Dispersion Mechanism Of Nanoparticles And Its Role On Mechanical, Thermal And Electrical Properties Of Epoxy Nanocomposites - A Review,
2023
Chulalongkorn University
Dispersion Mechanism Of Nanoparticles And Its Role On Mechanical, Thermal And Electrical Properties Of Epoxy Nanocomposites - A Review, Baljit Singh, Akash Mohanty, Amit Kumar Srivastava, Ajay Singh
Journal of Metals, Materials and Minerals
The combined effect of nano-reinforcements on the mechanical performance of nanocomposites, which are a novel class of epoxy matrix hybrid nanocomposites containing multiwall carbon nanotubes (MWCNT), graphene, and nanodiamonds (NDs), is drawing substantial attention from many research communities. The discussion concentrates on the dispersion techniques adopted for the preparation of epoxy composites containing different types of nanoparticles (3-D fillers, nanofibers, nanotubes, and plate-like fillers). This review paper covers the electrical, thermal, and mechanical properties of carbon nanotubes (CNTs), graphene, and nanodiamond-reinforced epoxy nanocomposites and correlates them with the topographical features, morphology, weight fraction, dispersion state, and surface functionalization of CNTs, …
Fabrication Of Granular Foam Glass Aggregates From Soda Lime Silicate Glass Waste,
2023
Chulalongkorn University
Fabrication Of Granular Foam Glass Aggregates From Soda Lime Silicate Glass Waste, Pat Sooksaen, Phumin Prakaisri, Pattraporn Teerapatpanid, Pathompong Puathawee
Journal of Metals, Materials and Minerals
Granular foam glass aggregates were fabricated from a soda lime silicate glass waste which utilized crude glycerol as a foaming agent and sodium silicate as a binder. The granulation and the foaming process were carried out by a granulator and an electric rotary furnace. The study investigated at first the foaming behavior of different foam glass formulations at various sintering temperatures. Three compositions were formulated which utilized glass powder at 85 wt%, 90 wt%, and 95 wt%, respectively. Sintering was carried out at temperatures from 800℃ to 1200℃ to evaluate for the foaming and melting characteristics. Foam glass with 90% …
Study Of Corrosion Properties Of Carbon Steel, 304 And 316l Stainless Steels In Sulfuric Acid And Their Degradation Products,
2023
Chulalongkorn University
Study Of Corrosion Properties Of Carbon Steel, 304 And 316l Stainless Steels In Sulfuric Acid And Their Degradation Products, Eakapoj Khamme, Rachsak Sakdanuphab
Journal of Metals, Materials and Minerals
In this study, corrosion properties of carbon steel and stainless steels, and degradation of sulfuric acid by the corrosion mechanism are presented. Carbon steel (CS), 304 stainless steel (SS304), and 316L stainless steel (SS316L) specimens were analyzed through their electrochemical response by using a potentiostat measurement. The specimens were submerged in concentrated 98 wt.% of H2SO4 acid for 0 day to 60 day. The degradation of H2SO4 was determined by its volume change, turbidity, and color due to the corrosion mechanism. Corrosion rate of CS, SS304 and SS316L specimens are 43.237 mm/year, 0.420 mm/year and 0.086 mm/year, respectively. After 60 …
Microstructure And Mechanical Properties Of 0.2c-3.9al-1.12mn-0.3mo Δ-Trip Steel As A Function Of Isothermal Bainitic Transformation Temperature,
2023
Chulalongkorn University
Microstructure And Mechanical Properties Of 0.2c-3.9al-1.12mn-0.3mo Δ-Trip Steel As A Function Of Isothermal Bainitic Transformation Temperature, Mahsa Gholambargani, Yahya Palizdar, Ali Khanlakhani, Ali Khanlakhani
Journal of Metals, Materials and Minerals
The present investigation employed a two-stage heat treatment on a δ-transformation-induced plasticity (TRIP) steel comprising 0.2C–4Al–1.2Mn–0.3Mo (wt%). The mechanical and microstructural characteristics that result from varied isothermal bainitic transformation (IBT) temperatures following inter-critical annealing at 820℃ for 10 min are thoroughly analyzed. The microstructure of the steels consisted of δ-ferrite, α-ferrite, bainitic ferrite, retained austenite (RA), and martensite, resulting in an optimum combination of the ultimate tensile strength (UTS) and total elongation (TE). The results of the investigation showed that IBT temperature had an effect on the stability of RA and the martensitic transition. Due to the increased mechanical stability …
