Systems: Characteristics And Dynamics, Alan J. Fitzmorris

Graduate Research Data

This file repository contains fifteen computer-generated datasets, two naturally occurring datasets, nineteen shipbuilding shop datasets, and sixty-one concrete plant datasets.  Each data set contains subdirectories associated with various aspects of the data analysis, including stationarity analysis, dynamic system analysis, and complexity analysis.  In each case, applicable R scripts are included.  The text file entitled “Directory_and_File_Names” depicts the directory structure and associated file names for a total of 225 directories encompassing 8008 files.

Buckling Analysis Of Auxetic Composite Laminates And Optimal Design Using Lamination Parameters And Machine Learning, Hans Bendon Maria Tamil Selvan

Mechanical and Aerospace Engineering Theses

Composite materials are widely used as structural panels in aerospace, automotive, and civil engineering applications, where buckling is often a critical failure mode. This thesis focuses on the analysis and design of composite laminates that maximize buckling performance under prescribed stiffness and thickness constraints.

The first part of the study investigates the buckling behavior of auxetic laminates, which exhibit a negative Poisson's ratio. While previous studies suggest that auxetic laminates can achieve higher critical buckling loads than non-auxetic laminates under simply supported boundary conditions with lateral restraint, the influence of other boundary conditions and plate aspect ratios has not been …

Thermal Transformations And Mechanical Properties Of All-D-Metal Mn2fecu Heusler-Type Shape Memory Alloy, Choji J. Daches, Joseph W. Newkirk, Mario Buchely

Materials Science and Engineering Faculty Research & Creative Works

All-d-metal Heusler alloys are emerging functional materials in which magnetic ordering, lattice distortion, and mechanical behavior are strongly coupled through d–d electronic interactions. This study systematically investigates the structural, thermal, magnetic, and mechanical properties of Mn₂FeCu synthesized within a Heusler-type compositional framework. SEM/EDS revealed a dual-phase FCC-based microstructure consisting of Mn–Fe–rich and Mn–Cu–rich domains, while XRD confirmed FCC symmetry with compositional partitioning rather than full L2₁ ordering. Differential scanning calorimetry identified partial melting of the Cu-rich phase near ~ 900 °C. Dilatometry showed a thermoelastic FCC → FCT transformation at ~ 770–780 °C with a recoverable strain of ~ 0.067%. …

The Effects Of Mold Flux Contamination On Oxide Scale Formation And Hydro-Descaling Efficiency During Steel Processing, Tochukwu Princewill Ojiako, Richard Osei, Mario Buchely, Haiming Wen, Simon Lekakh, Ronald O'Malley

Materials Science and Engineering Faculty Research & Creative Works

Oxide scale formation during thin-slab continuous casting has a complex structure, which is influenced by mold flux contamination, that modifies interfacial reactions during solidification, subsequent reheating, and descaling. While individual aspects of the oxidation behavior of carbon steel have been previously examined, the synergetic effects of mold flux contamination during continuous casting and subsequent reheating on scale modification and the efficiency of hydraulic descaling remain inadequately studied. This study quantitatively examines the effect of flux composition on oxide scale evolution, adhesion, and hydraulic removal in low-carbon steel under simulated industrial conditions. Slab samples with as-cast, cleaned, and flux-coated surfaces were …

Made On Mars: Design And Manufacturing Of Structural Polymer-Regolith Composites, Pailey M. Vitale

Williams Honors College, Honors Research Projects

Human exploration of Mars is constrained by harsh environmental conditions and the prohibitive cost of transporting materials from Earth. Long-term sustainability requires the local production of mechanical and structural components using resources available on Mars, thereby minimizing payload mass. This project investigates polymer–regolith composites derived from atmospheric CO₂ and mineral-rich regolith as a pathway toward in-situ manufacturing. These composites, when compatible with additive manufacturing, could replace imported plastics, enable on-demand fabrication, and support closed-loop recycling systems. The objective is to design and evaluate polymer–regolith composites that maintain mechanical integrity and environmental resistance under Martian conditions, including extreme temperature swings, radiation …

Utilizing Coal For Mesophase Pitch-Based Carbon Fiber Production: Precursors, Processes, And Progress, Christina M. Thompson

Theses and Dissertations--Chemistry

Graphitic materials possess unique properties due to the unique combination of layered crystalline structure and carbon’s low atomic weight. High performance carbon fiber is one such example, displaying exceptional strength-to-weight ratios, stiffness, and thermal and chemical resistance. These properties render high performance carbon fiber a critical structural reinforcement material in the manufacture of composites across various industries, such as for automotive and aerospace applications. However, balancing fiber performance with precursor and processing costs remains a challenge. As alternative carbonaceous feedstocks are explored, coal has gained interest for utilization in graphitic products as a relatively abundant and low-cost source of aromatic …

Critical Parameters Controlling Oxide Scale Formation And Hydro-Descaling Efficiency During Steelmaking, Tochukwu Princewill Ojiako

Doctoral Dissertations

In modern steelmaking, cast slabs are exposed to high-temperature oxidizing environments during secondary cooling, reheating, and hot rolling, resulting in the formation of multilayer oxide scales on the steel surface. These scales interact with mold-flux residues originating from the casting process (CC). The morphology, chemistry, and adhesion of oxide scale strongly influence its removability during high-pressure hydraulic descaling and ultimately determine the surface quality of hot-rolled products. However, the mechanistic relationship between oxide scale evolution, scale-steel interfacial structure, and hydraulic descaling performance remains poorly understood.

