Nanoscale Frictional Properties Of Nickel With One-Dimensional And Two-Dimensional Materials,
2016
University of Arkansas, Fayetteville
Nanoscale Frictional Properties Of Nickel With One-Dimensional And Two-Dimensional Materials, Timothy K. Schlenger
Mechanical Engineering Undergraduate Honors Theses
When looking at the nanoscale, material interface interactions have been observed to exhibit particularly interesting properties. Our research looks into various combinations of carbyne and graphene atop a nickel block to look into the interface friction properties between them. Both the carbyne and graphene are tested using steered molecular dynamics (SMD) in sheering and peeling directions along the surface of the nickel block. These tests are then analyzed by comparing the magnitude of the acting force versus the displacement of the carbon allotrope sample across the nickel block. It is found that as the width of a carbon allotrope sample …
Preparation And Performance Of 3d Graphene Type Porous Carbon Employing Nano Fe(Oh)3 As Template For Oxygen Reduction Catalyst,
2016
School of Chemical Engineering, Shandong University of Technology, Zibo 255049, Shandong, China
Preparation And Performance Of 3d Graphene Type Porous Carbon Employing Nano Fe(Oh)3 As Template For Oxygen Reduction Catalyst, Chong-Yun Sun, Zhong-Fang Li, Xue-Wei Lu, Xi-Zhan Zhong, Yu-Rong Liu
Journal of Electrochemistry
The 3D graphene type porous carbon was prepared using coal tar pitch as carbon source and nano Fe(OH)3 as template. Optimal conditions for the catalytic oxygen reduction performance were determined as: the mass ratio of coal tar, nano Fe(OH)3 and KOH is 6:8:4; the pyrolysis temperature is 800 oC. SEM images show that the products have uniformly porous structure. TEM images demonstrate that the products are porous with foam shapes. HRTEM images further indicate that the products have formed several-layers 3D graphene structure, which are also supported by XRD and Raman data, and the pore size mainly …
Special Issue: Electrocatalyst And Electrocatalysis In Fuel Cells Preface,
2016
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044, China;
Special Issue: Electrocatalyst And Electrocatalysis In Fuel Cells Preface, Zi-Dong Wei
Journal of Electrochemistry
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Recent Progress In Non-Precious Metal Oxygen Reduction Reaction Catalysts With An Encapsulation Structure,
2016
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;Laboratory of Advanced Power Sources, Changchun Institute of Applied Chemistry, Changchun 130022, China;
Recent Progress In Non-Precious Metal Oxygen Reduction Reaction Catalysts With An Encapsulation Structure, Mei-Ling Xiao, Jian-Bing Zhu, Chang-Peng Liu, Jun-Jie Ge, Wei Xing
Journal of Electrochemistry
Platinum-based materials, the state-of-the-art catalysts for fuel cells, suffer from prohibitive costs, limited resources and insufficient durability. Accordingly, tremendous efforts were made in searching for efficient, durable and inexpensive alternatives to precious-metal electrocatalysts for the oxygen reduction reaction (ORR). Transition-metals (Fe, Co)/nitrogen co-doped hybrids, heteroatom (N, P, S, F, et al) doped carbons and composites with transition-metals encapsulated in graphitic layers are reported as the most efficient non-precious metal ORR catalysts. Among the various non-precious metal ORR catalysts, transition-metals encased in graphitic layer catalysts are a novel type of catalysts for ORR with high activity and durability, and thus, the …
Mini-Review: Possible Applications Of Scanning Electrochemical Microscopy (Secm) In Characterizations Of Oxygen Reduction Reaction And Oxygen Evolution Reaction,
2016
School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, Liaoning, China;
Mini-Review: Possible Applications Of Scanning Electrochemical Microscopy (Secm) In Characterizations Of Oxygen Reduction Reaction And Oxygen Evolution Reaction, Xing-Xing Chen
