Analysis Of Tool Wear And Tool Life Of Cutting Tool Inserts Using Statistical Process Control Charts: A Case Study,
2017
Morehead State University
Analysis Of Tool Wear And Tool Life Of Cutting Tool Inserts Using Statistical Process Control Charts: A Case Study, Evan R. Ferrell
Morehead State Theses and Dissertations
A thesis presented to the faculty of the College of Business and Technology at Morehead State University in partial fulfillment of the requirements for the Degree of Master of Science by Evan R. Ferrell on April 28, 2017.
Recent Progress In Template-Assisted Synthesis Of Nitrogen-Doped Porous Carbons For Oxygen Electroreduction,
2017
New Energy Research Institute, School of Environment and Energy, South China University of Technology, Guangzhou Higher Education Mega Centre, Guangzhou 510006, China.;
Recent Progress In Template-Assisted Synthesis Of Nitrogen-Doped Porous Carbons For Oxygen Electroreduction, Wenhan Niu, Ligui Li, Shaowei Chen
Journal of Electrochemistry
Nitrogen (N)-doped porous carbons are potential alternatives to precious metal catalysts for oxygen reduction reaction (ORR) at the cathodes of proton exchange membrane fuel cells and metal-air batteries. Template-assisted synthesis has been used extensively as a robust and versatile method in the preparation of such carbon catalysts, where the ORR activity has been found to be dependent on various structural parameters, such as the concentrations and molecular configurations of the dopants, and the porosity, surface accessibility and electrical conductivity of the carbon materials. In this review, we summarize recent progress in this area of research focusing on the design, preparation …
Impact Of Nafion Loading And Anion Adsorption On The Synthesis Of Pt Monolayer Core-Shell Catalysts,
2017
Ballard Power Systems, 9000 Glenlyon Parkway, Burnaby, BC, V5J 5J8 Canada;Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, British Columbia, V6T 1Z3, Canada;
Impact Of Nafion Loading And Anion Adsorption On The Synthesis Of Pt Monolayer Core-Shell Catalysts, Lijun Yang, Dustin Banham, Elod Gyenge, Siyu Ye
Journal of Electrochemistry
Carbon supported palladium (Pd) nanoparticles were used as a model core material for the synthesis of platinum (Pt) monolayer core-shell catalysts using rotating disk electrode method and a copper (Cu) under potential deposition technique. The impact of Nafion on the synthesis process was revealed by electrochemical testing with various Nafion contents. The existence of Nafion influenced the Cu under potential deposition, galvanic replacement and eventually the oxygen reduction reaction activity of the core-shell catalyst. However, as long as the Nafion content was less than 5 wt% in the test film, adding Nafion could help to bind catalyst onto the surface …
Designing Pt-Skin Of Pt-Based Bimetallic Electrocatalysts For Oxygen Reduction Reaction,
2017
Institute for Superconducting and Electronic Materials, Australian Institute of Innovative Materials, University of Wollongong, Innovation Campus, Squires Way, North Wollongong, New South Wales 2500, Australia.;
Designing Pt-Skin Of Pt-Based Bimetallic Electrocatalysts For Oxygen Reduction Reaction, Binwei Zhang, Yunxiao Wang, Yanfei Xu, Huakun Liu, Shixue Dou
Journal of Electrochemistry
In the past decade, great advancement has been made in the development of nanocatalysts for energy conversion and storage. Pt-skin of Pt-based bimetallic has shown a great potential in the tuning the electronic structures of electrocatalytically active materials toward oxygen reduction reaction. Here, we offer a brief overview of the recent research on the design and preparation of catalysts. Our focus is paid on the systematic studies of preparation and performance of Pt-skin catalysts towards oxygen reduction reaction.
