Materials Science and Engineering Commons^™

Synthesis And Electrochemical Performance Of Si/C Composite Modified By Pani, Guang-Hui Zhang, Pei-Kang Shen, Ge Sang, Ren-Jin Xiong

Journal of Electrochemistry

Silicon/carbon (Si/C) composite materials were prepared through high-energy ball milling and high-temperature solid-phase method, and then coated with thin polyaniline (PAni) film by oxidation. The microstructure and component of the composites were characterized by SEM, XRD, IR, TG, and the electrochemical performance was investigated by cyclic voltammetry (CV) and galvanostatic charge-discharge tests. The results showed that the surface of PAni/Si/G/C composite was coating with complete lamellar structure of PAni film. Its reversible capacity was 784 mAh·g^-1 and 690 mAh·g^-1 could be maintained after 50th charge-discharge cycles.

Electrochemical Activities Of Oxygen-Doped Carbon Surface For V(Iv)/V(V) Redox Couple, Huan Zhang, Lin-Lin Qin, Yi-Ning Shi, Ming-Sen Zheng, Quan-Feng Dong, Zhao-Wu Tian

Journal of Electrochemistry

Graphite plate electrodes were treated with oxygen plasma and doped with oxygen as well as oxygen functional groups. With the treatment, the activities of graphite plate electrodes toward VO²⁺/VO₂⁺ redox reactions were improved. FT-IR and EDS analysis results indicated that oxygen functional groups were introduced to the surface of graphite plates after oxygen plasma treatment. In this paper, the graphite plate treated for 20 min showed the highest activity. The average charge efficiency reached 91%, suggesting an increase of 19%, compared with that of the untreated graphite plate under a current density of 8 mA·cm^{-2 …}

Solar Cell Design Using Metamaterials, Yang Liu, Yitung Chen, Jichun Li

College of Engineering: Graduate Celebration Programs

Natural structure with simultaneous negative permittivity and permeability has not been discovered yet. However, using specially-designed metal embedded in dielectric bodies can achieve a kind of artificial negative index. This periodic structure which is smaller than the guided wavelength is known as a metamaterial. However, recent designs of metamaterials have some disadvantages when they are used in the application of solar cell. The perfect absorption is only within a narrow band, and for most of the solar spectrum, the absorption is no more than 10%. Here, a new kind of absorber for the solar spectrum has been designed and analyzed, …

Analysis Of Bolted Joints Under Medium And High Impact Loading, Deepak Sankar Somasundaram, Mohamed Trabia, Brendan J. O'Toole

College of Engineering: Graduate Celebration Programs

• Develop test fixture for medium impact study on bolted joints
• Create FEA model that can replicate the experiment
• Develop test fixture for high impact loading
• Create FEA model and select material properties that can produce results that
  closely match experiments.
• Compare different modeling techniques for high impact loading

Vulnerability Of Progressive Collapse In Reinforced Concrete Flat-Plate Buildings, Jinrong Liu

College of Engineering: Graduate Celebration Programs

• Progressive collapse is the spread of initial local failure, causing partial or
  even total collapse of a building.
• Flat plate structure is widely used for office and residential buildings.
• There is a large inventory of older flat plate building without continuous slab bottom reinforcement through columns.
• Limited knowledge exists regarding the risk of disproportionate collapse in
  older flat-plates under sudden column removal during abnormal events.
• Reliable mechanical model is needed for structural evaluation.

Applied Analysis Of Ionic Polymer Metal-Composite Actuators, Siul Ruiz, Benjamin Mead, Woosoon Yim

College of Engineering: Graduate Celebration Programs

• IPMC is a type of smart material called an electroactive polymer
• Consists of an ionic polymer such as Nafion or Flemion and a conducive metal such as platinum or gold
• COMSOL multi-physics simulations accurately model the experimental displacement results
• Optimization performed using the multi-physics model to find the maximum deflection, force, and twisting
• Using the closed loop control system accurate IPMC tip location can be achieved
• This control system has been extended to function using a computer mouse as an input

Hydraulic And Thermal Performances Of A High Temperature Ceramic Plate-Fin Heat Exchanger (Pfhe), Vijaisri Nagarajan, Yitung Chen, Qiuwang Wang, Ting Ma

College of Engineering: Graduate Celebration Programs

• Numerical analysis was carried for novel configuration of high temperature PFHE
• Fluid flow and heat transfer properties were studied for various fin configurations
• Ripsaw fin design with thickness of 0.05 mm gives maximum heat transfer with less pressure drop and friction factor
• Validation and parametric study were carried out for all fin configurations

Plastic Deformation Of Astm A36 Steel Using Two-Stage Light Gas Gun, Shawoon Kumar Roy

College of Engineering: Graduate Celebration Programs

To characterize material deformation in high velocity impact. To validate material models for computation simulation purposes.

