Materials Science and Engineering Commons^™

Investigation Of Through-Hole Copper Electroplating With Methyl Orange As A Special Leveler, Jia-Ying Xu, Shou-Xu Wang, Yuan-Zhang Su, Yong-Jie Du, Guo-Dong Qi, Wei He, Guo-Yun Zhou, Wei-Hua Zhang, Yao Tang, Yu-Yao Luo, Yuan-Ming Chen

Journal of Electrochemistry

Methyl Orange (MO) with two kinds of functional groups can act as both an accelerator and an inhibitor, which has been used as a special leveler to simplify the electroplating additive system in the through-hole (TH) copper electroplating experiments. In this work, the role of MO in TH electroplating is characterized by molecular dynamics simulations and quantum chemical calculations. It is suggested that MO can spontaneously flatten the copper surface and be well adsorbed on the cathode surface, which inhibit the copper electrodeposition on the cathode. Electrochemical behavior of MO was evaluated by galvanostatic measurements (GM) and cyclic voltammetry (CV) …

Electrochemical Deposition Of Copper Pillar Bumps With High Uniformity, Bai-Zhao Tan, Jian-Lun Liang, Zi-Liang Lai, Ji-Ye Luo

Journal of Electrochemistry

Electrochemical deposition of copper pillar bumps (CPBs) is one of the key technologies for the advanced packaging. In this study, the effects of the additive concentration, the electrolyte convection, the current density, and the electroplating system on the uniformity of the CPBs have been systematically investigated. The results showed that the profiles of the CPBs were mainly determined by the additive concentration, the bath convection and the current density, while the heights of the CPBs were mainly affected by the electroplating system. For the CPBs profiles, it was found that the low leveler concentration and high current density would generally …

Bbt Acoustic Alternative Top Bracing Cadd Data Set-Norev-2022jun28, Bill Hemphill

STEM Guitar Project’s BBT Acoustic Kit

This electronic document file set consists of an overview presentation (PDF-formatted) file and companion video (MP4) and CADD files (DWG & DXF) for laser cutting the ETSU-developed alternate top bracing designs and marking templates for the STEM Guitar Project’s BBT (OM-sized) standard acoustic guitar kit. The three (3) alternative BBT top bracing designs in this release are
(a) a one-piece base for the standard kit's (Martin-style) bracing,
(b) 277 Ladder-style bracing, and
(c) an X-braced fan-style bracing similar to traditional European or so-called 'classical' acoustic guitars.

The CADD data set for each of the three (3) top bracing designs includes …

Synthesis And Consolidation Of The Aluminosilicate Mineral Anorthite, Lauren E. Eccles

Pursuit - The Journal of Undergraduate Research at The University of Tennessee

Solid-state ceramic synthesis is a fabrication process involving high temperature reactions of solid component powders and is used to prepare materials with novel and advanced properties. Regarding synthetic mineral ceramics, the solid-state process makes it possible to design synthetic minerals with specific compositions and properties not commonly found in their natural, comparatively impure, counterparts. This study focuses on the synthesis of the feldspar anorthite, CaAl₂Si₂O₈, via solid-state procedures and the densification of the synthesized powders using the technique of uniaxial hot-pressing. Constituent powders of aluminum sesquioxide (Al₂O₃), silicon dioxide (SiO …

The Effects Of Curing Temperature On The Hydration Kinetics Of Plain And Fly Ash Pastes And Compressive Strength Of Corresponding Mortars With And Without Nano-Tio2 Addition., Dan Huang, Mirian Velay-Lizancos, Jan Olek

International Conference on Durability of Concrete Structures

Incorporation of fly ash in cementitious systems containing ordinary portland cement (OPC) increases their long-term strength and durability. However, replacement of cement by fly ash also reduces the heat of hydration of such systems and reduces early-age strength development. The reduced rate of strength development can increase the risk of durability problems, e.g. scaling, in cases when young concrete is exposed to low temperatures and deicing chemicals. This study investigated the potential of nano-titanium dioxide (nano-TiO₂) particles to modify the hydration kinetics of fly ash pastes and compressive strength development of corresponding mortars cured under low (4°C) and …

