Engineering Science and Materials Commons^™

An Overview Of The Development Of Cement-Based Batteries For The Cathodic Protection Of Embedded Steel In Concrete, Aimee Byrne, Niall Holmes, Brian Norton

Conference papers

This paper presents an overview of the cement-based batteries developed in DIT for use in the cathodic protection of embedded steel in reinforced concrete undergoing chloride-induced corrosion. Cathodic protection delivers an external current (approximately 20mA per m2 of embedded steel) which effectively polarises the internal current generated during corrosion. The batteries developed in DIT comprise of a cement-based electrolyte containing different additives including sand, aggregate, salts, carbon black and plasticiser with protruding anode and cathode metal plates. These batteries produced an initial electrical output of 1.5V and 23mA through a 10 resistor as measured using data acquisition units and a …

In Situ Microscopy Of The Self-Assembly Of Branched Nanocrystals In Solution, Eli Sutter, Peter Sutter, Alexei V. Tkachenko, Roman Krahne, Joost De Graaf, Milena Arciniegas, Liberato Manna

Department of Mechanical and Materials Engineering: Faculty Publications

Solution-phase self-assembly of nanocrystals into mesoscale structures is a promising strategy for constructing functional materials from nanoscale components. Liquid environments are key to self-assembly since they allow suspended nanocrystals to diffuse and interact freely, but they also complicate experiments. Real-time observations with single-particle resolution could have transformative impact on our understanding of nanocrystal self-assembly. Here we use real-time in situ imaging by liquid-cell electron microscopy to elucidate the nucleation and growth mechanism and properties of linear chains of octapod-shaped nanocrystals in their native solution environment. Statistical mechanics modelling based on these observations and using the measured chain-length distribution clarifies the …

Influence Of Shear Stress Magnitude And Direction On Atherosclerotic Plaque Composition, Ryan M. Pedrigi, Vikram V. Mehta, Sandra M. Bovens, Zahra Mohri, Christian Bo Poulsen, Willy Gsell, Jordi L. Tremoleda, Leila Towhidi, Ranil De Silva, Enrico Petretto, Rob Krams

Department of Mechanical and Materials Engineering: Faculty Publications

The precise flow characteristics that promote different atherosclerotic plaque types remain unclear. We previously developed a blood flow-modifying cuff for ApoE^−/− mice that induces the development of advanced plaques with vulnerable and stable features upstream and downstream of the cuff, respectively. Herein, we sought to test the hypothesis that changes in flow magnitude promote formation of the upstream (vulnerable) plaque, whereas altered flow direction is important for development of the downstream (stable) plaque. We instrumented ApoE^−/− mice (n=7) with a cuff around the left carotid artery and imaged them with micro-CT (39.6 μm resolution) eight to nine weeks …

Quantitative Assessment Of Secondary Flows Of Single-Phase Fluid Through Pipe Bends, Z. Kaldy, O. Ayala

Engineering Technology Faculty Publications

Single-phase fluid flow was simulated passing through various three dimensional pipe elbows. The simulations varied by Reynolds number, curvature ratios, and sweep angles and were all conducted using the k-e model available in COMSOL Multiphysics 5.1. The intent of this research was to qualitatively assess the flow characteristics under several different conditions. Many similarities were seen especially when comparing curvature ratios, the vorticity location for the turbulent cases show near identical behavior at the elbow midsection. One of the variables quantified in this paper is the maximum secondary velocity module which shows increasing values until the midsection of the elbow.

Liquid-Phase Exfoliation Of Two-Dimensional Graphite For Ink-Jet Printing, Monica Michel

Open Access Theses & Dissertations

Over the last decade, the study of two-dimensional (2D) materials has seen an incredible growth due to their unique thermal, mechanical and electronic properties. Solution phase manufacturing offers a way in which they can be produced at large scale by creating dispersions from the exfoliated material. Once created, different options for assembling devices exist. One technique for large scale manufacturing of materials in this form is ink-jet printing, which is a form of additive manufacturing that has proven to be attractive for the printed electronics industry. One challenge that ink-jet printing still faces is the shortage of inks with appropriate …

Fiberglass Goes Green: Developing Phosphate Glass For Use In Biodegradable Composites, Christina Lee Arendt

Open Access Theses & Dissertations

Composite materials, such as the glass fiber reinforced polyester thermosets known as "fiberglass," are used in many applications. However, recycling processes for these materials are inefficient and not widely available. Specially engineered degradable polymers offer an opportunity to redesign these composites. Additionally, the composite could be tailored to be multi-use, such that upon degradation, the resulting products could be used as part of a zeoponic substrate (artificial soil) for growing plants. Such a material would be beneficial for long-duration space missions, terraforming, or in other agricultural applications.