This ongoing research is an attempt to study the plastic deformation of A36 steel plate (0.5” thick) under hypervelocity impact. Plastic deformation of the target plate was simulated using finite element software LS-DYNA.

Magnetic And Crystal Structures Of Sr2Iro4: A Neutron Diffraction Study, Feng Ye, Songxue Chi, Bryan C. Chakoumakos, Jaime A. Fernandez-Baca, Tongfei Qi, Gang Cao

Center for Advanced Materials Faculty Publications

We report a single-crystal neutron diffraction study of the layered Sr₂IrO₄. This work unambiguously determines the magnetic structure of the system and reveals that the spin orientation rigidly tracks the staggered rotation of the IrO₆ octahedra in Sr₂IrO₄. The long-range antiferromagnetic order has a canted spin configuration with an ordered moment of 0.208(3) μ_B/Ir site within the basal plane; a detailed examination of the spin canting yields 0.202(3) and 0.049(2) μ_B/site for the a axis and the b axis, respectively. It is intriguing that forbidden nuclear reflections …

Reversible Mn Segregation At The Polar Surface Of Lithium Tetraborate, Christina L. Dugan, Robert L. Hengehold, Stephen R. Mchale, Juan A. Colon Santana, John W. Mcclory, Volodymyr T. Adamiv, Yaroslav V. Burak, Ya B. Losovyj, Peter A. Dowben

Faculty Publications

We find Mn surface segregation for single crystals of Mn doped Li₂B₄O₇, nominally Li_1.95Mn_0.05B₄O₇(001), but as the temperature increases, evidence of this Mn surface segregation diminishes significantly. At room temperature, the surface photovoltaic charging is significant for this pyroelectric material but is quenched at a temperature well below that seen for the undoped Li₂B₄O₇ samples. The suppression of surface charging in the region of 120 °C that accompanies the temperature of Mn dissolution in the bulk of Li₂B_{4 …}

Managing Moisture - The Key To Healthy Internal Wall Insulation Retrofits Of Solid Walls, Joseph Little, Benat Arregi

Conference papers

This study investigates the appropriateness of internally insulating solid walls to the Passivhaus standard. A number of variables are assessed using numerical hygrothermal simulation (under EN 15026) to check (1) associated risk of mould growth on original substrate and (2) if they result in a greater likelihood of timber decay at built-in joist ends. While air and vapour control layers (AVCLs) perform well regarding mould risk in low absorption walls, the results question their appropriateness where joist ends are built-in: when AVCLs are used, moisture levels at joist ends can potentially rise above critical thresholds, even in low absorption walls. …

Predicting Creep In An Alloy 617 Pressure Vessel Using Uniaxial Bar Test Data, Justin Allen, Allyssa Bateman, Yudhishthir Bhetwal, Theodora Caldwell, Joseph Croteau, Elias Lindau

College of Engineering Poster Presentations

Alloy 617 is being investigated as a candidate for application in next generation nuclear plants (NGNPs), including the very high temperature reactor (VHTR). Creep deformation concerns the lifetime and failure of heat exchangers used at the very high operating temperatures and pressures of such plants. In order to meet the American Society of Mechanical Engineers’ Boiler and Pressure Vessel code (ASME B&PV), and be certified for use in NGNPs, a thorough understanding of creep must be demonstrated. Current methods of testing creep have limitations and there remains uncertainty and controversy as to the applicability of these tests to more complex …

Use Of Global Electrochemical Techniques To Characterize Localized Corrosion Behavior On Aluminum Alloys, Joe Croteau, Kerry N. Allahar, Darryl P. Butt, Michael F. Hurley

College of Engineering Poster Presentations

Precipitated intermetallic phases strengthen aluminum aircraft alloys; these inclusions also establish localized electrochemical environments, significantly influencing the bulk corrosion behavior of such alloys. To gain insight on the effects of intermetallic phases on the bulk corrosion behavior, two established forms of electrochemical characterization techniques were used, polarization scans and impedance spectroscopy. This effort was undertaken to:

• Provide a statistical body of electrochemical data for aluminum alloys,
• Provide fundamental electrochemical parameters to aide in a continuum scale modeling effort,
• Validate the effect of solution chemistry on bulk corrosion behavior,
• Determine the influence of precipitated intermetallic phases on the bulk corrosion behavior, …

