Environmental Engineering Commons^™

Spatial And Temporal Patterns Of Mercury Accumulation In Lacustrine Sediments Across The Laurentian Great Lakes Region, Paul E. Drevnick, Daniel R. Engstrom, Charles T. Driscoll, Edward B. Swain, Steven J. Balogh

Civil and Environmental Engineering - All Scholarship

Data from 104 sediment cores from the Great Lakes and “inland lakes” in the region were compiled to assess historical and recent changes in mercury (Hg) deposition. The lower Great Lakes showed sharp increases in Hg loading c. 1850-1950 from point-source water dischargers, with marked decreases during the past half century associated with effluent controls and decreases in the industrial use of Hg. In contrast, Lake Superior and inland lakes exhibited a pattern of Hg loading consistent with an atmospheric source - gradual increases followed by recent (post-1980) decreases. Variation in sedimentary Hg flux among inland lakes was primarily attributed …

2011 Nebraska Water Monitoring Programs Report, Marty Link

Nebraska Department of Environmental Quality: Reports

The Nebraska Department of Environmental Quality (NDEQ) is charged with monitoring, assessing, and to the extent possible, managing the state’s water resources. The purpose of this work is to protect and maintain good quality water and encourage or execute activities to improve poor water quality. Monitoring is done on the over 18,000 miles of flowing rivers and streams, our greater than 280,000 acres of surface water in lakes and reservoirs, and the vast storage of groundwater in Nebraska’s aquifers.

Effects Of Nitrogen Deposition And Empirical Nitrogen Critical Loads For Ecoregions Of The United States, Linda H. Pardo, Mike E. Fenn, Christine L. Goodale, Linda. H. Geiser, Charles T. Driscoll, Edith B. Allen, Jill S. Baron, Roland Bobbink, Williams D. Bowman, Christopher M. Clark, Bridget Emmett, Frank S. Gilliam, Tara L. Greaver, Sharon J. Hall, Erik A. Lilleskov, Lingli Liu, Jason A. Lynch, Knute J. Nadelhoffer, Steven S. Perakis, Molly J. Robin-Abbott, John L. Stoddard, Kathleen C. Weathers, Robin L. Dennis

Civil and Environmental Engineering - All Scholarship

Human activity in the last century has led to a significant increase in nitrogen (N) emissions and atmospheric deposition. This N deposition has reached a level that has caused or is likely to cause alterations to the structure and function of many ecosystems across the United States. One approach for quantifying the deposition of pollution that would be harmful to ecosystems is the determination of critical loads. A critical load is defined as the input of a pollutant below which no detrimental ecological effects occur over the long-term according to present knowledge.

The objectives of this project were to synthesize …

Infrared-Based Measurements Of Velocity, Turbulent Kinetic Energy, And Dissipation At The Water Surface In A Tidal River, C. Chris Chickadel, Stefan A. Talke, Alexander R. Horner-Devine, Andrew T. Jessup

Civil and Environmental Engineering Faculty Publications and Presentations

Thermal infrared (IR) based particle image velocimetry (PIV) is used to measure the evolution of velocity, turbulent kinetic energy (TKE), and the TKE dissipation rate at the water surface in the tidally influenced Snohomish River. Patterns of temperature variability in the IR imagery arise from disruption of the cool skin layer and are used to estimate the 2D velocity field. Comparisons of IR based PIV mean velocity made against a collocated acoustic velocimeter demonstrate high correlation (r2 > 0.9). Over a tidal period, surface TKE computed from the IR velocity varies from 10-4 J·kg-1 to 3x10-3 J·kg-1, with an average difference …

Environmental Study Of Solid Waste Collection, Mousa Awad Maimoun

Electronic Theses and Dissertations

The growing municipal solid waste generation rates have necessitated more efficient, optimized waste collection facilities. The majority of the US collection fleet is composed of diesel-fueled vehicles which contribute significant atmospheric emissions including greenhouse gases. In order to reduce emissions to the atmosphere, more collection agencies are investigating alternative fuel technologies such as natural gas, biofuels (bio-gas and bio-diesel), and hybrid electric technology. This research is an in-depth environmental analysis of potential alternative fuel technologies for waste collection vehicles. This study will evaluate the use of alternative fuels by waste collection vehicles. Lifecycle emissions, cost, fuel and energy consumption were …

