Preparation Of Pt/Dna-Mwcnts/Gc Electrode And Its Electrocatalytic Activity Toward H2O2 Reduction,
2014
College of Chemistry and Pharmaceutical Sciences, Guangxi Normal University, Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), Guilin 541004, Guangxi, China;
Preparation Of Pt/Dna-Mwcnts/Gc Electrode And Its Electrocatalytic Activity Toward H2O2 Reduction, Li-Li Fan, Li-Na Wu, Zhi-Yu Qu, Dan-Feng Liu, Jun-Ming Zhang, Si-Ming Fan, You-Jun Fan
Journal of Electrochemistry
The DNA-multi-walled carbon nanotubes (MWCNTs)/glassy carbon (GC) electrode was prepared by modifying the DNA functionalized MWCNTs composite on a GC electrode. A novel non-enzymatic H2O2 sensing electrode was fabricated by electrodepositing Pt nanoparticles on the DNA-MWCNTs/GC electrode. The modified electrodes were characterized by scanning electron microscope (SEM). The response properties of the sensing electrode to H2O2 were investigated by cyclic voltammetry and chronoamperometry. The results indicated that the sensing electrode exhibited a good linear relationship between response current and H2O2 concentration in the range of 0.04 ~ 18.07 mmol·L-1 with …
On The Origin Of The Errors Of IK As Estimated From K-L Equation In Rotating Disk Electrode System,
2014
University of Science and Technology of China
On The Origin Of The Errors Of IK As Estimated From K-L Equation In Rotating Disk Electrode System, Wei Chen, Ling-Wen Liao, Zheng-Da He, Yan-Xia Chen
Journal of Electrochemistry
Rotating disk electrode system is mainly used to study the kinetics of reactions whose reactants have very low solubility in the electrolyte. For an irreversible reaction, Koutecky-Levich equation (K-L Eq.) is frequently used to deduce the kinetic current ik). Since K-L Eq. is derived based on the assumption that a system should conform the steady-state diffusion conditions, the data recoded from the actual system which deviates from such a condition, great error may be induced for the ik estimated. In this work, polarization curves for oxygen reduction reaction at polycrystalline Pt electrode recorded in solutions with various …
Electrochemical And Spectroscopic Studies Of Ethanol Oxidation On Nano-Cubic Pt Modified By Tin Adatoms,
2014
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Electrochemical And Spectroscopic Studies Of Ethanol Oxidation On Nano-Cubic Pt Modified By Tin Adatoms, Lu Rao, Bin-Wei Zhang, Yan-Yan Li, Yan-Xia Jiang, Shi-Gang Sun
Journal of Electrochemistry
The nano-cubic Pt modified by tin (Sn) was synthesized and used to investigate the role of this adatom played in the ethanol oxidation. The onset potential of ethanol oxidation was significantly shifted negatively which can be forward about 300 mV when the coverage of Sn (θSn)was 0.9. The electrtochemical in situ FTIR result demonstrated that the amount of CO2 increased first, and then decreased with θSn increased, and reached the maximun when θSn was 0.38. Furthermore, the formation of acetic acid could be observed at very low potential (-0.05 V) after modifying Sn adatom, and the amount of acetic …
Effect Of Plasticizer On Oxygen Permeability Of Cast Polylactic Acid (Pla) Films Determined Using Dynamic Accumulation Method,
2014
Bogor Agricultural University
Effect Of Plasticizer On Oxygen Permeability Of Cast Polylactic Acid (Pla) Films Determined Using Dynamic Accumulation Method, Kurniawan Yuniarto, Bruce A. Welt, Aris Purwanto, Hadi Karia Purwadaria, Ayman Abdellatief, Titi C. Sunarti, Setyo Purwanto
Journal of Applied Packaging Research
Polylactic acid (PLA) is becoming an increasingly important biopolymer for packaging applications. PLA brittleness limits its applicability. This study evaluated PLA properties with increasing amounts of added polyethylene glycol (PEG) plasticizer. Oxygen transmission rate (OTR) of cast films was determined using the newly available Dynamic Accumulation (DA) method. Arrhenius temperature sensitivity of OTR and polymer Permeability was also determined. Permeability of neat PLA is 4.848 ml mm (STP)/m2 s kPa; hence, 4.84 ml mm (STP)/m2 s kPa, 4.07 ml mm (STP)/m2 s kPa and 5.42 ml mm (STP)/m2 s kPa by adding PEG 1 %, 5% …
Polycrystalline Iii-Nitrides,
2014
Air Force Institute of Technology
Polycrystalline Iii-Nitrides, Michael J. Callahan, Buguo Wang, John S. Bailey
AFIT Patents
This invention provides a process for producing high-purity dense polycrystalline III-nitride slabs. A vessel which contains a group III-metal such as gallium or an alloy of group III-metals of shallow depth is placed in a reactor. The group III-metal or alloy is heated until a molten state is reached after which a halide-containing source mixed with a carrier gas and a nitrogen-containing source is flowed through the reactor vessel. An initial porous crust of III-nitride forms on the surface of the molten III-metal or alloy which reacts with the nitrogen-containing source and the halide-containing source. The flow rate of the …