Improvement Of Specific Capacity Of Lithium Iron Phosphate Battery By Increasing The Surface Area And Electrical Conductivity Of Cathode Electrode Using Graphene Foam,
2023
Chulalongkorn University
Improvement Of Specific Capacity Of Lithium Iron Phosphate Battery By Increasing The Surface Area And Electrical Conductivity Of Cathode Electrode Using Graphene Foam, Phurida Kokmat, Patiphat Matsayamat, Kunaree Wongrach, Piyaporn Surinlert, Akkawat Ruammaitree
Journal of Metals, Materials and Minerals
Lithium iron phosphate (LFP) is widely used as an active material in a cathode electrode for lithium-ion batteries (LIBs). LFP has many remarkable properties such as high working voltage and excellent thermal stability. However, it suffers with slow ion diffusion and low electrical conductivity. Graphene foam has many outstanding properties such as large surface area and great electrical conductivity. These properties are suitable for improving the cathode electrode. In this work, the graphene foam was synthesized by chemical vapor deposition. The cathode electrode was prepared by dropping the LFP on the graphene foam. We found that the specific capacity of …
Synthesis Of Carbon Nanowalls By Oxy-Acetylene Torch Method,
2023
Chulalongkorn University
Synthesis Of Carbon Nanowalls By Oxy-Acetylene Torch Method, Bauyrzhan Zhumadilov, Aidar Kenzhegulov, Renata Nemkayeva, Gulmira Partizan, Yerassyl Yerlanuly, Maratbek Gadbullin
Journal of Metals, Materials and Minerals
This work presents a relatively new method for the synthesis of carbon nanowalls (CNWs) based on oxy-acetylene torch as a function of deposition time. The morphological and structural properties of the obtained CNW films were studied by scanning electron microscopy and Raman spectroscopy. Changes in the morphology and structural properties of the CNW films depending on the synthesis time were revealed. Shorter growth times lead to the formation of thinner CNW films with a dense labyrinth-like structure, while longer growth times lead to thicker CNW films with a petal-like structure. In addition, this study opens up the possibility of synthesizing …
Sustainable Innovation In Ballistic Vest Design: Exploration Of Polyurethane-Coated Hemp Fabrics And Reinforced Sandwich Epoxy Composites Against 9 Mm And .40 S&W Bullets,
2023
Chulalongkorn University
Sustainable Innovation In Ballistic Vest Design: Exploration Of Polyurethane-Coated Hemp Fabrics And Reinforced Sandwich Epoxy Composites Against 9 Mm And .40 S&W Bullets, Tannachart Wantang, Manop Pipathattakul, Fasai Wiwatwongwana
Journal of Metals, Materials and Minerals
This research aimed to evaluate the bulletproof capabilities of hemp fabrics and optimize the design factors for effective ballistic vests. Three main aspects were investigated: enhancing toughness with polyurethane-coated hemp fabrics, determining optimal placement of fabric-reinforced hemp epoxy composites in various configurations, and identifying the optimal number of fabric layers for performance against 9 mm and .40 S&W bullets. Penetration depth was measured in ballistic gelatin to analyze the results. The study showed strong statistical correlations between factor variables and penetration depth shifts. The most effective strategies included polyurethane-coated hemp on all layers and increased layering. The ammunition of 9 …
Structural And Electrical Properties Of 0.98(Ko0.5na0.5onboo3)-0.02(Bio0.5nao0.5tioo3) Ceramics,
2023
Chulalongkorn University
Structural And Electrical Properties Of 0.98(Ko0.5na0.5onboo3)-0.02(Bio0.5nao0.5tioo3) Ceramics, Swayam Aryam Behera, Sugato Hajra, Swati Panda, Ali Amanat, P. G. R. Achary
Journal of Metals, Materials and Minerals
In the present communication, lead-free ceramics having composition 0.98(K0.5Na0.5NbO3)-0.02(Bi0.5Na0.5TiO3) were synthesized by a high-temperature solid-state reaction route. The Rietveld refinement for the 0.98KNN-0.02BNT reveals an MPB with phase fraction Amm2 (87.76 %) and Pm-3m (12.27%). The SEM study predicted a mean diameter of 0.98KNN-0.02BNT grains as 0.52µm±0.19. The 0.98KNN-0.02BNTceramic displayed a typical hysteresis loop with a remnant polarisation(Pr) of 7.0 μC/cm2, saturation polarization (Ps) of 16 μC/cm2, and a coercive field (Ec) of 26 kV/mm. The electrical, Raman spectra, dielectric, and hysteresis loop study supported a morphotropic phase boundary. The synthesized KNN-BNT lead-free material can be an excellent material for …
