Engineering Science and Materials Commons^™

Oxygen Reduction Reaction On Glycin Modified Pt(111) Electrode, Ming-Fang Li, Jing Kang, Ling-Wen Liao, Yan-Xia Chen, Shen Ye

Journal of Electrochemistry

O

xygen reduction reaction (ORR) on glycin (NH₂CH₂COOH) modified Pt(111) electrode has been investigated using hanging meniscus rotating disk electrode system (HMRD) in 0.05 mol•L^-1 H₂SO₄ and 0.1 mol•L^-1 HClO₄ solutions, respectively. Cyclic voltammograms of the glycin modified Pt (111) electrode measured in 0.05 mol•L^-1 H₂SO₄ solution similar to that of CN^- modified Pt(111) electrodes, demonstrating that sulfate adsorption is strongly inhibited at the glycin modified Pt(111). From the polarization curve of ORR recorded in 0.05 mol•L^-1 H₂SO₄ solution, it is …

Porous Electrodes With High Pt Utilization Obtained By Ion-Exchange/Electrodeposition, Si-Guo Chen, Wei Ding, Xue-Qiang Qi, Li Li, Zi-Hua Deng, Zi-Dong Wei

Journal of Electrochemistry

We report a novel method based on ion-exchange/electrodeposition (IEE) for constructing high Pt utilization porous electrodes. The electrode prepared using IEE was assessed by linear sweep voltammetry (LSV), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and single cell test. The preliminary results show that the undesired ion-exchange between Pt anion and surface functional group in carbon black can be eliminated through the electrode preparation process, and every Pt particle prepared by IEE is expected to be deposited on the three-phase reaction zone and thus can be fully utilized in fuel cell reactions. The Pt particle size, shape and distribution …

Effect Of Ti/Pbo2 Electrodes Doped With Different Elements On Electrocatalytic Oxidation Characteristics Of Phenol, Xiao-Lei Liu, Yuan-Yuan Dan, Hai-Yan Lu, Hai-Bo Lin, Ming-Li Ouyang, Chuan-Jun Yun

Journal of Electrochemistry

Three types of electrodes, namely, Ti/PbO₂, F-doped PbO₂ (Ti/PbO₂-F) and nano-Co₃O₄-doped PbO₂ (Ti/PbO₂+Nano-Co₃O₄) electrodes, were prepared by electro-deposition method on the Ti substrate with the interlayer of SnO₂-Sb₂O₅. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to study the compositions, structures and film morphologies of the electrodes. Electrocatalytic oxidation characteristics to phenol on the prepared electrodes were investigated by electrochemical method. The experimental results showed that compared with the Ti/PbO₂ electrode, the potentials of oxygen …

A Dft Calculation Screening Of Pt-Based Bimetallic Catalysts For Oxygen Reduction, Li-Hui Ou, Sheng-Li Chen

Journal of Electrochemistry

Developing Pt-lean catalysts for oxygen reduction reaction (ORR) is the key for large-scale application of proton exchange membrane fuel cell (PEMFC). In this paper, we have proposed a multiple-descriptor strategy for screening efficient and durable ORR alloy catalysts of low Pt content. We argue that an ideal Pt-based bimetallic alloy catalyst for ORR should possess simultaneously negative alloy formation energy, negative surface segregation energy of Pt and a lower oxygen binding ability than pure Pt. By performing detailed DFT calculations on the thermodynamics, surface chemistry and electronic properties of various Pt-M alloys (M refers to non-precious transition metals in the …

Sodium Carbonate Catalyzed Photoelectrochemical Water Splitting Over Tio2 Nanotubes Photoanode, De-Sheng Kong, Jing Wang, Xue-Di Zhang, Xi Zhao, Chao Wang, Yuan-Yuan Feng, Wen-Juan Li

