Engineering Science and Materials Commons^™

Application Of Artificial Intelligence To Lithium-Ion Battery Research And Development, Zhen-Wei Zhu, Jing-Yi Qiu, Li Wang, Gao-Ping Cao, Xiang-Ming He, Jing Wang, Hao Zhang

Journal of Electrochemistry

Lithium-ion batteries (LIBs) have become one of the best solutions to the energy storage issue in modern society. However, the battery materials and device development are both complex, and involve multivariable problems. Traditional trial-and-error approach, which relies on researchers to conduct experiments, has encountered bottlenecks in the improvement of the battery performance. Artificial intelligence (AI) is the most potential technology to deal with this issue due to its powerful high-speed and capabilities of processing massive data. In particular, the capability of machine learning (ML) algorithms in assessing multidimensional data variables and discovering patterns in the sets are expected to assist …

Multi-Electron Reaction-Boosted High Energy Density Batteries: Material And System Innovation, Rui-Qi Guo, Feng Wu, Xin-Ran Wang, Ying Bai, Chuan Wu

Journal of Electrochemistry

The continuous development of the global energy structure transformation has put forward higher demands upon the development of batteries. The improvements of the energy density have become one of the important indicators and hot topic for novel secondary batteries. The energy density of existing lithium-ion battery has encountered a bottleneck due to the limitations of material and systems. Herein, this paper introduces the concept and development of multi-electron reaction materials over the past twenty years. Guided by the multi-electron reaction, light weight electrode and multi-ion effect, current development strategies and future trends of high-energy-density batteries are highlighted from the perspective …

Developing An In Vitro Validated 3d In Silico Internal Carotid Artery Sidewall Aneurysm Model, Hang Yi, Zifeng Yang, Mark Johnson, Luke Bramlage, Bryan Ludwig

Mechanical and Materials Engineering Faculty Publications

Introduction: Direct quantification of hemodynamic factors applied to a cerebral aneurysm (CA) remains inaccessible due to the lack of technologies to measure the flow field within an aneurysm precisely. This study aimed to develop an in vitro validated 3D in silico patient-specific internal carotid artery sidewall aneurysm (ICASA) model which can be used to investigate hemodynamic factors on the CA pathophysiology. Methods: The validated ICASA model was developed by quantifying and comparing the flow field using particle image velocimetry (PIV) measurements and computational fluid dynamics (CFD) simulations. Specifically, the flow field characteristics, i.e., blood flowrates, normalized velocity profiles, flow streamlines, …

Phase-Averaged, Frequency Dependence Of Jet Dynamics In A Scaled Up Vocal Fold Model With Full And Incomplete Closure, Nathaniel Wei, Abigail Haworth, Hunter Ringenberg, Michael Krane, Timothy Wei

Department of Mechanical and Materials Engineering: Faculty Publications

This study focuses on frequency dependence effects on glottal jet dynamics with a focus on the physiological condition in which the vocal folds do not fully close. Incomplete closure occurs naturally in children and adult females. But there are also pathological conditions that can be problematic. Experiments were conducted using a 10× scaled-up model in a free surface water tunnel. Two-dimensional vocal fold models with semicircular medial surfaces were stepper motor driven inside a square duct with constant opening and closing speeds. Cases with complete vocal fold closure and incomplete closure to only 15% of the maximum gap were examined. …

Sars-Cov-2 Detecting Rapid Metasurface-Based Sensor, Shobhit K. Patel, Jaymit Surve, Juveriya Parmar, Khaled Aliqab, Meshari Alsharari, Ammar Armghan

Department of Mechanical and Materials Engineering: Faculty Publications

We have proposed a novel approach to detect COVID-19 by detecting the ethyl butanoate which high volume ratio is present in the exhaled breath of a COVID-19 infected person. We have employed a refractive index sensor (RIS) with the help of a metasurface-based slotted T-shape perfect absorber that can detect ethyl butanoate present in exhaled breath of COVID-19 infected person with high sensitivity and in-process SARS-CoV-2. The optimized structure of the sensor is obtained by varying several structure parameters including structure length and thickness, slotted T-shape resonator length, width, and thickness. Sensor’s performance is evaluated based on numerous factors comprising …

