Acid Treated Carbon As Anodic Electrocatalysts Toward Direct Ascorbic Acid Alkaline Membrane Fuel Cells,
2018
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China;
Acid Treated Carbon As Anodic Electrocatalysts Toward Direct Ascorbic Acid Alkaline Membrane Fuel Cells, He-Mu Chen, Chen-Xi Qiu, Yuan-Yuan Cong, Hui-Yuan Liu, Zi-Hui Zhai, Yu-Jiang Song
Journal of Electrochemistry
In order to improve the hydrophilicity and electrocatalytic activity, commercial carbon black (BP 2000) was subjected to acid treatment to obtain acid-treated carbon (ATC). The generation of rich oxygen-containing groups on the surface of the ATC was proved by X-ray photoelectron spectra (XPS), Fourier transform-infra red spectra (FTIR), thermogravimetric analysis (TG) and contact angle measurement. UV-vis spectra were firstly recorded to calculate activation energy (Ea) of ascorbic acid (AA) chemical oxidation in alkaline conditions by oxygen in air and the Ea value was determined to be 37.1 kJ·mol-1. Additionally, electrochemical impedance spectra (EIS) were used to evaluate unprecedented …
Pd/C Catalysts For Co2 Electroreduction To Co:Pd Loading Effect,
2018
State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China;
Pd/C Catalysts For Co2 Electroreduction To Co:Pd Loading Effect, Dun-Feng Gao, Cheng-Cheng Yan, Guo-Xiong Wang, Xin-He Bao
Journal of Electrochemistry
Nanostructured heterogeneous catalysts have been widely used in the electrochemical carbon dioxide (CO2) reduction reaction (CO2RR), which can simultaneously achieve the electrocatalytic conversion of CO2 to fuels and the storage of renewable energy sources. Carbon supported palladium nanoparticles (Pd/C) catalysts have been previously reported to show excellent CO2RR performance. However, the crucial role of the metal loading in supported electrocatalysts has been rarely reported. In this work, we study the Pd loading effect on the structure of Pd/C catalysts as well as their activity and selectivity of CO2RR to CO. The …
Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell,
2018
The Key Laboratory of Fuel Cell Technology of Guangdong Province & The Key Laboratory of New Energy Technology of Guangdong Universities, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China;
Progress Of Self-Humidifying Membrane Electrode Assembly For Low Temperature Proton Exchange Membrane Fuel Cell, Bin Chi, Yue-Kun Ye, Shi-Jie Jiang, Shi-Jun Liao
Journal of Electrochemistry
The self/non-humidification membrane electrode assembly(SH-MEA)is an important pathway towards the self- humidification fuel cell and plays a crucial role for the large scale commercialization of low temperature proton exchange membrane fuel cell (LT-PEMFC), because it not only can reduce the volume and complexity of fuel cell system, resulting in the decrease of the cost, but also can improve the output power density of the fuel cell system. Currently, the researches on the self-humidifying MEA of LT-PEMFC mainly focus on three aspects: the preparation of self-humidification proton exchange membrane, the construction of self-humidification catalyst layer, and the construction of composite self-humidifying …
Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions,
2018
Department of Pharmaceutical Engineering, Zhejiang Pharmaceutical College, Ningbo 315100, Zhejiang, P.R. China;Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong 999077, P.R. China;Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering,Xiamen University, Xiamen 361005, Fujian, P.R. China.;
Palladium Adatoms On Gold Nanoparticles As Electrocatalysts For Ethanol Electro-Oxidation In Alkaline Solutions, Hui-Mei Chen, Shang-Qian Zhu, Jia-Le Huang, Min-Hua Shao
Journal of Electrochemistry
Palladium (Pd) is a good catalyst for ethanol electro-oxidation in alkaline solutions. The activity of Pd is further improved in this study by modifying the gold (Au) nanoparticles with Pd adatoms using a simple spontaneous deposition process. The Pd overlayer on the Au core (Au@Pd) is un-uniform with some Au atoms exposed to the electrolyte. The activity of Au@Pd/C toward ethanol oxidation reaction (EOR) is much higher than that of Pd/C in an alkaline solution. The peak current density of Au@Pd/C is 4.6 times higher than that of Pd/C with a 100 mV lower onset potential. The enhanced activity may …
Fuel Cells Reactor For Chemicals And Electric Energy Cogeneration,
2018
Shanghai Electrochemical Energy Devices Research Center, Department of Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, PR China;
