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Evaluation Of Additively Manufactured Lattices Under High Strain Rate Impact, Derek G. Spear 2021 Air Force Institute of Technology

Evaluation Of Additively Manufactured Lattices Under High Strain Rate Impact, Derek G. Spear

Theses and Dissertations

Several additively manufactured lattice designs and configurations were evaluated under compression loads under various strain rates from quasi-static to highly dynamic. These experiments examined how the mechanical behavior of the lattice changed based on the lattice design properties and the applied strain rates. The modulus of elasticity, yield strength, plateau stress, and toughness were observed to decrease with an increase in strain rate, revealing that the lattice designs exhibit a negative strain rate sensitivity. A new lattice flow stress model was developed to account for the mechanical response of the lattice and was incorporated into a computational model for simulation. …


Molecular Dynamics Simulations Of Self-Assemblies In Nature And Nanotechnology, Phu Khanh Tang 2021 CUNY Graduate Center

Molecular Dynamics Simulations Of Self-Assemblies In Nature And Nanotechnology, Phu Khanh Tang

Dissertations, Theses, and Capstone Projects

Nature usually divides complex systems into smaller building blocks specializing in a few tasks since one entity cannot achieve everything. Therefore, self-assembly is a robust tool exploited by Nature to build hierarchical systems that accomplish unique functions. The cell membrane distinguishes itself as an example of Nature’s self-assembly, defining and protecting the cell. By mimicking Nature’s designs using synthetically designed self-assemblies, researchers with advanced nanotechnological comprehension can manipulate these synthetic self-assemblies to improve many aspects of modern medicine and materials science. Understanding the competing underlying molecular interactions in self-assembly is always of interest to the academic scientific community and industry. …


Development And Characterization Of Composite Membranes For Use In Countercurrent Solvent Extraction, Lydia Neves Rodrigues 2021 New Jersey Institute of Technology

Development And Characterization Of Composite Membranes For Use In Countercurrent Solvent Extraction, Lydia Neves Rodrigues

Dissertations

Porous membranes having a particular wetting characteristic, hydrophobic or hydrophilic, are used for nondispersive membrane solvent extraction (MSX) where two immiscible phases flow on two sides of the membrane. The aqueous-organic phase interface across which solvent extraction/back extraction occurs remains immobilized on one surface of the membrane. This process requires the pressure of the phase not present in membrane pores to be either equal to or higher than that of the phase present in membrane pores; the excess phase pressure should not exceed a breakthrough pressure. In countercurrent MSX with significant flow pressure drop in each phase, this often poses …


Contact Angle Measurement Using A Hele-Shaw Cell: A Proof-Of-Concept Study, Haipeng Zhang, Jacob Gottberg, Sangjin Ryu 2021 University of Nebraska - Lincoln

Contact Angle Measurement Using A Hele-Shaw Cell: A Proof-Of-Concept Study, Haipeng Zhang, Jacob Gottberg, Sangjin Ryu

Department of Mechanical and Materials Engineering: Faculty Publications

Contact angle is an important property to quantify the wettability of a solid surface with a liquid, which characterizes interactions of the solid-liquid pair. Generally, to measure contact angle, special instruments such as a goniometer are necessary, but they are not readily available in certain research settings. In this study, an alternative method to measure contact angle based on a Hele-Shaw cell, microscopy imaging, and image processing is suggested. In this method, a liquid drop is injected into a transparent Hele-Shaw cell, the meniscus of the drop is captured in the top or bottom view using a brightfield microscope, and …


One-Pot Synthesis Of Fe2O3@Fe-N-C Oxygen Reduction Electrocatalyst And Its Performance For Zinc-Air Battery, Hua Lin, Yi-Jin Wu, Jun-Tao Li, Yao Zhou 2021 College of Energy, Xiamen University, Xiamen 361005, Fujian, China;

One-Pot Synthesis Of Fe2O3@Fe-N-C Oxygen Reduction Electrocatalyst And Its Performance For Zinc-Air Battery, Hua Lin, Yi-Jin Wu, Jun-Tao Li, Yao Zhou

Journal of Electrochemistry

Oxygen reduction reaction (ORR) plays a profound role in determining cathode performance in metal-air batteries and fuel cells. Owing to its inherently sluggish kinetics, high-performance ORR catalysts which favors the scissoring of O-O bond and formation of O-H bond are a requisite. In this regard, Pt has been explored as the most efficient ORR electrocatalysts. Nevertheless, due to its expensiveness, the usage of Pt catalysts represents one of the major sources of cost in those energy conversion devices. Thus, the development of alternative ORR electrocatalysts with minimized Pt utilization has been widely pursued over the past few decades. Metal-nitrogen-carbon catalysts …


