Engineering Science and Materials Commons^™

Variability And Characteristics Of Recycled Asphalt Shingles Sampled From Different Sources, Aaron Lodge

LSU Master's Theses

Recent literature studies have demonstrated depletion in natural resources; therefore, making resources needed for the pavement industry is more costly. There is a need to minimize cost and to try to reduce the depletion of natural resources. While the recycling of asphalt shingles is beneficial in reducing the consumption of virgin materials, pavement performance should not be compromised. One major concern with recycled asphalt shingles (RAS) relates to the variability in the properties of the recycled materials originating from different sources. In addition, the rheological properties of RAS have not been evaluated as well as its influence on the virgin …

Optimizing Light Requirements And Dilution Rates For Maximizing Algal Cell Growth And Lipid Content For Biofuel Feedstock Production, Beatrice Gabriela Terigar

LSU Doctoral Dissertations

There is a rapidly growing interest in the potential of microalgae as feedstock for the next generation of biofuels. The current study was designed to meet the following objectives: (1) Investigate the interdependence among cell density, biomass and lipid productivity to maximize feedstock production from outdoor cultures; (2) Investigate the effect of cycling high-intensity lights to identify optimum Dark:Light (D/L) ratios, which can be effectively used by researchers to maximize aerial biomass productivities; (3) Develop a deterministic model to simulate the biomass productivity in an continuous-flow bioreactor at various hydraulic retention times. Results indicated that variation in HRTs has a …

Experiments To Measure The Effects Of Timber Harvesting Equipment On Surface Lithic Scatters, Douglas J. Baughman

All Master's Theses

The importance of cultural resource preservation cannot be overstated; however local economies are at least as important. Due to conservative archaeological site protection practices in Region 5 of the United States Forest Service, the economy of Northeastern California is being adversely affected. In an attempt to help the Forest Service make more informed management decisions and improve the Northeastern California economy, I undertook experiments on the effects of timber harvesting on lithic scatters on Modoc National Forest. The experiments involved placement of 225 glass tiles (proxy lithics) in each of three plots subject to vehicle traffic and log dragging by …

Investigation Of Best Practices For Maintenance Of Concrete Bridge Railings, Angel Luis Lence

LSU Master's Theses

Biodeterioration on concrete surfaces of vertical elements of bridges represents a serious challenge to the highway infrastructure in Louisiana. This investigation aims to document the causes of biodeterioration of concrete surfaces and to document current conventional and state-of-the-art practices implemented to prevent and clean biofilm. A comprehensive literature review of previous research has been carried out in order to determine the cause and mechanisms of the biodeterioration as well as to identify current methods that state DOTs have implemented in order to maintain their bridges and allow them to function in optimal structural and performance conditions. A survey was developed …

Controversy Trend Detection In Social Media, Rajshekhar Vishwanath Chimmalgi

LSU Master's Theses

In this research, we focus on the early prediction of whether topics are likely to generate significant controversy (in the form of social media such as comments, blogs, etc.). Controversy trend detection is important to companies, governments, national security agencies, and marketing groups because it can be used to identify which issues the public is having problems with and develop strategies to remedy them. For example, companies can monitor their press release to find out how the public is reacting and to decide if any additional public relations action is required, social media moderators can moderate discussions if the discussions …

Design Flood Elevations Beyond Code Requirements And Current Best Practices, Frank H. Bohn

LSU Master's Theses

In the United States, nearly 9 million people, 3.0% of the population, live in areas subject to the 1% annual chance (100-yr) coastal flood hazard. New construction and substantial improvements in coastal high hazard areas require structures to be elevated above the design flood elevation (DFE), without the use of fill (Bellomo et al. 1999). Building code requirements for flood elevation are linked to the National Flood Insurance Program (NFIP) insurance policies, and represent the minimum requirement for building elevation. Current elevation procedures are limited to the 100-year base flood elevation with minimal guidance beyond the 100-year elevation in many …

A Metaheuristic-Based Simulation Optimization Framework For Supply Chain Inventory Management Under Uncertainty, Qinglin Duan