Energy Dissipation In A Sand Damper Under Cyclic Loading, Ehab Sabi

Civil and Environmental Engineering Theses and Dissertations

Various seismic and wind engineering designs and retrofit strategies have been in development to meet structures' proper and safe operation during earthquake and wind excitation. One such method is the addition of fluid and particle dampers, such as sand dampers, in an effort to reduce excessive and dangerous displacements of structures. The present study implements the discrete element method (DEM) to assess the performance of a pressurized sand damper (PSD) and characterize the dissipated energy under cyclic loading. The idea of a PSD is to exploit the increase in shearing resistance of sand under external pressure and the associated ability …

Nanoscale Imaging Of Antiferromagnetic Domains In Epitaxial Films Of Cr2O3 Via Scanning Diamond Magnetic Probe Microscopy, Adam Erickson, Syed Qamar Abbas Shah, Ather Mahmood, Ilja Fescenko, Christian H. Binek, Adbelghani Laraoui

Department of Mechanical and Materials Engineering: Faculty Publications

We report direct imaging of boundary magnetization associated with antiferromagnetic domains in magnetoelectric epitaxial Cr₂O₃ thin films using diamond nitrogen vacancy microscopy. We found a correlation between magnetic domain size and structural grain size which we associate with the domain formation process. We performed field cooling, i.e., cooling from above to below the Néel temperature in the presence of a magnetic field, which resulted in the selection of one of the two otherwise degenerate 180° domains. Lifting of such a degeneracy is achievable with a magnetic field alone due to the Zeeman energy of a weak …

An Application Of Optimized Bistable Laminates As A Low Velocity, Low Impact Mechanical Deterrent, Graham Lancaster

All Theses

This research considers the problem of using bistable laminates as a mechanical deterrent to the impending impact of a particle. The structure will be controlled through an algorithm that will utilize piezoelectric devices to activate them in unison with the bistable laminate to successfully deter. A novel experimental setup will be constructed to ensure that the bistable laminate stays fixed when acting as a mechanical deterrent. Piezoelectricity is the main driving force of the bistable laminate to morph and this study will use a Macro Fiber Composite (MFC) actuator that contains piezoelectric ceramic rods in a patch to transfer electrical …

Potential Of Mechanical Grain Dryers In Addressing Exposure Of Rice Farmers To Weather Risks, Hernaiz Malanon, Zenaida Sumalde

The Philippine Agricultural Scientist

Weather risks brought by prolonged rainfall and cloudy days hamper grain drying operations in the Philippines as majority still employ the sun drying method, which limits the opportunity of rice farmers to earn a higher income. While mechanical dryers are considered an important adaptation mechanism to address weather risks, more research needs to be done on their benefits and their disadvantages. This study adapted the Inter-governmental Panel on Climate Change (IPCC) concept which equates hazard, exposure, and vulnerability to quantify risk. Hazard was assessed in terms of the probability of four straight rainy- or cloudy-day occurrences based on a 30-year …

Using Ultrasonication For The Improvement Of Grade And Recovery In Molybdenum Sulfide Flotation, Wayne Alexander Campbell

Open Access Theses & Dissertations

Experimentation was performed on molybdenite slurry by using ultrasonication to elucidate the effects of ultrasonic-induced bubble cavitation on the grade, recovery, and gangue reduction during small-scale flotation tests and was followed by a topographical analysis of quartz particles using SEM. Ultrasonic waves at 20-80 kHz that propagate through a liquid medium cause microbubbles to form, grow, and implode. The cavitation bubble's implosion causes brief extreme local conditions where temperatures can reach 5,000 K and pressures of 1,000 bar. The resulting microjets create mechanical and chemical changes to the system and were directed at improving flotation dynamics in these experiments. Through …