Study On Mxene-Carbon Black/Sulfur Composite In Integrated Electrode Of Lithium-Sulfur Batteries, Ye-Peng Fan, Ye-Qiang Luo, Pei-Kang Shen 2021 1. Collaborative Innovation Center of Sustainable Energy Materials, Guangxi University, Nanning 530004, Guangxi, China;2. School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, Guangxi, China;

Study On Mxene-Carbon Black/Sulfur Composite In Integrated Electrode Of Lithium-Sulfur Batteries, Ye-Peng Fan, Ye-Qiang Luo, Pei-Kang Shen

Journal of Electrochemistry

Lithium-sulfur (Li-S) batteries are considered as a promising energy storage device due to their ultrahigh theoretical energy density of 2500 Wh·kg-1 and low cost. However, the practical application of Li-S batteries is seriously limited by their low actual energy density, the shuttle effect of polysulfides (LiPSs), and the insulating nature of sulfur and lithium sulfides. Carbon materials have been developed in the design of sulfur hosts due to their adjustable pore structure and high electrical conductivity, but their non-polar surfaces have weak interactions with LiPSs. Herein, MXene-carbon black/sulfur (Ti3C2Tx-CB/S) composites were prepared and …


Preparation Of 3d Semi-Interpenetrated Polymer Networks Polymer Electrolyte For Lithium Metal Battery, Yun-Feng Zhang, Jia-Ying Wang, Xiao-Jie Li, Shi-Yu Zhao, Yang He, Shi-Kang Huo, Ya-Ying Wang, Chang Tan 2021 Sustainable Energy Laboratory, Faculty of Material Science and Chemistry, China University of Geosciences (Wuhan), Wuhan 430074, Hubei, China;

Preparation Of 3d Semi-Interpenetrated Polymer Networks Polymer Electrolyte For Lithium Metal Battery, Yun-Feng Zhang, Jia-Ying Wang, Xiao-Jie Li, Shi-Yu Zhao, Yang He, Shi-Kang Huo, Ya-Ying Wang, Chang Tan

Journal of Electrochemistry

As the next generation high-energy batteries, lithium metal battery has attracted more and more attention due to its highest specific capacity (3860 mA·h·g-1) and the lowest anode potential (-3.04 V versus the standard hydrogen electrode, SHE). However, the safety problem caused by lithium dendrite growth is one of the biggest challenges for the commercialization of lithium metal batteries. Single ion conducting polymer electrolytes, which deliver high lithium ion transference number, represent one of the important strategies to inhibit lithium dendrite growth. However, the poor compatibility with electrodes and low ionic conductivity largely limit their practical application. In the …


A Comparison In Structural Transformation Of Li[NiXCoYMnZ]O2 (X = 0.6, 0.85) Cathode Materials In Lithium-Ion Batteries, Li-Juan Li, Zhen-Dong Zhu, Juan Dai, Rong-Rong Wang, Wen Peng 2021 Hefei Gotion High-Tech Power Energy Co., Ltd. Hefei 230012, Anhui, China;

A Comparison In Structural Transformation Of Li[NiXCoYMnZ]O2 (X = 0.6, 0.85) Cathode Materials In Lithium-Ion Batteries, Li-Juan Li, Zhen-Dong Zhu, Juan Dai, Rong-Rong Wang, Wen Peng

Journal of Electrochemistry

In this paper, the phase transformation voltage ranges of two layered oxide ternary cathode materials, namely, Li(Ni0.85Co0.10Mn0.05)O2 (referred to Ni85, presenting high Ni content) and Li(Ni0.6Co0.2Mn0.2)O2 (referred to Ni60, presenting common low Ni content), were classified and determined. The structural differences between high Ni and common low Ni ternary materials were studied in order to understand the structure instability of high nickel material during the charging process. At the same time, the differential capacity (dQ·dV-1) curves of Ni85 and Ni60 positive …


Storage Performance And Mechanism Of Mose2 Nanospheres In Lithium And Magnesium Ion Batteries, Yi Peng, Wei Zhang, Fang-Zhen Zuo, Hao-Ying Lv, Kai-Jun Hong 2021 No.38 Research Institute, China Electronics Technology Group Corporation, Hefei 230088, Anhui, China;

