Other Materials Science and Engineering Commons^™

A Sustainable Approach To Tensile Property Enhancement In Sand Casting Via Metal Chip–Sand Composite Molds, Maaruf Isyaku, Danjuma Saleh Yawas, Mathew Olatunde Afolayan, Terva Ause

Journal of Materials Exploration and Findings

The present work focuses on the study of the effect of adding different weight percentages and particle sizes of various metal chips to foundry sand on the tensile strength of aluminum alloy castings, utilizing Taguchi's optimization methodology and regression analysis. Characterization techniques such as X-ray fluorescence (XRF), thermogravimetry, and SEM were also used. The XRF analysis identified aluminum (76.61%), silicon (17.49%), and magnesium (1.28%) as the major elements in the aluminum alloy engine block. For the foundry sand, silicon (89.51%), phosphorus (7.41%), and potassium (1.7%) were found. In contrast, the major constituents in cast iron included iron (88.3%), carbon (3.7%), …

Self-Assembly Interactions In Magnetite-Coated Cellulose Nanocrystals: Implications For Magnetic Hyperthermia Applications, Mohammad J. Hasan, Erin L. Mcneill, Kishore Chand, Juganta Roy, Monishita Deb, Katherine Schlaak, Sydney Herzog, Yvonne Sun, Sarah Watzman, Esteban E. Ureña-Benavides, Erick S. Vasquez-Guardado

Chemical and Materials Engineering Faculty Publications

Magnetic cellulose nanocrystal (MCNC) nanocomposites are promising sustainable and biocompatible platforms for magnetic hyperthermia; however, the molecular mechanisms governing Fe3O4 adsorption and deposition onto CNCs remain poorly understood. Here, sulfated (S-CNC) and TEMPO-oxidized CNCs (T-CNC) were used to prepare nanocomposites at 1:2 and 1:4 CNC:Fe3O4 mass ratios, enabling a systematic evaluation of how surface chemistry and nanoparticle loading dictate interfacial interactions and magneto-colloidal behavior. Bare magnetite nanoparticles were 21 ± 5 nm by TEM but grew to 144 ± 18 in the DLS measurement at pH 7. The S-CNC nanocomposites had hydrodynamic sizes between 144 and 210 nm, not much …

Areosense, Josephine Turney

Williams Honors College, Honors Research Projects

The AeroSense growing system is designed to make indoor aeroponic gardening easy and accessible for everyone. By combining sensors, automation, and AI, the system can monitor and adjust humidity, lighting, and nutrient levels to help plants thrive without requiring expert knowledge. The goal is to create a self-regulating garden that takes the guesswork out of growing fresh herbs and vegetables at home. The project involves building a working aeroponic prototype equipped with misters, pumps, and environmental sensors, all managed by a Raspberry Pi. Using computer vision and machine learning, AeroSense will be able to assess plant health and respond automatically …

Data Set, R Scripts And Script Outputs For Manuscript: Manufacturing Systems: Characteristics And Dynamics, Alan J. Fitzmorris

Graduate Research Data

This file repository contains fifteen computer-generated datasets, two naturally occurring datasets, nineteen shipbuilding shop datasets, and sixty-one concrete plant datasets.  Each data set contains subdirectories associated with various aspects of the data analysis, including stationarity analysis, dynamic system analysis, and complexity analysis.  In each case, applicable R scripts are included.  The text file entitled “Directory_and_File_Names” depicts the directory structure and associated file names for a total of 225 directories encompassing 8008 files.

Field-Assisted Post-Processing Of Cold-Sprayed Pure Copper, Alan Hensley

Theses and Dissertations--Mechanical and Aerospace Engineering

The properties of materials processed through cold spray, and many other AM processes, are non-uniform and unpredictable. In most cases, post-processing is required to achieve desired properties and better uniformity. In cold spray, the typical method is an annealing heat treatment (AHT), which can improve bond strength, reduce porosity, and restore ductility, among other effects. AHT alone, however, is unable to completely remedy any of the unfavorable properties. In addition, long treatments at high temperatures are often needed for satisfactory results. This increases energy consumption and extends production times for products made by the process. For these reasons, numerous investigations …