Journal of Electrochemistry
Scanning electrochemical microscopy (SECM) has been proved to be a unique technique for combinatorial screening of localized phenomena for different electrocatalysts potentially used in new energy conversion and storage systems. This mini-review provides a brief summary of different SECM working modes, such as direct mode, feedback mode, generation-collection mode, redox competition mode and noise mode, which are especially applied for characterizing the oxygen reactions. Particularly, a series of important development in SECM screening of electrocatalysts for oxygen reduction reaction and oxygen evolution reaction from the author and W. Schuhmann’s group in Germany has been highlighted and overviewed. Finally, some prospects …
Multi-Scaled Carbon Supported Platinum As A Stable Electrocatalyst For Oxygen Reduction Reaction,
2016
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;University of Chinese Academy of Sciences, Beijing 100039, China;
Multi-Scaled Carbon Supported Platinum As A Stable Electrocatalyst For Oxygen Reduction Reaction, Yu-Ping Li, Lu-Hua Jiang, Su-Li Wang, Gong-Quan Sun
Journal of Electrochemistry
The stability of carbon supports is essential for electrocatalysts of fuel cells. Herein, the mesoporous carbon with the high graphitic degree (highly graphitic mesoporous carbon, HGMC) was synthesized by using resorcinol as the carbon precursor, SiO2 as the templates and urea as the reducing agent. The as-prepared HGMC was characterized by XRD, Raman spectroscopy, TEM, N2 adsorption. The stability of HGMC was evaluated by mimicking the start-up/shut-down conditions of fuel cells in a three-electrode system referring to the NREL standard. The obtained HGMC is of moderate surface area (187.4 m2•g-1) and is chemically stable under …
Recycling Mf Solid Waste Into Mesoporous Nitrogen-Doped Carbon With Iron Carbide Complex In Graphitic Layers As An Efficient Catalyst For Oxygen Reduction Reaction,
2016
College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093, China;Eco-materials Renewable Energy Research Center, Nanjing University, Nanjing 210093, China;
Recycling Mf Solid Waste Into Mesoporous Nitrogen-Doped Carbon With Iron Carbide Complex In Graphitic Layers As An Efficient Catalyst For Oxygen Reduction Reaction, Can-Yun Zhao, Lin Huang, Yong You, Ying-Fang Yao, Xiao-Gang Su, Hong Wan, Jian-Guo Liu, Cong-Ping Wu
Journal of Electrochemistry
Nitrogen-doped carbon materials with iron ions are known as catalytic growth agents for the oxygen reduction reaction (ORR) in fuel cells, but the design and synthesis of high-performance and low-cost catalysts still remain a significant challenge. Herein, we present a cost-effective approach to dispose of MF solid waste as the precursor for the synthesis of MCFes catalyst with the favorable structure features such as the high specific surface area, abundant active sites and suitable pore structure. The results showed that the MCFe-10/10/2 had specific surface area as high as 780.7 m2•g-1 and high efficient catalytic activity comparable …
Recent Progresses In Molybdenum-Based Electrocatalysts For The Hydrogen Evolution Reaction,
2016
Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China;
Recent Progresses In Molybdenum-Based Electrocatalysts For The Hydrogen Evolution Reaction, Ze-Xing Wu, Jie Wang, Jun-Po Guo, Jing Zhu, De-Li Wang
Journal of Electrochemistry
Electrochemical catalytic production of hydrogen has been considered as a promising and sustainable strategy for clean and renewable energy technologies. Molybdenum-based non noble metal catalysts for the hydrogen evolution reaction have attracted extensive attention due to its effective catalytic performance. In this review, the recent progresses in molybdenum-carbide, phosphide, nitride and sulfide electrocatalysts are presented. In addition, the strategies to improve the catalytic performance are analyzed and the prospects for the future development trends are expected.
