Oceanography and Atmospheric Sciences and Meteorology Commons^™

Studies On Hydroxyl Radical Formation And Correlated Photoflocculation Process Using Degraded Wood Leachate As A Cdom Source, Luni Sun, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

In this study, we examined hydroxyl radical (•OH) formation with respect to photoreactivity of colored dissolved organic matter (CDOM), the Fenton reaction, and photoflocculation using leachate from decaying wood. The relationship between •OH photoproduction rate and leachate optical properties (UV-visible absorption and fluorescence excitation-emission matrices (EEMS)) was studied during irradiation using a UV solar simulator. The results showed that the •OH photochemical formation rate is strongly related to humic-like fluorescence as characterized by parallel factor analysis (PARAFAC), and that these fluorescence components are more photolabile than most of the other CDOM components. Fourier transform infrared spectroscopy (FT-IR) indicated the photodegradation …

Measurement Of Antioxidant Activity Toward Superoxide In Natural Waters, D. Whitney King, Emma Berger, Zachary Helm, Eleanor Irish, Kenneth Mopper

Chemistry & Biochemistry Faculty Publications

Antioxidants are a class of molecules that provide a protective function against reactive oxygen species (ROS) in biological systems by out competing physiologically important molecules for ROS oxidation. In natural waters, the reactivity of antioxidants gives an estimate of oxidative stress, and may determine the reactivity and distribution of reactive oxidants. We present an analytical method to measure antioxidant activity in natural waters through the competition between ascorbic acid, an antioxidant, and MCLA, a chemiluminescent probe for superoxide. A numerical kinetic model of the analytical method has been developed to optimize analytical performance. Measurements of antioxidant concentrations in pure and …

Global Stratospheric Measurements Of The Isotopologues Of Methane From The Atmospheric Chemistry Experiment Fourier Transform Spectrometer, Eric M. Buzan, Chris A. Beale, Chris. D. Boone, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

This paper presents an analysis of observations of methane and its two major isotopologues, CH₃D and ¹³CH₄, from the Atmospheric Chemistry Experiment (ACE) satellite between 2004 and 2013. Additionally, atmospheric methane chemistry is modeled using the Whole Atmospheric Community Climate Model (WACCM). ACE retrievals of methane extend from 6 km for all isotopologues to 75 km for ¹²CH₄, 35 km for CH₃D, and 50 km for ¹³CH₄. While total methane concentrations retrieved from ACE agree well with the model, values of δD-CH₄ and δ¹³C-CH …

Detailed Source-Specific Molecular Composition Of Ambient Aerosol Organic Matter Using Ultrahigh Resolution Mass Spectrometry And H Nmr, Amanda S. Willoughby, Andrew S. Wozniak, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

Organic aerosols (OA) are universally regarded as an important component of the atmosphere that have far-ranging impacts on climate forcing and human health. Many of these impacts are related to OA molecular characteristics. Despite the acknowledged importance, current uncertainties related to the source apportionment of molecular properties and environmental impacts make it difficult to confidently predict the net impacts of OA. Here we evaluate the specific molecular compounds as well as bulk structural properties of total suspended particulates in ambient OA collected from key emission sources (marine, biomass burning, and urban) using ultrahigh resolution mass spectrometry (UHR-MS) and proton nuclear …

Upper Tropospheric Water Vapour Variability At High Latitudes- Part 1: Influence Of The Annular Modes, Christopher E. Sioris, Jason Zou, David A. Plummer, Chris D. Boone, C. Thomas Mcelroy, Patrick E. Sheese, Omid Moeini, Peter F. Bernath

Chemistry & Biochemistry Faculty Publications

Seasonal and monthly zonal medians of water vapour in the upper troposphere and lower stratosphere (UTLS) are calculated for both Atmospheric Chemistry Experiment (ACE) instruments for the northern and southern high-latitude regions (60-90° N and 60-90°S). Chosen for the purpose of observing high-latitude processes, the ACE orbit provides sampling of both regions in 8 of 12 months of the year, with coverage in all seasons. The ACE water vapour sensors, namely MAESTRO (Measurements of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation) and the Fourier Transform Spectrometer (ACE-FTS) are currently the only satellite instruments that can probe from …

Mipas Imk/Iaa Cfc-11 (Ccl3f) And Cfc-12 (Ccl2f2) Measurements: Accuracy, Precision And Long-Term Stability, E. Eckert, A. Laeng, S. Lossow, S. Kellmann, G. Stiller, T. Von Clarmann, N. Glatthor, M. Hopfner, M. Kiefer, H. Oelhaf, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