Made On Mars: Design And Manufacturing Of Structural Polymer-Regolith Composites, Pailey M. Vitale

Williams Honors College, Honors Research Projects

Human exploration of Mars is constrained by harsh environmental conditions and the prohibitive cost of transporting materials from Earth. Long-term sustainability requires the local production of mechanical and structural components using resources available on Mars, thereby minimizing payload mass. This project investigates polymer–regolith composites derived from atmospheric CO₂ and mineral-rich regolith as a pathway toward in-situ manufacturing. These composites, when compatible with additive manufacturing, could replace imported plastics, enable on-demand fabrication, and support closed-loop recycling systems. The objective is to design and evaluate polymer–regolith composites that maintain mechanical integrity and environmental resistance under Martian conditions, including extreme temperature swings, radiation …

Design New Stage For Vacuum Pin On Disk, Miranda Boyd

Williams Honors College, Honors Research Projects

For my senior design project, I am redesigning the moving stage for the vacuum pin-on-disk test used in the Akron Engineering Tribology Lab. This system is used to evaluate bearings and lubricants for aerospace applications under controlled vacuum conditions. The current stage design limits flexibility when adjusting for different testing parameters, so my goal is to develop a new movable stage that allows for varying weights and loads to be applied accurately and safely. The redesigned stage will improve test efficiency, adaptability, and precision, ensuring the system can accommodate a wider range of experimental conditions and materials while maintaining compatibility …

Strain-Induced Nonvolatile Domain Switching And Tunable Elastic Modulus In Ba1-Xsrxtio3 Membrane By Phase-Field Simulation., Laveeza Ahmad

Material Science and Engineering Dissertations

Ferroelectrics underpin a broad spectrum of technological applications due to its switchable ferroelectric polarization and the associated electro-mechanical responses under electrical, optical, thermal, and mechanical stimuli. Recent advancement in membrane technology offers new opportunities to tune ferroelectric polarizations via mechanical strains at relatively large magnitude and scale. However, its influence on the tunability of mechanical responses of the membrane remains underexplored. Herein, we developed a phase-field model for free-standing Ba_1-xSr_xTiO₃ ferroelectric membranes with stress-free boundary conditions on top/bottom surfaces and achieved strain-induced nonvolatile ferroelectric domain switching in the membrane. It is discovered that a …

Engineering Disorder, Defects, And Electrical Transport For High-Performance Thermoelectric Fe2val Heusler Alloys, James Russell Taylor Iv

Dartmouth College Ph.D Dissertations

Fe₂VAl is a promising low-temperature thermoelectric material for waste-heat energy conversion because it is easily processed and comprised of earth-abundant, non-toxic, and low-cost elements. However, viability for applications faces two major challenges: high thermal conductivity and low p-type Seebeck coefficients. This primarily experimental work aims to address these issues through extrinsic and self-doping, point-defect and disorder generation through thermal and electrical processing, disordered and metastable phase composition quantification, and comparison of transport measurements to modeled electronic features.

An accessible phase quantification method was developed for bulk Fe₂VAl using laboratory X-ray diffraction equipment to compare thermoelectric properties …

Mechanical Behavior Of Additively Manufactured Ti-6al-4v Eli Parts: Effects Of Laser Parameter Selection, Samuel Lopez

UNF Graduate Theses and Dissertations

Additive manufacturing (AM) of TI-6AL‑4V Extra‑Low Interstitial (ELI) enables complex geometries for fatigue‑critical medical device applications, yet fatigue performance remains sensitive to process‑induced defects. This work investigates the effect of laser process parameter selection on the microstructure, mechanical properties, and fatigue behavior of TI- 6AL‑4V ELI fabricated via laser powder bed fusion (L‑PBF) using a Renishaw RenAM system. The influence of laser parameters was isolated by holding powder chemistry, build orientation, scan strategy, sub‑transus annealing, and post‑processing constant between a non‑optimized baseline and an optimized parameter set selected based on tensile performance.

Optical microscopy showed the optimized condition exhibited improved …

Investigating The Effects Of Pressure On Fe And Co Intercalated 2h-Tas2 Through First-Principle Calculations, Ronald E. Putnam Jr.