Wear Behavior Of In-Situ Oxide Dispersion Strengthened Fe-8ni Alloy With Zr Additions,
2023
Chulalongkorn University
Wear Behavior Of In-Situ Oxide Dispersion Strengthened Fe-8ni Alloy With Zr Additions, Mustafa Tekin, Faiz Muhaffel, Hasan Kotan, Murat Baydoğan
Journal of Metals, Materials and Minerals
In this study, in-situ oxide dispersion strengthened (ODS) Fe91Ni8Zr1 and Fe88Ni8Zr4 alloys were produced by combination of high energy mechanical alloying (HEMA) and high temperature equal channel angular extrusion (HT-ECAE). The wear behaviors of the consolidated samples were investigated under different loads from 1 N to 4 N by reciprocating wear tests at room temperature. The Scanning electron microscopy (SEM) was used to examine the wear tracks to analyze the wear characteristics as a function of applied loads. The relative comparison of the wear results showed that under the lower loads of 1 N and 2 N, Fe88Ni8Zr4 alloy has …
Examination Of The Adhesion Of The Scale Formed On Hot-Rolled Steel With Different Silicon Content Using A Tensile Test,
2023
Chulalongkorn University
Examination Of The Adhesion Of The Scale Formed On Hot-Rolled Steel With Different Silicon Content Using A Tensile Test, Seksan Singthanu, Prayoon Surin, Thanasak Nilsonthi, Manop Pipatthattakul
Journal of Metals, Materials and Minerals
In the hot-rolling process, steel was subjected to high temperatures which results in the formation of an oxide layer called scale. The oxide scale can be affected to the surface characteristic of the hot-rolled steel product. The scale must be completely removed from the surface of the steel before further processing. This research aimed to examine the adhesion behavior of scale on hot-rolled steel with different silicon contents (0.01, 0.12, 0.18, and 0.29 wt%) using a tensile testing machine with an observation setup. The results showed that the scale thickness decreased with increasing silicon content in the range of 9 …
Corrosion Of A Spark Plasma Sintered Fe-Cr-Mo-B-C Alloy In 3.5% Nacl Solution,
2023
Chulalongkorn University
Corrosion Of A Spark Plasma Sintered Fe-Cr-Mo-B-C Alloy In 3.5% Nacl Solution, Mudassir Farooq, Sohail Muhammad, A. A. Sorour
Journal of Metals, Materials and Minerals
In this study, the corrosion behavior of a Fe-Cr-Mo-B-C alloy, fabricated by spark plasma sintering of an amorphous alloy powder, in 3.5% NaCl solution was analyzed. Electrochemical impedance spectroscopy and potentiodynamic polarization are techniques which were used for electrochemical performance estimation of samples and the results were further compared with conventional alloys: 1080 carbon steel and 304 stainless steel. Corrosion surface products were characterized through Scanning electron microscopy, Energy dispersive x-ray spectroscopy and X-ray photoelectron spectroscopy. Specimens sintered at 800℃ (S1-800) had achieved 94% densification approximately while the sample sintered at 900℃ (S2-900), had densified more which was 98% approximately. …
Synthesis Of Zircon Pigments From Rice Husk Ash And Their Performance In Ceramic Glaze,
2023
Chulalongkorn University
Synthesis Of Zircon Pigments From Rice Husk Ash And Their Performance In Ceramic Glaze, Niti Yongvanich, Peerapat Soysom, Worachet Ratkasemsak
Journal of Metals, Materials and Minerals
ZrSiO4-based pigments have been known to be very stable in ceramic glazes but require a high firing temperature required for phase formation. This study examined the feasibility of using rice husk waste as a substitute for crystalline SiO2. The amorphous form of silica with some impurities was obtained by calcining the rice husk at 800℃. The general chemical formula were (Zr0.9M0.1)SiO4, where M = V, Pr, Fe and Cr. The solid-state processing was achieved by firing at 1300℃ for 12 h with NaF (5 wt%). X-ray Diffraction revealed a lower relative fraction between ZrO2 (secondary phase) and ZrSiO4 in the …
Investigation Of Surface Hardness And Roughness On Formability Of Aluminum Alloy Sheet Aa2024-T3 Subjected To The Shot Peening Process By Silica Shots,