LSU Doctoral Dissertations

The need for inventory control models for practical real-world applications is growing with the global expansion of supply chains. The widely used traditional optimization procedures usually require an explicit mathematical model formulated based on some assumptions. The validity of such models and approaches for real world applications depend greatly upon whether the assumptions made match closely with the reality. The use of meta-heuristics, as opposed to a traditional method, does not require such assumptions and has allowed more realistic modeling of the inventory control system and its solution. In this dissertation, a metaheuristic-based simulation optimization framework is developed for supply …

Designing A Cost Effective Microalgae Harvesting Strategy For Biodiesel Production With Electrocoagulation And Dissolved Air Flotation, Adam James Dassey

LSU Doctoral Dissertations

Microalgal harvesting strategies for biodiesel production have been a major setback in the industry with high energy estimates of $3400/ton biomass by centrifugation. The present study utilized effective mass and energy balances to reduce these large operating costs. The energy for Stage 1 centrifugation was reduced by 82% when harvesting 28.5% of biomass at 18 L/min as opposed to 95% harvesting at 1 L/min. This strategy was further confirmed using electrocoagulation (EC) with Nannochloris and Dunaliella algae with perforated aluminum and iron electrodes at low (< 6 mg/L) metal ion concentrations. Despite 20% lower harvesting efficiencies, the iron electrodes were more energy and cost efficient with operating costs less than $0.03/L oil when flocculating and settling Nannochloris and Dunaliella cultures. Furthermore, a continuous multistage algae harvester using EC and dissolved air flotation (DAF) for Stage 1 harvesting and centrifugation for Stage 2 dewatering was designed. It was determined throughout the testing that greater EC costs for improved harvesting efficiencies were necessary to offset the large energy requirements of the DAF. The multistage system dewatered a low density (100 mg/L) Nannochloris to 20% solids for a final energy requirement of 1.536 kWh/kg algae ($138/ton). Using the data collected from this research and existing literature, a life cycle analysis was assembled to judge the sustainability of microalgal biofuels in Louisiana. High and low energy estimates for culturing (mixing, CO2, nutrients), harvesting, lipid extraction and energy conversion were compared with the current research. Scaling the EC/DAF system for a full size facility was expected to reduce the harvesting costs to 1.133 kWh/kg algae, resulting as $0.44/L oil for a culture with 20% lipids. Despite this improvement in harvesting costs, the production of algal for the sole purpose of biodiesel was not economically viable. Considering a system with a growth rate of 15 g/m2/day and lipid content of 20%, the energy inputs exceeded the outputs from biodiesel production by 36% under the most ideal conditions. However, incorporating additional revenue through wastewater treatment and biogas production from residual biomass could improve sustainability and profitability of algal biodiesel to an 18.5% energy surplus at its current state.

Carbon-Based Nanostructured Materials As Electrode In Lithium-Ion Batteries And Supercapacitors, Zhuo Yao

Browse all Theses and Dissertations

Carbon-based nancomposites attract much attention as electrode materials in electrochemical energy storage systems due to their low-cost, extraordinary high electrical and thermal conductivity, super high surface area etc. In this research, graphene nanosheets (GNS) and their nanocomposites with manganese oxides (GNS/MnOx) or silicon nanowires (GNS/SiNWs/CF) are studied for their applications in Li-ion batteries and supercapacitors. GNS powders are synthesized via a chemical oxidation of nature graphite followed by appropriate reduction process. GNS/MnOx composites are synthesized rendering MnOx nanoparticles embedded on the surfaces of GNS. SiNWs grown in carbon fibers are mechanically mixed with GNS powders. The impacts of the manganese …

Active Optimal Control Strategies For Increasing The Efficiency Of Photovoltaic Cells, Sharif Aljoaba

Theses and Dissertations--Electrical and Computer Engineering

Energy consumption has increased drastically during the last century. Currently, the worldwide energy consumption is about 17.4 TW and is predicted to reach 25 TW by 2035. Solar energy has emerged as one of the potential renewable energy sources. Since its first physical recognition in 1887 by Adams and Day till nowadays, research in solar energy is continuously developing. This has lead to many achievements and milestones that introduced it as one of the most reliable and sustainable energy sources. Recently, the International Energy Agency declared that solar energy is predicted to be one of the major electricity production energy …

Structural, Optical And Electrical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Abhilash Kongu