Sulfonated Styrene Grafted Sebs/Abs Made By Additive Manufacturing For Ion Exchange Applications, Avianna Elaine Gallegos

Open Access Theses & Dissertations

An interpenetrating polymer network (IPN) for cation exchange applications was synthesized from a blend of styrene-ethylene/butylene-styrene (SEBS) and acrylonitrile butadiene styrene (ABS), which was 3D printed, grafted with crosslinked polystyrene (PS), and sulfonated. A method for styrene grafting was applied to reduce the damage to polymer phases caused by the sulfonation reaction. Styrene and divinylbenzene monomers were introduced to the IPN and induced with heat treatment to polymerize in situ. The graft copolymerization reaction was enhanced with varying quantities of benzoyl peroxide as a chemical initiator. The samples were subsequently sulfonated with chlorosulfonic acid in dichloroethane and functionalized for ion …

Fabrication, Microstructure And Mechanical Characterization Of Crvnbtaw High Entropy Alloy Coatings Using Magnetron Sputtering, Jorge Quezada

Open Access Theses & Dissertations

In this project a CrVNbTaW high entropy alloy was evaluated. The samples were made using radio frequency magnetron sputtering and were made under similar conditions. The deposition parameters were explored to find the ideal deposition process. The process included a pressure from 0.1-2mTorr, 600C, 1 hour duration, at 100W power to guns, and constant argon flow. The samples were fabricated under similar parameters using silicon steel and sapphire substrates. The samples were analyzed and characterized using X-ray diffraction, scanning electron microscopy, atomic force microscopy, nanoindentation and corrosion testing. Based on these results we were able to get a better understanding …

Magnetic Structures Of Sawtooth Olivines Mn2six 4 (X = S, Se) Determined Through Neutron Powder Diffraction, Melaku Sisay Tafere

Open Access Theses & Dissertations

In olivine chalcogenide Mn2SiX 4 (X = S, Se) compounds, the Mn lattice produces a sawtooth, which is of critical significance in magnetism due to the potential for manifesting at bands in the magnon spectrum, a crucial component in magnonics. The compounds Mn2SiS4 and Mn2SiSe4 in Mn2SiX 4 family undergo antiferromagnetic phase transitions at T â?? 85 K and â?? 66 K, respectively, as determined from the specific heat, Cp(T). The average and local crystal structuresare determined using synchrotron X-ray, neutron diffraction, and X-ray total scattering data followed by Rietveld and pair distribution function (PDF) analysis. It is found from …

Towards The Electronic Response Of Carbon-Based Van Der Waals Heterostructures In A Diamond Anvil Cell, George Thomas Foskaris

UNLV Theses, Dissertations, Professional Papers, and Capstones

The nanoscale regime of materials has been at the forefront of research and interest in condensed matter physics for many years. In a merger of the fields of two-dimensional (2D) materials and high pressure physics, we present an investigation of the electronic response of carbon-based, van der Waals (vdW) heterostructures in a diamond anvil cell (DAC). Combining these fields presents us with the ability to study the characteristics of such systems both optically, and through electrical transport. Properties such as conductance, band structure, and layer number are considered. The samples in this study are assembled using exfoliation and stacking techniques …

Experimental Tests And Numerical Study Of Trajectories Of Different Types Of Dropped Objects, Yi Li

LSU New Orleans Theses and Dissertations

In marine and offshore engineering, dropped objects, such as drill pipes, anchor chains, containers and some small parts, can accidentally fall into the water from ships or offshore platforms, causing casualties on deck or damage to underwater equipment. Damaged equipment can further harm the environment, such as oil spills from damaged wellheads. Therefore, for safe engineering and environmental protection reasons, we need to develop methods and tools that can predict the trajectory of dropped objects.