Storage Performance And Mechanism Of Mose2 Nanospheres In Lithium And Magnesium Ion Batteries, Yi Peng, Wei Zhang, Fang-Zhen Zuo, Hao-Ying Lv, Kai-Jun Hong

Journal of Electrochemistry

Molybdenum diselenide (MoSe2) is a two-dimensional (2D) transition metal dichalcogenide (TMD) material, attracting wide attention in lithium ion battery (LIB) and exhibiting great potential in next-generation magnesium ion battery (MIB) due to its unique layered structure with fast ion mobility and weak van der Waals interlayer interaction. However, the reported literatures related to MoSe2 mainly focus on the enhancement of performance in LIB without deep storage mechanisms investigations. Meanwhile,the magnesium storage capacity and mechanisms have not been explored. In this work, MoSe2 nanospheres were synthesized via wet chemical route and followed by annealing treatment. When used …


Dft Study Of NiM@Pt1AuN-M-1 (N=19, 38, 55, 79; M = 1, 6, 13, 19) Core-Shell Orr Catalyst, Wen-Jie Li, Dong-Xu Tian, Hong Du, Xi-Qiang Yan 2021 1. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;

Dft Study Of NiM@Pt1AuN-M-1 (N=19, 38, 55, 79; M = 1, 6, 13, 19) Core-Shell Orr Catalyst, Wen-Jie Li, Dong-Xu Tian, Hong Du, Xi-Qiang Yan

Journal of Electrochemistry

The slow kinetics of oxygen reduction reaction (ORR) limits the performance of low temperature fuel cells. Thus, it needs to design effective catalysts with low cost. Core-shell clusters (CSNCs) show promising activity because of their size-dependent geometric and electronic effects. The ORR activity trend of Nim@Pt1Aun-m-1(n = 19, 38, 55, 79; m = 1, 6, 13, 19) was studied using the GGA-PBE-PAW methods. The adsorption configurations of *O, *OH and *OOH were optimized and the reaction free energies of four proton electron (H+ + e-) transfer steps …


Preparation And Electrochemical Evaluation Of Mos2/Graphene Quantum Dots As A Catalyst For Hydrogen Evolution In Microbial Electrolysis Cell, Hong-Yan Dai, Hui-Min Yang, Xian Liu, Xiu-Li Song, Zhen-Hai Liang 2021 1. Department of Materials and Chemical Engineering, Taiyuan College, Taiyuan 030032, Shanxi, China;

Preparation And Electrochemical Evaluation Of Mos2/Graphene Quantum Dots As A Catalyst For Hydrogen Evolution In Microbial Electrolysis Cell, Hong-Yan Dai, Hui-Min Yang, Xian Liu, Xiu-Li Song, Zhen-Hai Liang

Journal of Electrochemistry

Microbial electrolysis cell (MEC) is a relatively new bioelectrochemical technology that produces H2 and meanwhile treats organic wastewater. Cathode hydrogen evolution catalyst plays a key role in MEC. The doping of Graphene Quantum Dots (GQDs) into MoS2 nanosheets can improve the catalytic activity of MoS2 by creating abundant defect sites both in the edge plane and the basal plane, as well as enhancing the electrical conductivity. In this paper, using Na2MoO4 , cysteine and GQDs as raw materials, a series of MoS2/GQDs composites were firstly synthesized via hydrothermal method, and then loaded …


Study On Inhibition Of Lithium Dendrite Growth By Mg(No3)2 Additive In Carbonate Electrolyte, Biao Zhang, Yi Shuai, Yu Wang, Na-Chuan Yang, Kang-Hua Chen 2021 1. Powder Metallurgy Research Institute, Central South University, Changsha 410083, Hunan, China;

Study On Inhibition Of Lithium Dendrite Growth By Mg(No3)2 Additive In Carbonate Electrolyte, Biao Zhang, Yi Shuai, Yu Wang, Na-Chuan Yang, Kang-Hua Chen

Journal of Electrochemistry

In the lithium-sulfurized polyacrylonitrile battery system, the formation and growth of lithium dendrites in the negative electrode seriously deteriorate the charge and discharge performance of the battery. If the growth of lithium dendrites pierces the separator and causes thermal runaway, it will also bring serious damage to the battery, causing potential safety risks. In the carbonate electrolyte that is more conducive to stabilizing the positive electrode sulfurized polyacrylonitrile material, the growth of lithium dendrites is particularly serious. In this paper, magnesium nitrate was added to the carbonate electrolyte to investigate the combined effect of nitrate and magnesium ions on the …