Cnt-Reinforced Polymer Nanocomposite By Molecular Dynamics Simulations,
2014
Purdue University
Cnt-Reinforced Polymer Nanocomposite By Molecular Dynamics Simulations, Yaeji Kim
Open Access Dissertations
Polymer matrix composites reinforced with carbon nanotubes (CNTs) have received significant attention due to their potential for exceptional mechanical, electrical, thermal and optical properties. The enhancement of ultimate mechanical properties of CNT reinforced polymer composites is governed not just by the properties of the two phases but by dispersion of the CNTs, interactions in the interfacial region and local molecular changes in polymer due to the vicinity of the CNTs. Strong adhesive interactions between the matrix and CNT leads to good compatibility preventing the aggregation of the reinforcements and results in optimal mechanical response. Even though significant efforts have been …
Digital Image Correlation Of Heterogeneous Deformations In Polycrystalline Material With Electron Backscatter Diffraction,
2014
Purdue University
Digital Image Correlation Of Heterogeneous Deformations In Polycrystalline Material With Electron Backscatter Diffraction, Javier Esquivel
Open Access Theses
This work establishes the ability to conduct digital image correlation (DIC) investigations at varying length scales. DIC allows for a computational method of strain field measurements using multiple images to track random speckle patterns on material surfaces. The use of a powder silicon oxide speckle allows for high optical magnification correlation using conventional load frames. Self-assembling gold nanoparticles provide sub-micron resolution speckle patterns to study microstructure influences on deformation using scanning electron microscopy. The complex microstructure in aerospace grade aluminum and nickel-based superalloys, give rise to varied deformation fields, which can be studied using electron backscatter diffraction. Specimen preparation techniques, …
Mode I Fatigue Delamination Onset Of Carbon Fibre Reinforced Polymer With Novel Post-Cure Throughthickness Reinforcement,
2014
Purdue University
Mode I Fatigue Delamination Onset Of Carbon Fibre Reinforced Polymer With Novel Post-Cure Throughthickness Reinforcement, Christopher John Kourloufas
Open Access Theses
A novel trough thickness reinforcement (TTR) technique, proposed by Kravchenko et al., has been tested under mode I fatigue loading conditions in order to investigate characterisation of the onset of delamination growth in unidirectional 8552/IM7. The experimental results, following standard test method ASTM D6115-13, indicate that the mode I fatigue delamination onset behaviour can be altered by the inclusion of TTR both ahead and behind the crack tip. Tests have been conducted at a wide range of maximum displacement values, corresponding to percentages of the critical fracture toughness value determined for the maternal, GIC . The results were found …
Using A Centrifuge For Quality Control Of Pre-Wetted Lightweight Aggregate In Internally Cured Concrete,
2014
Purdue University
Using A Centrifuge For Quality Control Of Pre-Wetted Lightweight Aggregate In Internally Cured Concrete, Albert E. Miller
Open Access Theses
Early age shrinkage of cementitious systems can result in an increased potential for cracking which can lead to a reduction in service life. Early age shrinkage cracking can be particularly problematic for high strength concretes, which are often specified due to their high strength and low permeability. However, these high strength concretes frequently exhibit a reduction in the internal relative humidity (RH) due to the hydration reaction (chemical shrinkage) and self-desiccation which results in a bulk shrinkage, termed autogenous shrinkage, which is substantial at early ages. Due to the low permeability of these concretes, standard external curing is not always …
High-Purity Gallium Analysis By Inductively Coupled Plasma Mass Spectrometry,
2014
Purdue University
High-Purity Gallium Analysis By Inductively Coupled Plasma Mass Spectrometry, Kyungjean Min
Open Access Theses
The mobility of Two-dimensional Electron Gas in AlGaAs/GaAs heterostructures that are grown in the Molecular Beam Epitaxy (MBE) can be increased by purification of the gallium used to grow the films. To attain 200 million cm2/Vs mobility, the impurity concentration of gallium should be reduced to below 1 ppb. The commercial 7N (99.99999%) gallium with 100 ppb total impurity is currently used in the MBE at Purdue University and is being purified by zone refining. To evaluate the commercial 7N gallium and establish the methodology for the impurity measurement after zone refining, germanium, iron, and zinc in 6N and 7N …
