Engineering Science and Materials Commons^™

A Study Of The Frustrated Honeycomb Battery Material Na2ni2teo6, Nathan Christopher Episcopo

Open Access Theses & Dissertations

The P2-type layered hexagonal compound Na2Ni2TeO6 with Ni2+ on a honeycomb lattice was synthesized by the standard solid-state route. Structural characterization chemical phase purity was confirmed by Rietveld refinement of laboratory and synchrotron data. The crystal structure refines well in the P63/mcm space group. Single crystal growth trials using the self-flux-melt method were conducted with limited success. The magnetic transition temperature pertaining to Ni2+ lattice was confirmed by analysis of specific heat capacity to be . The magnetic susceptibility remains largely unchanged in magnetic field of and external pressure of . There is an almost linear response in isothermal magnetization …

New Generation Of Performance-Engineered Asphalt Mixtures Based On Balanced Mix Design Concept, Victor Manuel Garcia

Open Access Theses & Dissertations

Asphalt mixtures must ideally exhibit long-lasting durability and stability to perform wellin the field. However, improving the stability and durability of asphalt mixtures has become a major concern. Given that available design approaches rely mainly on stringent volumetric criteria for asphalt mixtures, design approaches and specifications that incorporate performance tests are needed to follow a performance-engineered mix design (PEMD) process, especially with the introduction of the balanced mix design (BMD) concept

This Dissertation study presents a comprehensive investigation of a feasible designapproach that can be implemented to develop PEMD specifications and produce BMD mixtures. An experimental evaluation of different mix …

Development And Testing Of Nanostructured Materials For Extreme Environment Applications, Nanthakishore Makeswaran

Open Access Theses & Dissertations

Nanostructured materials have many potential applications in the fields of power generation and transportation technologies, particularly in the areas of gas sensing technology, industrial gas turbines and protective coatings. In the former case β-Ga2O3 represents a promising candidate due to its high degree of stability and functionality for oxygen sensing at higher temperatures (>700oC). In the latter case, the application of Y-Si-Fe compounds acting as environmental barrier coatings for gas turbine and aerospace engine applications to protect from corrosion effects has been demonstrated in recent years. In both cases, however, there is room for improvement whether it is in …

Post Processing Of Electron Beam Melted Ti-6al-4v And Binder Jetted 17-4 Stainless Steel, Ahmad Omar Abu-Issa

Open Access Theses & Dissertations

An extensive assortment of HIP parameters have been altered on EBM fabricated Ti-6Al-4V and have shown that cooling rates of 103 oC/min from temperatures above and below the beta transus produced acicular alpha-prime martensite characteristic elongations < 10 %. Optimum yield strength (0.9 GPa), UTS (1.0 GPa) and elongation (~14 %) were achieved for slow cooling (at 102 oC/min) from 850 oC HIP which produced a dense, Widmanstatten alpha structure within the retained, as-fabricated columnar grains by alpha-prime decomposition. These results suggest that manipulation of AM process parameters to produce a small-grain, equiaxed microstructure, HIPed below the beta transus and slow cooled, will have a wide range of superior, isotropic mechanical properties corresponding to a Widmanstatten alpha microstructure within the equiaxed grains. Also, Binder Jetting printing parameters for differing PSD's of low-cost water-atomized 17-4 Stainless Steel were optimized in order to produce high dense parts. Densities ranging from 94-97.5% were achieved, and issues of inhomogeneous porosity were addressed using a fumed silica flow additive.