Journal of Electrochemistry

Surface recombination of the photogenerated electron-hole pairs at semiconductor/electrolyte interface is one of the most essential reasons responsible for lowering photoconversion efficiency (Φ) of light to chemical energy for photoelectrochemical (PEC) water splitting reaction. In this paper, the catalytic effect of sodium carbonate on the oxygen evolution reaction (OER) over TiO₂ nanotubes photoanode during PEC water splitting was investigated by performing photocurrent and ac impedance measurements. It was demonstrated that the addiction of 1 mmol•L^-1 Na₂CO₃ in 0.5 mol•L^-1 NaClO₄ electrolyte can effectively improve the charge transfer properties for the photogenerated holes across …

Room-Temperature Organic Ferromagnetism In The Crystalline Poly(3-Hexylthiophene): Phenyl-C61-Butyric Acid Methyl Ester Blend Film, Bin Yang, Zhengguo Xiao, Yongbo Yuan, Tanjore V. Jayaraman, Jeffrey E. Shield, Ralph Skomski, Jinsong Huang

Department of Mechanical and Materials Engineering: Faculty Publications

Pronounced ferromagnetism was observed in a crystalline blend film of conjugated polymer poly(3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) by using magnetic force microscopy measurements. A substantial room-temperature saturation magnetization of about 0.65 emu g−1 was measured by an alternating gradient field magnetometer. Multiple experimental evidences demonstrate the charge transfer from the P3HT to the PCBM and the formation of P3HT crystal domain are expected to be two critical factors for the originals of room-temperature organic ferromagnetism.

Me-Em 2012-13 Annual Report, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University

Department of Mechanical and Aerospace Engineering Annual Reports

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Analysis Of Laser Induced Spallation Of Electron Beam Physical Vapor Deposited (Eb-Pvd) Thermal Barrier Coatings, David Allen Beeler

Browse all Theses and Dissertations

The use of thermal barrier coatings (TBCs) has been an important factor in the efficiency improvements of jet engines due to their ability to withstand the extreme environments within the engine. With this improved resistance, TBCs have also become more difficult to remove without damaging the substrate. Mound Laser & Photonics Center, Inc. (MLPC) has developed an innovative, laser based technique to spall this coating. The intention of this work was to investigate and better understand the removal mechanism. Through experimentation and analysis (such as high speed video, Scanning Electron Microscopy and Energy Dispersive Spectroscopy, semi-logarithmic analysis, and a numerical …

Structure And Properties Of Cocoons And Silk Fibers Produced By Attacus Atlas, Narendra Reddy, Yi Zhao, Yiqi Yang

Department of Textiles, Merchandising and Fashion Design: Faculty Publications

Silk fibers in the three layers of Attacus atlas (A. atlas) cocoons have morphological structure and tensile properties similar to that of Bombyx mori silk. Attempts are being made to produce silk for commercial applications from cocoons of relatively unknown wild insects due to the unique properties of the fibers and as a source of income and employment. In this research, A. atlas cocoons were used to study the chemical composition, morphology, physical structure and tensile properties of the silk fibers in the cocoons and ability of the fibers to support the attachment and proliferation of mouse fibroblast cells. It …

A Mathematical Evaluation Of Hemodynamic Parameters After Carotid Eversion And Conventional Patch Angioplasty, Alexey Kamenskiy, Iraklis I. Pipinos, Yuris A. Dzenis, Prateek K. Gupta, Syed A. Jaffar Kazmi, Jason N. Mactaggart

Department of Mechanical and Materials Engineering: Faculty Publications

Carotid endarterectomy has a long history in stroke prevention, yet controversy remains concerning optimal techniques. Two methods frequently used are endarterectomy with patch angioplasty (CEAP) and eversion endarterectomy (CEE). The objective of this study was to compare hemodynamics-related stress and strain distributions between arteries repaired using CEAP and CEE. Mathematical models were based on in vivo three-dimensional arterial geometry, pulsatile velocity profiles, and intraluminal pressure inputs obtained from 16 patients with carotid artery disease. These data were combined with experimentally derived nonlinear, anisotropic carotid artery mechanical properties to create fluid-structure interaction models of CEAP and CEE. These models were then …