The Degradation Of Concrete Tunnel Wall Panels: A Case Study, Christian Paglia

International Conference on Durability of Concrete Structures

Concrete panels are often used along tunnel walls for technical and aesthetic purposes. Generally, the environment in contact with such materials is aggressive. Emission gases from the vehicles, sulphates, chlorides coming from the winter salt spreading, high temperature and humidity promote an acceleration of the deterioration phenomena. In this work 30 years old concrete panels placed along a 16 km long highway tunnel across the Alps were investigated with respect to their durability. The focus was given to the tunnel entrance zone. This region of the tunnel exhibited a critical environment with respect to the durability of the cementitious material …

Rheological Properties And Structural Build-Up Of 3d Printed Magnesium Potassium Phosphate Cement, Hui Zhi Zhao

International Conference on Durability of Concrete Structures

This paper focuses on the rheological properties of 3D printed magnesium potassium phosphate cements (MKPCs) with different magnesium-to-phosphate (M/P) mass ratio, MgO fineness and supplementary cementitious materials (SCMs) types. The variable shear rate tests were used to monitor the extrudability. The highest slope of the evolution of storage modulus (G') and the maximum static yield stress (M_τs) value were used as an indication of the rigidification rate. The increased M/P mass ratio, MgO fineness and SCMs addition resulted in the promoted structural build-up of 3D printed MKPCs. The consistency between the evolution of G' and M_τs with …

Mechanical Properties Of Engineering Cement-Based Materials Containing Modified Shape Memory Alloy Fiber, Song Mengfan

International Conference on Durability of Concrete Structures

在这项研究中，提出了一种 SMA 纤维的表面改性方法，以改善水泥基复合材料中纤维的界面性能。SMA 纤维涂有 SiO ₂，预计会与 Ca(OH) _2反应由水泥水化形成，减少了薄弱区的可能性，并在纤维-基体界面处形成了更致密的微观结构。采用扫描电子显微镜 (SEM)、能量色散光谱 (EDS) 和红外吸收光谱 (IR) 对表面改性后的 SMA 纤维进行表征。此外，还进行了抗弯强度试验、抗压强度试验和四点弯曲试验，以评价宏观尺度上界面力学性能的增强情况。实验结果表明，包覆的 SiO ₂，导致改性 SMA 纤维-水泥界面处的 CSH 凝胶量增加和孔隙率降低。改性后的SMA纤维与水泥基体之间的紧密粘附有利于建立更强的界面结合力，有利于提高抗弯强度、抗压强度、四点抗弯强度和挠度。抗弯强度、抗压强度、四点抗弯强度和挠度均在28d时显着增加。结果支持了所提出的表面改性方法适用于 SMA 纤维以提高其在工程水泥基材料中的增强效率的结论。

Super-Hydrophobic Hybrid Coatings Preparation Used By Methyltrithoxysilane (Mtes) And Tetraethylorthosilicate(Teos), Quanwei Li

International Conference on Durability of Concrete Structures

超疏水材料由于其优异的疏水自洁性能，在航空航天、海洋工程、除冰防腐等领域具有广阔的应用前景。本文采用简单的溶胶-凝胶制备超疏水涂层。 . 以甲基三乙氧基硅烷（MTES）和原硅酸四乙酯（TEOS）为前驱体，水解缩合后形成粗糙结构，1H,1H,2H,2H-全氟癸基三乙氧基硅烷（FAS）为低表面能的表面活性剂，系统研究了各自的最佳配比零件。涂层的疏水性和形貌分别通过水接触角测量、扫描电子显微镜（SEM）表征。同时，其官能团通过红外光谱表征。基于大量的实验和优化测试，

Corrosion Performance Of Embedded Steel Bar In Cl--Contaminated Limestone Calcined Clay Cement (Lc3) At Initial Stage Of Hydration, Weiwen Li, Zuhua Xu, Yaocheng Wang, Xin Wang, Feng Xing

International Conference on Durability of Concrete Structures

Limestone Calcined Clay Cement (LC3) presents brilliant properties in binding Cl^- so that the embedded steel bars are probably protected in Cl^--contaminated condition, which meets the need of sea sand application. However, the corrosion performance of steel bars embedded in LC3 paste with Cl^‑ is unclear, especially in early age hydration. Thus, a series of experiments were carried out to evaluate the corrosion performance of steel bars on initial and hardened stages of hydration, including concentration of OH^- and Cl^- in real pore solution, open circuit potential (OCP) and chemical elements of steel bars. …

