Oceanography and Atmospheric Sciences and Meteorology Commons^™

National Climate Change Action Plan 2013 - 2017, Government Of Kenya

East Africa

In recognition of the serious threats posed by climate change my Government has taken and continues to take bold measures to secure the country’s development against the risks and impacts of climate change. The Constitution of Kenya provides for maintenance of at least ten per cent tree cover of the land area. The Kenya Vision 2030 targets the planting of at least seven billion trees to address food, water and energy security. During the last ten (10) years, Kenya has been able to restore 6% of forest cover. There are clear indications we will be able to attain the 10% …

Uncertainties In Modelling Heterogeneous Chemistry And Arctic Ozone Depletion In The Winter 2009/2010, I. Wohltmann, T. Wegner, R. Müller, R. Lehmann, M. Rex, G. L. Manney, M. L. Santee, P. Bernath, O. Suminska-Ebersoldt

Chemistry & Biochemistry Faculty Publications

Stratospheric chemistry and denitrification are simulated for the Arctic winter 2009/2010 with the Lagrangian Chemistry and Transport Model ATLAS. A number of sensitivity runs is used to explore the impact of uncertainties in chlorine activation and denitrification on the model results. In particular, the efficiency of chlorine activation on different types of liquid aerosol versus activation on nitric acid trihydrate clouds is examined. Additionally, the impact of changes in reaction rate coefficients, in the particle number density of polar stratospheric clouds, in supersaturation, temperature or the extent of denitrification is investigated. Results are compared to satellite measurements of MLS and …

Advances In Marine Ecosystem Dynamics From Us Globec: The Horizontal-Advection Bottom-Up Forcing Paradigm, Emanuele Di Lorenzo, David Mountain, Harold Batchelder, Nicholas Bond, Eileen E. Hofmann

CCPO Publications

A primary focus of the US Global Ocean Ecosystem Dynamics (GLOBEC) program was to identify the mechanisms of ecosystem response to large- scale climate forcing under the assumption that bottom-up forcing controls a large fraction of marine ecosystem variability. At the beginning of GLOBEC, the prevailing bottom-up forcing hypothesis was that climate-induced changes in vertical transport modulated nutrient supply and surface primary productivity, which in turn affected the lower trophic levels (e.g., zooplankton) and higher trophic levels (e.g., fish) through the trophic cascade. Although upwelling dynamics were confirmed to be an important driver of ecosystem variability in GLOBEC studies, the …

Investigations For Utilizing Pteropods As Bioindicators Of Environmental Change Along The Western Antarctic Peninsula, Paul Mark Suprenand

USF Tampa Graduate Theses and Dissertations

Pteropods are holoplanktonic gastropod molluscs found globally. Although species diversity is greater at lower latitudes, species abundance is greater at temperate and polar latitudes. Declines in pteropod populations have not only been correlated to declines of their major predators, but pteropods have also been used as bioindicators of global environmental changes such as ocean acidification. With high latitude abundances, pteropods provide significant sustenance for species such as the Atlantic salmon in the Atlantic Ocean and Pleuragramma antarcticum in the Southern Ocean. Because pteropods eat phytoplankton and other pteropods, factors that affect pteropod abundance influence many trophic levels. This dissertation explores …

Meta-Analysis Reveals Complex Marine Biological Responses To The Interactive Effects Of Ocean Acidification And Warming, Ben P. Harvey, Dylan Gwynn-Jones, Philippa J. Moore

Research outputs 2013

Ocean acidification and warming are considered two of the greatest threats to marine biodiversity, yet the combined effect of these stressors on marine organisms remains largely unclear. Using a meta-analytical approach, we assessed the biological responses of marine organisms to the effects of ocean acidification and warming in isolation and combination. As expected biological responses varied across taxonomic groups, life-history stages, and trophic levels, but importantly, combining stressors generally exhibited a stronger biological (either positive or negative) effect. Using a subset of orthogonal studies, we show that four of five of the biological responses measured (calcification, photosynthesis, reproduction, and survival, …

Toward A Phen(Omen)Ology Of The Seasons: The Emergence Of The Indigenous Weather Knowledge Project (Iwkp), John Charles Ryan

