Engineering Science and Materials Commons^™

Effect Of Calcination Frequency On The Thermoelectric Properties Of Ti Doped Cucro By Solid State Method, Doli Bonardo, Nono Darsono, Syahrul Humaidi, Agung Imaduddin, Noni Surtiana Silalahi

Journal of Metals, Materials and Minerals

In this study, the influence of titanium oxide (TiO2) dopants and varying calcination processes on the thermoelectric properties of CuCrO2 was systematically explored. It was emphasized that these factors were not only affecting dislocation density but also exerting a profound influence on thermoelectric performance through the modulation of Seebeck coefficient and resistivity. The findings highlighted CrT-2, which incorporated TiO2 and underwent a two-time calcination process, as the top-performing sample in terms of power factor values, underscoring the significance of TiO2 as a dopant for enhancing thermoelectric efficiency. Conversely, Cr-4, exposed to four calcination cycles, exhibited slightly lower power factor values …

Electrical And Water Resistance Properties Of Conductive Paste Based On Gold/Silver Composites, Sutthipoj Wongrerkdee, Supab Choopun, Pichitchai Pimpang

Journal of Metals, Materials and Minerals

This study aimed to investigate the effects of a corrosive environment on both the electrical and the water resistance properties of conductive paste based on gold/silver composites. The conductive paste was prepared by incorporating silver and gold powders, polyvinyl acetate, polyvinyl chloride as adhesive components, and methyl isobutyl ketone as a diluent. The gold/silver composite powder was prepared with different mass ratios of gold and silver. The paste was coated on a substrate and heated at 80℃ to form the conductive paste film. Characterizations of conductive paste were performed by using FT-IR spectroscopy, electrometry, cyclic voltammetry, and contact angle measurements. …

Molybdenum Disulfide-Zirconium Dioxide Composite With Enhance Supercapacitance Performance, Razan Nadhim Shaker, Sami Mohammed, Yousra Ali Abdulsayed

Journal of Metals, Materials and Minerals

As a supercapacitor active material, molybdenum disulfide (MoS2) layer offers good conductivity, large surface area, and electrochemical stability. In practice, however, its capacitance is low in comparison to other materials. This work synthesized MoS2-zirconium dioxide (ZrO2) composite in a simple, high-throughput way to test it as a supercapacitor active layer. During the tests, the composite shows a gravimetric capacitance of 500.0 F⸳g-1, while MoS2 and ZrO2 have capacitances of 265.12 and 152.43, respectively. The increase in capacitance of composite stems from the synergistic effect between ZrO2's pseudocapacitor behavior and MoS2's electric double layer capacitance (EDLC). Moreover, the composite has a …

Dome Tester, Clark Bates, Nikolas M. Kulin

Williams Honors College, Honors Research Projects

We are reconfiguring and modifying the previously built dome tester to be more user friendly and mechanically applicable. This has a long-term goal of being a usable teaching tool for manufacturing education within the college of engineering and polymer sciences. The dome tester pushes a metal dome into a clamped sheet of metal to test its forming limits and where necking occurs. We have implemented a better method of viewing the sheet sample as it is being deformed, and improved measuring methods for the distance a sample is deformed. By introducing these changes in conjunction with improved documentation of the …

Space Force Design Project, Emily Greene, Ashton Orosa, Julia Patek, Nathan Doty

Williams Honors College, Honors Research Projects

The objective of our research project is to develop a lab testbed composed of a curved surface to represent a spacecraft hull, a mobile robot equipped with repair tools, and a robotic arm equipped with a laser 3D scanner. This project is part of a larger grant to the University of Akron from Space Force and Air Research Labs. The lab testbed developed in this project will be used to assist in creating and testing a software and algorithm to inspect and repair spacecraft while in orbit. The project will involve researching spacecraft hulls to create an accurate simulation bed, …

Comparative Study Of Mof's In Phosphate Adsorption, Eniya Karunamurthy

Browse all Theses and Dissertations

High concentrations of phosphate are known to adversely affect the environment. Excess phosphate can lead to eutrophication that eventually fosters uncontrollable growth of aquatic plants and algae. This can result in depletion of oxygen content which adversely impacts underwater organism’s survival rates. Metal organic frameworks (MOFs) consist of organic linkers in conjunction with metal ions or clusters arranged within a crystalline structure. They are highly porous and have larger surface area due to their ability to possess extensive void spaces while remaining bulky in nature. MOFs can absorb phosphate from aqueous solutions. We have investigated the use of commercially available …

Characterization Of Aerosol Jet Printed Silver Thin Films Sintered By A Scanning Laser, William A. Metzger