Mechanical Properties And Microstructure Of High Strength Lc3 Pastes With Varying Limestone/Calcined Clay Ratios And Different Curing Conditions, Yemin Dong

International Conference on Durability of Concrete Structures

研究（抗施工蒸馏）石石和石榴石在淀粉胶系统（即0标准和低水印）下的水胶系统（即0标准和低水墨）X射线比、水量值水量-电子背基相关研究.61.25 .25.25.25.0.25.25.25.25.25.0.25.25.25.25.25.1.25.7.25.0.0.0.0.0.0.0.0.0.0.0.0.0.0.1.25.1.25.25.1.25.1.25.1.25.1.25.1.25.1 .25.1.25.1.25.1.25.1.25.1.25.0.0.0.0.0.0.0.00.0.0.1.25.1.25.1.25.1.25.1.25.0.0.0.00.0.0.0.0.0.0.0.0.0.0.0.0.0.00.0 .00.0.00.X射线比值、水量-电子显微镜相关研究测量值。早期的水泥水化程度小水的压合含煤量，降低了水泥石的。因此，需要采用合适的钙铝内容和体系以提高碳系统的性能。

Development And Properties Of Sulfate-Resistant And Corrosion-Inhibiting Admixtures, Tongwei Lu, Jie Zhang, Guisheng Cai, Linmao Wang, Xiangyang Guo

International Conference on Durability of Concrete Structures

Sulfate and chloride-induced corrosion of concrete and steel reinforcement are the most important causes of premature failure of durability of concrete structures. To prevent damage in concrete structures, the application of sulfate-resistant and corrosion-inhibiting admixtures has proven to be an effective method. In this study, a new type of corrosion-inhibiting admixtures including organic and special inorganic components are developed and the properties of mortar mixed with them was investigated. The results show that NC-CZ series of sulfate-resistant and corrosion-inhibiting admixtures have been successfully developed. The mortar with NC-CZ has good resistance to sulfate attack, whose corrosion resistance coefficient of mortar …

Study On The Effect Of Fly Ash On The Properties Of Potassium Magnesium Phosphate Cement, Bo Pang

International Conference on Durability of Concrete Structures

In this paper, the effect of fly ash on the setting time and mechanical properties of potassium magnesium phosphate cement is studied. The early hydration process of potassium magnesium phosphate cement was studied by TAM-Air, and the hydration products were analyzed by XRD. The results show that fly ash can effectively prolong the setting time and the compressive strength of the cement paste was decreased; The addition of fly ash would not change the phase composition of the hydration products of the potassium magnesium phosphate cement, which affect the hydration process, the amount of the hydration products and the degree …

Study On Hydration Properties Of Grinded Tuff-Cement Cementitious Material System, Hao Wang

International Conference on Durability of Concrete Structures

The chemical composition and microscopic morphology characteristics of grinded tuff(GT) and fly ash(FA) were compared and analyzed in the paper. The chemical bound water content and hydration heat were tested for investigating the hydration properties of grinded tuff-cement cementitious material system (GTCS) and fly ash-cement cementitious material system (FACS). The results shown that, the chemical composition of GT was similar with that of FA, however the loss on ignition of the GT was obviously higher than FA. The microstructure of the GT particles was polygonal and irregular, while the microstructure of FA particles were mostly smooth spheres. The hydrated heat …

Investigation On The Properties Of Calcium Sulfoaluminate Cement Waterproof Repair Mortar Modified With Ethylene-Vinyl Acetate Powder, Dong Dong

International Conference on Durability of Concrete Structures

本文采用乙烯-醋酸乙烯酯（EVA）粉体和CSA水泥制备了防水修复砂浆，并对其水化和性能进行了研究。结果表明，EVA粉体延长了凝固时间，提高了防水修补砂浆的流动性，使其在实际工程中更容易应用。EVA粉提高了防水修复砂浆的不渗透性，降低了吸水性。虽然EVA粉降低了防水修补砂浆的抗弯强度和抗压强度，但它仍然符合JC/T 2381-2016标准对刚性修复砂浆的要求。EVA粉体降低了防水修复砂浆的收缩率，改善了界面过渡区和拉伸粘接强度、弯曲粘接强度等粘接性能。EVA粉末抑制CSA水泥的水合作用6 h，在3 d水化年龄时抑制作用消失。

