Cmk-3/Sulfur Composite (CXSY) And Room-Temperature Na/S Battery,
2013
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, No. 94 Weijin Road, Tianjin 300071, China;
Cmk-3/Sulfur Composite (CXSY) And Room-Temperature Na/S Battery, Qing Zhao, Yu-Xiang Hu, Kai Zhang, Li-Jiang Wang, Zhan-Liang Tao, Jun Chen
Journal of Electrochemistry
A series of ordered mesoporous carbon (CMK-3)/sulfur composite (CxSy) with different sulfur contents were synthesized via a melt-diffusion method. XRD, Raman, BET, SEM, and TEM techniques were used to characterize the structure and morphology of the as-prepared composite. The electrochemical performance of CMK-3/sulfur composite as the electrode of Na/S battery was tested at room temperature. Cyclic voltammograms show that one obvious reduction peak was located at about 1.61V, which is corresponding to the formation of Na2Sx (x=2~5), while two oxidation peaks were displayed at about 1.82V and 1.95V, which are belonging to the …
Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization,
2013
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China;
Preparation Of The Particle Size Controllable Lifepo4/C And Its Electrochemical Profile Characterization, Ming-E Wang, Jing-Yuan Liu, Meng-Yan Hou, Yong-Yao Xia
Journal of Electrochemistry
We adopted an effective route to prepare the particle size controllable core-shell structure carbon-coated LiFePO4 from different sized FePO4 precursors, varying from 80 nm, 200 nm and 1 μm by an in situ polymerization method integrated with a surface modification technology. The discharge capacities of the three sized LiFePO4/C are, respectively, 162 mAh·g-1, 142 mAh·g-1 and 92 mAh·g-1 at 0.1C rate. The nano-sized LiFePO4-a/C (80 nm) delivers a discharge capacity as large as 100 mAh·g-1 even at 30C, while the macroscopic LiFePO4-c/C (1 μm) exhibits a much …
Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method,
2013
Key Laboratory of Lithium Battery Materials of Jiangsu Province, Institute of Chemical Power Sources, Soochow University, Suzhou, 215006, Jiangsu, China;
Preparation And Electrochemical Properties Of Amorphous Znsno3/C By Hydrothermally Carbonization Method, Guo-Qing Fang, Rui-Xue Zhang, Wei-Wei Liu, Bing-Bo Xia, Hong-Dan Sun, Hai-Bo Wang, Jing-Jing Wu, Shinko Kaneko, De-Cheng Li
Journal of Electrochemistry
The amorphous ZnSnO3@C composite was synthesized via a simple glucose hydrothermal and subsequent carbonization approach. The structure, morphology and electrochemical property of the composite were characterized by XRD, TEM and electrochemical measurements. Compared to bare ZnSnO3, the ZnSnO3/C composite exhibited markedly enhanced lithium storage property and cycle performance, delivering a reversible capacity of 659 mAh·g-1 after 100 cycles at a current density of 100 mA·g-1.
Synthesis And Electrochemical Property Of Li2Fesio4/C Cathode Material By Solid State Method,
2013
School of Chemistry and Material Science, Guizhou Normal University, Guiyang 550001, Guizhou, China;
Synthesis And Electrochemical Property Of Li2Fesio4/C Cathode Material By Solid State Method, Jiao-Li Sun, Zhi-Jiao Chen, Yi-Xiao Li, Hu Cheng
Journal of Electrochemistry
Li2FeSiO4/C cathode material was synthesized using Li2SiO3 and FeC2O4 as raw materials by solid state method. The structure and morphology of the material were characterized by XRD and SEM. The electrochemical properties of the material were studied by constant-current cyclic testing. The results show that Li2FeSiO4/C has a good electrochemical performance. The first discharge capacity of Li2FeSiO4/C cathode material at 30oC reached 167 mAh∙g-1 when cycled at 10 mA∙g-1 between 1.5 and 4.8 V.
Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries,
2013
1. Department of Chemistry, Wuhan University, Wuhan, 430072, Hubei, China
Electrochemical Na-Storage Materials And Their Applications For Na-Ion Batteries, Jiang-Feng Qian, Xue-Ping Gao, Han-Xi Yang
Journal of Electrochemistry
Oncoming large scale electric energy storage (EES) requires battery systems not only to have sufficient storage capacity but also to be cost-effective and environmentally friendly. Li-ion batteries for widespread EES applications may be limited due to the constraint of global lithium resource. From the considerations of available resources and environmental impact, Na-ion batteries have potential advantages as next generation secondary batteries and an alternative to Li-ion batteries. However, in the present state of the art, the Na-storage cathodes reported so far are still deficient both in energy density and power capability, while the carbon and alloy anodes for Na-ion batteries …
Surface Composition Structure And Electrochemical Performance Of Aluminum Doped Lifepo4,
2013
College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, P. R. China;
Surface Composition Structure And Electrochemical Performance Of Aluminum Doped Lifepo4, Huai-Fang Shang, Wei-Feng Huang, Wang-Sheng Hu, Ding-Guo Xia, Zi-Yu Wu
Journal of Electrochemistry
Despite there are many successful reports about the preparation of electrode materials with surface coating for lithium ion batteries, the study in surface self-coating of cathode materials using segregation of doping elements and their electrochemical properties is still very rare. The LiFePO4 particles with rich-Al on the surface were synthesized by one step solvothermal route. TEM results demonstrated that the surface of the obtained LiFePO4 particles was well-covered by the amorphous coating. The soft X-ray absorption spectroscopy (XAS) and Auger electron spectroscopy (AES) component analyses revealed that the amorphous coating was composed of LiFe1-xAlxPO …
Modeling Reliability Growth In Accelerated Stress Testing,
2013
Air Force Institute of Technology
Modeling Reliability Growth In Accelerated Stress Testing, Jason K. Freels
Theses and Dissertations
Qualitative accelerated test methods improve system reliability by identifying and removing initial design flaws. However, schedule and cost constraints often preclude sufficient testing to generate a meaningful reliability estimate from the data obtained in these tests. In this dissertation a modified accelerated life test is proposed to assess the likelihood of attaining a reliability requirement based on tests of early system prototypes. Assuming each prototype contains an unknown number of independent competing failure modes whose respective times to occurrence are governed by a distinct Weibull law, the observed failure data from this qualitative test are shown to follow a poly-Weibull …
Characterization And Processing Evaluation Of Starch/High-Density Polyethylene Materials In Extrusion Blow Molding,
2013
Brigham Young University - Provo
Characterization And Processing Evaluation Of Starch/High-Density Polyethylene Materials In Extrusion Blow Molding, Bradley Dale Bacigalupi
Theses and Dissertations
The growing negative impacts of non-biodegradable plastics derived from non-renewable materials have created increasing interest throughout the world for new materials that are both biodegradable and renewable, that can be combined with or replace traditional plastics. Plant-based thermoplastic starch (TPS), a promising alternative material to traditional petroleum based resin, is both biodegradable and renewable and has great potential for use in plastic manufacturing processes. Two major obstacles that prevent more widespread use of TPS include; TPS base material, which is typically manufactured in a flake or powder, is incompatible with standard plastics production equipment that require pelletized resin, the second …
Influence Of Microstructure On The Propagation Of Fatigue Cracks In Inconel 617,
2013
Boise State University
Influence Of Microstructure On The Propagation Of Fatigue Cracks In Inconel 617, Benjiman Michael Albiston
Boise State University Theses and Dissertations
Inconel 617 is a candidate material for use in the intermediate heat exchanger of the Next Generation Nuclear Plant. Because of the high temperatures and the fluctuations in stress and temperature, the fatigue behavior of the material is important to understand. The goal of this study was to determine the influences of the microstructure during fatigue crack propagation. For this investigation, Inconel 617 compact tension samples, fatigue tested by Julian Benz at the Idaho National Laboratory, were obtained. The testing conditions included two environments at 650 °C (lab air and impure-He) and varied testing parameters including: loading waveform (triangular, trapezoidal), …
Me-Em Enewsbrief, December 2013,
2013
Michigan Technological University
Me-Em Enewsbrief, December 2013, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University
Department of Mechanical and Aerospace Engineering eNewsBrief
No abstract provided.