2023
Chulalongkorn University
Investigation Of Surface Hardness And Roughness On Formability Of Aluminum Alloy Sheet Aa2024-T3 Subjected To The Shot Peening Process By Silica Shots, Jurarat Sawangpan, Sansot Panich, Tanakorn Jantarasricha, Anak Khantachawana
Journal of Metals, Materials and Minerals
Shot peening is one type of modified surface treatment that produces a residual compressive stress on the material subsurface and improves surface properties while generating plastic deformation on the surface. This research work aims to improve surface properties, which include the enhanced material formability of aluminum alloy 2024-T3 sheet having 1.2 mm of thickness, by providing residual compressive stress on the surface using the shot peening process, which uses silica particles of 0.1 mm in diameter. First, shot peening was performed using various process parameters: compressed air, distance from nozzle to target, and duration time. Based on the obtained peening …
Development Of Inexpensive Device For Methanol Detection In Hand Sanitizer Gel Using Manganese-Doped Zinc Sulfide Quantum Dots Modified By N-Methylpolypyrrole,
2023
Chulalongkorn University
Development Of Inexpensive Device For Methanol Detection In Hand Sanitizer Gel Using Manganese-Doped Zinc Sulfide Quantum Dots Modified By N-Methylpolypyrrole, Sophanat Khenthaphak, Pakorn Juleang, Wanida Wonsawat, Orawon Chailapakul, Eakkasit Punrat
Journal of Metals, Materials and Minerals
A method for methanol detection by an inexpensive device using a nanomaterial modified by N-methylpolypyrrole (NMPPY) has been developed. Manganese-doped zinc sulfide quantum dots (Mn/ZnS-QDs) were synthesized and then characterized by a fluorescence spectrophotometer to study their spectroscopic properties. Mn/ZnS-QDs were modified with NMPPy and studied by digital-image colorimetry to optimize conditions for methanol detection. A 2 mL of 3000 mg∙L–1 Mn/ZnS-QDs modified with 300 μL of 1000 mg∙L-1 of NMPPy was chosen to be a detecting reagent for methanol determination. Under the optimum conditions, the linear range was found to be 2%v/v to 50%v/v of methanol with R-square of …
Surface Modification Of Activated Carbon From Sago Waste,
2023
Chulalongkorn University
Surface Modification Of Activated Carbon From Sago Waste, Khaeriah Dahlan, Yane Oktovina Ansanay, Alda Filadelfi Runggaweri, Marlifon Merani
Journal of Metals, Materials and Minerals
In this paper, we analyzed the effect of surface modification on the surface properties of the active carbon from sago waste using varied oxidizers, namely H2O2, HNO3, and H2SO4. The ordinary active carbon has an initial surface area of 546.6 m2∙g-1, with a phenol and carboxylic functional group. The porosity, functional groups and morphological surface, together with the chemical composition of activated carbon were examined using a nitrogen adsorption-desorption through the Brunauer Emmett Teller (BET) method and the calculation of Barret-Joyner-Hall (BJH), a Fourier-transformed infrared spectroscopy, and a scanning electron microscopy with energy dispersive spectroscopy. The results found that the …
Impact Of Microwave Synthesis Time On The Shape Of Silver Nanostructures And Their Antibacterial Activity,
2023
Chulalongkorn University
Impact Of Microwave Synthesis Time On The Shape Of Silver Nanostructures And Their Antibacterial Activity, Nhat Hieu Hoang, Van Nghia Nguyen, Thi Tho Nguyen, Thi Mong Diep Nguyen
Journal of Metals, Materials and Minerals
Silver is a well-known effective antibacterial and disinfectant material with relatively few side effects. Nanosilver derived from it, have strong antibacterial, antifungal and broad-spectrum antiviral properties. This study describes how the microwave synthesis durations of silver nanoparticles affect their shape, and the effect of the shapes of these nanoparticles on their antibacterial activity. The optical properties of the nanosilver were examined through UV-Vis absorption spectroscopy. The morphology of the grain was determined by transmission electron microscopy (TEM), and the crystallinity of the nanosilver was confirmed by X-ray diffraction (XRD). The antibacterial activities were assessed using bacterial pathogens Bacillus cereus and …