Research outputs 2013

Since European settlement, the Western calendar has insufficiently accounted for the seasonal nuances and multiple temporalities of Australia. Beginning with Tim Entwistle’s recent proposal to revise the four-season Australian norm, this article traces the emergence of the Western calendar in Europe and its institutionalization ‘Down Under.’ With its emphasis on land-based calendars, the Indigenous Weather Knowledge Project (IWKP) is a partnership between Aboriginal communities and the Bureau of Meteorology aimed at preserving and promoting knowledge of the endemic seasons of Australian regions. As the most recent addition to the IWKP, the six-season Nyoongar calendar of the South-West of Western Australia …

Millennial Scale Impact On The Marine Biogeochemical Cycle Of Mercury From Early Mining On The Iberian Peninsula, Oscar Serrano Gras, A. Martinez-Cortizas, M. A. Mateo, H. Biester, R. Bindler

Research outputs 2013

The high-resolution mercury record of a Posidonia oceanica mat in the northwest Mediterranean provides an unprecedented testimony of changes in environmental mercury (Hg) loading to the coastal marine environment over the past 4315 yr BP. The period reconstructed made it possible to establish tentative preanthropogenic background Hg levels for the area (6.8!1.5 ng g–1 in bulk sediments). A small, but significant, anthropogenic Hg increase was identifiable by ~2500 yr BP, in agreement with the beginning of intense mining in Spain. Changes in the record suggest four major periods of anthropogenic Hg pollution inputs to the Mediterranean: first, during the Roman …

Tropical Cyclone Intensity Estimation Using Temporal And Spatial Features From Satellite Data, Gholamreza Fetanat Haghighi

Dissertations

Accurate intensity estimation of tropical cyclones (TC) is an important topic of research due to its economic impact and public safety concerns. An accurate measure of the current wind strength is necessary to accurately predict TC intensity. We have developed and tested automated method to estimate TC intensity based on the existing historical satellite images alone. The Hurricane Satellite data (HURSAT-B1) is used to develop the algorithm, which focuses on the North Atlantic from 1978-2009. The algorithm is trained and validated using aircraft reconnaissance-based data. Here, the data is restricted to include only fixes that are over water and are …

Production Mechanisms, Number Concentration, Size Distribution, Chemical Composition, And Optical Properties Of Sea Spray Aerosols, Nicholas Meskhidze, Markus D. Petters, Kostas Tsigaridis, Tim Bates, Colin O'Dowd, Jeff Reid, Ernie R. Lewis, Brett Gantt, Magdalena D. Anguelova, Prakash V. Bhave, Andrew Wozniak

Chemistry & Biochemistry Faculty Publications

(First paragraph)

The impact of sea spray aerosols on global climate remains one of the most uncertain components of the aerosol–radiation–climate problem, but has received less attention than the impacts of terrestrial and anthropogenic aerosols. The last decade has produced a large body of information regarding the sources and composition of marine aerosols, resulting in a reassessment of the complex role that sea spray particles play in climate and various geophysical phenomena. As sea spray aerosol contributes substantially to the preindustrial, natural background which provides the baseline on top of which anthropogenic forcing should be quantified, and because the ocean …

Ace-Fts Observations Of Acetonitrile In The Lower Stratosphere, J. J. Harrison, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

This work reports the first infrared satellite remote-sensing measurements of acetonitrile (CH₃CN) in the Earth's atmosphere using solar occultation measurements made by the Atmospheric Chemistry Experiment Fourier transform spectrometer (ACE-FTS) between 2004 and 2011. The retrieval scheme uses new quantitative laboratory spectroscopic measurements of acetonitrile (Harrison and Bernath, 2012). Although individual ACE-FTS profile measurements are dominated by measurement noise, median profiles in 10 degrees latitude bins show a steady decline in volume mixing ratio from similar to 150 ppt (parts per trillion) at 11.5 km to < 40 ppt at 25.5-29.5 km. These new measurements agree well with the scant available air-and balloon-borne data in the lower stratosphere. An acetonitrile stratospheric lifetime of 73 ± 20 yr has been determined.