Effects Of Mode Coupling On The Admittance Of An At-Cut Quartz Thickness-Shear Resonator, Huijing He, Jiashi Yang, Wei-Ping Zhang, Ji Wang

Department of Mechanical and Materials Engineering: Faculty Publications

We study the effects of couplings to flexure and face-shear modes on the admittance of an AT-cut quartz plate thickness-shear mode resonator. Mindlin’s two-dimensional equations for piezoelectric plates are employed. Electrically forced vibration solutions are obtained for three cases: pure thickness-shear mode alone; two coupled modes of thickness shear and flexure; and three coupled modes of thickness shear, flexure, and face shear. Admittance is calculated and its dependence on the driving frequency and the length/thickness ratio of the resonator is examined. Results show that near the thickness-shear resonance, admittance assumes maxima, and that for certain values of the length/thickness ratio, …

Use Of Comsol Simulation For Undergraduate Fluid Dynamics Course, Hyun J. Kwon

Faculty Publications

The COMSOL software was used to introduce CFD and teach fluid dynamics more effectively. Introduction of CFD has become an important part of fluid dynamics in recent years; however, undergraduate students have less access to practical exposure to it, unless they take additional elective courses which are seldom offered in undergrad predominant institutes. Simulation has become an essential step in designing and optimizing process in many engineering problems. Therefore, the COMSOL simulation project was assigned to undergraduate CFD as a part of their term project to enhance their exposure to simulation software and help understanding the use of simulation on …

A Comparative Study Of The Dry And Wet Nano-Scale Electro-Machining, M. P. Jahan, K. R. Virwani, Kamlakar P. Rajurkar, A. P. Malshe

Department of Mechanical and Materials Engineering: Faculty Publications

In recent years, a nano-electromachining (nano-EM) process based on a scanning tunneling microscope (STM) platform has been demonstrated. Nano-EM is capable of machining nano-features, under both, liquid dielectric (wet nano-EM) and air dielectric (dry nano-EM) media. The objective of this paper is to present a comparative study between the wet and dry nano-EM processes based on process mechanism, machining performance, consistency and dimensional repeatability of these two processes. The comparison of the two processes has been conducted at near field nano-EM, where the gap between the tool electrode and workpiece is 2 nm and the machining is performed at room …

Inducing Neurite Outgrowth By Mechanical Cell Stretch, Suzanne Higgins, Jeong Soon Lee, Ligyeom Ha, Jung Yul Lim

Department of Mechanical and Materials Engineering: Faculty Publications

Establishing extracellular milieus to stimulate neuronal regeneration is a critical need in neuronal tissue engineering. Many studies have used a soluble factor (such as nerve growth factor or retinoic acid [RA]), micropatterned substrate, and electrical stimulation to induce enhanced neurogenesis in neuronal precursor cells. However, little attention has been paid to mechanical stimulation because neuronal cells are not generally recognized as being mechanically functional, a characteristic of mechanoresponsive cells such as osteoblasts, chondrocytes, and muscle cells. In this study, we performed proof-of-concept experiments to demonstrate the potential anabolic effects of mechanical stretch to enhance cellular neurogenesis. We cultured human neuroblastoma …

Systems Biology Of The Functional And Dysfunctional Endothelium, Jennifer Frueh, Nataly Maimari, Takayuki Homma, Sandra M. Bovens, Ryan M. Pedrigi, Leila Towhidi, Rob Krams

Department of Mechanical and Materials Engineering: Faculty Publications

This review provides an overview of the effect of blood flow on endothelial cell (EC) signalling pathways, applying microarray technologies to cultured cells, and in vivo studies of normal and atherosclerotic animals. It is found that in cultured ECs, 5–10% of genes are up- or down-regulated in response to fluid flow, whereas only 3–6% of genes are regulated by varying levels of fluid flow. Of all genes, 90%are regulated by the steady part of fluid flow and 10% by pulsatile components. The associated gene profiles show high variability from experiment to experiment depending on experimental conditions, and importantly, the bioinformatical …