In this dissertation, we first study containers dropped from ships. More and more containers are falling into the sea due to bad weather. Containers lost …

High Throughput And Highly Controllable Methods For In Vitro Intracellular Delivery, Justin Brooks, Grayson Minnick, Prithvijit Mukherjee, Arian Jaberi, Lingqian Chang, Horacio D. Espinosa, Ruiguo Yang

Department of Mechanical and Materials Engineering: Faculty Publications

In vitro and ex vivo intracellular delivery methods hold the key for releasing the full potential of tissue engineering, drug development, and many other applications. In recent years, there has been significant progress in the design and implementation of intracellular delivery systems capable of delivery at the same scale as viral transfection and bulk electroporation but offering fewer adverse outcomes. This review strives to examine a variety of methods for in vitro and ex vivo intracellular delivery such as flow-through microfluidics, engineered substrates, and automated probe-based systems from the perspective of throughput and control. Special attention is paid to a …

Hierarchical Structure And Material Integration For Electrocatalytic Co2 Reduction, Hamed Mehrabi

Graduate Theses and Dissertations

CO2 released by the combustion of fossil fuels is driving significant changes to the earth’sclimate. The natural cycle for removing CO2 from the atmosphere, namely photosynthesis, cannot keep up with the rate at which it is being added. Developing engineering approaches to remove CO2 from the atmosphere is becoming essential to reduce these effects. Removal leads to further issues of carbon sequestration and favorable CO2 reuse strategies, including the electrochemical transformation of recovered CO2 to useful products such as fuels and materials. Copper is an important electrocatalyst for the CO2 reduction reaction (CO2RR) because of its unique capability for producing …

Nano-Engineered Soft Magnets: Potential Application In Water Treatment, Hyperthermia And Molecular (Organic) Magnets, Yohannes Weldemariam Getahun

Open Access Theses & Dissertations

Scrutinizing the remarkable and tunable properties of magnetic materials at a nanoscale size "There's Plenty of Room at the Bottom..." Richard Feynman, this study attempts to find sustainable solutions to some of the deteriorating environmental, health, and energy problems the world is encountering. Due to their simple preparation, surface adaptability, and tunable magnetic and optical properties, magnetic nanoparticles have been extensively investigated in water treatment, cancer therapy, data storage, and more. However, relying on non-reusable and chemical-based treatment agents in water, complex and costly cancer treatment procedures and molecular magnets that operate far below room temperature limited those attempts from …

The Qualification Of Sealability And Creep Relaxation Of Additively Manufactured Zytel Gaskets For Pem Fuel Cells, Robert Lazarin

Open Access Theses & Dissertations

The purpose of this thesis is to study the feasibility of low-cost additive manufacturing of gaskets for proton exchange membrane fuel cells exposed to extreme temperature conditions ranging from -55°C to 100°C. With the growing popularity and decreasing costs of additive manufacturing technologies, specifically Material Extrusion (ME), research is being conducted to determine the feasibility of ME components. Thermally cycled PEMFCs may exhibit accelerated gasket deterioration, therefore, the mechanical stability of material extruded gaskets following a harsh thermal cycle must be assessed. The feasibility of the material extruded gaskets will be proven by manufacturing optimization and mechanical testing. The target …

Novel Interlaminar Reinforcement To Enhance The Impact Damage Resistance Of Carbon Fiber-Reinforced Polymer Matrix Composites, Daisy Haidee Mariscal

Open Access Theses & Dissertations

Aerospace, aircraft, marine, and automobile applications are increasingly using composite materials for lighter, higher stiffness, and strength properties. Despite these advantages, composite materials have one major disadvantage. The through-thickness properties are extremely weak when subjected to impact damage. When a composite material is subjected to a low-velocity impact, there is hardly any visible damage on the surface compromising the composite material internally without any external notice. Internal damage may be delamination, which is the most common, matrix cracking, and fiber breakage. A composite material is made up of layers of fiber. The interlaminar region is located in between these layers. …