Quantifying The Impact Of Boreal Forest Fires On Tropospheric Oxidants Over The Atlantic Using Aircraft And Satellites (Bortas) Experiment: Design, Execution And Science Overview, P. I. Palmer, M. Parrington, J. D. Lee, A, C. Lewis, A. R. Rickard, P. F. Bernath, T. J. Duck, D. L. Waugh, D. W. Tarasick, S. Andrews

Chemistry & Biochemistry Faculty Publications

We describe the design and execution of the BORTAS (Quantifying the impact of BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites) experiment, which has the overarching objective of understanding the chemical aging of air masses that contain the emission products from seasonal boreal wildfires and how these air masses subsequently impact downwind atmospheric composition. The central focus of the experiment was a two-week deployment of the UK BAe-146-301 Atmospheric Research Aircraft (ARA) over eastern Canada, based out of Halifax, Nova Scotia. Atmospheric ground-based and sonde measurements over Canada and the Azores associated with the planned …

Improved Method For Quantifying The Air-Sea Flux Of Volatile And Semi-Volatile Organic Carbon, Emily Hauser, Rebecca M. Dickhut, Renee Falconer, Andrew S. Wozniak

Chemistry & Biochemistry Faculty Publications

A method for quantifying the diffusive air-sea exchange of gaseous organic carbon (OC) was developed. OC compounds were separated into two operational pools-those that were kinetically air limited in diffusion across the air-sea interface and those that were water limited-during simultaneous air/water sampling. The method separates OC compounds into low Henry's law constant (low-H) semivolatile OC (SOC) and high Henry's law constant (high-H) volatile OC (VOC) pools that can be categorized by relating diffusion kinetic parameters to Henry's Law constant. Air limited (low-H; H << similar to 0.1 L atm mol(^-1)) compounds were collected in pure water traps and were quantified as dissolved OC, whereas …

Ace-Fts Observations Of Pyrogenic Trace Species In Boreal Biomass Burning Plumes During Bortas, K. A. Tereszchuk, G. G. Abad, C. Clerbaux, J. Hadji-Lazaro, D. Hurtmans, P. F. Coheur, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

To further our understanding of the effects of biomass burning emissions on atmospheric composition, the BORTAS campaign (BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites) was conducted on 12 July to 3 August 2011 during the boreal forest fire season in Canada. The simultaneous aerial, ground and satellite measurement campaign sought to record instances of boreal biomass burning to measure the tropospheric volume mixing ratios (VMRs) of short- and long-lived trace molecular species from biomass burning emissions. The goal was to investigate the connection between the composition and the distribution of these pyrogenic outflows and …

Stratospheric Lifetimes Of Cfc-12, Ccl4, Ch4, Ch3cl And N20 From Measurements Made By The Atmospheric Chemistry Experiment-Fourier Transform Spectrometer, A. T. Brown, C. M. Volk, M. R. Schoebert, C. D. Boone, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Long lived halogen-containing compounds are important atmospheric constituents since they can act both as a source of chlorine radicals, which go on to catalyse ozone loss, and as powerful greenhouse gases. The long-term impact of these species on the ozone layer is dependent on their stratospheric lifetimes. Using observations from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) we present calculations of the stratospheric lifetimes of CFC-12, CCl₄, CH₄, CH₃Cl and N₂O. The lifetimes were calculated using the slope of the tracer-tracer correlation of these species with CFC-11 at the tropopause. The …

Harmonized Dataset Of Ozone Profiles From Satellite Limb And Occultation Measurements, V. F. Sofieva, N. Rahpoe, J. Tamminen, E. Kyrölä, N. Kalakoski, M. Weber, A. Rozanov, C. Von Savigny, A Laeng, T. Von Clarmann, P. Bernath, R. J. Hargreaves

Chemistry & Biochemistry Faculty Publications

In this paper, we present a HARMonized dataset of OZone profiles (HARMOZ) based on limb and occultation measurements from Envisat (GOMOS, MIPAS and SCIAMACHY), Odin (OSIRIS, SMR) and SCISAT (ACE-FTS) satellite instruments. These measurements provide high-vertical-resolution ozone profiles covering the altitude range from the upper troposphere up to the mesosphere in years 2001-2012. HARMOZ has been created in the framework of the European Space Agency Climate Change Initiative project. The harmonized dataset consists of original retrieved ozone profiles from each instrument, which are screened for invalid data by the instrument teams. While the original ozone profiles are presented in different …

Validation Of Stratospheric And Mesospheric Ozone Observed By Smiles From International Space Station, Y. Kasai, H. Sagawa, D. Kreyling, E. Dupuy, P. Baron, J. Mendrok, K Suzuki, T. O. Sato, T. Nishibori, S. Mizobuchi, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