A Preliminary Study On Graphene Film-Metal Composites Prepared By Electrodeposition, Shuang-Juan Liu, Hai-Jing Wang, Jing Guo, Peng-Cheng Wang, Hao Zhou, Cai Meng, Han-Jie Guo 2021 1. School of Metallurgical and Ecological Engineering, University of Science & Technology Beijing, Beijing 100089, China;

A Preliminary Study On Graphene Film-Metal Composites Prepared By Electrodeposition, Shuang-Juan Liu, Hai-Jing Wang, Jing Guo, Peng-Cheng Wang, Hao Zhou, Cai Meng, Han-Jie Guo

Journal of Electrochemistry

Graphene film (GF) has excellent electrical and thermal conductivity, but low strength and hardness. In order to obtain good comprehensive mechanical properties to improve the practical value of GF, the concept of preparing GF-metal composite materials was proposed. This work was conducted to preliminarily study the feasibility of using electrodeposition method to prepare GF-metal composites. Two kinds of composites, GF-Cu and GF-Cr, were successfully prepared by using GF as the cathode, and pure Cu and DSA (Dimensionally Stable Anode) as the anodes, respectively, with applying DC power externally. Employing certain electrochemical parameters, the cation in the electrolyte moved towards the …


Effect Of Conductive Additives On Electrochemical Performance Of All-Solid-State Li-S Batteries, Dong-Hao Wang, He-Feng Yan, Zheng-Liang Gong 2021 College of Energy, Xiamen University, Xiamen 361005, Fujian, China;

Effect Of Conductive Additives On Electrochemical Performance Of All-Solid-State Li-S Batteries, Dong-Hao Wang, He-Feng Yan, Zheng-Liang Gong

Journal of Electrochemistry

All-solid-state lithium sulfur batteries (ASSLSBs) with inorganic solid electrolytes offer an opportunity to realize both high energy density (lithium metal ~ 3860 mAh·g-1, sulfur ~ 1675 mAh·g-1), safety and reliability, via eliminating the polysulfides shuttle effect and flammable liquid electrolyte. However, it still remains a huge challenge for ASSLSBs to achieve high areal active mass loading, high utilization efficiency of the active materials and good cycle stability simultaneously due to the insulating nature of sulfur and Li2S (conductivities of sulfur and Li2S are 5×10-30 S·cm-1 and 3.6×10-7 S·cm-1 …


Preparation Of Coo/Rgo@Ni Foam Electrode And Its Electrocatalytic Reduction Of Co2, Qian Guo, Jia-Long Fu, Cheng-Yan Zhang, Chao-Yue Cai, Cheng Wang, Li-Hua Zhou, Rui-Bo Xu, Ming-Yan Wang 2021 College of Environment and Chemical Engineering, Jiangsu Ocean University, Lianyungang 222005, Jiangsu, China;

Preparation Of Coo/Rgo@Ni Foam Electrode And Its Electrocatalytic Reduction Of Co2, Qian Guo, Jia-Long Fu, Cheng-Yan Zhang, Chao-Yue Cai, Cheng Wang, Li-Hua Zhou, Rui-Bo Xu, Ming-Yan Wang

Journal of Electrochemistry

The worldwide extensive release of carbon dioxide (CO2) has caused serious environmental pollution and unprecedented climate change problems. Thus, for the sustainable development of human society, it is very necessary to convert CO2 to renewable fuels through clean and economical processes. The electrochemical CO2 reduction reaction (CO2RR) is regarded as a promising approach for the recycling of carbon resource and the generation of sustainable fuels. However, the slow kinetics and formation of multiple products in CO2RR hinder its large-scale application. Hence, great research efforts are made to develop electrocatalysts with high product …


Research On The Methods Of Ship's Autonomous Collision Avoidance In Complex Environment, Hongguang Lyu 2021 World Maritime University

Research On The Methods Of Ship's Autonomous Collision Avoidance In Complex Environment, Hongguang Lyu

Maritime Safety & Environment Management Dissertations (Dalian)

No abstract provided.


