Oceanography and Atmospheric Sciences and Meteorology Commons^™

Twenty-One Years Of Global Atmospheric Chlorine Inventories From Atmospheric Chemistry Experiment Fourier Transform Spectrometer (Ace-Fts) Measurements, N. Raymond, P. Bernath, C. Boone, M. P. Chipperfield

Chemistry & Biochemistry Faculty Publications

We present atmospheric chlorine inventories over 21 years (2004-2024) and five latitude bands (82-60°N, 60-30°N, 30°N-30°S, 30-60°S, 60-82°S) across altitudes from the surface up to 61 km. These inventories were calculated using the Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS) version 5.3 retrievals of the volume mixing ratios (VMRs) of 13 chlorine-containing species. Of these, five are product gases: HCl, HOCl, ClONO₂, COClF, COCl₂, and eight are source gases: CCl₄, CH₃Cl, CFC-11 (CCl₃F), CFC-12 ( CCl₂F₂), CFC-113 (CClF₂CCl₂F}), HCFC-22 (CHF₂Cl), HCFC-141b ( C₂H₃Cl₂F), and HCFC-142b (C₂H₃}Cl₂F). Where necessary, ACE-FTS data were supplemented with data from the TOMCAT 3-D chemical transport model, …

Mapping Coastal Vegetation To Evaluate Salt Marsh Decline From 2016 To 2025 In South Carolina, Usa, Zak Henry Bartholomew

Theses, Dissertations and Capstones

Accelerating sea-level rise and storm surge events pose a substantial threat to salt marsh ecosystems, which provide critical ecosystem services. Classification and mapping of coastal vegetation through remote sensing can identify marsh dieback events and provide spatial context for patterns of marsh vulnerability. We used a multi-sensor approach that incorporated LiDAR data, multispectral imagery, and field-derived cover estimates to classify Spartina alterniflora (smooth cordgrass) dominated marsh types on Marine Corps Recruit Depot Parris Island (MCRDPI), a sea island in South Carolina, USA. In summer 2025, surveys were conducted within marsh classes to collect training and validation data. We used random …

Greenhouse Gas Report For Western Australian Wild-Catch Fisheries And Aquaculture 2004-2025, Christophe D'Abbadie, Johnny Machon, Dipesh Maharjan, Mark Goninon, Pia Dobson, Jason How, Rodney Duffy Dr., Ainslie Denham, Shaye Carman, Trina Anderson

Climate Science Published Reports

This report provides a comprehensive analysis of greenhouse gas (GHG) emissions from Western Australian wild-catch fisheries and aquaculture for the fiscal years (FY) 2004/05 to 2024/25. These industries represent important components of the Western Australian primary production sector, with distinct emissions profiles and trends.

Key Findings:

Emissions from wild-catch fisheries have declined significantly over time, from approximately 0.341 million tonnes of carbon dioxide equivalent (Mt CO₂e) in FY 2004/05 to 0.136 Mt CO₂e in FY 2024/25, a reduction of approximately 60%.

Emissions from aquaculture in FY 2024/25 were approximately 0.350 Mt CO₂e, reflecting substantial industry growth from near-negligible levels in …

Identification And Characterization Of Tornado Seismic Signals In The Central U.S., Seth Thompson

Theses and Dissertations--Earth and Environmental Sciences

Tornadoes cause extensive property damage and endanger lives. While Doppler radar can indicate the potential for tornado development, it cannot confirm that a tornado is in contact with the ground unless a debris signature is present. While on the ground, a significant amount of a tornado’s energy may be transferred into the earth as seismic vibrations. Thus, seismometers have the potential to detect on-the-ground tornadoes. Since 1960, only five papers have published seismic recordings from tornadoes. These studies have mostly reported on seismic waves generated by tornadoes at a relatively large range, from 0.01-2.5 Hz, representing uncertainty in the dominant …