Mode I Fracture Toughness Of Eight-Harness-Satin Carbon Cloth Weaves For Co-Cured And Post-Bonded Laminates,
2013
California Polytechnic State University, San Luis Obispo
Mode I Fracture Toughness Of Eight-Harness-Satin Carbon Cloth Weaves For Co-Cured And Post-Bonded Laminates, Josh E. Smith
Master's Theses
Mode I interlaminar fracture of 3k 8-Harness-Satin Carbon cloth, with identical fill and weft yarns, pre-impregnated with Newport 307 resin was investigated through the DCB test (ASTM D5528). Crack propagations along both the fill and weft yarns were considered for both post-bonded (co-bonded) and co-cured laminates. A patent-pending delamination insertion method was compared to the standard Teflon film option to assess its applicability to mode I fracture testing. The Modified Beam Theory, Compliance Calibration method, and Modified Compliance Calibration method were used for comparative purposes for these investigations and to evaluate the validity of the proposed Equivalent Stiffness (EQS) method. …
Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate,
2013
University of Nebraska-Lincoln
Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate, Jason G. Vogeler
Department of Engineering Mechanics: Dissertations, Theses, and Student Research
Polycarbonate (PC) is a tough, transparent engineering thermoplastic. Its impact strength and ability undergo large plastic deformations without shatter make PC an ideal protective material for impact-resilient eyewear, aircraft windows and transparent armor. A good understanding of the response of this material to large deformations at high strain rates is critical for its utilization in these applications. To this end, a striker-less Kolsky bar device is employed in this work for the needed material characterization. The apparatus allow impulsive torsion and/or compression loadings with pulse durations sufficiently long for the plastic flow behavior to develop fully. Three new testing techniques …
Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate,
2013
University of Nebraska-Lincoln
Kolsky Bar Experiment For High-Rate Large Deformations Of Polycarbonate, Jason Gerald Vogeler
Department of Engineering Mechanics: Dissertations, Theses, and Student Research
Polycarbonate (PC) is a tough, transparent engineering thermoplastic. Its impact strength and ability undergo large plastic deformations without shatter make PC an ideal protective material for impact-resilient eyewear, aircraft windows and transparent armor. A good understanding of the response of this material to large deformations at high strain rates is critical for its utilization in these applications. To this end, a striker-less Kolsky bar device is employed in this work for the needed material characterization. The apparatus allow impulsive torsion and/or compression loadings with pulse durations sufficiently long for the plastic flow behavior to develop fully. Three new testing techniques …
Feasibility Of The Use Of Ultrasound Measurements For Grade Verification Of The Performance Grade Asphalt Binders,
2013
University of Nevada, Las Vegas
Feasibility Of The Use Of Ultrasound Measurements For Grade Verification Of The Performance Grade Asphalt Binders, Mehdi Khalili
UNLV Theses, Dissertations, Professional Papers, and Capstones
This research investigates the feasibility of application of high frequency immersion ultrasonic measurement (UM) to discriminate different performance grade (PG) asphalt binders. PG asphalt binder is one of the main components of hot mix asphalt used for roadway construction. UT may provide an inexpensive alternative to sophisticated tests currently used for quality control of PG asphalt binders. Nine different PG asphalt binders used were selected for this investigation. Velocity (V) and integrated response (IR) of the ultrasonic wave were measured. The IR is a measure of the ratio of ultrasonic energy transmitted into the material to the ultrasonic energy reflected …
Ergonomichandle And Articulating Laparoscopictool,
2013
Lincoln, NE
Ergonomichandle And Articulating Laparoscopictool, M. Susan Hallbeck, Dmitry Oleynikov, Kathryn Done, Tim Judkins, Allison Dimartino, Jonathan Morse, Lawton N. Verner
Department of Mechanical and Materials Engineering: Faculty Publications
The present invention relates to a laparoscopic apparatus. The apparatus includes a handle having a body portion, a top surface, opposite bottom surface, a proximal and distal end. The top surface of the base is contoured to compliment the natural curve of the palm. The apparatus further includes a shaft projecting from the distal end of the handle. The shaft has a proximal and distal end. A control sphere is located on the handle. The control sphere can be moved by one or more of a user's fingers to indicate direction. An end effector is located at the distal end …
Assessment Of The Effectiveness Of An Aid For The Development Of The Kinetic Skills Required For T.I.G. Welding,
2013
Maurice collins
