Oceanography Commons^™

Molecular Characterization And Photochemical Transformation Of Dissolved Organic Matter From Land To Ocean, Hongmei Chen

Chemistry & Biochemistry Theses & Dissertations

Molecular characterization and photochemical transformation of dissolved organic matter (DOM) in both rivers and the ocean is the main research focus of this dissertation. Chemical characterization of DOM is hampered by the limited application of advanced techniques to desalt, concentrate, isolate and then molecularly characterize DOM. An affordable, commercially available mini-electrodialysis (mini-ED) system has been evaluated and recommended for the efficient desalting of small volume samples of seawater prior to analysis by electrospray Fourier transform ion cyclotron resonance mass spectrometry (ESI FTICR-MS).

A high-recovery technique of DOM isolation – reverse osmosis coupled with electrodialysis (RO/ED) – was used to isolate …

Effects Of Predation Upon The Long-Spined Sea Urchin Diadema Antillarum By The Spotted Spiny Lobster Panulirus Guttatus, Meredith D. Kintzing, Mark J. Butler Iv

Biological Sciences Faculty Publications

Sea urchins, important herbivores in marine ecosystems, are strongly impacted by both the direct and indirect effects of predation, and the long-spined sea urchin Diadema antillarum is no exception. Once abundant on Caribbean coral reefs, D. antillarum populations were decimated by disease in the early 1980s, and only where their natural predators have been over-fished has D. antillarum recovery been observed. Spiny lobsters (Palinuridae) are predators of sea urchins, and although there are several species of spiny lobster in the Caribbean, only the spotted spiny lobster Panulirus guttatus is restricted to coral reefs where D. antillarum dwells. We investigated the …

Cosee Ocean Inquiry Group Report: Opportunities For Creating Lifelong Ocean Science Literacy, Paul Boyle, Vince Breslin, Lisa Craig Brisson, John Fraser, Alan J. Friedman, Katie Gardner, Sarah Schoedinger, Jerry Schubel, Steve Uzzo, Steven Yalowitz

School for the Environment General Publications

This Inquiry Group Report for the Centers for Ocean Sciences Education Excellence Ocean Communities in Education And Social Networks (COSEE OCEAN) provides a fresh look at how broader ocean science literacy can be developed, especially through less-recognized channels such as opportunistic learning, the private and “third” sectors, and the enormously varied activities under the heading of informal science education. The 10 authors of this report (see Contributors section) have been working together for two years to find and review a range of issues and resources for current and potential ocean science literacy providers, both professional and volunteer.

Several chapters provide …

Sea-Ice Melt Co2-Carbonate Chemistry In The Western Arctic Ocean: Meltwater Contributions To Air-Sea Co2 Gas Exchange, Mixed-Layer Properties And Rates Of Net Community Production Under Sea Ice, N. R. Bates, R. Garley, K. E. Frey, K. L. Shake, J. T. Mathis

Geography

The carbon dioxide (CO2)-carbonate chemistry of sea-ice melt and co-located, contemporaneous seawater has rarely been studied in sea-ice-covered oceans. Here, we describe the CO2-carbonate chemistry of sea-ice melt (both above sea-ice as "melt ponds" and below sea-ice as "interface waters") and mixed-layer properties in the western Arctic Ocean in the early summer of 2010 and 2011. At 19 stations, the salinity (∼0.5 to <6.5), dissolved inorganic carbon (DIC; ∼20 to <550 μmol kg-1) and total alkalinity (TA; ∼30 to <500 μmol kg-1) of above-ice melt pond water was low compared to the co-located underlying mixed layer. The partial pressure of CO2 (pCO2) in these melt ponds was highly variable (∼<10 to >1500 μatm) with the majority of melt ponds acting as potentially strong sources of CO2 to the atmosphere. The pH of melt pond waters was also highly variable ranging from mildly acidic (6.1 to 7) to slightly …

Tropical Pacific Influence On The Source And Transport Of Marine Aerosols To West Antarctica, Alison S. Criscitiello, Sarah B. Das, Kristopher B. Karnauskas, Matthew J. Evans, Karen E. Frey, Ian Joughin, Eric J. Steig, Joseph R. Mcconnell, Brooke Medley