Open Access Theses & Dissertations

Hafnium oxide (HfO2) has emerged as the most promising high-k dielectric for Metal-Oxide-Semiconductor (MOS) devices and has been highlighted as the most suitable dielectric materials to replace silicon oxide because of its comprehensive performance. In the present research, yttrium-doped HfO2 (YDH) thin films were fabricated using RF magnetron sputter deposition onto Si (100) and quartz with a variable thickness. Cross-sectional scanning electron microscopy coupled with Filmetrics revealed that film thickness values range from 700 A° to 7500 A°. Electrical properties such as AC Resistivity and current-voltage (I-V) characteristics of YDH films were studied. YDH films that were relatively thin (<1500 A°) crystallized in monoclinic phase while thicker films crystallized in cubic phase. The band gap (Eg) of the films was calculated from the optical measurements. The band gap was found to be ∼5.60 eV for monoclinic while it is ∼6.05 eV for cubic phase of YDH films. Frequency dependence of the electrical resistivity (ρac) and the total conductivity of the films were measured. Resistivity decreased (by three orders of magnitude) with increasing frequency from 100 Hz to 1 MHz, attributed due to the hopping mechanism in YDH films. Whereas, while ρac∼1Ω-m at low frequencies (100 Hz), it decreased to ∼ 104 Ω-cm at higher frequencies (1 MHz). Aluminum (Al) metal electrodes were deposited to fabricate a thin film capacitor with YDH layer as dielectric film thereby employing Al-YDH-Si capacitor structure. The results indicate that the capacitance of the films decrease with increasing film thickness. A detailed analysis of the electrical characteristics of YDH films is presented.

Experimental Study On The Fabrication Of Advanced Materials For Energy Applications Using High Energy Mechanical Milling, Ashvin Kumar Narayana Swamy

Open Access Theses & Dissertations

The reaction of aluminum (Al) powder with water has the potential for on demand hydrogen generation. Conventional Al powders, however, react with water slowly due to a highly protective oxide layer on the particle surface. Current methods for Al activation involve harmful and expensive materials. The nano-scale Al powders also remain very expensive and have problems such as a large amount of oxide on the surface. The use of aluminum in an energy generation cycle is also hindered by the fact that, although Al is the most abundant metal in the Earth's crust, its recovery from ore consumes a lot …

Comparative Characterization Of Ni-Base Superalloys Fabricated By Laser And Electron Beam Melting Technologies, Krista Amato

Open Access Theses & Dissertations

Nickel-base superalloys have been used in cast and wrought, and powder metallurgy forms for nearly four decades for industrial and automotive applications. One drawback of cast alloys is that upon solidification, there is minimal microstructural control. Another issue to be improved is to eliminate the limitations of shapes and forms of fabricated alloys.

Rapid prototyping is a new technology of additive manufacturing that shows to be promising for the freeform fabrication of novel superalloys, including nickel-base alloys. New rapid manufacturing technologies allow us to produce parts in any shape that can be designed by computer-aided design (CAD) software. Additionally, the …

Rbd2po4: Room Temprature Synthesis, Chemical And Structural Stablity Upon Heating, Masoud Mollaee

Open Access Theses & Dissertations

Monoclinic RbD2PO4 polycrystals were synthesized via the room temperature crystallization of RbH2PO4 dissolved in D2O. Powder x-ray diffraction (XRD) data collected at T=25 ºC indicate that this deuterated compound crystallizes in space group P21/m with unit cell parameters a=7.688í?, b=6.192í?, c=4.781í? and β=109.02°, and is isomorphic with the intermediate-temperature phase of its hydrogenated counterpart rubidium dihydrogen phosphate (RDP). We found no evidence of previously reported [Phase Transitions 80, 17 (2007)] polymorphic phase transition in rubidium dideuterium phosphate (DRDP) upon heating from room temperature to 210 ºC. All lattice parameters vary smoothly within this temperature range, demonstrating that the P21/m phase …

Structure And Electronic Properties Of Pure And Nitrogen Doped Nanocrystalline Tungsten Oxide Thin Films, Vemnkata Rama Sesha Ravi Kumar Vemuri