Shrinkage And Durability Of Cement Mortars With Recycled Aggregates, Wencui Yang

International Conference on Durability of Concrete Structures

In recent years, the rapid growth of economy and urbanization process in China resulted in the massive construction and demolition wastes (C&DW). The reutilization of C&DW as recycled aggregates (RA) fully or partially to replace natural aggregates is an effective way to solve the environmental and economic problems caused by C&DW. The properties of cement mortars could be influenced by recycled fine aggregates due to their high absorption and the quantity of fine particles. This paper presents the main results of the research to explore the effect of recycled aggregate (RA) on shrinkage and durability properties of masonry mortars. Four …

Investigation On Structural Heritability And Durability Of High Sulfate Resistance Portland Cement Mortar Modified By Aluminum Salt, Jun Xu

International Conference on Durability of Concrete Structures

The essential hydration and hardened properties of high sulfate resistance Portland cement paste/mortar were investigated with Al₂(SO₄)₃ as admixture. Experiment results showed that that the addition of Al₂(SO₄)₃ promoted the hydration of HSRP cement pastes, and the hydration rate accelerated with the increase of the addition amount. The mechanical properties and chloride diffusion coefficient of cement mortar were obviously improved with 0.25% Al₂(SO₄)₃ addition . For instance, the compressive strength of AS0.25 cement mortars was 24.8% higher than AS0 samples and the chloride ion migration …

Mechanical And Thermal Insulation Properties Of Clay-Based Lightweight Concrete, Chuang Shi, Chuanlin Hu

International Conference on Durability of Concrete Structures

建材生产和住宅采暖将消耗大量能源并排放大量CO_2。在混凝土制备中，使用陶土制备具有优异隔热性能的轻质混凝土，并使用煅烧粘土代替部分波特兰水泥，可以大大降低能耗。本研究采用页岩陶土和陶砂分别作为粗骨料和细骨料制备轻质混凝土。首先，确定最佳体积砂比。然后，使用煅烧粘土和石灰石的剂量从30%，50%到70%。研究了煅烧粘土和石灰石含量对混凝土微观结构、力学性能和隔热性能的影响。结果表明，最佳体积砂比为50%。当煅烧粘土和石灰石的用量为30%时，强度在所有年龄段最高，28 d时强度可达33.6 MPa，比对照组高12%。当更换水平不断增加时，所有年龄段的实力开始下降。所制备的粘土基轻质混凝土的导热系数低至0.144 W/mK，表现出优异的保温性能。本研究制备的轻质混凝土具有较高的强度和优异的保温性能，具有良好的应用前景。

Obtaining Wrapping Paper Used In Furniture Wrapping And Quality Delivery And Determining Its Quality Indicators, E A. Egamberdiyev, A R. Makhkamov, G R. Rakhmonberdiev

Technical science and innovation

Composite materials samples have been obtained from cellulose and bazalt fibers based on cellulose-containing plants. The properties of paper samples have been studied: the amound of cellulose, the amound of ash, water absorption and breaking load. Gained results show that the composite material with the addition of basalt fibers is more durable. Half-finished cellulose fibers obtained from basalt, straw and wastepaper are more prouse than ones obtained from cotton plant

Study Thermodynamics Of The Magnetite Sulfidation In Copper Smelting Processes, A S. Khasanov, Q T. Ochildiyev, B T. Berdiyarov, Sh T. Khojiev, S T. Matkarimov

Technical science and innovation

The article discusses the problem of reducing the amount of magnetite in the impregnation of copper in the slag generated after the conversion process in copper production in the furnace to reduce slag. Accordingly, a method of lowering magnetite by sulfidation has been proposed, using elemental sulfur as a local and relatively inexpensive sulfiding-reducing agent. The mechanism of chemical phenomena occurring in the interaction regions of magnetite and elemental sulfur has been developed. Based on the mechanism of chemical reactions produced, each chemical reaction that occurs in the process is analysed from a thermodynamic point of view. According to the …