Geography

The climate of West Antarctica is strongly influenced by remote forcing from the tropical Pacific. For example, recent surface warming over West Antarctica reflects atmospheric circulation changes over the Amundsen Sea, driven by an atmospheric Rossby wave response to tropical sea surface temperature (SST) anomalies. Here, it is demonstrated that tropical Pacific SST anomalies also influence the source and transport of marine-derived aerosols to theWest Antarctic Ice Sheet. Using records from four firn cores collected along the Amundsen coast of West Antarctica, the relationship between sea ice-modulated chemical species and large-scale atmospheric variability in the tropical Pacific from 1979 to …

The Impact Of Changing Surface Ocean Conditions On The Dissolution Of Aerosol Iron, Matthew P. Fishwick, Peter N. Sedwick, Maeve C. Lohan, Paul J. Worsfold, Kristen N. Buck, Thomas M. Church, Simon J. Ussher

OES Faculty Publications

The proportion of aerosol iron (Fe) that dissolves in seawater varies greatly and is dependent on aerosol composition and the physicochemical conditions of seawater, which may change depending on location or be altered by global environmental change. Aerosol and surface seawater samples were collected in the Sargasso Sea and used to investigate the impact of these changing conditions on aerosol Fe dissolution in seawater. Our data show that seawater temperature, pH, and oxygen concentration, within the range of current and projected future values, had no significant effect on the dissolution of aerosol Fe. However, the source and composition of aerosols …

Did A Submarine Landslide Contribute To The 2011 Tohoku Tsunami?, David R. Tappin, Stephan T. Grilli, Jeffrey C. Harris, Robert J. Geller, Timothy Masterlark, James T. Kirby, Fengyan Shi, Gangfeng Ma, K.K.S. Thingbaijam, P. Martin Mai

Civil & Environmental Engineering Faculty Publications

Many studies have modeled the Tohoku tsunami of March 11, 2011 as being due entirely to slip on an earthquake fault, but the following discrepancies suggest that further research is warranted. (1) Published models of tsunami propagation and coastal impact underpredict the observed runup heights of up to 40. m measured along the coast of the Sanriku district in the northeast part of Honshu Island. (2) Published models cannot reproduce the timing and high-frequency content of tsunami waves recorded at three nearshore buoys off Sanriku, nor the timing and dispersion properties of the waveforms at offshore DART buoy #21418. (3) …

Detection Of Seagrass Scars Using Sparse Coding And Morphological Filter, Ender Oguslu, Sertan Erkanli, Victoria J. Hill, W. Paul Bissett, Richard C. Zimmerman, Jiang Li, Charles R. Bostater Jr. (Ed.), Stelios P. Mertikas (Ed.), Xavier Neyt (Ed.)

OES Faculty Publications

We present a two-step algorithm for the detection of seafloor propeller seagrass scars in shallow water using panchromatic images. The first step is to classify image pixels into scar and non-scar categories based on a sparse coding algorithm. The first step produces an initial scar map in which false positive scar pixels may be present. In the second step, local orientation of each detected scar pixel is computed using the morphological directional profile, which is defined as outputs of a directional filter with a varying orientation parameter. The profile is then utilized to eliminate false positives and generate the final …

Reproductive Phase Determination In Male Meagre (Argyrosomus Regius, Sciaenidae): Testis Development And Histologic Corroboration Of A Gross Anatomical Scale, Nuno Prista, Leonel Gordo, José Lino Costa, Maria José Costa, Cynthia Jones

OES Faculty Publications

Reproductive stage determination of male gonads has received sparse attention in fish biology literature with few studies detailing the building of gross anatomical- and histologic scales. The meagre (Argyrosomus regius) is one of the world's largest sciaenids and supports a significant regional fishery in European and North African waters whose reproductive patterns are yet to be fully investigated. In the present study, we derive a macroscopic grading system for meagre testis using semi-quantitative graphs that feature the testis variability along the species size range and time of the year. We then describe the histological stages and reproductive phases of male …

The Great 2012 Arctic Ocean Summer Cyclone Enhanced Biological Productivity On The Shelves, Jinlun Zhang, Carin Ashjian, Robert Campbell, Victoria Hill, Yvette H. Spitz, Michael Steele