Fuel Cells Reactor For Chemicals And Electric Energy Cogeneration, Zhi-Lin Heng, Xiao-Zi Yuan, Yi-Mei Yin, Zi-Feng Ma
Journal of Electrochemistry
As an energy conversion device, fuel cells can efficiently convert chemical energy into electrical energy. With the developing of technology, it is used as a reactor to conduct the synthesis of high value-added chemicals while generating electrical energy. Having benefits such as mild reaction conditions, controllability of the reaction process, high selectivity of the product, as well as high efficiency of energy utilization, it is widely used in many fields such as preparation of high value-added industrial products, gas separation, water treatment, etc. This paper introduces the current trends and statuses of fuel cell reactors in the cogeneration of chemicals …
Durability Performance Of The High-Power Fuel Cell System,
2018
Sunrise Power Co., ltd./National Engineering Research Center of FC&H2 Technology, Dalian, China, 116085;
Durability Performance Of The High-Power Fuel Cell System, Ke-Yong Wang, Wei-Yu Shi, Ren-Fang Wang, Jia Liu, Zhong-Jun Hou
Journal of Electrochemistry
Fuel cell durability is the crucial challenge in fuel cell vehicle, and the lifetime of more than 5000 hours is believed to be necessary for vehicle application. Few works on durability test of the full fuel cell system have been reported. In this work, the long lifetime HySYS-30 fuel cell system was developed in Sunrise Power based on the improved MEA durability and system control strategy. The durability performance of the system was investigated under vehicle duty cycle for more than 6000 hours, and only 8.1% performance loss was observed, implying that the durability of HySYS-30 fuel cell system could …
Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction,
2018
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China;
Recent Progress In Pt-Based Catalysts For Oxygen Reduction Reaction, Jing Li, Xin Feng, Zi-Dong Wei
Journal of Electrochemistry
One major challenge for a large-scale commercialization of the proton-exchange membrane fuel cells (PEMFCs) technologies that enable a shift to ‘zero-emission’ personal transportation, is the expensive and unstable Pt catalysts, which are mainly used to catalyze the sluggish kinetics of the oxygen reduction reaction (ORR) occurred on the air electrode of PEMFCs. Many research works have targets to improve the stability of Pt-based catalysts and to construct Pt/transitional metal alloys with low Pt loading amount. Herein, we provide a minireview for the Pt-based ORR catalysts based on our recent work, which covers a brief background introduction, the stability improvement of …
Facile Synthesis Of Pt-Cu Alloy Nanodendrites As High-Performance Electrocatalysts For Oxygen Reduction Reaction,
2018
Institute of Fuel Cells, School of Mechanical Engineering, MOE Key Laboratory of Power & Machinery Engineering;
Facile Synthesis Of Pt-Cu Alloy Nanodendrites As High-Performance Electrocatalysts For Oxygen Reduction Reaction, Liu-Xuan Luo, Guang-Hua Wei, Shui-Yun Shen, Feng-Juan Zhu, Chang-Chun Ke, Xiao-Hui Yan, Jun-Liang Zhang
Journal of Electrochemistry
Structures and compositions have significant effects on the catalytic properties of nanomaterials. Herein, a facile etching-based method was employed to synthesize Pt-Cu nanodendrites (NDs) with uniform and homogeneous alloy structures for enhancing oxygen reduction reaction (ORR). The formation of dendritic morphology was ascribed to the etching effect caused by the oxidative etchants of the Br-/O2 pair. The atomic ratio of Pt/Cu in Pt-Cu NDs could be easily tuned by altering the ratio of the Pt/Cu precursors, without deteriorating the dendritic morphology. The most active carbon-supported Pt1Cu1 NDs (Pt1Cu1 NDs/C) exhibited the …
Transport Logistics Of Transit Potential Of “Uzbekistan Temir Yullari” Jsc,
2018
O'zbekiston temir yo'llari Joint stock company
Transport Logistics Of Transit Potential Of “Uzbekistan Temir Yullari” Jsc, U.N. Ibragimov, O.T. Aliyev, M.M. Tohirov
Journal of Tashkent Institute of Railway Engineers
Uzbekistan occupies an important geostrategic position in Central Asia, through the territory of which the Great Silk Road, where numerous trade routes converged, was in ancient times, and an intensive process of mutual enrichment of the cultures of the peoples of the world was under way. And today, there are crossroads of transport routes leading from the East to the West, from the South to the North. For us, the task of preserving a place in international transport with the purpose of developing the efficiency of transportation must be urgent.
