Materials Science and Engineering Commons^™

Structure-Property Relations Of Binary Ferrite Melts, C. J. Benmore, C. Shi, O. L.G. Alderman, J. P. Harvey, D. Lipke, J. K.R. Weber

Materials Science and Engineering Faculty Research & Creative Works

Molten ferrite systems are used in the smelting and refining processes in steelmaking, to reduce the loss of metals in slags and to accelerate reaction rates. Here, high-energy x-ray diffraction experiments have been performed on aerodynamically levitated molten spheres of 43BaO-57FeOX and 43SrO-57FeOX at 1873 K using laser beam heating. The composition was varied within the range of x = 1-1.5 by changing the oxygen partial pressure of the levitation gas. The corresponding x-ray pair distribution functions have been interpreted using empirical potential structure refinement (EPSR) modeling. In oxygen-rich melts (x = 1.5), our EPSR models indicate very similar structures …

Metal Nitrides As Cathode Hosts For Lithium-Sulfur Batteries, Hai-Ji Xiong, Cheng-Wei Zhu, Ding-Rong Deng, Qi-Hui Wu

Journal of Electrochemistry

Lithium-sulfur batteries are considered as one of the potential solutions as integrating renewable energy systems for large-scale energy storage because of their high theoretical energy density (2600 Wh·kg^–1) and specific capacity (1675 mAh·g^–1). Currently, various strategies have been proposed to overcome the technical barriers, e.g., “shuttle effect”, capacity decay and volumetric change, which impede the successful commercialization of lithium-sulfur batteries. This paper reviews the applications of metal nitrides as the cathode hosts for high-performance lithium-sulfur batteries, summarizes the design strategies of different host materials, and discusses the relationship between the properties of metal nitrides and their …

Sno2 Particles Embedded Into Carbon Coated Mesoporous SioX Rod As High Volumetric Capacity Anode For Lithium-Ion Batteries, Jia-Lin Guo, Ni-Ni Li, Peng Zheng

Journal of Electrochemistry

Due to the high capacity and moderate volume expansion of silicon protoxide SiO_x (160%) compared with that of Si (300%), reducing silicon dioxide SiO₂ into SiO_x while maintaining its special nano-morphology makes it attractive as an anode of Li-ion batteries. Herein, through a one-pot facile high-temperature annealing route, using SBA15 as the silicon source, and embedding tin dioxide SnO₂ particles into carbon coated SiO_x, the mesoporous SiO_x-SnO₂@C rod composite was prepared and tested as the anode material. The results revealed that the SnO₂ particles were distributed uniformly in the …

Enhancing Cycle Life Of Graphite ‖ Lifepo4 Batteries Via Copper Substituted Li2Ni1-XCuXO2 Cathode Prelithiation Additive, Jian-Ming Zheng, Jing-Wen Zhang, Tian-Peng Jiao

Journal of Electrochemistry

Lithium nickel oxide (Li₂NiO₂), as a sacrificial cathode prelithiation additive, has been used to compensate for the lithium loss for improving the lifespan of lithium-ion batteries (LIBs). However, high-cost Li₂NiO₂ suffers from inferior delithiation kinetics during the first cycle. Herein, we investigate the effects of the cost-effective Cu substitution of Li₂Ni_1-xCu_xO₂ (x = 0, 0.2, 0.3, 0.5, 0.7) synthesized by high-temperature solid-phase method on the structure, morphology, electrochemical performance of graphite‖LiFePO₄ battery. The X-ray Diffraction (XRD) refinement result demonstrates that Cu substitution strategy is favorable …

Fatigue Behaviour Of Al 6063 Alloy In Heat Treated, Deep Cryogenic Treated And Equal Channel Angular Pressing (Ecap) Processed Conditions, Sreearravind M

Theses and Dissertations

This research focuses on improving the Low Cycle Fatigue (LCF) life of Al6063 using three different processing techniques – Heat Treatment (HT), Deep Cryogenic Treatment (DCT), and Equal Channel Angular Pressing (ECAP). Al 6063, widely used in structural applications, has limited fatigue performance, necessitating the exploration of advanced processing techniques to enhance its LCF life.