Study Of Static And Dynamical Properties Of Complex Antiferroelectrics Materials, Kinnary Yogeshbhai Patel

Graduate Theses and Dissertations

The aim of this dissertation is the investigation of the static and dynamical properties of the complex antiferroelectric materials using Effective Hamiltonian method and First principles calculations. In chapter 3, a novel elemental interatomic coupling in perovskite materials which bilinearly couples the antiferroelectric displacements of cations with the rotations of the oxygen octahedra. This new coupling explains a very complex crystal structure of prototypical antiferroelectric PbZrO3. My explanation provides a unified description of many other complex antipolar crystal structures in variety of perovskite materials, including the occurrence of incommensurate phases in some of them. In chapter 4, results and analysis …

Mixed Mode Crack Propagation In Iliac Bone, E. Baesu, Dm. Iliescu, Bv. Radoiu, S. Halichidis

Department of Mechanical and Materials Engineering: Faculty Publications

Bone is a complex material that can be regarded as an anisotropic elastic composite material. The problem of crack propagation in hu- man bone is analyzed by using a generalization of the maximum tensile stress criterion (MTS). The results concern the critical stress for crack propagation and the direction of the crack path in Iliac bone.

Special Issue “Cfd Modeling Of Complex Chemical Processes: Multiscale And Multiphysics Challenges”, Li Xi, De-Wei Yin, Jae Sung Park

Department of Mechanical and Materials Engineering: Faculty Publications

No abstract provided.

Application Of Atomically Precise Metal Nanoclusters In Electrocatalysis, Zhi-Hua Zhuang, Wei Chen

Journal of Electrochemistry

Metal nanoclusters (M NCs) consist of only several to a few hundred of metal atoms and possess core sizes less than 2 nm. Owing to the quantum size effect, the electronic states of M NCs evolve to discrete levels similar to the molecule energy gaps, other than a continuous density of states to produce plasmon characteristic of bulk metal nanoparticles (M NPs). In comparison with the conventional M NPs, M NCs exhibit dramatically unique electronic and optical properties, such as molecule-like energy gaps, strong photoluminescence and high catalytic properties, which make them promising for potential application in numerous fields, such …

Electrochemiluminescence Imaging Hydrogen Evolution Reaction On Single Platinum Nanoparticles Using A Bipolar Nanoelectrode Array, Xiang Qin, Zhong-Qiu Li, Jian-Bin Pan, Jian Li, Kang Wang, Xing-Hua Xia

Journal of Electrochemistry

A high-density (5.7 × 10⁸ cm^-2) nanoelectrode array with the electrode diameter of 200 nm and the interelectrode distance of 450 nm were fabricated. The nanoelectrode array consisted of gold nanowires embedded in a porous anodic aluminum oxide (AAO) matrix, having regular nanoelectrode distribution and highly uniform nanoelectrode size. The gold nanoelectrode array was used as a closed bipolar nanoelectrode array combined with electrochemiluminescence (ECL) method to map the electrocatalytic activity of platinum nanoparticles toward hydrogen evolution reaction (HER) by modifying the catalysts on single nanoelectrodes. Results show that HER on single bipolar nanoelectrodes could be imaged …

Oxygen-Exposure Induced Rapid Oxidation Of Spiro-Ometad In Cspbibr2 Perovskite Solar Cells, Wei-Guo Wang, Tian Bai, Gao-Fei Xue, Mei-Dan Ye

Journal of Electrochemistry

2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenyl-amine)-9,9′-spirobifluorene (Spiro-OMeTAD) is the most widely used hole transport material in perovskite solar cells (PSCs). However, its oxidation in the air takes a long time and results in the attack of perovskite by water. In this regard, we performed the oxidation process of Spiro-OMeTAD in oxygen, where perovskite can be protected from water, guaranteeing the integrity of perovskite. It was demonstrated that the champion Spiro-OMeTAD based CsPbIBr₂ PSCs after oxygen oxidation achieved a 7.19% power conversion efficiency (PCE), showing a higher PCE than 6.29% of the champion device oxidized in air. A series of electrochemical characterization methods were applied …

Theoretical Studies Of Metal-N-C For Oxygen Reduction And Hydrogen Evolution Reactions In Acid And Alkaline Solutions, Xue-Ping Qin, Shang-Qian Zhu, Lu-Lu Zhang, Shu-Hui Sun, Min-Hua Shao