Liutex - A Fluid Vortex, Oscar Alvarez

Mathematics Dissertations

Fluid vortices are found everywhere in our universe. A vortex can take the form of almost anything - from the classical spiral vortex to chaotic plumes. Defining a vortex physically and mathematically is absolutely necessary if we desire to study vortices and their interactions with each other as well as our physical world. Fluid vortices are incredibly important in the study of turbulent flows. From determining wear, optimizing design for better flow, efficiency, etc., to even predicting the weather on Earth or other planets, having the ability to measure vortices in fluid flow is invaluable. In this study, I investigate …

On The Contribution Of The Gulf Stream To High Frequency Coastal Sea Level Variability, Tal Ezer

CCPO Publications

Long-term Atlantic Ocean and Gulf Stream (GS) variability were linked in past studies to coastal sea level (CSL) change along the U.S. East Coast - a weakening GS can lead to rise in CSL and increased coastal flooding. However, high frequency variability (HFV) in CSL is, in most cases, attributed to atmospheric weather events. This study is focused on HFV (intraseasonal variations with periods between similar to 1 week and similar to 2 months) in the GS and in CSL. First, wavelet and spectral analysis of observations of the Florida Current transport and CSL characterized the HFV in the data, …

Lessons For Transformative Ocean Science From The Integrated Marine Biosphere Research (Imber) Project, Deborah Santos Prado, Ella-Kari Muhl, Mia Strand, Derek Armitage, Nina Bednaršek, Stephanie Brodie, Christopher Cvitanovic, John Claydon, Sam Dupont, Karen Evans, Alistar Hobday, Eileen Hofmann, Raleigh Hood, Laura Kaikkonen, Dongyan Liu, Jessica Melbourne-Thomas, Franz Mueter, Eugene Murphy, Prateep Kumar Nayak, Alice Newton, Heidi Pethybridge, Carol Robinson, Samiya Selim, Rowan Trebilco, Micaela Trimble, Fang Zuo

CCPO Publications

This paper synthesizes the key contributions and lessons learned from Integrated Marine Biosphere Research (IMBeR), a large-scale global research project aimed at fostering ocean sustainability under global change for the benefit of society. The UN Decade of Ocean Science for Sustainable Development has catalyzed a renewed focus on the importance of transforming ocean science. IMBeR’s global activity over the past decade has focused on promoting transformative science by generating, mobilizing, and communicating the knowledge needed to support ocean governance. Key contributions from IMBeR participants include quantifying and comparing historic and present structure and functioning of linked ocean and human systems, …

Basal Melting Variability Of The Ross Ice Shelf From Mixing Ratios Of Simulated Water Masses (1993-2018) And Potential Climatic Drivers, Enrico Pochini, Andrea Bergamasco, Florence Colleoni, Manuel Bensi, Giorgio Budillon, Pasquale Castagno, Michael S. Dinniman, Pierpaolo Falco, Emanuele Forte, Vedrana Kovačević, Stefanie L. Mack

CCPO Publications

Several water masses circulate under the Ross Ice Shelf (RIS), the largest ice shelf in Antarctica, each causing basal melting with a specific spatio-temporal pattern. To investigate these patterns and their variability, we applied a mixing ratio analysis to simulated water masses from a new numerical ocean model of the Ross Sea. The simulation, which was run over 26 years (1993–2018) and which includes the RIS cavity, shows good agreement with seaborne and mooring observations. The total RIS basal melt rate is 90 Gt/yr on average, and is caused mostly by High Salinity Shelf Water (HSSW) (68%), which enters the …

Regional Oceanographic Controls On Water Column Nitrogen Fixation In Northern Australian Waters, Douglas G. Capone, Ajit Subramaniam, Yubin Raut, Joseph P. Montoya, Margaret R. Mulholland, Rachel Ann Foster, Miles Furnas, Edward J. Carpenter