UNF Graduate Theses and Dissertations

Using first-principles methods, we investigate the effects of applied isotropic pressure on the electronic and magnetic properties of intercalated Fe1/3TaS2 and Co1/3TaS2. Fe1/3TaS2 has been shown to be a ferromagnet that undergoes structural and magnetic phase transitions under applied pressure. The magnetic phase transitions are observed to be linked to the structural shift, and a mixture of magnetic phase states is present between 3 GPa and 6 GPa. Co1/3TaS2 was found to be antiferromagnetic, as confirmed by experimental work. One- and two-unit-cell systems of Co1/3TaS2 are analyzed, both showing band splitting that disappears under pressure. The application of pressure forces …

Towards All-Epitaxial Josephson Junctions With High-Temperature Superconductors, Daniela Amalfi Ojeda

UNF Graduate Theses and Dissertations

Josephson junctions are fundamental components of superconducting electronics. Although junctions based on conventional superconductors are well established, reproducible devices based on high-temperature superconductors remain challenging. This work investigates the growth, fabrication, and electrical characterization of all-epitaxial DyBa₂Cu₃O₇₋ₓ (DBCO) /SrTiO₃ (STO) /DBCO trilayer heterostructures for potential Josephson junction applications. An initial optimization of YBa₂Cu₃O₇₋ₓ (YBCO) growth produced reproducible films with a zero-resistance critical temperature ( ) of K and a maximum  of 89 K. These growth conditions were adapted to DBCO, resulting in reproducible superconducting films with values of approximately 80 K. DBCO/STO/DBCO trilayers were grown by molecular beam epitaxy and …

Next-Generation Computing Hardware: Advancements In Tantalum Oxide Reram For Ai And Neuromorphic Applications, Rajas Ravindra Mathkari

Electronic Theses & Dissertations (2024 - present)

The rapid development of artificial intelligence, machine learning, and data-intensive computing has exposed the fundamental limitations of conventional von Neumann architectures, in which energy and time are continuously lost transferring data between physically separate memory and processing units. In contrast, the human brain performs complex computations directly at the point of memory storage through billions of parallel synaptic connections, a paradigm known as in-memory computing. Realizing this in hardware requires memory devices that are fast, energy-efficient, non-volatile, and capable of storing multiple resistance levels in an analog manner. Resistive Random Access Memory (ReRAM) based on tantalum oxide (TaOx) is one …

Effects Of Foam Type And Thickness On Impact Resistance, Thermal Insulation, And Cost-Effectiveness Of Medical Containers For Drone Delivery, Josh Henry C. Soriano, Eriel V. Fonte, Lambertsus S. Novera, Nicolai Paolo B. Villarin, Joel B. Jalon, Jr.

Sinaya: A Philippine Journal for Senior High School Teachers and Students

Accessible healthcare remains a challenge for rural communities lacking reliable infrastructure for medical supply delivery. Delivery drones have recently emerged as a viable alternative, dropping medical containers during flight. However, the effectiveness of different foam types and thicknesses combined with corrugated cardboard as shock-absorbing materials in a medical container for delivery drones has yet to be tested. Thus, this study designed cost-effective containers using corrugated cardboard and multiple foam types and thicknesses, aiming to preserve the integrity of the contents, withstand impact, and control temperatures. Four foam types—polystyrene, polyurethane, polyethylene, and expanded polystyrene (EPS) —were tested at 1 cm, 2 …

Effect Of Niobium Addition On Corrosion Behavior, Mechanical Properties, And Microstructures Of U6zr Alloys In An Aerated Environment, Masrukan Masrukan, Djati Handoko, Dede Djuhana, Rohmad Sigit, M. Husna Al Hasa, Wisnu Ari Adi, Siti Mardiah

Makara Journal of Science

The effect of Nb addition on the corrosion behavior of U–6Zr alloys within an aerated, demineralized water (DW) environment (pH 5.61) and its correlation of this addition with the mechanical and microstructural properties of the alloys were investigated. The U–6Zr–xNb alloys (x = 1, 4, and 7 wt.%) were synthesized by arc-melting U, Zr, and Nb. Additionally, the samples were mounted and polished, after which they were subjected to electrochemical corrosion analysis using a potentiostat. This evaluation was conducted in a DW medium (pH 5.6), representing an aerated atmosphere, at room temperature (27°C) and a potentiodynamic scan rate of 1 …