Optimization Of Useful Hard X-Ray Photochemistry,
2018
University of Nevada, Las Vegas
Optimization Of Useful Hard X-Ray Photochemistry, David Lewis Goldberger
UNLV Theses, Dissertations, Professional Papers, and Capstones
X-ray induced damage is generally considered a nuisance, but in the field of Useful Hard X-ray Photochemistry we harness the highly ionizing and penetrating properties of hard X-rays (> 7 keV) to initiate novel photochemical decomposition and synthesis at ambient and extreme conditions. Preliminary experiments suggest that the energy of irradiating photons and the sample pressure play roles in determining the nature of X-ray induced damage. Here, we present the X-ray energy dependence of damage induced in strontium oxalate, strontium nitrate, and barium nitrate, as well as the pressure dependence of X-ray induced damage of strontium oxalate. Our results indicate …
Multifunctional Nanocomposites Based On Bacterial Cellulose,
2018
Washington University in St. Louis
Multifunctional Nanocomposites Based On Bacterial Cellulose, Qisheng Jiang
McKelvey School of Engineering Graduate Student Theses & Dissertations
Cellulose is biodegradable, renewable, and abundant in nature thus cellulose (or paper)-based products can be inexpensively produced and recycled. Among cellulosic materials, bacterial nanocellulose (BNC) draws a special research attention due to the inherent three-dimensional nanofibrous structure, excellent mechanical flexibility, high purity and well-defined surface chemistry, and cost-efficient, scalable and environment-friendly synthesis. BNC can be biosynthesized by Gluconacetobacter xylinus, which is the most characterized BNC producer among various microorganisms. BNC is composed of highly pure cellulose nanofibrils, produced from well-defined dextrose through biochemical steps and subsequent self-assembling of the secreted cellulose fibrils which has the dimension ranges from 25 to …
Multifunctional Nanocomposites Based On Bacterial Cellulose,
2018
Washington University in St. Louis
Multifunctional Nanocomposites Based On Bacterial Cellulose, Qisheng Jiang
McKelvey School of Engineering Graduate Student Theses & Dissertations
Cellulose is biodegradable, renewable, and abundant in nature thus cellulose (or paper)-based products can be inexpensively produced and recycled. Among cellulosic materials, bacterial nanocellulose (BNC) draws a special research attention due to the inherent three-dimensional nanofibrous structure, excellent mechanical flexibility, high purity and well-defined surface chemistry, and cost-efficient, scalable and environment-friendly synthesis. BNC can be biosynthesized by Gluconacetobacter xylinus, which is the most characterized BNC producer among various microorganisms. BNC is composed of highly pure cellulose nanofibrils, produced from well-defined dextrose through biochemical steps and subsequent self-assembling of the secreted cellulose fibrils which has the dimension ranges from 25 to …
Reinventing The Wheel,
2018
California Polytechnic State University, San Luis Obispo
Reinventing The Wheel, Esther K. Unti, Ahmed Z. Shorab, Patrick B. Kragen, Adam M. Menashe
Mechanical Engineering
Reinventing the Wheel selected tires and designed wheels for the 2018 Cal Poly, San Luis Obispo Formula SAE combustion vehicle. Available tire options were evaluated for steady-state and transient performance as well as vehicle integration. A single-piece composite wheel with hollow spokes was designed to meet stiffness, strength, and tolerance requirements. A detailed study of wheel loading and geometric structural efficiency was performed. Finite element analysis was used to iterate the geometry and laminate. A two-piece male mold was designed and machined to manufacture the wheel. Removable silicone inserts were used to create the hollow spokes.
Simplified Approach For Structural Evaluation Of Flexible Pavements At The Network Level,
2018
University of Texas at Tyler
Simplified Approach For Structural Evaluation Of Flexible Pavements At The Network Level, Mena Souliman, Stefan Romanoschi, Samer Dessouky
Publications
Currently, there are few available simple procedures to identify structurally weak pavement sections utilizing Falling Weight Deflectometer (FWD) data at the network level (e.g., city, state or province). A simple method is required to determine the structural condition of pavement sections that can be directly implemented and automated in current pavement databases. The objective of this research study is to develop a simple analysis method to determine the structural condition of pavement sections utilizing the currently available non-destructive testing (NDT) deflection measurement devices at the network level that can be directly implemented and automated in the database of a typical …
Me-Em Enewsbrief, December 2018,
2018
Michigan Technological University
Me-Em Enewsbrief, December 2018, Department Of Mechanical Engineering-Engineering Mechanics, Michigan Technological University
Department of Mechanical and Aerospace Engineering eNewsBrief
No abstract provided.