OES Faculty Publications

Large blooms of the diazotrophic cyanobacteria, Trichodesmium, have been re-ported along the north coast of Australia and are readily evident in remote sensing images. During a research cruise in November 1999, we sampled from Townsville to Broome, examined Trichodesmium population densities and their rates of carbon and N₂ fixation alongside microscopy-based cell counts of them and other cyanobacte-rial diazotrophs. Additionally, we also enumerated the picophytoplankton community using flow-cytometry, measured bulk chlorophyll concentrations, carbon and N₂ fixation rates, and water column hydrography, enabling comparison of diazotrophic and picophytoplankton functional groups across the system. Agglomerative hierarchical clustering analysis of physicochemical oceanographic …

Differential Growth Dynamics Of Common Salt Marsh Species Spartina Alterniflora And Juncus Roemerianus Under Varied Sediment Amendments, Caitlin Hemphill, Richard P. Hale, Erik S. Yando

Biological Sciences Faculty Publications

Introduction

Many coastal wetlands are at high risk of degradation or loss due to sea‐level rise. Restoration techniques for maintaining coastal marshes are paramount, with thin‐layer placement (TLP) emerging as one feasible solution. Despite TLP's utilization, additional research is needed on species‐ and sediment‐specific responses.

Objectives

Our research combines greenhouse and field experimentation to test species and sediment composition responses aimed at maximizing vegetation while maintaining increased elevation.

Methods

The greenhouse experiment used two common marsh plants, Spartina alterniflora and Juncus roemarianus. Five centimeters of sediment (mud, sand, and sand/mud mix) was added, and subsequent sediment and vegetation metrics …

Global Characterization Of Stratospheric Sulfate Aerosols By The Atmospheric Chemistry Experiment (Ace), Peter Bernath, Manish Bhusal, Michael Lecours, Chris Boone

Chemistry & Biochemistry Faculty Publications

Stratospheric sulfate aerosol (SSA) is an important part of the Earth's climate system. SSA climate impact is determined in part by particle composition, which has been measured from orbit. The weight percent of sulfuric acid in SSA has been determined from atmospheric infrared transmittance spectra recorded with the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) in limb geometry using the Sun as a light source (solar occultation). The global average SSA composition varies from about 50 to 80 percent with lowest values during the Antarctic winter. Atmospheric extinction at a wavelength of 1 μm was included in the analysis to …

An Updated Infrared Solar Spectrum From Ace-Fts And A Ch Rovibrational Line List, Manish Bhusal, Peter F. Bernath, Léo Lavy, Chris D. Boone, Frank Hase

Chemistry & Biochemistry Faculty Publications

An updated Atmospheric Chemistry Experiment Fourier Transform Spectrometer infrared solar spectrum has been produced from low-Earth orbit covering 1829-4440 cm^-¹ (2.252-5.467 mu m). Spectroscopic constants for the v = 4 and v = 5 vibrational levels of the X²Π state of CH radical have been updated by incorporating additional vibration-rotation lines from the new solar spectrum and from an archival laboratory spectrum. New ab initio calculations of the permanent dipole moment function for the X²Π state were performed with the MOLPRO quantum chemistry package using the internally contracted multireference configuration interaction method. This dipole moment function, along with …

Forecasting Precipitation In Cuba Using Graph Based Deep Learning, Taufiqul Islam

Earth & Environmental Sciences Theses

Daily precipitation forecasting remained a challenging problem in regions characterized by strong spatial heterogeneity, nonlinear atmospheric dynamics, and intermittent rainfall behavior. Cuba represented a particularly complex case due to the combined influence of tropical cyclones, easterly waves, mesoscale convective systems, and orographic effects, which produced highly variable rainfall patterns in both space and time. Conventional statistical and machine-learning models typically treated stations independently and therefore overlooked spatial dependencies that strongly influenced rainfall variability across the island.