Contact Angle Measurement Using A Hele-Shaw Cell: A Proof-Of-Concept Study, Haipeng Zhang, Jacob Gottberg, Sangjin Ryu 2021 University of Nebraska-Lincoln

Contact Angle Measurement Using A Hele-Shaw Cell: A Proof-Of-Concept Study, Haipeng Zhang, Jacob Gottberg, Sangjin Ryu

Department of Mechanical and Materials Engineering: Faculty Publications

Contact angle is an important property to quantify the wettability of a solid surface with a liquid, which characterizes interactions of the solid-liquid pair. Generally, to measure contact angle, special instruments such as a goniometer are necessary, but they are not readily available in certain research settings. In this study, an alternative method to measure contact angle based on a Hele-Shaw cell, microscopy imaging, and image processing is suggested. In this method, a liquid drop is injected into a transparent Hele-Shaw cell, the meniscus of the drop is captured in the top or bottom view using a brightfield microscope, and …


Yо‘L Harakatini Tashkil Etish Sohasidagi Mavjud Muammolar, Ularning Oqibatlari, Bartaraf Etishga Doir Vazifalar Va Takliflar, I.S. Sodiqov, А.A. Sattorov 2021 Tashkent State transport University (Tashkent, Uzbekistan)

Yо‘L Harakatini Tashkil Etish Sohasidagi Mavjud Muammolar, Ularning Oqibatlari, Bartaraf Etishga Doir Vazifalar Va Takliflar, I.S. Sodiqov, А.A. Sattorov

The Scientific Journal of Vehicles and Roads

Avtotransport vositalari sonining oshib borayotganligi ularning xavfsizligini ta’minlash va yо‘l harakatini tashkil etishning davr talablariga muvofiq bо‘lgan normativ-huquqiy bazasini ham birdek takomillashtirib borishni taqozo etadi. О‘zbekiston Respublikasida yо‘l harakati xavfsizligi sohasidagi munosabatlar О‘zbekiston Respublikasining “Yо‘l harakati xavfsizligi tо‘g’risida”gi qonuni normalari asosida tartibga solingan


Qattiq Maishiy Chiqindilarni Tekislashda Buldozer Otvalining Samaradorlik Kо‘Rsatkichini Aniqlash, N.R. Aslonov, S.M. Mirxoliqov 2021 Tashkent State transport University (Tashkent, Uzbekistan)

Qattiq Maishiy Chiqindilarni Tekislashda Buldozer Otvalining Samaradorlik Kо‘Rsatkichini Aniqlash, N.R. Aslonov, S.M. Mirxoliqov

The Scientific Journal of Vehicles and Roads

Qattiq chiqindilarni utilizasiyalashtirish, kо‘plab rivojlangan va rivojlanayotgan mamlakatlarning shaharlarida ham, qishloq tumanlarida ham juda muhim va keng tarqalgan muammo hisoblanadi. Qattiq maishiy chiqindilarni yig’ish va utilizasiyalashtirish bugungi kunda jahonning kо‘plab mamlakatlarini shahar muhitining asosiy muammolaridan biri. Qattiq maishiy chiqindilarni boshqarish bо‘yicha qarorlar moliyaviy turg’un, texnik amalga oshiriluvchan, ijtimoiy, yuridik maqbul va ekologik toza bо‘lishi kerak. Qattiq chiqindilarni boshqarish masalasi, ham kichik, ham katta shaharlarning xokimiyatlari uchun juda katta muammo hisoblanadi.


Metal Oxide Nanoparticles Synthesized By Nonthermal Plasma For Electrochemical Applications, Qinyi Chen 2021 Washington University in St. Louis

Metal Oxide Nanoparticles Synthesized By Nonthermal Plasma For Electrochemical Applications, Qinyi Chen

McKelvey School of Engineering Graduate Student Theses & Dissertations

Metal oxide nanocrystals can be synthesized by colloidal processing and gas-phase processing routes. High-quality nanocrystals produced by colloidal routes typically have surface ligands. Transport of electrons and ions among nanocrystals is hindered by surface ligand, and degrades related electrical performance. Gas-phase processing, for example combustion and thermal plasma, can make free-standing nanocrystals. However, nanocrystals produced by combustion method are heavily agglomerated, which further limits the usage of nanoparticles in electrochemical applications. Nonthermal plasma, as an emerging attractive route, has been initially focused on the synthesis of elemental group IV materials, and extended to include the synthesis of multicomponent materials, such …


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