Comparative Studies Of Fe, Ni, Co And Their Bimetallic Nanoparticles For Electrochemical Water Oxidation,
2017
Department of Chemistry, Lakehead University, 955 Oliver Road, Thunder Bay, Ontario P7B 5E1, Canada;
Comparative Studies Of Fe, Ni, Co And Their Bimetallic Nanoparticles For Electrochemical Water Oxidation, Maduraiveeran Govindhan, Brennan Mao, Aicheng Chen
Journal of Electrochemistry
The design of efficient, durable, and earth-abundant electrocatalysts via environmentally compatible strategies for the oxygen evolution reaction (OER) is a vital for energy conversion processes. Herein we report a facile approach for the fabrication of low-cost and earth abundant metal catalysts, including iron (Fe), nickel (Ni), cobalt (Co), CoNi, and CoFe nanoparticles (NPs) on titanium (Ti) substrates through a one-step electrochemical deposition. Field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) spectrocopy, X-ray photoelectron spectroscopy (XPS), and electrochemical techniques were employed to characterize these nanoparticles. Our electrochemical results revealed that among the five synthesized nanomaterials, the …
Comparison Of Oxygen Reduction Reaction Activity Of Pt-Alloy Nanocubes,
2017
Department of Chemistry and Biochemistry, Miami University, Oxford, OH 45056, USA;Department of Chemistry, Oakland University, Rochester, MI 48039, USA;
Comparison Of Oxygen Reduction Reaction Activity Of Pt-Alloy Nanocubes, Yongan Tang, Lin Dai, Shouzhong Zou
Journal of Electrochemistry
Alloying Pt with the first row non-noble transition metals has been demonstrated to increase the catalytic activity toward oxygen reduction reaction (ORR), which is the cathode reaction of the proton exchange membrane fuel cells (PEMFCs) and metal-air batteries. However, how much the ORR activity improvement comes from the alloying elements remains controversial. In this paper, the nanocubes of PtMn, PtFe, PtCo, and PtNi with the similar size and composition were prepared and their ORR activities were explored, in order to investigate the effects of alloying elements on the catalytic activity. The use of cubic shape particles minimizes the contribution to …
Novel Composites Between Nano-Structured Nickel Sulfides And Three-Dimensional Graphene For High Performance Supercapacitors,
2017
College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China;
Novel Composites Between Nano-Structured Nickel Sulfides And Three-Dimensional Graphene For High Performance Supercapacitors, Xiaomin Wang, Huanglin Dou, Zhen Tian, Jiujun Zhang
Journal of Electrochemistry
In this paper, a three-dimensional graphene (3DG) network grown on nickel foam was employed as a template for synthesizing graphene-based composite materials of supercapacitor electrode. The composites (crystal Ni3S2 nanorods on the surface of 3DG (abbreviated as Ni3S2/3DG)) were obtained through a one-step hydrothermal reaction. The morphological and structural evolution of the Ni3S2/3DG composites were investigated by SEM, TEM, XRD and Raman spectroscopy. Detailed electrochemical characterization showed that the Ni3S2/3DG-coated electrodes exhibited both a specific capacitance as high as 1825 F·g-1 at 5 mV·s …
Electrodeposition Of Ruo2 Layers On Tio2 Nanotube Array Toward Co2 Electroreduction,
2017
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, Fudan University, Shanghai 200433, China;
Electrodeposition Of Ruo2 Layers On Tio2 Nanotube Array Toward Co2 Electroreduction, Bei Jiang, Lina Zhang, Xianxian Qin, Wenbin Cai
Journal of Electrochemistry
RuO2/TiO2 composite materials have multitude of electrocatalytic applications including but not limited to CO2 reduction reaction (CO2RR). RuO2/TiO2 electrodes were previously prepared by repetitive coating and thermal decomposition (TD) of a Ru(III) precursor solution on Ti substrate. In this work, electrochemical potential cycling is applied to deposit amorphous RuO2 (α-RuO2) layers onto TiO2 nanotube array (TNA) (RuO2CV/TNA) preformed on Ti foil. SEM, GIXRD, and voltammetry are applied to characterize the structures of the resulting RuO2CV/TNA. Ru loading on the RuO2 …
Effects Of Yttria Concentration And Microstructure On Electric Breakdown Of Yttria Stabilized Zirconia,
2017
Missouri University of Science and Technology
Effects Of Yttria Concentration And Microstructure On Electric Breakdown Of Yttria Stabilized Zirconia, Oratai Jongprateep, Vladimir Petrovsky, Fatih Dogan
Materials Science and Engineering Faculty Research & Creative Works
Ceramic materials have great potentials for capacitor application. However, low breakdown strength of the materials remains a key challenge for development of high-performance capacitors. In this study, yttria stabilized zirconia (YSZ) were fabricated and tested for breakdown strength. YSZ samples with 3, 8, and 10 mol% yttria were carefully processed to control grain size and porosity level. Experimental results revealed that breakdown strength as high as 2 MV/cm could be achieved. The breakdown strength was not significantly affected by porosity level, but it was by yttria concentration. Relationship among yttria concentration, residual porosity and breakdown strength is discussed in this …
Fabrication And Study Of The Structure And Magnetism Of Rare-Earth Free Nanoclusters,
2017
University of Nebraska-Lincoln
Fabrication And Study Of The Structure And Magnetism Of Rare-Earth Free Nanoclusters, Bhaskar Das
Department of Physics and Astronomy: Dissertations, Theses, and Student Research
No abstract provided.