Mass Conservation Analysis For The Lower St. Johns River Using Continuous And Discontinuous Galerkin Finite Element Methods, Lillie E. Thomas

Electronic Theses and Dissertations

This thesis provides a mass conservation analysis of the Lower St. Johns River for the purpose of providing basis for future salinity transport modeling. The analysis provides an assessment of the continuous (CG) and discontinuous (DG) Galerkin finite element methods with respect to their mass conservation properties. The following thesis also presents a rigorous literature review pertaining to salinity transport in the Lower St. Johns River, from which this effort generates the data used to initialize and validate numerical simulations. Two research questions are posed and studied in this thesis: can a DG-based modeling approach produce mass conservative numerical solutions; …

Zinc Speciation In Power Plant Burning Mixtures Of Coal And Tires, Luis F.O. Silva, Marcos L.S. Oliveira, Carmen Serra, James C. Hower

Coal Combustion and Gasification Products Journal Archive

Fly ash from the cyclone-boiler co-combustion of high-S, high volatile bituminous coal and tire-derived fuel (tdf) was studied using a variety of chemical, optical, and microbeam techniques. Fly ash, dominated by Al-Si glass with lesser amounts of coalderived carbons, Fe-spinels, and tire-derived carbons, has Zn concentrations ranging from 2200 ppm (1st ESP row) to 6900 ppm Zn (3rd ESP row). Zinc occurs in Zn-rich nanoparticles in the Al-Si glass phases and as ZnO in amorphous and crystalline nanominerals, Fe- and Zn-sulfides, Pb-Al-Fe sulfates, and Zn sulfates. Iron-rich, Al- and Ti-bearing spinels contain accessory Zn2+,Cr3+,Mn2+, and Pb2+. Fe-sulfates and phosphates nanoparticles …

Co-Disposal Of Dry Fgd By-Product With Coal Gasification Ash And Inorganic Brines, Jabulani S. Mahlaba, P.C. Pretorius, Subal Maharajh, M.P. Augustyn

Coal Combustion and Gasification Products Journal Archive

There is a growing pressure from the environmental authorities and public bodies to reduce anthropogenic pollution. Stringent environmental legislation is being implemented for industries around the world, even more so for coal consuming industries. Control of gaseous emissions is one of the areas that are receiving considerable attention towards sustainable development. Coal combustion in coal-fired power utilities emits SO~x~ to the atmosphere. Dry flue gas desulphurisation (FGD) is a well known technology often used to mitigate sulphur emissions in coal-fired power utilities. It traditionally uses lime to neutralise SO~x~, and forms a mixture of anhydrite (CaSO~4~), and calcium sulphite (CaSO~3~). …

Magnetite Nanoparticles For Medical Mr Imaging, Zachary R. Stephen, Forrest M. Kievit, Miqin Zhang

Department of Agricultural and Biological Systems Engineering: Faculty Publications

Magnetic resonance imaging (MRI) has become one of the most widely used and powerful tools for non-invasive clinical diagnosis due to its high soft tissue contrast, spatial resolution, and penetration depth1. In addition, images are acquired without the use of ionizing radiation or radiotracers that would cause unwanted harmful side-effects. A considerable amount of research in medical MR imaging is focused on the development of contrast agents that can provide better delineation between healthy and diseased tissue. Magnetic nanoparticles (MNPs) are a major class of nanoscale material currently under extensive development for improved diagnosis of a wide range of diseases, …

A Multi-Analytical Approach To Understand The Chemistry Of Fe-Minerals In Feed Coals And Ashes, Marcos L.S. Oliveira, Frans Waanders, Luis F.O. Silva, Andre Jasper, Carlos H. Sampaio, Dursman Mchabe, Rachel S. Hatch, James C. Hower