Journal of Electrochemistry

Single atom catalysts (SAC) have been regarded as the promising alternatives to platinum group metals due to their low costs and potentially high catalytic activities in various electrocatalytic reactions. The atomic mechanism understanding of activity discrepancy among different metal and nitrogen co-doped carbon-based catalysts is still lacking. Here, non-precious metal and nitrogen co-doped carbons (Me-N-C, Me = Fe and Co) as the model catalysts are investigated by combining experimental and theoretical studies to explore the catalytic activities and corresponding reaction mechanisms toward oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) at universal pHs. Atomic theoretical simulations suggest that Fe-N-C …

Lithium Storage Performance Of Hard Carbons Anode Materials Prepared By Different Precursors, Zhen-Lang Liang, Yao Yang, Hao Li, Li-Ying Liu, Zhi-Cong Shi

Journal of Electrochemistry

Hard carbon is one of the most promising anode material for lithium ion batteries (LIBs) owing to its high stability, widespread availability, low-cost, and excellent performance. The electrochemical properties of hard carbon materials depend strongly on the type of precursors. It is, therefore, very important to choose an excellent hard carbon precursor. Polyacrylonitrile, petroleum pitch and peanut shells were used as raw materials to prepare different hard carbon anode materials for LIBs. These hard carbon anode materials were successfully synthesized in two steps. The selected precursor was firstly carbonized at 600℃ for 1 h in argon atmosphere using heating rate …

Pd-Based Electrocatalysts For Oxygen Reduction And Ethanol Oxidation Reactions: Some Recent Insights Into Structures And Mechanisms, Zhi-Peng Wu, Chuan-Jian Zhong

Journal of Electrochemistry

The development of efficient electrocatalysts for applications in fuel cells, including proton-exchange membrane fuel cell (PEMFC) and direct ethanol fuel cell (DEFC), has attracted extensive research attention in recent years. Oxygen reduction reaction and ethanol oxidation reaction are two of the key reactions where the design of active, stable and low-cost electrocatalysts is critical for the mass commercializations of PEMFCs and DEFCs. This challenge stems largely from the limited understanding of the catalyst structures and reaction mechanisms. Progress has been made in investigations of electrocatalysts derived from Pd-based alloy nanomaterials both experimentally and computationally. We highlight herein some of the …

Preparation And Characterization Of "Water-In-Salt" Polymer Electrolyte For Lithium-Ion Batteries, Xu Hou, Xin He, Jie Li

Journal of Electrochemistry

Since the development of wearable and flexible electronic products, the demand of flexible energy storage devices such as batteries and super capacitors is in urgent. To enhance the safety and cycling stability for flexible lithium-ion batteries, “water-in-salt” polymer electrolyte was prepared by introducing 21 mol·kg^-1 LiTFSI electrolyte into cross-linked polyacrylamide (PAM) after freeze-drying. A great amount of holes with the size range of 10 ~ 20 μm can be found on the surface and in the bulk of polyacrylamide, which is benefited from the freeze-drying process and acts as a great support for the electrolyte uptake. The “water-in-salt” polymer …

Electrochemical Surface-Enhanced Raman Spectroscopic Studies On Nickel Ultramicroelectrode, Li-Wen Wu, Wei Wang, Yi-Fan Huang

Journal of Electrochemistry

Nickel (Ni) electrodes are widely used in electrochemical researches. Understanding electrochemical processes on Ni electrodes through in-situ characterization of adsorbed species on their surfaces is helpful for rational optimization and application of Ni electrochemistry. Microelectrochemical surface-enhanced Raman spectroscopy (μEC-SERS) combines the mass transfer feature of ultramicroelectrode with high-sensitivity characterizations of molecular structures, which is a powerful method for studying Ni electrochemistry on polarization and non-equilibrium conditions. The key point of performing μEC-SERS is to make a SERS-active Ni ultramicroelectrode.
Here, we demonstrate a method of preparing a SERS-active Ni ultramicroelectrode through electrochemical deposition of several atomic layers of …