The research presented in this Dissertation focuses on developing phosphate glass for use …

Yttria Rich Tbcs As Candidates For Cmas Resistant Top Coats, Juan Jose Gomez

Open Access Theses & Dissertations

State of the art thermal barrier coatings (TBC) commonly made of 7-8 wt. % yttria stabilized zirconia (7YSZ) are used in modern gas turbines to generate a thermal protection to the underlying super alloy components. TBCs allow higher operating temperatures for hot gas path components, thus, generating higher engine efficiency. The infiltration of molten glassy mineral deposits composed of CaO-MgO-Al2O3-SiO2 (CMAS) represents one of the major threats in reducing performance and service life in aero and land based gas turbine engines. The CMAS deposits are ingested into the engine carried commonly in sand, runways debris, fly ash and volcanic ash. …

Improving The Engineering Properties Of Pla For 3d Printing And Beyond, Carmen R. Rocha

Open Access Theses & Dissertations

Additive manufacturing (AM), now more commonly known as 3D printing, has been classified as efficient, fast, and practical in the prototyping sector of product development. In the work presented here, we will use one of the AM techniques known as Material extrusion 3D printing (ME3DP), which has all the advantages of AM. However, one of the biggest challenges facing ME3DP technologies is the limitation of the range of materials used by this technique. Acrylonitrile butadiene styrene (ABS) and poly-lactic acid (PLA) are currently the most common thermoplastics materials used in ME3DP because of their ability to melt and be reprocessed. …

Development Of Enzyme-Free Hydrogen Peroxide Biosensor Using Cerium Oxide And Mechanistic Study Using In-Situ Spectro-Electrochemistry, Shashank Saraf

Electronic Theses and Dissertations

During recent development, it has been demonstrated that cerium oxide nanoparticles (CNPs) have exhibited catalytic activity which mimics naturally existing enzymes such as superoxide dismutase (SOD) and catalase. The underlying mechanism is attributed to the modulation of oxygen vacancies on CNPs lattice by dynamic switching of the oxidation states between Ce3+ and Ce4+ due to the electron transfer resulting from the redox reaction between CNPs and reactive oxygen species such as hydrogen peroxide (H2O2). Thereby the redox potential of CNPs is dependent on the surface chemistry i.e. the surface concentration of Ce3+ and Ce4+ Currently, the ratio of Ce3+/ Ce4+ …

Design Of Surface Chemical Reactivity And Optical Properties In Glasses, Antoine Lepicard

Electronic Theses and Dissertations

Thermal poling is a technique which involves the application of a strong DC electric field to a glass substrate heated below its glass transition temperature (Tg). Following the treatment, a static electric field is frozen inside the glass matrix, effectively breaking its centrosymmetry. Historically, this treatment has been used as a way to gain access to second order non-linear optical properties in glasses. However, recent efforts have shown that the treatment was responsible for structural changes as well as surface property modifications. Our study was focused on using this technique to tailor surface properties in oxide (borosilicate and niobium borophosphate) …

Automated Generation And Visualization Of Initial Construction Schedules From Building Information Models, Yibrah Weldemihret Weldu

LSU Doctoral Dissertations

Recent advances in digital technology have had a significant influence on the quality and speed of sharing and communicating project information in the architecture, engineering, and construction (AEC) industry. The process of acquiring the design intent in order to develop and communicate project schedules, as critical components of project delivery, have similarly been benefitting from such progress. With the relatively recent techniques of Building Information Modeling (BIM) and its capability to integrate the facility design with its construction schedule, meaningul strides have been made in improving the information flow and eventually visualizing the final schedule in 4D. However, the need …

Analysis And Management Of The Price Volatility In The Construction Industry, Alireza Joukar

LSU Doctoral Dissertations

The problem of price volatility as it pertains to material and labor is a major source of risk and financial distress for all the participants in the construction industry. The overarching goal of this dissertation is to address this problem from both viewpoints of risk analysis and risk management. This dissertation offers three independent papers addressing this goal. In the first paper using the Engineering News Record Construction Cost Index (ENR CCI), a predictive model is developed. The model uses General Autoregressive Conditional Heteroscedastic (GARCH) approach which facilitates both forecasting of the future values of the CCI, and capturing and …

Numerical Simulations Of Wind Effects On Wave Nonlinearity And Hurricane-Induced Sediment Transport On Louisiana Coast, Ke Liu

LSU Doctoral Dissertations

The objective of this study is to model wind effects on wave nonlinearity and the sediment suspension, transport and redistribution caused by hurricanes. The following questions are addressed through numerical simulations: (1) How do winds affect wave triad interactions and wave shape in the shallow water? (2) What is the role of hurricanes in coastal landscape evolution? Do they create more erosion or deposition? (3) Where does the observed post-hurricane deposition on coastal wetlands come from? First, wind effects were incorporated into a Boussinesq-type wave model, and evolution equations were derived for triad interactions with winds. Second, a coupled modeling …