Coal Combustion and Gasification Products Journal Archive

Seven feed coals used in the Brazilian power generation industry were obtained and subsequently analysed together with fly ash and bottom ash from a major Brazilian power plant. The samples were investigated by means of room temperature FeMo¨ssbauer analyses, X-ray diffraction, Raman spectroscopy, scanning electron microscope and petrographic analysis. In addition, nanometer-sized crystalline phases in coals and ashes were characterised using an energy-dispersive X-ray spectrometer and a high-resolution transmission electron microscope. The major identified Fe-bearing minerals in the coals were found to be actinolite, ankerite, chalcopyrite, chlorite, goethite, illite, ilmenite, magnesioferrite, natrojarosite, pyrite, pyrrhotite, and siderite; whilst in the fly …

Compositional Variations In Pilot Gasifier And Laboratory-Produced Slags And Their Impacts On Slag Viscosity And Coal Assessment, Alexander Ilyushechkin, Daniel Roberts, David Harris

Coal Combustion and Gasification Products Journal Archive

The flow behaviour of coal mineral matter at high temperatures is an important parameter for coal use in entrained-flow gasification technologies. Recently, gasification performance data was obtained from a series of pilot-scale gasification tests on a suite of well-characterised Australian black coals. Evaluation of the results of the pilot tests and the detailed laboratory investigations provided the opportunity for evaluation of the practical applicability of different laboratory and modelling techniques for coal assessment in terms of mineral matter behaviour in entrained flow gasification. A series of viscosity measurements was made over the range 1200–1600uC using slags produced in a pilot …

Compaction Of High-Ca Fly Ash-Al- And Al-Alloy-Composites: Evaluation Of Their Microstructure And Tribological Performance, Grigorios Itskos, Angeliki Moutsatsou, Pradeep K. Rohatgi, Nikolaos Koukouzas, Charalampos Vasilatos, Eleni Katsika

Coal Combustion and Gasification Products Journal Archive

In this study, highly calcareous and siliceous fly ash particles were utilized for the fabrication of Al- and Al-alloy-based MetalMatrix Composites (MMCs) by means of powder metallurgy. After compacting and sintering Al and Al/Si powders containing 10, 15, and 20wt. % ash particles, the homogenous (and with minimal amount of voids) microstructure of the produced composites was verified by means of Scanning Electron Microscopy (SEM). The composites were tested for their dry sliding wear behavior using a pin-on-disc machine against spheres of alumina. The worn surfaces of composites were then examined by using SEM and Energy Dispersive X-Ray Spectroscopy (EDS). …

Influence Of Chemical Reagents On Rheological Properties Of Fly Ash-Water Slurry At Varying Temperature Environment, H.K. Nail, M.K. Mishra, Karanam U.M. Rao

Coal Combustion and Gasification Products Journal Archive

About 70% of total electrical energy is generated from thermal power plants in India which in turn release about 160 Mt of fly ash as solid waste annually. Transportation and disposal of such a huge amount of fly ash is a major problem faced by the power plants. Presently fly ash is transported as lean slurry in pipe lines requiring about 80 to 85% of water with high energy input. A major impediment in high volume transportation of fly ash is its high specific gravity as compared to that of water. The objective of the present study was to evaluate …

Impact Of Manufactured Coal Ash Aggregates On Water Quality During Open Pit Restoration: 1. A Statistical Screening Test, Sangchul Hwang, Isomar Latorre

Coal Combustion and Gasification Products Journal Archive

Utilization of manufactured coal ash aggregates (MAs) as a subsoil substitute during restoration of an open pit was assessed in a three-factor, two-level factorial analysis. The factors of interest were the MA application rate (2:1 or 1:2 topsoil/MA volume ratio), rainfall intensity (high or low), and aggregate size (2.36–4.75 mm or 4.75–9.53 mm). Among the water quality parameters examined (pH, turbidity, heavy metal content (lead and cadmium), conductivity, and hardness), the last two parameters were significantly higher (p,0.05) in soil amended with MAs than in a control reactor using sand. A low rainfall intensity and larger aggregate size resulted in …

The Leachability Of Major Elements At Different Stages Of Weathering In Dry Disposed Coal Fly Ash, S.A. Akinyemi, A. Akinlua, W.M. Gitari, R.O. Akinyeye, L.F. Petrik