This study developed a spatiotemporal deep-learning framework for daily precipitation forecasting across 40 spatial nodes in Cuba using data from 1979 to 2023. The …

The Critical Role Of Near-Surface Dynamics In Identifying Spawning Areas Of Atlantic Bluefin Tuna In The Gulf Of Mexico, Donald R. Johnson, William J. Teague, Harriet Perry, James S. Franks

Gulf and Caribbean Research

Atlantic Bluefin Tuna, Thunnus thynnus (ABFT), migrate long distances to broadcast spawn in the Gulf of Mexico (GOM) basin, the Mediterranean Sea and the Slope Sea (NW Atlantic). These areas have commonalities including a highly dynamic upper ocean eddy environment that draws nutrients from shallow thermoclines and adjacent continental shelves and can provide temporal sanctuaries from some larval predators. In the GOM basin, the Loop Current (LC) and its energetic spin—off eddies sweep weak swimming predators such as jellyfish (Pelagia noctiluca) into lines and aggregations, leaving relatively open areas as temporal sanctuaries for ABFT larvae during the vulnerable …

The Hitran2024 Molecular Spectroscopic Database, I. E. Gordon, L. S. Rothman, R. J. Hargreaves, F. M. Gomez, T. Bertin, C. Hill, R. V. Kochanov, Y. Tan, P. Wcisło, V. Yu. Makhnev, P. F. Bernath, M. Birk, V. Boudon, A. Campargue, A. Coustenis, B. J. Drouin, R. R. Gamache, J. T. Hodges, D. Jacquemart, E. J. Mlawer, A. V. Nikitin, V. I. Perevalov, M. Rotger, S. Robert, J. Tennyson, G. C. Toon, H. Tran, V. G. Tyuterev, E. M. Adkins, A. Barbe, D. M. Bailey, K. Bielska, L. Bizzocchi, T. A. Blake, C. A. Bowesman, P. Cacciani, P. Čermák, A. G. Császár, L. Denis, S. C. Egbert, O. Egorov, A. Yu. Ermilov, A. J. Fleisher, H. Fleurbaey, A. Foltynowicz, T. Furtenbacher, M. Germann, E. R. Guest, J. J. Harrison, J. -M. Hartmann, A. Hjältén, S. -M. Hu, X. Huang, T. J. Johnson, H. Jóźwiak, S. Kassi, M. V. Khan, F. Kwabia-Tchana, T. J. Lee, D. Lisak, A. -W. Liu, O. M. Lyulin, N. A. Malarich, L. Manceron, A. A. Marinina, S. T. Massie, J. Mascio, E. S. Medvedev, V. V. Meshkov, G. Ch. Mellau, M. Melosso, S. N. Mikhailenko, D. Mondelain, H.S.P. Müller, M. O' Donnell, A. Owens, A. Perrin, O. L. Polyansky, P. L. Raston, Z. D. Reed, M. Rey, C. Richard, G. B. Rieker, C. Röske, S. W. Sharpe, E. Starikova, N. Stolarczyk, A. V. Stolyarov, K. Sung, F. Tamassia, J. Terragni, V. G. Ushakov, S. Vasilchenko, B. Vispoel, K. L. Vodopyanov, G. Wagner, S. Wójtewicz, S. N. Yurchenko, N. F. Zobov

Chemistry & Biochemistry Faculty Publications

The HITRAN database is a curated compilation of validated molecular spectroscopic parameters, established in the early 1970s. It is used by various computer codes to predict and simulate the transmission and emission of light in gaseous media (with an emphasis on terrestrial and planetary atmospheres). The HITRAN compilation is composed of six major components. These components include the line-by-line spectroscopic parameters required for high-resolution radiative-transfer codes, experimentally derived absorption cross-sections (for molecules where it is not yet feasible for representation in a line-by-line form), collision-induced absorption data, aerosol indices of refraction, and general tables (including partition sums) that apply globally …

Pressure Field Estimation From 2d-Piv Measurements: A Case Study Of Fish Suction-Feeding, Jensine C. Coggin, Duvall Dickerson-Evans, Erin E. Hackett, Roi Gurka