An Overview Of Biomass-Derived Graphene Oxide And Its Characteristics For Future Sustainable Applications, Afif Wardana, Ahmad Nabil Shahab, Donanta Dhaneswara, Nofrijon Sofyan

Journal of Materials Exploration and Findings

The production of graphene oxide (GO) from biomass presents considerable promise as a sustainable alternative substitute for traditional semiconductors. Biomass waste, abundant and often underutilized worldwide, is distinguished by its high carbon content and regenerative characteristics, rendering it an optimal resource for sustainable material production. By heating its biopolymers, lignocellulosic biomass can be used as a new material to make graphene, which forms three-dimensional turbostratic crystallites. These crystallites, composed of partially defective aromatic carbon sheets with graphite-like characteristics, make it easier to create GO with specialized functions for cutting-edge applications. Its capability underscores the revolutionary potential of biomass waste in …

Production Of Rare Earth Elements By Molten-Salt Electrolysis, Mohammed Moro

Graduate Theses & Non-Theses

Rare earth elements (REEs) are indispensable, high-value resources that play a crucial role in renewable energy, defense systems and advanced technological systems. REEs are commonly extracted from natural ores or recycled materials such as permanent magnets using hydrometallurgical or pyrometallurgical techniques. In hydrometallurgy, the REE source is leached with acid, followed by solvent extraction and precipitation steps to obtain rare earth compounds like oxides and fluorides. Pyrometallurgy involves dissolving rare earth compounds in a molten halide bath, followed by high-temperature electrolysis to convert them into metals, which are then recovered at the cathode. This process typically includes melting, refining, and …

In-Situ Investigations Of Calcium-Magnesium-Aluminosilicates (Cmas) Infiltration Effects On Thermal Barrier Coatings Under Extreme Environments Replicating Jet Engines, Zachary Stein

Doctoral Dissertations and Master's Theses

Calcium-magnesium-aluminosilicate (CMAS) particulates, such as sand or volcanic ash, are ingested by gas turbine jet engines during operation. When operating within high abundance regions, these particulates negatively interact and degrade the high temperature thermal barrier coatings (TBC) protecting underlying superalloy turbine blades vital to engine operation. These CMAS particulates melt within the engine and infiltrate into the ceramic coatings. In electron-beam physical vapor deposited (EB-PVD) TBCs, the CMAS within the intercolumnar gaps stiffens the coatings and causes thermomechanical induced high stress concentrations, risking crack formation. While molten, the CMAS thermochemically alters and destabilizes the coating, also risking coating failure. Premature, …

Integrating Dft And Machine Learning To Predict Structural Properties In High Entropy Alloys, Nathan Linton

All Dissertations

In the past decade, a paradigm shift in the design of metal alloys has been observed. These new alloys are commonly referred to as high entropy alloys (HEAs), multi-principal element alloys (MPEAs), or complex, concentrated alloys (CCAs). In contrast to conventional alloys, which consist of one main element (for example 80%) with other elements in small amounts, HEAs are made of four or more main elements ranging from 5 to 35% each element. Due to the large presence of multiple elements, HEAs have shown substantial material property improvements over conventional alloys such as steel. For example, they have high ductility …

Emerging Solid Electrolytes For Solid-State Sodium Batteries: Synthesis And Interface Study., Xiaolin Guo

Electronic Theses and Dissertations

Over the past decade, solid-state batteries have attracted significant attention as the next-generation energy storage technology due to their higher energy density and enhanced safety. Given the abundant sodium (Na) resources relative to lithium (Li), the development of sodium-based batteries has become increasingly compelling. Within a solid-state battery, the solid electrolytes (SEs) serve the dual function of (i) electronically insulating and physically separating the electrodes, and (ii) transporting ions between the anode and cathode. To meet these essential requirements, ideal SEs must process high ionic conductivity with negligible electronic conductivity, robust structural and chemical stability, a wide electrochemical window, and …