In HT phase, Al 6063 T5 samples were subjected to solid solution HT followed by air and water quenching. The air-quenched (T6A) and water-quenched (T6W) samples were subjected to precipitation hardening. The Ultimate Tensile Strength (UTS) of the T6A sample increased to 188 MPa from …

In-Situ Thermal Measurement Of Polymers, Carson Powers, Jungkyu Park, Dal Hyung Kim, Fahim Dorsey, Peter Bearden

Symposium of Student Scholars

In this research, we conducted a detailed experimental

investigation into how strain affects the thermal conductivity of

Ecoflex elastomer, utilizing a newly developed method for

measuring thermal conductivity under mechanical strain for the

first time. In situ thermal conductivity measurement apparatus

was developed by combining the KLA T150 nanoscale tensile tester

and a custom-fabricated thermal measurement sensor. The

development of an experimental method for measuring the thermal

conductivity of nanomaterials under mechanical testing

simultaneously will contribute to the development of novel

materials for flexible electronics by helping us to better

understand the strain effect on their thermal performance.

Interestingly, the …

A Comparative Mathematical Analysis Of Ice Modulation Measurement Techniques: Unifying Thermal Hysteresis, Freezing Point Depression, And Colligative Effects, Hayden Calvert Barry

Engineering Undergraduate Senior Theses

Thermal hysteresis (TH) measurement techniques for ice binding proteins (IBPs) have historically lacked standardization, making cross-study comparisons challenging and potentially impeding development of these materials for practical applications. This study provides a comprehensive comparison of three measurement techniques: differential scanning calorimetry (DSC), microlitre osmometry, and cryostage microscopy. Through systematic experimentation with Wild Type III Antifreeze Protein (AFP) at varying concentrations (10μM, 100μM, 1mM), along with cell lysate AFP and Pseudomonas syringe ice nucleating protein (INP), mathematical relationships were established between measurement techniques, and cryostage microscopy was identified as the most reproducible and reliable method. Regression analysis revealed strong relationships between …

Mechanism Of Mud Pumping On Plateau Highway Under Traffic Loads And Its Treatment Strategy, Zhang Junhui, Chen Zhide, Gao Feng, Na Qicai, Ma Pengfei, Xiao Lin

Journal of China & Foreign Highway

The dynamic hydraulic response and particle migration of subgrade structures under traffic loads are fundamental to reveal the formation and development mechanisms of mud pumping.The driving mechanism of fine particle migration in the mud pumping state was explored by conducting laboratory tests on layered gravel-sandy silt columns under dynamic loads.The results show that the slurry sloshing causes alternating positive and negative pressure gradients within the gravel layer.This oscillating pressure gradient enhances the pore permeability in the underlying sandy silt layer,providing the necessary hydrodynamic conditions for fine particle migration.Fine particle migration increases the slurry turbidity to a stable value.Upon the removal …

Risk Zoning Of Hazards Along Highways To Xizang Based On Information Model, Liu Weimin, Guo Guanmiao, Cai Qing ’E, Yu Xueyong, Dong Xiaobo, Chen Peicong

Journal of China & Foreign Highway

The frequent occurrence of hazards along the highways in the Qinghai ‒ Xizang Plateau seriously affects road traffic and threatens the security of lives and property of the people.Conducting a risk zoning assessment of hazards along the highways to Xizang is crucial to enhancing hazard prevention and mitigation.This paper summarized the regional geological environment and development patterns of hazards along the highways to Xizang and analyzed the overall performance of highway traffic operations.On this basis,the Xinjiang‒Xizang Highway was taken as the research object,and the evaluation factors were selected based on the regional geological environment and the main controlling factors of …

Seismic Performance Of Bridge Pile Foundation Considering Effects Of Material Freeze-Thaw Deterioration And Permafrost Degradation, Zhang Xiyin, Yu Shengsheng, Wang Wanping, Wen Hairong

Journal of China & Foreign Highway

In cold and high-seismic regions,such as the Qinghai‒Xizang Plateau in China,the deterioration of material properties caused by freeze-thaw cycles and permafrost degradation due to climate change have become increasingly severe,posing significant challenges for the seismic performance assessment of bridge pile foundations.To systematically investigate the impact of permafrost degradation and material freeze-thaw deterioration on the seismic performance of bridge pile foundations and ensure proper seismic design,a finite element model was established,considering the dual effects of permafrost degradation and material freeze-thaw deterioration.A comparative analysis was conducted to evaluate the influence mechanisms of various factors on the seismic performance of bridge pile foundations …