Syntheses Of Carbon Paper Supported High-Index Faceted Pt Nanoparticles And Their Performance In Direct Formic Acid Fuel Cells,
2016
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China;
Syntheses Of Carbon Paper Supported High-Index Faceted Pt Nanoparticles And Their Performance In Direct Formic Acid Fuel Cells, Long Huang, Mei Zhan, Yu-Cheng Wang, Yan-Fen Lin, Shuo Liu, Ting Yuan, Hui Yang, Shi-Gang Sun
Journal of Electrochemistry
Direct formic acid fuel fuels (DFAFCs) are promising energy source for portable electronic devices. Palladium (Pd) is more active than platinum (Pt) for the formic acid electrooxidation. However, the stability of Pd is much poorer than that of Pt. Unfortunately, the ultra-low natural abundance of the Pt makes it extremely expensive and limits its application as a fuel cell catalyst. Boosting both the activity and stability of Pt nanoparticles to enhance their efficiency is urgent. As previous works illustrated, nanoparticles enclosed with high-index facets usually bare a higher activity toward fuel cell related reactions than those nanoparticles with low-index facet. …
Dynamic Simulation Of Oxygen Reduction Reaction In Pt/C Electrode For Proton Exchange Membrane Fuel Cells,
2016
State Key Laboratory of Advanced Technology for Materials Synthesis and Progressing, Hubei Fuel Cell Key Laboratory, Wuhan University of Technology, Wuhan 430070,China;
Dynamic Simulation Of Oxygen Reduction Reaction In Pt/C Electrode For Proton Exchange Membrane Fuel Cells, Shang Li, Fen Zhou, Lei Chen, Mu Pan
Journal of Electrochemistry
It is an urgent need to reduce the Pt loading in electrode for practical fuel cell applications worldwide. Herein, we theoretically investigate the oxygen distribution, generated current, and minimum Pt loading of Pt/C electrode for practical applications based on kinetic model of oxygen reduction reaction. The results indicate that with increasing electrode effective thickness to 40 mm, serious concentration polarization is expected for Pt/C electrode. To generate a power density of 1.4 W⋅cm-2 (2.1A⋅cm-2@0.67 V) for fuel cell, the cathode catalyst layer thickness in PEMFC should be as thin as 3 mm. The minimum Pt loading will …
Synthesis Of Structurally Ordered Platinum-Iron Catalysts With Enhanced Oxygen Reduction Reaction Activity,
2016
State Key Laboratory of Chemical Resource Engineering, School of Science, Beijing University of Chemical Technology, Beijing100029, China;
Synthesis Of Structurally Ordered Platinum-Iron Catalysts With Enhanced Oxygen Reduction Reaction Activity, Ye-Zheng Cai, Ming-Chuan Luo, Fang-Hui Wang, Zhao-Nan Sun, Hong Zhu
Journal of Electrochemistry
To improve oxygen reduction reaction catalytic activity of the precious metals platinum for fuel cell, the precursors of carbon-supported structurally disordered platinum-iron alloy (D-Pt3Fe/C and D-PtFe/C) catalysts with different compositions were synthesized via a modified polyol reduction method. Then, by optimizing the annealing conditions in the inert gas, we turned the structurally disordered platinum-iron alloy to the structurally ordered platinum-iron alloy (O-Pt3Fe/C and O-PtFe/C) catalysts. The structural characterizations of the as-prepared catalysts were performed by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), and X-ray photoelectron spectroscopy (XPS). The results …
Rambling Between "Zhong Yong" And "Catalysis",
2016
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044;
Rambling Between "Zhong Yong" And "Catalysis", Zi-Dong Wei
Journal of Electrochemistry
“Zhong Yong” represents a traditional Chinese wisdom, which was first proposed by Confucius and continuously richened by his followers. “Zhong Yong” pursues the balances among all kinds of contradictions, and insists that neither “too much” nor “not enough” is good. For a successful catalyst, on which the adsorption of reactants must be not so strong and not so weak either. On this point of view, there are the same pursuits for “Zhong Yong” and catalysis. In this paper, the author starts his story with a conversation between Confucius and his student, followed by 3 interesting stories happening in the ancient …
Nitrogen, Fluorine Co-Doped Silk-Derived Carbon For Electrochemical Oxygen Reduction With High Performance In Alkaline Solution,
2016
School of Chemical Engineering and Environment, Weifang University of Science and Technology, Shouguang, Shandong, 262700, China
Nitrogen, Fluorine Co-Doped Silk-Derived Carbon For Electrochemical Oxygen Reduction With High Performance In Alkaline Solution, Fang-Fang Liu, Hong-Liang Peng, Shi-Jun Liao
Journal of Electrochemistry
A high-performance, doped carbon-based catalyst was synthesized by pyrolyzing hydrothermally treated silkworm cocoon. The effects of preparation conditions and fluorine promotion on various catalysts’ performance were investigated. The catalyst prepared under optimal conditions and doped with nitrogen and fluorine possessed the high specific surface area of more than 1000 m2⋅g-1 and contained 3.5 and 7.3% (by mass, the same below) N and F, respectively. The activity of the catalyst toward oxygen reduction reaction in an alkaline medium was comparable to that of commercial Pt/C, showing both superior tolerance to methanol poisoning and better durability. Doping with fluorine …
Human-Assisted Fluid Power Vehicle,
2016
Western Michigan University
Human-Assisted Fluid Power Vehicle, Aaron Huntoon
Honors Theses