Experimental Comparison Study Of The Response Of Polycarbonate And Laminated Glass Blast Resistant Glazing Systems To Blast Loading, Joshua Calnan

Theses and Dissertations--Mining Engineering

This thesis recounts the experimental study of the dynamic response of polycarbonate blast resistant glazing systems to explosive loading through the use of triaxial load cells, pressure sensors, and a laser displacement gauge. This instrumentation captured the response of the glazing systems to blast loading over three phases of testing. The first phase of testing characterizes the load distribution around the perimeter and the second phase examines the repeatability of the results. The final phase of testing pushes the samples to failure. The results are then compared to HazL, a commonly used blast resistant glazing system analysis software tool. The …

Analysis Of An Actuated Two Segment Leg Model Of Locomotion, Nikhil Vinayak Rao

Open Access Theses

Research studies on dynamic models of legged locomotion have generally focused on telescoping-type leg models. Such telescoping spring loaded inverted pendulum (SLIP) models have been able to accurately predict observed center of mass (CoM) trajectories. There have been comparatively fewer studies on dynamics of locomotion

with segmented legs. Some earlier studies on the dynamics due to leg segmentation appear straightforward. For example, a simple model with the only joint moment being due to a passive springy knee has been shown to behave similarly to a telescoping spring-mass model. However, in real-life animal locomotion, there are multiple joint-moments acting at the …

Orientation Controllable Epitaxial Vapor-Liquid-Solid Semiconductor Nanowire Synthesis On Silicon Substrate, Sung Hwan Chung

Open Access Dissertations

Semiconductor nanowires synthesized via the vapor-liquid-solid (VLS) mechanism have attracted extensive research interest in recent years owing to their unique structure as a promising candidate for the future electronic devices. Germanium and silicon nanowires, in particular, are compatible with the current silicon-based technology via direct assembly. However, one of the main challenges for the successful nanowire application in large-scale is the lack of the method for obtaining nanowires in desired positions and directions. Therefore, the comprehensive, systematic understanding of epitaxial nanowire growth and the more suitable method to align nanowires on novel structure are required. In this work, the synthesis …

Non-Equilibrium Pressure Control Of The Height Of A Large-Scale, Ground-Coupled, Rotating Fluid Column, R. L. Ash, I. R. Zardadhkan

Mechanical & Aerospace Engineering Faculty Publications

When a ground-coupled, rotating fluid column is modeled incorporating non-equilibrium pressure forces in the Navier-Stokes equations, a new exact solution results. The solution has been obtained in a similar manner to the classical equilibrium solution. Unlike the infinite-height, classical solution, the non-equilibrium pressure solution yields a ground-coupled rotating fluid column of finite height. A viscous, non-equilibrium Rankine vortex velocity distribution, developed previously, was used to demonstrate how the viscous and non-equilibrium pressure gradient forces, arising in the vicinity of the velocity gradient discontinuity that is present in the classical Rankine vortex model, effectively isolate the rotating central fluid column from …

Microstructure And Mechanical Properties Of Titanium Nitride Optical Coatings Made By Dc Magnetron Sputtering, Gustavo Martinez

Open Access Theses & Dissertations

Titanium nitride (TiNx) thin films were grown by DC (Direct Current) magnetron sputtering method onto Si(100) substrates by varying time of deposition to produce films with variable thickness (dTiN) in the range of 20-120 nm. The grown TiNx films were characterized by studying their structure, composition, and mechanical properties. Nuclear reaction analysis (NRA) combined with Rutherford backscattering spectrometry (RBS) analyses indicate that the grown films were stoichiometric TiN. Grazing incidence X-ray diffraction (GIXRD) measurements indicate that the texturing of the TiN films changes as a function of dTiN. The (111) and (002) peaks appear initially; with increasing dTiN, (111) becomes …