Assessment Of The Effectiveness Of An Aid For The Development Of The Kinetic Skills Required For T.I.G. Welding, Maurice Collins, Robert Morris
Conference papers
This action research project was carried out in the Technological University Dublin, Ireland. The authors are both Lecturers of Engineering in this college and have a keen interest in providing the best possible aids to their students learning. Three groups of engineering apprentices and one group of part time students took part in this project. At the time these students were taking a third level Tungsten Inert Gas welding (T.I.G.) training module. Qualified T.I.G. welders are in very high demand worldwide and as such can demand a very high rate of pay for their services. The kinetic skills applicable to …
Scalar Differential Equation For Slowly-Varying Thickness-Shear Modes In At-Cut Quartz Resonators With Surface Impedance For Acoustic Wave Sensor Application,
2013
University of Nebraska-Lincoln
Scalar Differential Equation For Slowly-Varying Thickness-Shear Modes In At-Cut Quartz Resonators With Surface Impedance For Acoustic Wave Sensor Application, Huijing He, Jiashi Yang, John A. Kosinski
Department of Mechanical and Materials Engineering: Faculty Publications
For time-harmonic motions, we generalize a 2-D scalar differential equation derived previously by Tiersten for slowly-varying thickness-shear vibrations of AT-cut quartz resonators. The purpose of the generalization is to include the effects of surface acoustic impedance from, e.g., mass layers or fluids for sensor applications. In addition to the variation of fields along the plate thickness, which is considered in the usual 1-D acoustic wave sensor models, the equation obtained also describes in-plane variations of the fields, and therefore can be used to study the vibrations of finite plate sensors with edge effects. The equation is compared with the theory …
Synthesis Of Pani/Nihcf Nanocomposite Particles And Eqcm Measurement Of Ion Exchange Properties In Solutions Containing Cd2+,
2013
Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China;
Synthesis Of Pani/Nihcf Nanocomposite Particles And Eqcm Measurement Of Ion Exchange Properties In Solutions Containing Cd2+, Yu-Jiao Yang, Xiao-Gang Hao, Xu-Li Ma, Zhong-De Wang, Zhong-Lin Zhang, Nian-Chen Han
Journal of Electrochemistry
The PANI/NiHCF nanocomposite particles were synthesized on the CNTs-modified Pt substrate by one-step co-polymerization using cyclic voltammetry. Electrochemical quartz crystal microbalance (EQCM) technique was adopted to investigate the polymerization process of the nanocomposite particles and the mechanism of ion exchange in aqueous solution containing Cd2+． The morphology and structure of the as-prepared composite particles were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), and Fourier transform infrared spectroscopy (FT-IR). Combined with cyclic voltammetry (CV) and energy dispersive spectroscopy (EDS), the electrochemical behavior and the mechanism of ion exchange were also investigated in electrolytes of Cd2+ …
A Comparative Study In Pretreatments Of Acid Chemical Wastewater By Electrochemical Oxidation And Ozonation,
2013
College of Chemical Engineering and Materials Science, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310032,China;
A Comparative Study In Pretreatments Of Acid Chemical Wastewater By Electrochemical Oxidation And Ozonation, Han-Shui Liu, Su Yu, Shao-Ping Tong, Chun-An Ma
Journal of Electrochemistry
Under the condition of keeping certain acidity, the pretreatment efficiency of an acid chemical wastewater (pH 0.85) by electrochemical oxidation was compared with that by ozonation. The results showed that the electrochemical oxidation pretreatment could obtain a better result than the ozonation at pH 0.85. After the addition of 2 g·L-1 NaCl and with the electrochemical oxidation pretreatment at 30 mA·cm-2, the removal rate of chemical oxygen demand (CODCr) reached 43.4%, and the value of biochemical oxygen demand/chemical oxygen demand (BOD5/CODCr) also increased from 0.034 to 0.14 in 20 minutes, indicating significantly improvement …
Preparation Of Benzoquinone From Phenol By Electrooxidation,
2013
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China;
Preparation Of Benzoquinone From Phenol By Electrooxidation, Dong-Fang Niu, Cheng-Kai Yu, Xin-Sheng Zhang
Journal of Electrochemistry
The benzoquinone was prepared from phenol by electrooxidation in an H-type cell with cation exchange membrane, in which lead plates were used both as an anode and a cathode, while H2SO4 was used as a supporting electrolyte. The effects of current density, concentration of sulphuric acid, concentrations of benzoquinone in electrolyte and extractant on the yields and efficiencies of electrolysis were investigated. Under the optimized conditions of current density being 4 A·dm-2, concentration of sulphuric acid 1 mol·L-1, passed charge 3.2 A·h, the yield and current efficiency of benzoquinone could reach 68% and …