Sorption Of Ions Of Some Metals On Synthesized Weakly Basic Ion Exchangers, Dilmurod Azimov, S. Turabjanov, Farrukh Igitov, Rano Nazirova, Tulkin Tursunov

CHEMISTRY AND CHEMICAL ENGINEERING

The purpose of the study is to test a weakly basic anion exchanger of the polycondensation type in the processes of sorption of ions of copper, nickel, cobalt, zinc, cadmium. Among the indicated metal ions, the maximum sorption was established for copper ions.

To study the process of sorption of copper ions by the tested anion exchanger, the method of potentiometric titration was used. It was found that copper ions are sorbed by the anion exchanger in the form of a complex in the range of pH = 3,4-4,2. The formation of the copper ions complexes decreases with an increase …

Fabrication And Characterization Of Highly Ordered Aao Nanotubes, Anvar Khamidov, Farhod Hoshimov, Suvonkul Erkhanovich Nurmonov, Olim Ruzimuradov, Shavkat Mamatkulov

CHEMISTRY AND CHEMICAL ENGINEERING

Investigated the electrochemical synthesis and characterized of a nanometer scale porous anodic aluminum oxide (AAO) membranes with a mean pore diameter about of 80-100 nm. The anodizing process done by varying the anodizing temperature from 20 °C to 25 °C. The membranes exhibit interesting properties such as controllable pore diameters, periodicity and density distribution. These properties can preselected by adjusting the controlling parameters of a temperature controlled two-step anodization process. The surface features of the nanometer scale membrane such as pore density, pore diameter and interpore distance were quantified using scanning electron microscopy (SEM) and atomic force microscopy (AFM). SEM …

Improving Accuracy Of Unmanned Aerial System Thermal Infrared Remote Sensing For Use In Energy Balance Models In Agriculture Applications, Mitchell S. Maguire, C.M.U. Neale, Wayne E. Woldt

Department of Mechanical and Materials Engineering: Faculty Publications

Unmanned aerial system (UAS) remote sensing has rapidly expanded in recent years, leading to the development of several multispectral and thermal infrared sensors suitable for UAS integration. Remotely sensed thermal infrared imagery has been used to detect crop water stress and manage irrigation by leveraging the increased thermal signatures of water stressed plants. Thermal infrared cameras suitable for UAS remote sensing are often uncooled microbolometers. This type of thermal camera is subject to inaccuracies not typically present in cooled thermal cameras. In addition, atmospheric interference also may present inaccuracies in measuring surface temperature. In this study, a UAS with integrated …

Durability Of Concrete Using Foundry Waste Sand, Meshari Alrajab

Morehead State Theses and Dissertations

A thesis presented to the faculty of the College of Business and Technology Morehead State University in partial fulfillment of the requirements for the Degree Master of Science by Meshari Alrajab on April 20, 2021.

Quantifying Surface Morphology Of Manufactured Activated Carbon And The Waste Coffee Grounds Using The Getis-Ord-Gi* Statistic And Ripley’S K Function, Sanghoon Lee, Sukjoon Na, Olivia G. Rogers, Sungmin Youn

All Engineering Faculty Research

Activated carbon can be manufactured from waste coffee grounds via physical and/or chemical activation processes. However, challenges remain to quantify the differences in surface morphology between manufactured activated carbon granules and the waste coffee grounds. This paper presents a novel quantitative method to determine the quality of the physical and chemical activation processes performed in the presence of intensity inhomogeneity and identify surface characteristics of manufactured activated carbon granules and the waste coffee grounds. The spatial density was calculated by the Getis-Ord-Gi* statistic in scanning electron microscopy images. The spatial characteristics were determined by analyzing Ripley’s K function and complete …