Open Access Theses & Dissertations

Tungsten oxide (WO₃) is a multifunctional material which has applications in electronics, sensors, optoelectronics, and energy-related technologies. Recently, electronic structure modification of WO₃ to design novel photocatalysts has garnered significant attention. However, a fundamental understanding of nitrogen induced changes in the structure, morphology, surface/interface chemistry, and electronic properties of WO₃ is a prerequisite to producing materials with the desired functionality and performance. Also, understanding the effect of thermodynamic and processing variables is highly desirable in order to derive the structure-property relationships in the W-O/W-O-N material system. The present work was, therefore, focused on studying the effects …

Effect Of Hafnium-Incorporation On The Microstructure And Dielectric Properties Of Cobalt Ferrite Ceramics, Stephen Josiah Wells

Open Access Theses & Dissertations

The effect of hafnium ion (Hf⁴⁺) incorporation in cobalt ferrite (CFO) was studied. Samples of Hf substituted CFO ceramic (CoFe_2-xHf_xO₄), were synthesized in the laboratory with hafnium concentrations ranging from x=0.000 to x=0.200. X-ray diffraction scans show that the Hafnium CFO crystalizes in the inverse spinel phase. Inclusion of hafnium causes lattice expansion, increasing the lattice parameter from 8.374 í? for pure CoFe2O4 to 8.391 í? for the highest concentration of hafnium tested (x=0.020). The dielectric properties of CFO are greatly enhanced by inclusion of hafnium. The enhancement is due to the …

Thermal Barrier Coatings (Tbc's) For High Heat Flux Thrust Chambers, Christopher Michael Bradley

Open Access Theses & Dissertations

The last 30 years materials engineers have been under continual pressure to develop materials with a greater temperature potential or to produce configurations that can be effectively cooled or otherwise protected at elevated temperature conditions. Turbines and thrust chambers produce some of the harshest service conditions for materials which lead to the challenges engineers face in order to increase the efficiencies of current technologies due to the energy crisis that the world is facing. The key tasks for the future of gas turbines are to increase overall efficiencies to meet energy demands of a growing world population and reduce the …

Microstructure And Properties For Titanium Aluminide Superalloy Prototypes Fabricated By Electron Beam Melting And Thermally Processed, Jennifer Hernandez

Open Access Theses & Dissertations

Gamma TiAl has been considered to be an ideal replacement for Ni-base superalloy aerospace applications, particularly in weight-critical applications. While bulk, fully dense gamma-TiAl is 50% less dense than Ni-base superalloys, it also has excellent mechanical properties at high temperature (up to ~800°C). Pre alloyed (Ti-48Al-2Cr-2Nb) powder was used to fabricate solid, fully dense (3.85 g/cm3) components and foam components with densities ranging from 0.33 g/cm³ to 0.46 g/cm³ by electron beam melting (EBM). A 10:1 blend of 2-phase TiAl (Ti-48Al-2Cr-2Nb in ^a/_o) : Inconel 625 (Ni-22Cr-6Mo-2Nb in ^a/_o) pre-alloyed powders produced …

New Topics On Nanoindentation Of Polymers And Composite Materials, Ricardo Martinez-Hernandez

Open Access Theses & Dissertations

In this study, nanoindentation was used to determine Young's modulus of homogeneous plastic materials as well as inhomogeneous epoxy woven fabric composites using various indenters. In the first part, homogeneous PMMA and polycarbonate were characterized using conical and spherical indenters. The conventional approach of the inverse analysis was modified in order to account for effects obtained during spherical nanoindentation. The experimental results were verified using FEA analysis in ABAQUS. It was found that viscous effects were present in conical nanoindentations which led to an overestimation of contact stiffness. The second part, the response of carbon and glass fiber woven fabric …

Reducing Metal Alloy Powder Costs For Use In Powder Bed Fusion Additive Manufacturing: Improving The Economics For Production, Fransisco Medina

Open Access Theses & Dissertations

Titanium and its associated alloys have been used in industry for over 50 years and have become more popular in the recent decades. Titanium has been most successful in areas where the high strength to weight ratio provides an advantage over aluminum and steels. Other advantages of titanium include biocompatibility and corrosion resistance. Electron Beam Melting (EBM) is an additive manufacturing (AM) technology that has been successfully applied in the manufacturing of titanium components for the aerospace and medical industry with equivalent or better mechanical properties as parts fabricated via more traditional casting and machining methods. As the demand for …