Measurement Of The Responses Of Polyurethane And Confortm Foams And The Development Of A System Identification Technique To Estimate Polyurethane Foam Parameters From Experimental Impulse Responses,
2014
Purdue University
Measurement Of The Responses Of Polyurethane And Confortm Foams And The Development Of A System Identification Technique To Estimate Polyurethane Foam Parameters From Experimental Impulse Responses, Vaidyanadan Sundaram
Open Access Theses
Flexible polyurethane foam is the main cushioning element used in car seats. Optimization of an occupied seat's static and dynamic behavior requires models of foam that are accurate over a wide range of excitation and pre-compression conditions. Experiments were conducted to measure the response of foam over a wide range of excitation which include slowly varying uniaxial compression tests on a 3 inch cube foam sample, base excitation and impulse excitation test on a foam-mass system. The foam used was the same in all of the experiments, thus obtaining all the responses on the same foam sample which helps eliminate …
Dissolution Rate And Mechanism Of Metals In Molten Aluminum Alloy A380,
2014
Purdue University
Dissolution Rate And Mechanism Of Metals In Molten Aluminum Alloy A380, Hengyu Zhu
Open Access Theses
Shot sleeve is a very easily worn out part in a high-pressure die-casting machine due to serious dissolution of the area underneath the pouring hole. It is because during a normal pouring process, the high temperature molten aluminum will impact and dissolve that area of the shot sleeve by complex chemical and physical process. Rotation experiment was carried out to H13 and four kinds of refractory metal samples. SEM and EDS pictures were taken in order to investigate the microstructure and the dissolution mechanism of these materials. This suggests a high strength niobium is an ideal material for that area …
Solid Oxide Fuel Cell Electrolytes Produced Via Very Low Pressure Suspension Plasma Spray And Electrophoretic Deposition,
2014
Purdue University
Solid Oxide Fuel Cell Electrolytes Produced Via Very Low Pressure Suspension Plasma Spray And Electrophoretic Deposition, James D Fleetwood
Open Access Dissertations
Solid oxide fuel cells (SOFCs) are a promising element of comprehensive energy policies due to their direct mechanism for converting the oxidization of fuel, such as hydrogen, into electrical energy. Both very low pressure plasma spray and electrophoretic deposition allow working with high melting temperature SOFC suspension based feedstock on complex surfaces, such as in non-planar SOFC designs. Dense, thin electrolytes of ideal composition for SOFCs can be fabricated with each of these processes, while compositional control is achieved with dissolved dopant compounds that are incorporated into the coating during deposition. In the work reported, sub-micron 8 mole % Y …
Ultrasound Assisted Low-Temperature Synthesis Of Tib2 And Al3ti Particulates In Molten Aluminum,
2014
Purdue University
Ultrasound Assisted Low-Temperature Synthesis Of Tib2 And Al3ti Particulates In Molten Aluminum, Zhiwei Liu
Open Access Dissertations
In situ formed TiB2 and Al3Ti are two typical representatives of ceramic and intermetallic reinforcements in the in situ particulate reinforced Al composites. TiB2 particulates can be synthesized in molten Al via the mixed-salts reaction by adding mixed K2TiF6 and KBF4 salts into the Al melt at high temperatures. Al3 Ti particulates can be produced by the direct-melt reaction between solid Ti powders and liquid Al at high temperatures. Generally, a high reaction temperature is always needed to obtain both reinforcements. Some issues, however, such as high cost and burning loss …
The Role Of Microstructure On The Combustion And Impact Behavior Of Mechanically Activated Nickel/Aluminum Reactive Composites,
2014
Purdue University
The Role Of Microstructure On The Combustion And Impact Behavior Of Mechanically Activated Nickel/Aluminum Reactive Composites, Benjamin Aaron Mason
Open Access Dissertations
Metal-based reactive composites are a class of materials that consist of at least one metals, such as Ni/Al, that have high-energy densities and can produce significant energy output during exothermic reaction after thermal or mechanical initiation. However, conventionally these materials typically have slow reaction rates and are difficult to ignite at typical micron particle size ranges limiting their application. Therefore, mechanical activation techniques have been used to create materials with high surface areas and smaller characteristic dimensions in order to increase combustion velocity and ignition sensitivity. Their combustion and mechanical impact behavior is being studied to develop the understanding needed …