OES Faculty Publications

A coupled biophysical model is used to examine the impact of the great Arctic cyclone of early August 2012 on the marine planktonic ecosystem in the Pacific sector of the Arctic Ocean (PSA). Model results indicate that the cyclone influences the marine planktonic ecosystem by enhancing productivity on the shelves of the Chukchi, East Siberian, and Laptev seas during the storm. Although the cyclone's passage in the PSA lasted only a few days, the simulated biological effects on the shelves last 1 month or longer. At some locations on the shelves, primary productivity (PP) increases by up to 90% and …

Lack Of Equivalence In The Elemental And Stable Isotope Chemistry Within The Sagittal Otolith Pair Of The Summer Flounder, Paralichthys Dentatus, Antranik Kajajian, Jason J. Schaffler, Cynthia M. Jones

OES Faculty Publications

In fish that are not bilaterally symmetrical, the left and right sagittae are often not symmetrical, exhibiting divergent growth patterns and mass, and may have differences in chemical composition. We investigated this in the asymmetrical summer flounder Paralichthys dentatus, collected from different nursery habitats along the US east coast. Significant differences were detected in otolith mass, δ¹³C, δ¹⁸O, Li:Ca, Mg:Ca, and Sr:Ca, and overall chemical signatures. These results refute the hypothesis of left-right equivalence that is prevalent for bilaterally symmetrical fishes. We tested whether a specific side was better suited for classification. The best models …

Can We Predict The Future: Juvenile Finfish And Their Seagrass Nurseries In The Chesapeake Bay, Cynthia M. Jones

OES Faculty Publications

The importance of estuarine seagrass beds as nurseries for juvenile fish has become a universal paradigm, especially for estuaries that are as important as the Chesapeake Bay. Yet, scientific tests of this hypothesis were equivocal depending on species, location, and metrics. Moreover, seagrasses themselves are under threat and one-third of seagrasses have disappeared worldwide with 65 of their losses occurring in estuaries. Although there have been extensive studies of seagrasses in the Chesapeake Bay, surprisingly few studies have quantified the relationship between seagrass as nurseries for finfish in the Bay. Of the few studies that have directly evaluated the use …

Phytoplankton And Nutrient Dynamics In A Tidally Dominated Eutrophic Estuary: Daily Variability And Controls On Bloom Formation, Ryan E. Morse, Margaret R. Mulholland, Todd A. Egerton, Harold G. Marshall

OES Faculty Publications

To better understand nutrient dynamics and factors that promote the initiation of algal blooms, the Lafayette River, a tidal subestuary of Chesapeake Bay that experiences seasonal algal blooms, was sampled daily for a period of 54 d in the fall of 2005. Three phytoplankton blooms (chl a concentrations exceeding twice the average of monthly measurements from 2000 to 2009) occurred during this period: a mixed bloom of Akashiwo sanguinea and Gymnodinium sp., a monospecific Skeletonema costatum bloom, and a monospecific Gymnodinium sp. bloom. Over the sampling period, nutrient concentrations increased following precipitation events and were elevated between bloom periods but …

Weekly Gridded Aquarius L-Band Radiometer/Scatterometer Observations And Salinity Retrievals Over The Polar Regions - Part 2: Initial Product Analysis, L. Brucker, Emmanuel P. Dinnat, L. S. Koenig

Biology, Chemistry, and Environmental Sciences Faculty Articles and Research

Following the development and availability of Aquarius weekly polar-gridded products, this study presents the spatial and temporal radiometer and scatterometer observations at L band (frequency similar to 1.4 GHz) over the cryosphere including the Greenland and Antarctic ice sheets, sea ice in both hemispheres, and over sub-Arctic land for monitoring the soil freeze/thaw state. We provide multiple examples of scientific applications for the L-band data over the cryosphere. For example, we show that over the Greenland Ice Sheet, the unusual 2012 melt event lead to an L-band brightness temperature (TB) sustained decrease of similar to 5K at horizontal polarization. Over …