Browse all Theses and Dissertations

Direct write printing, which is part of additive manufacturing (AM) technology, offers unique capabilities that can complement traditional methods of electronics fabrication. Printing of electrical interconnects via aerosolization is one of the areas in AM that is very important in electronics fabrication. Post-print sintering is a critical step in printed electrical interconnects because it strongly influences the electrical resistivity of the interconnects. Interconnects require the lowest possible resistivity to achieve better performance. Thermal sintering is the most common technique employed in printed interconnects. However, it is limited to substrates that can handle the high temperature requirement for sintering. For polymers …

Establishing The Foundation To Robotize Complex Welding Processes Through Learning From Human Welders Based On Deep Learning Techniques, Rui Yu

Theses and Dissertations--Electrical and Computer Engineering

As the demand for customized, efficient, and high-quality production increases, traditional manufacturing processes are transforming into smart manufacturing with the aid of advancements in information technology, such as cyber-physical systems (CPS), the Internet of Things (IoT), big data, and artificial intelligence (AI). The key requirement for integration with these advanced information technologies is to digitize manufacturing processes to enable analysis, control, and interaction with other digitized components. The integration of deep learning algorithm and massive industrial data will be critical components in realizing this process, leading to enhanced manufacturing in the Future of Work at the Human-Technology Frontier (FW-HTF).

This …

Understanding The Feasibility Of Improving Interfacial Properties In Direct Ink Writing Of Silicone-Polyurethane Resin Hybrid Material, Ayobami Samuel Akinfenwa

College of Graduate Studies: Theses & Dissertations

The progress in materials engineering and the ability to make various models possible have made soft robotics a popular alternative to traditional robotics. Still, soft robots need various parts, like Printed Circuit Boards (PCBs), batteries, cables, fittings, and more, to work correctly or to get attached to other complex parts. These parts can have different material properties, like elastic moduli, strength, etc. Because of these differences, mechanical failures happen at the points where two materials meet, making soft robots less durable and less lasting in real-life situations due to failure. Conventionally, the fabrication of soft robot parts is through moulding. …

Advanced Modeling And Innovative Transcranial Magnetic Stimulation Coil Designs For The Treatment Of Neurological Disorders, Mohannad Tashli

Theses and Dissertations

Transcranial magnetic stimulation (TMS) is a safe, effective and non-invasive treatment for several mental and psychiatric disorders. TMS is an FDA approved treatment and is commonly applied to patients who do not respond to medications for the treatment of clinical depression, smoking cessation, obsessive-compulsive disorder and migraine. Recently, there has been an increase in the development of electromagnetic neuromodulation techniques targeted at enhancing the effectiveness of TMS devices for the treatment of mental diseases. In TMS stimulation, focality is an important factor which determines the specificity of the pulses induced in different brain tissues. The electromagnetic pulses must be confined …

อิทธิพลของระยะวิ่งต่อการชาร์จและอัตราการชาร์จของยานยนต์ไฟฟ้าต่อการให้บริการ Ride Sharing ในพื้นที่จุฬา-สามย่าน, ภูมิรพี ขัดศรี

Chulalongkorn University Theses and Dissertations (Chula ETD)

หนึ่งในรูปแบบการเดินทางสมัยใหม่คือ ride sharing ซึ่งเป็นองค์ประกอบสำคัญร่วมกับระบบขนส่งสาธารณะที่จะนำไปสู่รูปแบบ Mobility as a Service ที่จะยกระดับคุณภาพและความสะดวกสบายในการเดินทางในเมืองได้มาก งานวิจัยนี้ศึกษาการใช้งานบริการ ride sharing ในพื้นที่จุฬา-สามย่าน ที่จะตอบสนองพฤติกรรมการเดินทางในพื้นที่มหาวิทยาลัย โดยมีการนำข้อมูลจากบริการจริงมาใช้ในการศึกษาผลกระทบของระยะวิ่งต่อการชาร์จและอัตราการชาร์จของยานยนต์ไฟฟ้าในการให้บริการ ride sharing ผ่านการจำลอง การจำลองบริการใน ride sharing ในพื้นที่จุฬามีขนาด 6.88 ตารางกิโลเมตร ในส่วนของ range มี 3 ขนาดได้แก่ long range, medium range, short range ตามลำดับ อัตราการชาร์จแบ่งออกเป็น 3 ขนาดได้แก่ fast charge, medium charge, slow charge ดังนั้น การจำลองจึงมี 9 สถานการณ์จำลองด้วยกันและใช้ยานพาหนะ 20 คัน ตัวชี้วัดสำหรับการจำลองการให้บริการ ได้แก่ Vehicle Kilometer Traveled (VKT) , service distance, %served และรายได้จากการให้บริการ ผลลัพธ์จากการวิเคราะห์พฤติกรรมและรูปแบบการเดินทางในพื้นที่ด้วย ride sharing ภายในจุฬาลงกรณ์มหาวิทยาลัยพบว่ามีช่วงการใช้งานสูงสุดอยู่ในช่วง 11:30-12:30 น. โดยมีจำนวนการเรียก 1 คนราว 70% และราว 92% คือการเรียกรถแบบไม่เกิน 3 คน ระยะเดินทางด้วย ride sharing ขั้นต่ำอยู่ที่ระยะทาง 400 เมตร สำหรับผลลัพธ์จากการจำลองทั้ง 9 สถานการณ์จำลองนั้น พบว่าผลกระทบจากการปรับอัตราการชาร์จนั้นส่งผลต่อการให้บริการมากกว่า range อย่างเห็นได้ชัดในทุกกรณี ซึ่งจากการสอบทวนผลลัพธ์กับผู้ประกอบการ ผลลัพธ์สอดคล้องกับการให้บริการจริง นอกจากนั้นจากผลลัพธ์พบว่าการเพิ่ม Range นั้นไม่ได้ให้ผลลัพธ์การบริการที่ดีขึ้นเสมอไป โดยกรณี short range:medium charge มี %served …