Profiles of CFC-11 (CCl₃F) and CFC-12 (CCl₂F₂) of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) aboard the European satellite Envisat have been retrieved from versions MIPAS/4.61 to MI-PAS/4.62 and MIPAS/5.02 to MIPAS/5.06 level-1b data using the scientific level-2 processor run by Karlsruhe Institute of Technology (KIT), Institute of Meteorology and Climate Research (IMK) and Consejo Superior de Investigaciones Cientificas (CSIC), Instituto de Astrofisica de Andalucia (IAA). These profiles have been compared to measurements taken by the balloon-borne cryosampler, Mark IV (MkIV) and MIPAS-Balloon (MIPAS-B), the airborne MIPAS-STRatospheric aircraft (MIPAS-STR), the satellite-borne Atmospheric Chemistry …

Geospatial Approaches To Support Pelagic Conservation Planning And Adaptive Management, L. M. Wedding, Sara M. Maxwell, D. Hyrenbach, D. C. Dunn, J. J. Roberts, D. Briscoe, E. Hines, P. N. Halpin

Biological Sciences Faculty Publications

Place-based management in the open ocean faces unique challenges in delineating boundaries around temporally and spatially dynamic systems that span broad geographic scales and multiple management jurisdictions, especially in the 'high seas'. Geospatial technologies are critical for the successful design of pelagic conservation areas, because they provide information on the spatially and temporally dynamic oceanographic features responsible for driving species distribution and abundance in the open ocean, the movements of protected species, and the spatial patterns of distribution of potential threats. Nevertheless, there are major challenges to implementing these geospatial approaches in the open ocean. This Theme Section seeks to …

The Sea Is Rising… But Not Onto The Policy Agenda: A Multiple Streams Approach To Understanding Sea Level Rise Policies, Juita-Elena (Wie) Yusuf, Katharine Neill, Burton St. John Iii, Ivan K. Ash, Kaitrin Mahar

School of Public Service Faculty Publications

There has been little policy effort to address sea level rise in coastal states in the US. It is important to examine, at the state level, how the multitude of different (and changing) actors with different preferences and perspectives contribute to such inertia. This study examines state-level legislative inaction with regards to sea level rise. Using Kingdon's multiple streams framework, we draw a picture of the policy landscape in Virginia as one where the problem of sea level rise is perceived as a low priority, with little consensus on achievable policy solutions, and is politically controversial. We find that policy …

Assessing The Evolution Of Soil Moisture And Vegetation Conditions During The 2012 United States Flash Drought, Jason A. Otkin, Martha C. Anderson, Christopher R. Hain, Mark D. Svoboda, David K. Johnson, Richard Mueller, Tsegaye Tadesse, Brian D. Wardlow, Jesslyn Brown

National Drought Mitigation Center: Faculty Publications

This study examines the evolution of several model-based and satellite-derived drought metrics sensitive to soil moisture and vegetation conditions during the extreme flash drought event that impacted major agricultural areas across the central U.S. during 2012. Standardized anomalies from the remote sensing based Evaporative Stress Index (ESI) and Vegetation Drought Response Index (VegDRI) and soil moisture anomalies from the North American Land Data Assimilation System (NLDAS) are compared to the United States Drought Monitor (USDM), surface meteorological conditions, and crop and soil moisture data compiled by the National Agricultural Statistics Service (NASS).

Overall, the results show that rapid decreases in …

The Implications Of Climate Change For Nebraska: Summary Report Of Sector-Based Roundtable Discussions, Donald A. Wilhite, Kimberly Morrow

National Drought Mitigation Center: Faculty Publications

This report is the result of the work of many individuals that contributed to the success of the series of eight sector-based roundtable events that were held in September and October of 2015. First and foremost, we would like to thank the organizers and the organizations they represent for their leadership in bringing together a diverse set of key stakeholders to discuss the implications of climate change on their sector. It was such a pleasure to work with such a dedicated group of individuals. Second, we would like to thank the more than 350 people who participated in these discussions …

New Tools For Assessing Drought Conditions For Rangeland Management, Cody Knutson, Brian Fuchs

National Drought Mitigation Center: Faculty Publications

Historical drought assessment and ongoingmonitoring is essential for understanding past drought occurrence, the relationships between past drought and its impacts, and for triggering action during current drought events. • A variety of new products have recently been developed to better monitor drought conditions and assess past occurrences at the local scale. • A growing number of resources are available to assist rangeland managers to develop a monitoring system and incorporate it into a drought management plan.

Hydrodynamic Variability In A Microtidal Coastal Bay Geographically Susceptible To North East Trade Winds, Israel Medina-Gómez, Cecilia Enríquez, Björn Kjerfve, Ismael Mariño, Jorge Herrera-Silveira

Gulf and Caribbean Research

The ecological integrity and overall health conditions of natural coastal systems are largely based upon the balance among physical processes. The objective of this study was to assess the effects of tides and winds on the water level variability, circulation patterns, and turnover time in Bahia de la Ascension (BA), a shallow, tropical coastal bay in the Mexican Caribbean prone to the influence of Trade winds due to its geographical location. The analysis of the hydrodynamics of BA using a 2D numerical model indicates that the tidal flow in the inlets and central basin of the bay vary by tidal …

Predicting The Water Quality Of Shallow Arctic Ponds Using Remote Sensing, Gabriela Tarin