This dissertation investigates oxide scale formation, modification, and removal in low-carbon thin-slab steels produced by …

Modeling Of Transformation Temperatures In Cast Martensitic Stainless Steels-Ca6nm: Effects Of Composition, Heating Rate, And Grain Size, Ugochukwu Agbedo, Mario Buchely, Laura Bartlett, Caelan Kennedy

Materials Science and Engineering Faculty Research & Creative Works

Accurate prediction of the critical transformation temperatures Ac1 and Ac3 is one of the essential factors in the heat treatment of CA6NM cast martensitic stainless steel. In this study, the influence of alloy composition, heating rate, and prior austenite grain size on the critical temperatures was quantified using dilatometric measurements and statistical modeling. Six heat treatment conditions produced prior austenite grain sizes ranging from ~75 to 247 µm. Experimental results showed that grain size variations produced only minor changes in Ac1 and Ac3, indicating a weak dependence of transformation temperatures on prior austenite grain size within the investigated range. In …

Multiphysics Simulation And Experimental Validation Of Phase Transformation And Hardness In Jominy End-Quenched Low-Alloy Steels, J. S. Alabi, E. Heidari, M. F. Buchely, K. Chandrashekhara, S. N. Lekakh, R. J. O'Malley, V. A. Athavale, A. Kumar

Materials Science and Engineering Faculty Research & Creative Works

High-volume industrial continuous hot-rolled steel heat treatment processes involve sophisticated multi-phase modeling. The performance of a given process can be optimized by coupling phase transformation kinetics with the cooling conditions of the process. This study develops a multiphysics model to simulate an intensive quenching process for steel, which is inherently transient and highly dependent on numerous parameters. The simulated object was a Jominy end-quenched specimen geometry using two commercial steels, AISI 4130 and AISI 4140, with the goal of transferring a verified methodology to the heat treatment process for industrial heavy-section products (bars, slabs). The simulation employs thermal, mechanical, and …

Innovative Strategies For Stabilizing Zinc Anodes: From Molecular Design To Practical Zinc-Ion Batteries, Nhat Anh Thi Thieu

Graduate Theses, Dissertations, and Problem Reports (ETD)

Aqueous zinc-ion batteries (AZIBs) have become increasingly attractive as grid-scale energy storage solutions due to their safety, low cost, and environmental friendliness. However, the anode-electrolyte interface in AZIBs is prone to instability due to severe dendrite growth, self-corrosion, parasitic water-induced side reactions, and hydrogen evolution reactions (HER), which collectively lead to poor cyclability. To date, various interfacial engineering strategies have been investigated to address these challenges and improve the stability of Zn metal anodes. This dissertation presents a unified strategy for regulating Zn deposition through synergistic electrode and electrolyte design in laboratory-scale coin cells and then applies these concepts to …

Compression Forming Of Basic Oxygen Furnace Slag-Gypsum Blocks: Performance Enhancement And Environmental Assessment, Fengyi Zhang

Student Works (2020-2029)

The construction industry plays a crucial role in global development but faces significant environmental challenges, particularly CO2 emissions from cement production. Gypsum blocks provide a sustainable alternative to traditional cement concrete blocks. However, the low mechanical strength and water resistance of gypsum materials limit the widespread adoption of gypsum-based materials in the construction industry. This study initially produced gypsum-based blocks using compression forming, adding supplementary cementitious materials (SCMs), and subjecting accelerated carbonation curing (ACC). It was found that compression forming addressed the shortcomings of traditional block manufacturing (high energy consumption and long production time), and the addition of SCMs generated …

Shaking Table Test And Numerical Simulation Of Seismic Response Characteristics Of Rock Slope With Muddy Interlayer, Duan Chenggang, Fang Yanlin, Tian Yeqing, Zhou Zhijun

Journal of China & Foreign Highway

In order to study the seismic macroscopic failure process and dynamic response characteristics of rock slope with muddy interlayer and reveal the influence of muddy interlayer on slope stability,a similar slope model with concave and convex slope types was designed,and shaking table test was carried out;finite element analysis was used for numerical modeling analysis,and the results obtained by the two models were compared.The results show that:① The macroscopic deformation and failure process of the model slope is divided into three stages.Muddy interlayer dislocates,and cracks occur;mud interlayer slips,and cracks expand;slope collapses;② The seismic load has a decisive influence on the stability …

Effect Of Lithium Slag Dosage On Strength And Dry Shrinkage Properties Of Cement Stabilized Recycled Macadam, Zhao Ziyu, Gan Xianyong

Journal of China & Foreign Highway

To improve the mechanical properties and dry shrinkage properties of cement stabilized bases formed by cold in-place recycling of cement concrete pavements,lithium slag was mixed into the recycled mixture in mass ratios of 0%,6%,9%,and 12%.The effects of lithium slag dosage on the mechanical,dry shrinkage,and water stability properties of the recycled base were analyzed through the unconfined compressive strength,splitting,dry shrinkage,and water stability tests,and the mechanism underlying the improving effect of lithium slag on the cement stabilized base formed by cold in-place recycling of the cement concrete pavement was analyzed by X-ray diffraction (XRD ) and scanning electron microscopy (SEM ).The results …