We observed ozone O₃ in the vertical region between 250 and 0.0005 hPa (~ 12-96 km) using the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES) on the Japanese Experiment Module (JEM) of the International Space Station (ISS) between 12 October 2009 and 21 April 2010. The new 4K superconducting heterodyne receiver technology of SMILES allowed us to obtain a one order of magnitude better signal-to-noise ratio for the O₃ line observation compared to past spaceborne microwave instruments. The non-sun-synchronous orbit of the ISS allowed us to observe O₃ at various local times. We assessed the quality of the vertical …

The Relation Between Atmospheric Humidity And Temperature Trends For Stratospheric Water, S. Fueglistaler, Y. S. Liu, T. J. Flannaghan, P. H. Haynes, D. P. Dee, W. J. Read, E. E. Remsberg, L. W. Thomason, D. F. Hurst, J. R. Lanzante, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

We analyze the relation between atmospheric temperature and water vapor-a fundamental component of the global climate system-for stratospheric water vapor (SWV). We compare measurements of SWV (and methane where available) over the period 1980-2011 from NOAA balloon-borne frostpoint hygrometer (NOAA-FPH), SAGE II, Halogen Occultation Experiment (HALOE), Microwave Limb Sounder (MLS)/Aura, and Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) to model predictions based on troposphere-to-stratosphere transport from ERA-Interim, and temperatures from ERA-Interim, Modern Era Retrospective- Analysis (MERRA), Climate Forecast System Reanalysis (CFSR), Radiosonde Atmospheric Temperature Products for Assessing Climate (RATPAC), HadAT2, and RICHv1.5. All model predictions are dry biased. The interannual …

Hydrocarbons In The Upper Troposphere And Lower Stratosphere Observed From Ace-Fts And Comparisons With Waccm, Mijeong Park, William J. Randel, Douglas E. Kinnison, Louisa K. Emmons, Peter F. Bernath, Kaley A. Walker, Chris D. Boone, Nathaniel J. Livesey

Chemistry & Biochemistry Faculty Publications

Satellite measurements from the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) are used to examine the global, seasonal variations of several hydrocarbons, including carbon monoxide (CO), ethane (C₂H₆), acetylene (C₂H₂), and hydrogen cyanide (HCN). We focus on quantifying large-scale seasonal behavior from the middle troposphere to the stratosphere, particularly in the tropics, and furthermore make detailed comparisons with the Whole Atmosphere Community Climate Model (WACCM) chemistry climate model (incorporating tropospheric photochemistry, time-varying hydrocarbon emissions, and meteorological fields nudged from reanalysis). Comparisons with Microwave Limb Sounder (MLS) measurements of CO are also included …

Water Vapor And The Equatorial Mesospheric Semi-Annual Oscillation (Msao), R. L. Gattinger, E. Kyröla, C. D. Boone, W. F. J. Evans, K. A. Walker, I. C. Mcdade, P. F. Bernath, E. J. Llewellyn

Chemistry & Biochemistry Faculty Publications

Observations of the mesospheric semi-annual oscillation (MSAO) in the equatorial region have been reported dating back several decades. Seasonal variations in both species densities and airglow emissions are well documented. The extensive observations available offer an excellent case study for comparison with model simulations. The broad range of measurements is summarised with emphasis on the 80 to 100 km region. Photochemical model simulations are described for near-equinox and near solstice conditions, the two lines with notable differences in the observed MSAO parameters. Diurnal tides are included in order to facilitate comparisons of observations made at different local times. The roles …

A Preliminary Examination Of An In Situ Dual Dye Approach To Measuring Light Fluxes In Lotic Systems, Elizabeth C. Minor, Elizabeth James, Jay A. Austin, Veronica Nelson, Ryan Lusk, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

Light is a critical parameter in aquatic ecosystems, affecting primary production and in situ photochemistry. However, measuring light exposure for suspended particles or dissolved components in a dynamic water column can be challenging with existing Eulerian approaches. Here, we assess the simultaneous deployment of two dyes differing in photolability (rhodamine WT and fluorescein) as a Lagrangian measure of sunlight exposure in a lotic system. Fluorescein is sensitive to light exposure; rhodamine WT is relatively photostable. We examined dye fluorescence at various pH, salinity, and temperature conditions. We also tested dye photolability as a function of pH and wavelength range. In …