Control Of Morphology Al-Fe-Si Phase In Al-Si-Cu Hypoeutectic Alloy,
2014
Purdue University
Control Of Morphology Al-Fe-Si Phase In Al-Si-Cu Hypoeutectic Alloy, Meng Wang
Open Access Dissertations
Aluminum-Silicon (Al-Si) alloys are one of the most versatile aluminum alloys. Iron is considered one of the most harmful elements in Al-Si diecasting alloy because its presence leads to the precipitation of many AlFeSi intermetallic phases and unacceptable mechanical properties, such as reduction in ductility. Thus controlling the fraction and morphology of AlFeSi phase, especially the β-AlFeSi phase is an important way to improve the ductility of Al-Si die casting alloys. ^ In this dissertation, thermodynamics calculation of AlFeSi phase formation and fraction change during solidification process were conducted using Thermo-Calc software. A series of experiments, including adjusting cooling rates, …
Nano-Modification For High Performance Cement Composites With Cellulose Nanocrystals And Carbon Nanotubes,
2014
Purdue University, United States
Nano-Modification For High Performance Cement Composites With Cellulose Nanocrystals And Carbon Nanotubes, Yizheng Cao
Open Access Dissertations
One of the new engineering frontiers is the exploration of infrastructure materials with novel combinations of properties that break traditional paradigms. The goal of this study is to utilize two different nano-fibers, cellulose nanocrystals (CNCs) and carbon nanotubes (CNTs) to modify the nanoscale structures of cement composites and thereby improve the performance at the macro-level. This study also evaluates the mechanism behind the modification, since fiber bridging, the most common reinforcing mechanism for fiber-reinforced composites, cannot be simply applied because CNCs are too short to bridge cracks in cement composites. ^ The mechanical tests show an increase in the flexural …
Effects Of Energetic Irradiation On Materials And Devices Based On Graphene And Topological Insulators,
2014
Purdue University
Effects Of Energetic Irradiation On Materials And Devices Based On Graphene And Topological Insulators, Isaac Childres
Open Access Dissertations
This report focuses on the optical and electronic properties of graphene and topological insulators and how these Dirac fermion systems interact with energetic irradiation. We first present data exploring the effects of electron-beam and oxygen plasma induced disorder on the electronic properties and Raman spectra of graphene. These initial investigations were important for relating Raman peak intensities and weak localization features to each other and to an average disorder length in graphene, LD. ^ We then integrate gate-effect measurements into the Raman spectroscopy study to fully explore the relationships between carrier density, disorder and Raman spectrum signatures. We …
A Regression Approach For Estimation Of Anthropogenic Heat Flux Based On A Bottom-Up Air Pollutant Emission Database,
2014
Kongju National University
A Regression Approach For Estimation Of Anthropogenic Heat Flux Based On A Bottom-Up Air Pollutant Emission Database, Sanghyun Lee, Stuart A. Mckeen, David J. Sailor
Mechanical and Materials Engineering Faculty Publications and Presentations
A statistical regression method is presented for estimating hourly anthropogenic heat flux (AHF) using an anthropogenic pollutant emission inventory for use in mesoscale meteorological and air-quality modeling. Based on bottom-up AHF estimated from detailed energy consumption data and anthropogenic pollutant emissions of carbon monoxide (CO) and nitrogen oxides (NOx) in the US National Emission Inventory year 2005 (NEI-2005), a robust regression relation between the AHF and the pollutant emissions is obtained for Houston. This relation is a combination of two power functions (Y = aXb) relating CO and NOx emissions to AHF, giving a determinant …
Investigation Of Microstructural Alterations In M50 And 52100 Steel Using Nanoindentation,
2014
Purdue University
Investigation Of Microstructural Alterations In M50 And 52100 Steel Using Nanoindentation, Kristin R. Paulson
Open Access Theses
Bearing steels are used in rolling elements and are designed to withstand heavy loads for an extended period of time. At the end of life, microstructural alterations within the material have been observed and are linked to failure. In this study, a three ball-on-rod fatigue tester was used to test M50 and 52100 steel cylindrical rods at differing loads of 4.0 GPa, 4.5 GPa, and 5.0 GPa and in lubricated and unlubricated conditions to 10 8 cycles in an attempt to produce microstructural alterations. Microstructural alterations characterized as butterflies were observed and investigated further in two M50 samples that were …