Analysis Of Disruptions In The Gulf Of Mexico Oil And Gas Industry Supply Chain And Related Economic Impacts, Negar Dahitaleghani

LSU Doctoral Dissertations

Catastrophic events are human and economic tragedies in collaboration. Oil spills have enormous impacts on the local economy of the area and for the local labor markets. The Deepwater Horizon oil spill was caused by an explosion on semisubmersible drilling rig (Macondo) on April 20, 2010. Another regional disaster, Hurricane Katrina as it ripped over the core of the Gulf of Mexico producing zone, one of the most important oil and gas production region. With Geological complexities, continued of drilling and production in GoM increases the risk of having leak/spill. Therefore, the Econometrics methods, and Modeling to forecast impacts of …

Production Of Fermentable Sugars From Energy Cane Bagasse, Saeed Oladi

LSU Doctoral Dissertations

Lignocellulosic biomass contains cellulose and hemicellulose which are composed of hexose and pentose sugars. These sugars can be used in the sustainable production of fuels and chemicals. However, the recalcitrant nature of lignocellulosic biomass makes this conversion a challenging process. An effective pretreatment can remove lignin, solubilize the hemicellulose, decrease cellulose crystallinity, and prepare the biomass for enzymatic hydrolysis and conversion into green renewable chemicals. The research study presented in this dissertation addressed some of the challenges associated with the conversion of lignocellulosic biomass into green fuels and chemicals. This study was divided into three main goals. The first goal …

Internal Cooling Using Novel Swirl Enhancement Strategies In A Slot Shaped Single Pass Channel, Del Alan Segura

LSU Doctoral Dissertations

A series of heat transfer tests using a single pass slot shaped channel utilizing varying configurations of trapezoid shaped turbulence enhancement strip or varying configurations of high velocity jets issuing from side channels are studied. Thermochromatic Liquid Crystal techniques are used to determine local heat transfer coefficients, which are converted to normalized Nusselt values. The results show a marked improvement over traditional heat transfer enhancements used in the mid-span region of first stage turbine blades.

Deflector Effects In Fixed Bed (Biomass) Combustors And Non-Combusting Packed Beds, Babak Rashidian

Theses: Doctorates and Masters

Combustion can be used to thermally process biomass fuels and yield both heat and power in a sustainable manner. At present, direct combustion of solid biomass is the primary approach for generating electricity and heat when these fuels are used at a commercial scale.

Deflectors have been used in the freeboard section of industrial combustors to reduce radiant heat loss through flue gases and for particle emissions abatement. Freeboard deflectors can also influence emissions and freeboard temperature distributions by changing the flow dynamics. Despite much research into laboratory scale biomass combustion and packed beds, there have been no systematic studies …

Integration And Testing Of An Advanced Conformable Cng Tank In A Full-Sized Light-Duty Pickup, Abayomi Famuyiwa

Dissertations, Master's Theses and Master's Reports

Michigan Technological University is collaborating with Southwestern Energy and REL Inc. to develop and integrate a compressed natural gas (CNG) matrix tank that enables efficient packaging, increases range, and reduced cost for CNG vehicle applications. The vehicle being used in this project is a light-duty pickup truck to take advantage of the open space underneath the body and bed of the vehicle. With today’s cylindrical CNG tanks consuming cargo space, a solution is to develop a tank capable of being shaping to the underbody of the truck to free cargo space. University faculty and graduate students utilizes Finite Element Analysis …

Methodology For Analyzing Epoxy-Cnt Phononic Crystals For Wave Attenuation And Guiding, Madhu Kolati

Dissertations, Master's Theses and Master's Reports

Phononic crystals (PhnCs) control, direct and manipulate sound waves to achieve wave guiding and attenuation. This dissertation presents methodology for analyzing nanotube materials based phononic crystals to achieve control over sound, vibration and stress mitigation. Much of the analytical work presented is in identifying frequency band gaps in which sound or vibration cannot propagate through these PhnCs. Wave attenuation and mitigation analysis is demonstrated using finite element simulation. Engineering principles from current research areas of solid mechanics, solid-state physics, elasto-dynamics, mechanical vibrations and acoustics are employed for the methodology. A considerable effort is put to show that these PhnCs can …

Damage Tolerance And Assessment Of Unidirectional Carbon Fiber Composites, Mark David Flores

Open Access Theses & Dissertations

Composites are beginning to be used in a variety of different applications throughout industry. However, certification and damage tolerance is a growing concern in many aerospace and marine applications. Although compression-after-impact have been studied thoroughly, determining a damage tolerance methodology that accurately characterizes the failure of composites has not been established. An experimental investigation was performed to study the effect of stacking sequence, low-velocity impact response, and residual strength due to compression and fatigue. Digital Image Correlation (DIC) captured the strains and deformation of the plate due to compression. Computational investigations integrated non-destructive techniques (C-Scan, X-Ray) to determine the extent …