Marine Science

Particle image velocimetry (PIV) flow measurements are common practice in laboratory settings in a wide variety of fields involving fluid dynamics, including biology, physics, engineering, and medicine. Dynamic fluid pressure is a notoriously difficult property to measure non-intrusively, yet its variation is a driving flow force and critical to model correctly. Techniques have been developed to estimate the pressure from velocity and velocity gradient measurements. Here, we highlight a novel application of boundary conditions when applying such pressure estimation techniques based on two-dimensional PIV data; the novel method is especially relevant to problems with complex boundary conditions. As such, it …

Gone But Not Forgotten: Collaborative Telemetry Network Provides Insight Into Out-Of-System Movements Of Common Snook, Victoria S. Goldner, Mack White, Cody W. Eggenberger, Alia A. Jones, Cameron C. Atkinson, Jonathan R. Rodemann, W. Ryan James, Jordan A. Massie, Andrea M. Kroetz, Patrick M. O’Donnell, Ross E. Boucek, Rolando O. Santos, Jennifer S. Rehage

Marine Science

Objective The objective of this study was to examine the movements of Common Snook Centropomus undecimalis, a tropical euryhaline species, out of the Shark River, Everglades National Park, Florida, USA, and gain a better understanding of their long-distance regional movements. Methods This study used 7 years (2017–2023) of acoustic telemetry data from the Shark River Florida Coastal Everglades Array and from five other collaborative telemetry arrays in southwestern Florida to assess out-of-system movements for 119 Common Snook. Generalized linear models were used to assess the relationships between out-of-system movements and biological and environmental variables. Results Most Common Snook departures took …

Decomposing Shadow Prices Under Climate-Driven Growth Scenarios: Insights From An Elk Herd Case Study, Ranjit Bawa, Drew Bennett, Wai Yan Siu, Bailey Kirkland, David Finnoff, Jacob Hochard

ODU Articles

Natural capital accounting provides a framework for integrating ecological processes with economic valuation, but the mechanics of shadow price formation often remain opaque to resource managers and policymakers. Using the Clarks Fork elk herd in northwestern Wyoming as a case study, we decompose the shadow price of natural capital into its ecological, economic, and institutional components. Population dynamics are estimated using a linearized Ricker model and projected forward using a logistic projection, incorporating climate-driven reductions in intrinsic growth rates. These ecological scenarios are linked to a shadow pricing formulation that explicitly accounts for marginal benefits, harvest policy responses, discounting, and …

Data Improved Models Applied To Essential Oceanographic Processes In Rhode Island Coastal Waters, Ainsley Fruhwirth

Open Access Master's Theses

The Ocean State Ocean Model (OSOM), funded and developed through the National Science Foundation’s (NSF) Established Program to Stimulate Competitive Research (EPSCoR), was designed to simulate the physical dynamics of Rhode Island’s estuaries and shelf waters. However, the model struggled to capture key features of summer circulation in Rhode Island Sound (RIS), most notably the westward flowing coastal current and vertical stratification profile found in May through September. Significant errors in modeled lateral and vertical density gradients indicated that the thermohaline structure, physical mixing parameters, and forcing inputs required comprehensive revision. Using historical datasets from the National Oceanic and Atmospheric …

Analysis Of Δ¹¹B As A Seawater Ph Proxy: Comparing Ocean Circulation Inverse Model Output With Marine Calcifier Geochemistry, Jesse I. Dong

CMC Senior Theses

Increasing anthropogenic carbon flux into the oceans decreases seawater pH, alters dissolved inorganic carbon speciation, and reduces biogenic calcification. The marine calcifiers— specifically corals and coralline algae—incorporate elements from surrounding seawater into their carbonate structures, which preserve past records of ocean carbon chemistry. In particular, boron in biogenic carbonate is a potentially valuable proxy for historical ocean pH across human timescales. Within seawater, boron primarily exists as boric acid B(OH)3 and borate ions B(OH)4 - , where higher pH favors the formation of borate ions. Borate ions preferentially incorporate the heavier ¹¹B isotope over 10B. On the other hand, if …