Application Of Multi-Scale Computational Techniques To Complex Materials Systems, Mujan N. Seif

Theses and Dissertations--Chemical and Materials Engineering

The applications of computational materials science are ever-increasing, connecting fields far beyond traditional subfields in materials science. This dissertation demonstrates the broad scope of multi-scale computational techniques by investigating multiple unrelated complex material systems, namely scandate thermionic cathodes and the metallic foam component of micrometeoroid and orbital debris (MMOD) shielding. Sc-containing "scandate" cathodes have been widely reported to exhibit superior properties compared to previous thermionic cathodes; however, knowledge of their precise operating mechanism remains elusive. Here, quantum mechanical calculations were utilized to map the phase space of stable, highly-faceted and chemically-complex W nanoparticles, accounting for both finite temperature and chemical …

Solid-State Electrolytes For Long Duration Molten Sodium Batteries, Ryan C. Hill

Theses and Dissertations--Chemical and Materials Engineering

Rechargeable batteries have become a staple of modern society, driving the development and expansion of portable electronics and electric vehicles. The long lifetime and high energy density provided by batteries have made them excellent candidates for use in the emerging field of long duration, grid-scale energy storage. However, traditional battery chemistries, such as Li-ion, are not an ideal solution for grid-scale storage, due to high-cost raw materials that are often sourced from volatile markets. Sodium-based batteries are a promising alternative for long duration storage, owing to the domestic abundance of raw materials and energy densities that nearly rival that of …

Assessing A Byproduct Of The Cbd Ethanol Extraction Process For Potential As A Wood Finishing Product, Avani M. Flanagan

Masters Theses

Developments in regulations concerning the use of CBD products as therapeutic remedies have allowed the global cannabidiol (CBD) market to take off within the past five years. Despite producers of CBD oil wanting to optimize their methods and increase product yields, several waste streams still exist. During the winterization phase of the ethanol extraction process, CBD oil is cooled and filtered so the fats, waxes, and lipids from the Cannabis sativa plant can coagulate and be removed, creating a purer oil with higher potency but contributing to the 58% (crude weight) total loss that occurs throughout the process. The removed …

The High Temperature Degradation Of Ferritic Stainless Steel In Solid Carbon Atmospheres, Prakeaw Ngamsri, Suwijak Pokwitidkul, Paweena Treewiriyakitja, Penpisuth Thongyoug, Ratchapon Nilprapa, Jennarong Tungtrongpairoj

Journal of Metals, Materials and Minerals

Stainless steel is widely used for many components and parts in coal-fired thermal power plants. AISI 430 ferritic stainless steel (FSS) is one common grade to combat the degradation at high temperatures in coal combustion atmospheres containing flue gas, coal ash, and soot (impure solid carbon particles). However, the effect of the solid carbon particles on the degradation of FSS needs to be clarified. Graphite powder was used to simulate solid carbon atmospheres for investigating the degradation of AISI 430 at high temperatures of 1150℃ to 1350℃ in coal-fired boilers. After the carbothermic reduction, the mass gain of a pre-oxidized …