Measuring Characteristic Shrinkage Variability Due To Metal Loading Effects In Low Temperature Co-Fired Ceramic Using Image Processing,
2018
University of Arkansas, Fayetteville
Measuring Characteristic Shrinkage Variability Due To Metal Loading Effects In Low Temperature Co-Fired Ceramic Using Image Processing, John Ezekiel Zumbro
Graduate Theses and Dissertations
Low temperature co-fired ceramic (LTCC) has many benefits when it comes to electronic packaging due to the low dielectric loss, reliability in extreme environments, and high breakdown voltage. Though the ceramic has a lot of benefits it is not widely used due to the high cost and complexities associated with manufacturing. One of these issues with manufacturing is compensating for the shrinkage of the ceramic, this is accomplished by using an expansion factor, creating the “green” or manufactured design. This expansion factor is approximated through knowledge of the ceramic factors such as the metal loading, layers of ceramic tape, firing …
Comparative Study Of Power Semiconductor Devices In A Multilevel Cascaded H-Bridge Inverter,
2018
University of Arkansas, Fayetteville
Comparative Study Of Power Semiconductor Devices In A Multilevel Cascaded H-Bridge Inverter, Kenneth Mordi
Graduate Theses and Dissertations
This thesis compares the performance of a nine-level transformerless cascaded H-bridge (CHB) inverter with integrated battery energy storage system (BESS) using SiC power MOSFETs and Si IGBTs. Two crucial performance drivers for inverter applications are power loss and efficiency. Both of these are investigated in this thesis. Power devices with similar voltage and current ratings are used in the same inverter topology, and the performance of each device is analyzed with respect to switching frequency and operating temperature. The loss measurements and characteristics within the inverter are discussed. The Saber® simulation software was used for the comparisons. The power MOSFET …
Analysis Of Casting Defect, Tensile Strength, And Hardness Of Al-Si Casting Alloy With Percentage Variation Of Clay Binder Bangkalan,
2018
Department of Mechanical Engineering, Faculty of Engineering, Universitas Negeri Malang, Bachelor Program, Mechanical Engineering Department, Universitas Negeri Malang
Analysis Of Casting Defect, Tensile Strength, And Hardness Of Al-Si Casting Alloy With Percentage Variation Of Clay Binder Bangkalan, Imam Muhtarom, Sunomo Sunomo
Journal of Mechanical Engineering Science and Technology (JMEST)
Casting is one of method that used in forming the work piece by melting specific metal and pouring into moulding that has been prepared. This study aimed to determine the effect of the use of Bangkalan clay as binder in sand moulding against tensile strength, hardness, and defects in Al-Si casting alloy by using gravity casting method. The method used in this study was experimental method then using descriptive analysis. Descriptive analysis included explanation of the test result of tensile strength, hardness, and the type of surface defect of Al-Si casting. Based on the research result obtained the highest shear …
Analysis Of Hardness, Quality And Fluidity Al-Si Casting Result By Using Clamshell (Placuna Placenta) As The Mixture Of Sand Moulding,
2018
Industrial Chemical Technology Program, Faculty of Science and Technology, Universiti Sains Islam Malaysia
Analysis Of Hardness, Quality And Fluidity Al-Si Casting Result By Using Clamshell (Placuna Placenta) As The Mixture Of Sand Moulding, Shikh Mohd Shahrul Nizan Shikh Zahari, Saif Aziz Saputra, Putut Murdanto
Journal of Mechanical Engineering Science and Technology (JMEST)
Metal is an element that cannot be separated from human life. Almost all of human activities includes metal element in it. Metals can be formed through several ways, one of which is metal casting. Metal casting is one of technique in producing products where the metal was melted in crucible and then poured in a moulding which is similar to the original shape of the product. Moulding that are commonly used are sand moulding. Commonly, binder which used in sand casting process is bentonite. Bentonite, was kind of mineral which can be run out during its usage. This study aimed …
Analysis Of Mechanical Properties And Permeability Of Sand Moulding By Using Eggshell In Sand Casting,
2018
Department of Mechanical Engineering, Faculty of Engineering, Universitas Negeri Malang, Bachelor Program; Mechanical Engineering Department, Universitas Negeri Malang
Analysis Of Mechanical Properties And Permeability Of Sand Moulding By Using Eggshell In Sand Casting, Wahyu Kurnianto, Poppy Puspitasari, Wahono Wahono
Journal of Mechanical Engineering Science and Technology (JMEST)
This study aimed to analyse the usage of Eggshell as mixture material of bentonite in metal casting process which used dried sand moulding. Eggshell variations in this study were 4%, 7%, 10% eggshell, and additional 3% of bentonite on each sample. This study used pre-experimental method and included to OneShot Case Study model. The highest strength was found on the sample 3 ES 10%. Tensile strength of dried sand moulding reach up to 0.09 kg/cm2, the compressive strength of dried sand moulding reached up to 3.11 kg/cm2, and the shear strength of dried sand moulding reached up to 1.13 kg/cm2. …