Antiferromagnetism In The Van Der Waals Layered Spin-Lozenge Semiconductor Crte3,
2017
Oak Ridge National Laboratory
Antiferromagnetism In The Van Der Waals Layered Spin-Lozenge Semiconductor Crte3, Michael Mcguire, V. Ovidiu Garlea, Santosh Kc, Valentino Cooper, Jiaqiang Yan, Huibo Cao, Brian Sales
Faculty Publications
The crystallographic, magnetic, and transport properties of the van der Waals bonded, layered compound CrTe3 have been investigated on single-crystal and polycrystalline materials. The crystal structure contains layers made up of lozenge-shaped Cr4 tetramers. Electrical resistivity measurements show the crystals to be semiconducting, with a temperature dependence consistent with a band gap of 0.3 eV. The magnetic susceptibility exhibits a broad maximum near 300 K characteristic of low dimensional magnetic systems. Weak anomalies are observed in the susceptibility and heat capacity near 55 K, and single-crystal neutron diffraction reveals the onset of long-range antiferromagnetic order at this temperature. Strongly dispersive …
Interference Of Light In Multilayer Metasurfaces: Perfect Absorber And Antireflection Coating,
2017
University of South Florida
Interference Of Light In Multilayer Metasurfaces: Perfect Absorber And Antireflection Coating, Khagendra Prasad Bhattarai
USF Tampa Graduate Theses and Dissertations
We have studied several metamaterials structures with multiple layers by explaining them theoretically and verifying experimentally. The engineered structures we have designed work either as a perfect absorber or antireflection coating. The multilayer model as we call it Three Layer Model (TLM) has been developed, which gives the total reflection and transmission as a function of reflection and transmission of individual layers. By manipulating the amplitude and phase of the reflection and the transmission of the individual layers, we can get the required functionality of the optoelectronic devices. To get zero reflection in the both perfect absorber and the antireflection …
Effect Of Plasma Dynamics On Gallium Nitride Nanorod And Growth By Molecular Beam Epitaxy,
2017
University of Arkansas Little Rock
Effect Of Plasma Dynamics On Gallium Nitride Nanorod And Growth By Molecular Beam Epitaxy, Dever Paul Norman
Theses and Dissertations
GaN is a wide bandgap semiconductor known for its use in high-frequency switching electronics and laser diodes, its stability as a high-temperature transistor material, and a radiation resistance which makes it an ideal material for space applications. Additionally, the discovery of the bandgap tunability of nitride materials using GaN has led to successful development of adjustable wavelength LED devices. However, the success of devices far outpaces the understanding of their material growth, making advances difficult to build upon. Plasma- Assisted Molecular Beam Epitaxy (PA-MBE) is an ideal growth method for achieving very precise structures for detailed study. Although plasma itself …
Wall Panel Optimization For Refugee Shelters In Germany: An Ahp Study,
2017
Western Kentucky University
Wall Panel Optimization For Refugee Shelters In Germany: An Ahp Study, Zhu Jiadong
Masters Theses & Specialist Projects
The German government is experiencing difficulties housing and assimilating Syrian refugees in its borders. Erecting temporary shelters on location is one way to deal with the current crises. This thesis attempts to use Analytic Hierarchy Process (AHP) to determine the optimum combination of materials and construction methods to be used in the shelter’s walls in order to improve the living conditions of the refugees and to ensure that the cost is acceptable to the German government. This thesis compares six existing wall panel products from China, which have the lowest cost on the worldwide market. The R-value, strength, price, weight, …
Tracking Characteristics Of Tracer Particles For Piv Measurements In Supersonic Flows,
2017
School of Aeronautics and Astronautics
Tracking Characteristics Of Tracer Particles For Piv Measurements In Supersonic Flows, Fang Chen, Hong Liu, Zifeng Yang, Hui Hu
Mechanical and Materials Engineering Faculty Publications
The tracking characteristics of tracer particles for particle image velocimetry (PIV) measurements in supersonic flows were investigated. The experimental tests were conducted at Mach number 4 in Multi-Mach Wind Tunnel (MMWT) of Shanghai Jiao Tong University. The motion of tracer particles carried by the supersonic flow across shockwaves was theoretically modelled, and then their aerodynamic characteristics with compressibility and rarefaction effects were evaluated. According to the proposed selection criterion of tracer particles, the PIV measured results clearly identified that the shockwave amplitude is in good agreement with theory and Schlieren visualizations. For the tracer particles in nanoscales, their effective aerodynamic …
Adsorption Of Salicylhydroxamic Acid On Selected Rare Earth Oxides And Carbonates,