Open Access Theses & Dissertations

Barrow, Alaska is in a region dominated by Arctic tundra of which a substantial part is covered by lakes and ponds. Despite their dominance in the landscape, freshwater ecosystems in the Arctic have been insufficiently studied. It is clear that furthering understanding of how Arctic water bodies are responding to warming will depend on the analysis of changes in the concentration of organic and inorganic constituents in the water; however, scientists are faced with the task of sampling many remote sites in a relatively hostile environment. Thus, the exploration and incorporation of remote methods for monitoring changes in water quality. …

Study Of No2 Photolysis Rate Coefficients For The Paso Del Norte Region, Pema Wangchuk

Open Access Theses & Dissertations

The photolysis of nitrogen dioxide is one of the most influential chemical processes in the formation of photochemical air pollution. In this study, we compared simulated and measured nitrogen dioxide photolysis rate coefficients (J_(NO_2 )) for the Paso Del Norte (PdN) region. The Tropospheric Ultraviolet-Visible (TUV) radiation transfer model was used to calculate J_(NO_2 ) values. The measurements of hemi-spherically integrated, spectrally resolved solar photon flux between the wavelengths 400 and 700 nm were used to obtain the photolysis rate coefficients for ã??NOã??_2. Results are presented for a selected episode on July, 2015. The work investigated the use of measured …

Relocation Based On Slow-Onset Climate-Induced Environmental Change In Keta, Ghana, Abdul-Moomin Ansong Salifu

Walden Dissertations and Doctoral Studies

Coastal indigenous communities in Keta, Ghana, are experiencing resettlement as a result of slow-onset, climate-induced flooding and erosion. Previous researchers have documented the risk of relocation from rapid-onset events, but little is known about the effectiveness of policies developed in response to slow-onset changes. This phenomenological study investigated the ongoing lived experiences of adult household members in Keta who were relocated by the government. Jun's critical theory provided a constructionist interpretive framework to determine whether Ghana's national policy on climate change resettlement adequately meets Rawls's criteria for distributive social justice. Policy documents and transcriptions of interviews with a purposeful sample …

Improved Prediction Of Severe Thunderstorms Over The Indian Monsoon Region Using High-Resolution Soil Moisture And Temperature Initialization, K. K. Osuri, R. Nadimpalli, U. C. Mohanty, F. Chen, M. Rajeevan, Dev Niyogi

Department of Earth, Atmospheric, and Planetary Sciences Faculty Publications

The hypothesis that realistic land conditions such as soil moisture/soil temperature (SM/ST) can significantly improve the modeling of mesoscale deep convection is tested over the Indian monsoon region (IMR). A high resolution (3 km foot print) SM/ST dataset prepared from a land data assimilation system, as part of a national monsoon mission project, showed close agreement with observations. Experiments are conducted with (LDAS) and without (CNTL) initialization of SM/ST dataset. Results highlight the significance of realistic land surface conditions on numerical prediction of initiation, movement and timing of severe thunderstorms as compared to that currently being initialized by climatological fields …

Statistical Analysis Of The Effectiveness Of Seawalls And Coastal Forests In Mitigating Tsunami Impacts In Iwate And Miyagi Prefectures, Roshanak Nateghi, Jeremy D. Bricker, Seth D. Guikema, Akane Bessho

School of Industrial Engineering Faculty Publications

The Pacific coast of the Tohoku region of Japan experiences repeated tsunamis, with the most recent events having occurred in 1896, 1933, 1960, and 2011. These events have caused large loss of life and damage throughout the coastal region. There is uncertainty about the degree to which seawalls reduce deaths and building damage during tsunamis in Japan. On the one hand they provide physical protection against tsunamis as long as they are not overtopped and do not fail. On the other hand, the presence of a seawall may induce a false sense of security, encouraging additional development behind the seawall …

The Tornado That Struck Embry-Riddle Aeronautical University On Christmas Day, 2006: Lessons Learned From A Near-Miss, John M. Lanicci

Journal of Aviation/Aerospace Education & Research

An F2 tornado that touched down in Daytona Beach on Christmas Day afternoon caused over $50 million of damage to the Embry-Riddle Aeronautical University campus and nearby neighborhoods. The tornado was part of a severe-weather outbreak over Florida, Georgia, and South Carolina that began during the overnight hours of 25 December 2006. Examination of surface and upper-level meteorological charts and vertical soundings on the morning of 25 December showed stability and wind-shear conditions favorable for tornadic thunderstorms over this region. The evolution of the squall line that moved through east-central Florida, and the parent thunderstorm that produced the tornado was …

Earthkam In The Classroom: Enhanced Stem Learning Through Earth Observations, Angela Burke

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.

Characteristics Of Tornado Debris Signatures In The 30 June-1 July 2014 Quasi-Linear Convective System Tornado Outbreak, Adam Clayton

Summer Community of Scholars Posters (RCEU and HCR Combined Programs)

No abstract provided.