Cracking Characteristics Of Cement-Stabilized Macadam With Early Strength Agent Under Variable Temperature And Humidity Curing Conditions, Ge Dongdong, Liu Dingyuan, Lyu Songtao, Jiang Xiangyang, Xue Yanhua, Yu Yang

Journal of China & Foreign Highway

In environments with large temperature variations and low humidity,the curing conditions of cement-stabilized macadam fail to meet the specifications,leading to slow early strength development and increased susceptibility to cracking.This study aimed to investigate the effects of actual environmental temperature,humidity,curing age,and addition of early strength agents on the cracking characteristics of cement-stabilized macadam.Variable temperature conditions were determined based on actual environmental temperature data.Four curing conditions were set by combining temperatures (variable temperature and standard temperature ) with relative humidity of 95%,80%,and 65%,respectively.Three types of specimens were prepared with 0%,10%,and 15% early strength agent contents and cured for 14 and 28 days,respectively.The …

Identification And Prediction Model For Traffic Blockage State Of Highways To Xizang, Wu Ling, Liu Jianbei, Zhang Zhiwei, Shan Donghui, Chi Gandu

Journal of China & Foreign Highway

To identify the traffic blockage state on highways to Xizang in extreme environments,comprehensive evaluation indicators for traffic blockage state based on the entropy-weighted TOPSIS method were proposed by using the traffic blockage event parameters observed on four major highways to Xizang:Sichuan ‒ Xizang Highway,Yunnan ‒ Xizang Highway,Qinghai ‒ Xizang Highway,and Xinjiang ‒ Xizang Highway.The K-Medoids clustering algorithm was used to categorize the traffic blockage state into different levels.By considering factors such as hazard types,road types,traffic volume,and vehicle type ratios,a classification model for the traffic blockage state on highways to Xizang was constructed based on machine learning algorithms.The results show that …

Influence Of Urease-Induced Calcium Carbonate Precipitation On Frost Heave Characteristics Of Saline Soil, Li Jue, Wen Zili, Liu Zhengnan

Journal of China & Foreign Highway

This study investigated the impact of the soybean urease-induced calcium carbonate precipitation (SICP ) technique on frost heave characteristics of saline soil,specifically addressing the frost heave in saline soil used as a subgrade.The relationships between compaction degree,moisture content,volume ratio of the reaction liquid,and curing temperature with the frost heave rate of treated soil were explored.The results show that SICP significantly reduces the frost heave rate of soil samples by over 28%,with the most noticeable improvement occurring under conditions of higher compaction degree and lower moisture content.Additionally,the increased volume ratio of reaction liquid enhances reaction efficiency,while lower curing temperatures are crucial …

Prediction And Evaluation Of Road Service Performance In Cold Regions Based On Uncertainty Quantification Theory, Liu Yuanyuan, Si Junling, Zheng Hao, Ren Daoju, Fan Shaobing, Quan Lei

Journal of China & Foreign Highway

In cold regions,road service performance is influenced by various nonlinear dynamic factors under complex hydrothermal environments and freeze-thaw cycles.Traditional empirical and mechanical models exhibit significant limitations in comprehensively considering the impacts of complex environments and conducting quantitative analyses.This study proposed a method to predict and assess the service performance of constructed roads in cold regions.The method integrated deep neural networks with uncertainty quantification theory,addressing the inadequacies of existing models in adapting to complex environments and analyzing multiple influencing factors.By utilizing data from Montana road sections in the LTPP database,the study employed deep neural networks to predict the international roughness index …

Permanent Deformation Prediction Model Of Subgrade Soil Under Freeze-Thaw Cycles Based On Lstm And Transformer, Zhang Anshun

Journal of China & Foreign Highway

To accurately predict the permanent deformation of subgrade soil under the coupling effect of freeze-thaw cycles and traffic loads,a hybrid neural network model based on long short-term memory (LSTM ) and Transformer was proposed,building upon the results of dynamic triaxial tests.This model effectively captured the temporal dependencies and complex interactive effects among input variables,thereby significantly enhancing the accuracy and generalization ability of permanent deformation prediction of subgrade soil.The results indicate that higher confining pressure improves the resistance of subgrade soil to deformation,but its permanent deformation behavior is still significantly influenced by the magnitude of cyclic loading and the number of …