2017
Montana Tech
Adsorption Of Salicylhydroxamic Acid On Selected Rare Earth Oxides And Carbonates, Greer Galt
Graduate Theses & Non-Theses
Adsorption behavior of the anionic collector salicylhydroxamic acid (SHA) on a selected group of rare earth oxides (REOs) and carbonates (RECs) was studied via experimental methods and modelling software. Synthetic oxide and carbonate powders of the rare earth elements cerium (Ce), praseodymium (Pr), europium (Eu), and terbium (Tb) were tested for this research. Studies were conducted at different pH levels to analyze the kinetics of collector adsorption onto the oxide and carbonate surfaces in attempts to optimize recovery parameters for commercial flotation processes using SHA. In addition, thermodynamic software StabCal was implemented to compare theoretical adsorption behavior of collectors SHA …
Encapsulation Process Of Propolis Extract By Casein Micelle Improves Sunscreen Activity,
2017
Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok 16424, Indonesia
Encapsulation Process Of Propolis Extract By Casein Micelle Improves Sunscreen Activity, Muhamad Sahlan, Dara Dienayati, Darul Hamdi, Soraya Zahra, Heri Hermansyah, Malyn Chulasiri
Makara Journal of Technology
Propolis, a wax bee glue, have antioxidant activity and effective as broad spectrum UVB and UVA photoprotection sunscreens agent. To improve photoprotection activity in sunscreen cream, the propolis was encapsulated by casein micelle. The Indonesian propolis was extracted by ethanol and separated the wax by freeze precipitation. The extract was encapsulated by casein and reduced their size by ball mill homogenizer with the encapsulation efficiency about 80% and size of particles about 80 nm. The particles was applied in sunscreen cream, evaluate their stabillity and photoprotection activity Sun Protection Factor (SPF) spectrophotometer (Optometric 290s). The results shows that the selected …
Synthesis Of Libob Fine Powder To Increase Solubility,
2017
Research Center for Physics, Indonesian Institute of Sciences, Puspiptek Serpong, Tangerang Selatan 15314, Indonesia
Synthesis Of Libob Fine Powder To Increase Solubility, Etty Marti Wigayati, Titik Lestariningsih, Christin Rina Ratri, Ibrahim Purawiardi, Bambang Prihandoko
Makara Journal of Technology
Lithium bis (oxalate) borate or LiBOB compound has captured interest of researchers, because it is potentially viable to be used as electrolyte salt in lithium-ion battery system. This compound is easy to synthesize and considered to be more environmentally friendly compared to conventional electrolyte salt because LiBOB does not contain halogen element. This research focused on the synthesis of LiBOB fine powder, which main purpose is improving LiBOB salt solubility in liquid electrolyte solution. This will aid the ion transfer between electrodes which in turn will increase the electrolyte performance. Solid state reaction was employed in this experiment. Synthesis of …
The Impact Of A Dynamic Environment On Deposition And Cellular Response To Silver Nanoparticles,
2017
University of Dayton
The Impact Of A Dynamic Environment On Deposition And Cellular Response To Silver Nanoparticles, Robert F. Uhrig
Honors Theses
Silver nanoparticles (AgNPs) are utilized in many different applications, such as an antibacterial agents or as protective coating against ultraviolet light. However, these AgNPs are known to cause potentially harmful biological effects, including toxicity, induction of stress, and immune activation. In this study, the effects of AgNPs on a human lung cell model were examined within both a static and dynamic environment. Most NP-based research is carried out in static environments, but do not accurate reflect dynamic physiological conditions. Dynamic fluid movement was introduced to the cell culture through the use of a multi-channel peristaltic pump. To further characterize the …
Assessing Time-Dependent Density Functional Theory As A Computational Tool To Model Chromophores Intercalated Into Dna Scaffolds,
2017
Boise State University
Assessing Time-Dependent Density Functional Theory As A Computational Tool To Model Chromophores Intercalated Into Dna Scaffolds, Eric Nelson
McNair Scholars Research Journal
Understanding first-principles energy transport in organic molecules reveals novel energy harvesting systems, quantum computing, and solar power energy transportation and production. DiSC2(5), also named Cy5, exhibits bright fluorescence signals and has shown promising lossless exciton transport properties, as well as tunable energy absorption and emission when conjoined with DNA. This paper focuses on functional groups of organic molecules, specifically the chromophoric red dye DiSC2(5) and its interaction with H- and J-aggregates and with DNA. Density functional theory (DFT) and time dependent density functional theory (TD-DFT) are applied to investigate the chromophore Cy5 in vertically stacked (H-aggregates) …