Recovery Of Pure Silver From Spent Silver Electroplating Solutions Via Electrochemical Process And Zinc Cementation, Tapany Patcharawit, Chatisa Kansomket, Woranittha Kritsarikun, Ketmanee Taseela, Chonthicha Paernaphan, Thiwavan Laphosin, Teerawut Tannukit, Sakhob Khumkoa

Journal of Metals, Materials and Minerals

Recycling of spent silver electroplating solutions has been investigated via electrowinning and electrorefining in comparison to zinc cementation technique in this research. Two different compositions of transparent and dark waste solutions were used having the remaining silver contents of 17.71 g⸳L-1 and 33.36 g⸳L-1 respectively. The waste solutions were used as an electrolyte in the first step of electrowinning at low current density of 0.015 A⸳cm-2. It was found that increasing electrowinning time from 4 h to 24 h increased the recovery of silver cathode for both types of waste solutions. The optimum electrowinning time was higher than 8 h, …

Effects Of Indium And Gallium Ratio On Tarnish Resistance, Corrosion And Mechanical Properties Of 950 Silver Alloy, Aumphol Yanil, Patama Visuttipitukul, Ekasit Nisaratanaporn, Charasphat Preuksarattanawut

Journal of Metals, Materials and Minerals

The effects of Indium (In) and Gallium (Ga) ratio on tarnish resistance, corrosion and mechanical properties of 950 silver alloy were studied. 950 Silver alloy with aluminium (Al), silica (Si) and germanium (Ge) were added with In and Ga at the range of 0.44 to 1.90 weight percent. The increment of secondary structure with Ge-Si rich phase in Ag-Al alloy increases hardness, but reduces ultimate tensile strength. The addition of In and Ga improves tarnish and corrosion resistance. The color differences as indicated by Delta E tolerances (DE*) of Ag-Al alloys are in the range of 8.64 to 11.40 while …

Investigating The Effect Of Temperature And Nacl Concentration On Corrosion Behavior Using Commercial Food Cans, Samar S. Hussein, Abeer A. Radhi, Wafaa K. Mahmood

Journal of Metals, Materials and Minerals

In the present work, commercial tin-plate used as storage cans for three different products (salmon fish, green peas, and corn) are used to investigate the corrosion to storage temperature and salt concentration. The corrosion process was electrochemically monitored using the potentiodynamic polarization method and the structure and concentrations of the corrosion products were investigated using X-ray diffraction (XRD). To characterize the resulting sample morphology, emission scanning electron microscopy (FESEM) was used. The results showed that the corrosion resistance of the tin-coating, was important constant and by changing the NaCl concentration and operation temperature, the corrosion resistance was lower. It is …

Optimized Conditions For Cobalt Diffusion In Sri Lankan Colorless Topaz And Coloration Mechanism Elucidation Through Spectro-Chemical Investigation, Chandana P. Udawatte, Sunil Abeyweera, L. R. K. Perera, Sandun Illangasinghe, Chirath Weerasooriya, Chakkaphan Sutthirat, Naleen Jayasinghe, Tilak Dharmaratne, Saranga Diyabalanage

Journal of Metals, Materials and Minerals

Most of natural topaz is colorless; thus, methods of color enhancement are widely used for coloring this mineral. Currently, blue color is obtained by cobalt diffusion due to drawbacks in existing coloration methods. In this study, optimum conditions suitable for Cobalt diffusion in Sri Lankan colorless topaz were investigated and coloration mechanism was elucidated. The diffusion agent was prepared by mixing CoCO3 with Na2CO3, CaCO3 and carbon powder and diffusion was carried-out by varying the temperature and soaking time. Chemical analysis, UV-Vis absorption spectrum, infrared absorption spectra, and Raman peaks of diffused and non-diffused topaz were tested. The results clearly …

Fabrication Of Glass-Ceramics Composite By Infiltration Of Lithium Tetraborate Glass Into Porous Magnesium Aluminate Spinel Ceramic, Nattawat Kulrat, Chumphol Busabok, Saweat Intarasiri, Somsak Dangtip, Wasana Khongwong

Journal of Metals, Materials and Minerals

Magnesium aluminate spinel (MAS) glass-ceramics composite has excellent mechanical and optical properties. It can be obtained from porous ceramic by infiltrating the proper choice of glass. In this study, porous MAS ceramic was prepared by conventional sintering from MAS powder to reach a bulk density of 2.48 g∙cm-3 (70.1% of relative density). The porous MAS ceramic was then infiltrated with molten lithium tetraborate glass (Li2B4O7; LTB) at 950℃ for 30 (IF30) and 60 (IF60) min. They were left to cool down to 700℃ inside the furnace before being taken out to quench in ambient. The glass-ceramics composite was obtained with …