Analysis Of Joint Load Transfer Performanc E Of Prefabricated Steel‑Concrete Hollow Pavement Slab, Zhu Guangshan, Dong Zihao, Yang Ye, Wang Jinshan

Journal of China & Foreign Highway

In order to study the joint load transfer capacity of a prefabricated steel-concrete hollow pavement slab,a finite element model was established with ABAQUS to carry out numerical analysis.The variation laws of the maximum deflection value and joint load transfer coefficient of the pavement slab with and without cavitation were compared to analyze the load transfer capacity.The results show that when cavitation occurs in the slab,the load transfer coefficient of the slab decreases with the increase in the cavitation area,but the load transfer coefficient of the slab does not change significantly when the cavitation depth reaches a certain level.When there is …

Preparation And Performance Of Emulsified Asphalt With High-Temperature Resistant And Wheel Sticking-Free Effects, Yan Han, Zha Xudong, Kang Xiaogang, Gong Yan, Zhang Zhengji, Zhang Wenshuai

Journal of China & Foreign Highway

To address the problem of wheel sticking at high temperatures in the construction process of existing wheel sticking-free emulsified asphalt of tack coat,this paper adopted the composite modification method of 70# and 15# matrix asphalt and waterborne polyurethane resin (WPR ) to prepare hard asphalt-WPR (HA-WPR )-modified emulsified asphalt in accordance with the high-temperature resistant and wheel sticking-free requirements.Through a series of laboratory tests,the technical performance,wheel sticking-free performance,and interlayer bonding performance of the emulsified asphalt were researched and compared with ordinary wheel sticking-free emulsified asphalt and ordinary emulsified asphalt tack coat oil.The results show that the technical performance of the …

A Review Of Performance Of Cement- Stabilized Base Materials Containing Recycled Conc Rete Aggregate, Song Chengzhe, Li Jiaquan, Kong Jingxun, Zhou Changjun, An Xing

Journal of China & Foreign Highway

Semi-rigid base offers excellent performan ce and is widely used as a high-grade highway subgrade in China.Currently,with a large stockpile of waste concrete in the country,using it as aggregate in pavement base materials is of great significance for environmental protection,energy conservation,and emission reduction.In this paper,the basic performance indicators of recycled concrete aggregate (RCA ) and the performance of cement-stabilized base materials containing RCA,including strength,shrinkage,fatigue,and erosion resistance were reviewed.It finds that the basic performance indicators of RCA are lower than those of natural aggregate.Therefore,the proportion of RCA in base materials may be limited to 20% ‒ 50%.The shrinkage and erosion resistance …

Research Progress Of Modified Asphalt With Graphene Materials, Zhang Zongwei, He Kai

Journal of China & Foreign Highway

To clarify the research status of mo dified asphalt properties with graphene materials,relevant research literature in China and abroad was consulted to compare the effects of various graphene materials and preparation parameters on asphalt.The results show that graphene,nano graphite sheets,and oxidized graphene can improve the microstructure and road performance of asphalt,increase the service life of asphalt,and reduce the maintenance cost of asphalt.Continuously optimizing the preparation parameters of modified asphalt and exploring the mechanism of modified asphalt with new material not only help the promotion and application of new road asphalt technologies but also reduce energy consumption,pollutants,and carbon emissions,providing new ideas …

Model Analysis Of Axial Compressive Mechanical Properties Of Concrete Column Constrained By Textile-Reinforced Engineered Cementitious Composites, Ma Gao, Wang Zhaoyang

Journal of China & Foreign Highway

In order to avoid the problem of matrix cracking in textile-reinforced concrete (TRC ),a reinforcement method of textile-reinforced engineered cementitious composites (ECC ),namely TRECC composed of textile and high-performance ECC was proposed.However,the research on the axial compressive mechanical properties of TRECC-constrained concrete in China and abroad is still insufficient,and there is a lack of reliable strength and ultimate strain analysis models.A total of 116 axial compression test results of TRC-constrained concrete columns and 125 axial compression test results of TRECC-constrained concrete columns were collected.The confinement mechanisms and failure modes of TRECC and TRC-constrained concrete were compared.Then,the strength models and ultimate …