Mechanical Behavior And Physicochemical Modifications In Lignosulfonate-Treated Fique (Furcraea Andina) Fibers,
2023
Chulalongkorn University
Mechanical Behavior And Physicochemical Modifications In Lignosulfonate-Treated Fique (Furcraea Andina) Fibers, Beatriz Dantas Lourenço Da Silva, Paula Lage Agrize, Betina Carvalho Veiga, Lucio Fabio Cassiano Nascimento, Camila Aparecida Abelha Rocha, Fábio De Oliveira Braga
Journal of Metals, Materials and Minerals
One of the most frequent problems in biocomposites is the physical/chemical incompatibility between natural lignocellulosic fibers (NLF) and the matrix. Physical and/or chemical treatments are the most common approach to improve interface properties. Seeking for environmentally friendly treatments, lignosulfonates (LSs) have been considered for surface modification of NLF due to their amphiphilic properties. Thus, the objective of the present work is to evaluate the influence of sodium LS (SLS) treatment protocols in the properties and mechanical behavior of fique (Furcraea Andina) fibers. X-ray diffraction (XRD), Thermogravimetric (TGA) and spectroscopic (FTIR) analyzes were performed, as well as optical microscopy, …
Thermal And Mechanical Evaluation Of Natural Fibers Reinforced Gypsum Plaster Composite,
2023
Chulalongkorn University
Thermal And Mechanical Evaluation Of Natural Fibers Reinforced Gypsum Plaster Composite, Tugba Mutuk, Kerem Arpacioğlu, Sevim Alişir, Gökhan Demir
Journal of Metals, Materials and Minerals
Many problems such as the increase in the world population, global drought, and greenhouse gases have caused materials used in industries to be reconsidered. This is how the concept of green composite material emerged. Using natural fibers to obtain such materials is important in terms of sustainability. This study is aimed to use hemp fiber and banana fiber as natural fiber additives in the gypsum composite to produce green bio-composite. Natural fibers are chemically modified with 5% NaOH solution. In this way, a good fiber/matrix interface interaction is provided. The composite hardness test result of 5 wt% HB fiber added …
Investigation Of Oxide Scale Adhesion On Hot-Rolled Steel Using The Tensile Test And Acoustic Emission,
2023
Chulalongkorn University
Investigation Of Oxide Scale Adhesion On Hot-Rolled Steel Using The Tensile Test And Acoustic Emission, Seksan Singthanu, Prayoon Surin, Manop Pipathattakul, Thanasak Nilsonthi
Journal of Metals, Materials and Minerals
This article addresses applying a tensile test with a CCD camera to assess scale adhesion on hot-rolled steel as a function of hot-rolled coil position. The scale adhesion in this study was shown in the value of the strain initiating the first scale spallation. The result of strain initiating the first scale spallation was confirmed with an acoustic emission (AE) method. The as-received hot-rolled coil was studied at the head, middle, and tail positions. A scanning electron microscope (SEM) and X-ray diffraction (XRD) were used to examine the scale morphology and phase identification respectively. The results show that the oxide …
Effect Of Nano Cdo-Zno Content On Structural, Thermal, Optical, Mechanical And Electrical Properties Of Epoxy Composites,
2023
Chulalongkorn University
Effect Of Nano Cdo-Zno Content On Structural, Thermal, Optical, Mechanical And Electrical Properties Of Epoxy Composites, Chaitra Srikanth, Gattumane Motappa Madhu
Journal of Metals, Materials and Minerals
Cadmium oxide doped zinc oxide nanoparticles were synthesized by solution combustion technique. CdO-ZnO nanoparticles were reinforced into epoxy by ultrasonication technique. CdO-ZnO nano-particles are well known semiconducting materials which are found to exhibit excellent semiconducting behavior even at high frequencies. Hence it was introduced into epoxy to study the semiconducting nature of CdO-ZnO/epoxy composites. The polymer composites exhibited interesting phenomenon such as minimum heat losses at high frequencies indicating semi-conducting behaviour of the composites. The polymer composite was also analysed for its structural, thermal, optical and mechanical properties. The enhanced interaction of CdO-ZnO nanoparticles with epoxy has resulted in superior …