The rising cost of energy has prompted industrial and technology companies to research and implement renewable or green energy sources in every aspect of their business. This green technology can consist of sources such as: solar, wind, fluid, or others to create energy from renewable sources. The use of these various sources reduces the pollution associated with standard methods of energy development, and it will ultimately drive costs down to benefit the general population. One of the largest benefactors to the use of renewable energy sources is the transportation industry. Billions of people rely on various modes of transportation every …
Application Of Web Published Virtual Instruments In Delivering Engineering Instructions And Performing Experimental Research,
2016
Georgia Southern University
Application Of Web Published Virtual Instruments In Delivering Engineering Instructions And Performing Experimental Research, Shahnam Navaee
GS4 Student Scholars Symposium
In this presentation the special utility of the LabVIEW Virtual Instruments published as HTML files is documented and discussed. The Virtual Instruments (LabVIEW programs) created using the software's web publishing tool can be used to complement the effectiveness of the classroom instructions and extend the reach of engineering researchers in more effectively conducting laboratory and field experimentation. The Virtual Instruments (VIs) created as web documents can be placed on a web-server and made available to users at remote locations. These files can enhance the collaborations and interactions among individuals at these stations. For example, the created VIs for a course …
Emotion Recognition Using Fuzzy Clustering Analysis,
2016
Georgia Southern University
Emotion Recognition Using Fuzzy Clustering Analysis, Tejal Udhan
GS4 Student Scholars Symposium
This research project investigates using fuzzy clustering algorithms for emotion recognition. Emotion recognition has gained significant attention in recent years in applications such as artificial intelligence, human-computer interaction, speech and voice recognition. The ability of a computer or machine to understand human emotion and respond to users in a more human way can lead to significant advances in conversational speech recognition systems, improved quality of life in persons with speech disorders, such as Parkinson’s disease and even in voice response systems, such as Google Voice or Apple’s Siri. Experimental results in this area can inform discovery and innovation of machine …
Particle Boards Created From Modified Lignin,
2016
Georgia Southern University
Particle Boards Created From Modified Lignin, Robbie Kazen
GS4 Student Scholars Symposium
My name is Robert Kazen, a student directed under Dr. Rafael Quirino currently working on the Lignin Modification project. The research project involves the isolation of lignin from black liquor, a byproduct produced by the paper pulping industry. Isolated chemically the lignin was then modified using two methods, (1) acrylation acid and (2) transesterification with tung oil modifications. The black liquor obtained was sent by the Arizona Chemical and Herty Advanced Materials Development Center. Currently the tung oil modification gives the most valuable product physically and its products will be mainly used for particle board creation and testing. The tung …
Accelerated Insulation Recycling System (Airs),
2016
Georgia Southern University
Accelerated Insulation Recycling System (Airs), Debalina Ghosh
GS4 Student Scholars Symposium
Construction and demolition waste accounts for 52 % of the total landfilled space. While many advances in disassembly sequencing in buildings have been proposed to recycle concrete, steel, and tile associated with construction and demolition waste, the insulation contained within every building persists as a significant environmental challenge to recycle and reuse. Adding to this problem is the fact that when petroleum based foams are incinerated, it emits carbon monoxide, nitrogen oxides, isocyanine, acrylonitrile, and hydrogen cyanide in levels exceeding those allowed by the EPA, posing a significant threat to the environment and human health. Design for Disassembly (DfD) approach …
Warning Systems Evaluation For Overhead Clearance Detection,
2016
Georgia Southern University
Warning Systems Evaluation For Overhead Clearance Detection, Clayton Rogers
GS4 Student Scholars Symposium
The accurate detection of road vehicle heights is a need that arises in departments of transportation across the nation. Usually, this dimension is required to solve various transportation issues. In particular, numerous bridges in the state of Georgia have been affected by repetitive crashes of tall vehicles against their structural elements. As an example, a recent inspection report of the Houlihan Bridge over the Savannah River documents damages resulting from numerous hits by overheight vehicles. This case emphasizes the urgency of finding preventive measures. To address this issue, a number of solutions are investigated. The known methods of vehicle height …
Autonomous Methods In The Application Of Simple Swarm Capabilities,
2016
Georgia Southern University
Autonomous Methods In The Application Of Simple Swarm Capabilities, Joseph Watt Iii
GS4 Student Scholars Symposium
Swarm technology is a relatively new aspect to the drone industry. It involves multiple drones being able to communicate with each other and relay this back to the user. From this standpoint one operator can control all of them at once while only giving directions to one or more. This involves the use of different autonomous algorithms, similar to autopilot where programs fly the plane, that relay to one another on what adjustments to make or where to go. This idea is very useful in search and rescue operations where it might be too dangerous to insert a human. Also …