Anisotropic Compositional Expansion And Chemical Potential For Amorphous Lithiated Silicon Under Stress Tensor, Valery I. Levitas, Hamed Attariani

Mechanical and Materials Engineering Faculty Publications

Si is a promising anode material for Li-ion batteries, since it absorbs large amounts of Li. However, insertion of Li leads to 334% of volumetric expansion, huge stresses, and fracture; it can be suppressed by utilizing nanoscale anode structures. Continuum approaches to stress relaxation in Li_xSi, based on plasticity theory, are unrealistic, because the yield strength of Li_xSi is much higher than the generated stresses. Here, we suggest that stress relaxation is due to anisotropic (tensorial) compositional straining that occurs during insertion-extraction at any deviatoric stresses. Developed theory describes known experimental and atomistic simulation …

Sci-Tech Book News Reviews, Susan Fingerman

Sci-Tech News

No abstract provided.

Analysis Of Hole Lifetime In Soi Mosfet Single-Photon Detector, Dedy Septono Catur Putranto, Wei Du, Hiroaki Satoh, Atsushi Ono, Purnomo Sidi Priambodo, Djoko Hartanto, Hiroshi Inokawa

Makara Journal of Technology

Hole lifetime in the silicon-on-insulator (SOI) metal-oxide-semiconductor field-effect transistor (MOSFET) singlephoton detector was evaluated by the analysis of drain current histograms for different light intensities and substrate voltages. It was found that the peaks in the histogram corresponding to the larger number of stored holes grew as the gate bias decreased. This was attributed not to the increased light absorption efficiency or collection efficiency of the photo-generated holes, but to the prolonged hole lifetime presumably caused by the higher transverse electric field inside the body of SOI MOSFET.

Compositional And Structural Analysis Of Nitrogen Incorporated And Ion Implanted Diamond Thin Films, Elias James Garratt

Dissertations

Significant progress in area of nano-structured thin film systems has taken place in recent decades. In particular, diamond thin film systems are being widely studied for their wear resistant, optical and electronic properties. Of the various methods researchers use to modify the structure of such films, three techniques in particular are of interest due to their versatility: modification of the growth atmosphere, growth on metalized substrates, providing an interfacial layer, and modification through post-growth ion implantation. The aim of this study is to investigate the effects each has to the structure and composition of elements. Different techniques are applied in …

Biodiesel Reactor Design With Glycerol Separation To Increase Biodiesel Production Yield, Budy Rahmat, Imas Siti Setiasih, Roni Kastaman

Makara Journal of Technology

The study consisted of reactor design used for transesterification process, effect of glycerol separation on transesterification reaction, determination of biodiesel quality, and mass balance analysis. The reactor was designed by integrating circulated pump/stirrer, static mixer, and sprayer that intensify the reaction in the outer tank reactor. The objective was to reduce the use of methanol in excess and to shorten the processing time. The results showed that the reactor that applied the glycerol separation was able to compensate for the decreased use of the reactant methanol from 6:1 to 5:1 molar ratio, and changed the mass balance in the product, …

Development Of Seebeck-Coefficient Measurement Systems Using Kelvin-Probe Force Microscopy, Kazutoshi Miwa, Faiz Salleh, Hiroya Ikeda

Makara Journal of Technology

Thermoelectric device is investigated by a number of researchers in order to enhance the thermoelectric efficiency. It is known that the efficiency can be improved by quantum effect. However, it is difficult to measure the thermoelectric characteristics of nanometer-scale structures. Thus a new measurement method is expected to be developed. We propose to apply Kelvin-probe force microscopy (KFM) to characterization of thermoelectric materials. KFM can locally observe surface potential of Fermi energy of a sample without touching the sample surface. In the present paper, we estimate the Seebeck coefficient of thin Si-on-insulator layers using KFM.

Recognition System Of Indonesia Sign Language Based On Sensor And Artificial Neural Network, Endang Supriyati, Mohammad Iqbal

Makara Journal of Technology

Sign language as a kind of gestures is one of the most natural ways of communication for most people in deaf community. The aim of the sign language recognition is to provide a translation for sign gestures into meaningful text or speech so that communication between deaf and hearing society can easily be made. In this research, the Indonesian sign language recognition system based on flex sensors and an accelerometer is developed. This recognition system uses a sensory glove to capture data. The sensor data that are processed into feature vector are the 5-fingers bending and the palm acceleration when …