Coal Combustion and Gasification Products Journal Archive

Large quantities of solid residue are generated by coal-fired power stations in many parts of the World. The disposal and management of the unused fly ash remains a major problem to the environment. The weathered dry disposed ash cores comprise of major element constituents such as Al, Si, Ca, Mg, Fe, Mn, Na+ and K+. The mobility patterns and mineralogical associations of major elements in weathered dry disposed ash dumps aged 1-year-old, 8-year-old and 20-year-old from a coalfired power station in South Africa were investigated using a modified sequential extraction scheme. The extraction sequence was as follows: (1) water soluble, …

The Impact Of Driving Conditions On Phev Battery Performance, Nathan Christensen, John Patten, Steven Srivastava, Gary P. Nola

Green Manufacturing Research Journal

The battery performance of a modified Prius with a 5 kWh plug-in battery was documented for a year to determine the impact of environmental conditions and user attributes on vehicle performance.  Both fuel economy and pure electrical efficiency were compared to ambient temperature.  The fuel economy has a positive relationship with ambient temperature until approximately 70˚F where the efficiency begins to drop.  Electrical performance has a positive linear relationship with ambient temperature.  With the emergence of electric vehicles (EVs) and PHEVs from a variety of automotive manufacturers, information on EV and PHEV performance for consumers will become more important.

Biodegradation Kinetics For 1,2-Dichloroethane And Ethylene Dibromide In Anaerobic Enrichment Cultures Grown On Each Compound, Rong Yu

All Theses

1,2-Dichloroethane (DCA) and ethylene dibromide (EDB) are among the top 15 chlorinated aliphatic compounds on the Agency for Toxic Substances and Disease Registry's Priority List of Hazardous Substances. Co-contamination of groundwater with EDB and 1,2-DCA resulted mainly from environmental releases of leaded gasoline; these compounds were added as lead scavengers. A microcosm study by Henderson et al. with soil and groundwater from a site contaminated with leaded gasoline demonstrated anaerobic biodegradation of EDB at a higher rate, and to a greater extent, than 1,2-DCA. Both compounds were transformed mainly by dihaloelimination to ethene. The objectives of this study were to …

A 2009 Mobile Source Emissions Inventory Of The University Of Central Florida, Johanna Marie Clifford

Electronic Theses and Dissertations

This thesis reports on the results of a mobile source emissions inventory for the University of Central Florida (UCF). For a large urban university, the majority of volatile organic compounds (VOC), oxides of nitrogen (NOx), and carbon dioxide (CO2) emissions come from onroad sources: personal vehicles and campus shuttles carrying students, faculty, staff, and administrators to and from the university, as well as university business trips. In addition to emissions from daily commutes, non-road equipment such as lawnmowers, leaf blowers, small maintenance vehicles, and other such equipment utilized on campus contributes to a significant portion to the total emissions from …

Scenario Generation And Climate Change Modelling Of Nitrous Oxide Emissions From Grasslands In Ireland, Mark Cochrane

Theses

Described as a two-year study in relation to nitrous oxide emissions from agricultural grassland in the Republic of Ireland under a set or climate and environmental policy scenarios. Nitrous oxide is a greenhouse gas, with a global warning potential approximately three hundred times that or carbon dioxide. lt is required under the Kyoto Protocol that national inventories or all greenhouse gas emissions are established. The Intergovernmental Panel on Climate Change (IPCC) Tier approach is designed to establish current inventories of greenhouse gas emissions; however a scenario approach is also employed in order to estimate emissions in future years. Scenario sets …

The Optimum Energy Crop In Ireland For Biofuel, Eoin Deasy

Theses

The motivation for this research stems from the potential of biofuels to assist Ireland in meeting obligations outlined in the 'Renewable Energy Source Directive' (2009/28/EC) and to reduce dependency on fossil fuels. The purpose of this work is to establish the merits of biofuel production Ireland ,with a keen focus on the technical, economic and environmental aspects of each. The three biofuel options investigated are biodiesel, bioethanol and biomethane. Eight crop varieties were investigated, these include; wheat, oats, barley, OSR, maize silage, sugar beet, grass silage and potatoes. The approach taken within this thesis was to perform a life cycle …