How Does Climate Change Affect Coral Reefs?, Rachel Goff

Honors Theses

Climate change is a very real phenomenon that currently affects many of the ecosystems on Earth. Climate change occurs on a global scale and can be very detrimental to different environments. This occurrence can cause ocean warming, sea level rise, ocean acidification, and increased storm intensity. According to the EPA, the ocean's temperature has increased 1.4°F over the past century, and sea levels have risen 3.2 millimeters through the past 20 years. These changes to the oceans can greatly affect many of the ecosystems that reside in them. One of the main ecosystems that are being affected by climate change …

Shark Community Structure In Winyah Bay, Sc, Keenen Fryman

Honors Theses

Assessments of local shark stocks are vital to understand population trends and their causes. Local data are incomplete despite many studies over many years. The first published study listed all of the shark species found off the coast of SC (Bearden 1965). Following Bearden's work, Schwartz (2003) used a 30 year data set to describe the elasmobranchs found in NC and SC. In 2004, a survey of coastal habitats in southeast NC helped to identify the nursery habitat for C. acronotus, C. brevipinna, C. limbatus, C. obscurus, C. plumbeus, M. canis, R. terraenovae, S. tiburo, and S. lewini (Thorpe et …

Marine Diatom Assemblage Variation Across Pleistocene Glacial–Interglacial Transitions And Neogene Diatom Biostratigraphy Of Site C9001, Nw Pacific Ocean, Marcella K. Purkey

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

In 2006, D/V-Chikyu cruise CK06-06 drilled Hole C9001C at Site C9001 in the Northwest Pacific Ocean, 80 km east of the Shimokita Peninsula, Japan. An existing chronostratigraphic framework provides a continuous glacial-interglacial (GI) climate record from which a diatom record of paleoenvironmental changes was developed across several GI cycles. Species counts, diatom temperature values, calculated sea-surface temperatures (SST) and factor analysis were produced for each sample and calibrated to prior diatom studies in this region. These features were used to characterize and compare interglacial maxima of Marine Isotope Stages (MIS) 1, 5e, 9 and 11 and transitions from the preceding …

Development And Application Of A Gis-Based Long Island Sound Eelgrass Habitat Suitability Index Model, Jamie M.P. Vaudrey, Justin Eddings, Christopher Pickerell, Lorne Brousseau, Charles Yarish

Department of Marine Sciences

The primary objectives of the Eelgrass Habitat Suitability Index Model (EHSI Model) are to assist in the evaluation of sites being considered for eelgrass restoration efforts in the Long Island Sound (LIS) area and to identify areas where water quality issues reduce or eliminate the potential for natural eelgrass colonization. To achieve this goal, geospatial processing of data available from the Long Island Sound area was conducted using ArcGIS v10.0 including the 3D Analyst and Spatial Analyst extensions. The result is a series of maps presented in this report and a GIS-based model available for users to interact with the …

Mass Bays Resource Inventory: Summary And Findings From The Review Of Plans And Assessments, Urban Harbors Institute, University Of Massachusetts Boston

Urban Harbors Institute Publications

The Massachusetts Bays Program (MBP) contracted with the Urban Harbors Institute (UHI) of the University of Massachusetts Boston to conduct a review of papers, presentations, reports, and other relevant material produced from 1996 (the last CCMP) to present, that might inform the MBP’s update of their Comprehensive Conservation and Management Plan (CCMP). The review focused on five topics identified as priority topics by the MBP: water quality, invasive species, climate change/vulnerability, continuity of estuarine habitat, and estuarine habitat protection in the geographic region of the Mass Bays Program, particularly the 47 nearshore estuaries and embayments identified in the 2012 MBP …

Corals On Acid: An Inquiry-Based Activity Leading Students To A Better Understanding Of Ocean Acidification Impacts, Casey L. Boleman, Philip M. Gravinese, Ellen N. Muse, Andrea E. Marston, John G. Windsor

Ocean Engineering and Marine Sciences Faculty Publications

The objective of this inquiry-based lesson is for students to gain an understanding of how increasing ocean acidity can affect the calcification of marine organisms. During this activity, students: (1) design an experiment to quantify the CaCO3 concentration of two invertebrate skeletal samples, one that has been soaked in normal seawater and another in a low pH solution, and (2) use critical thinking and discussion to evaluate possible explanations for the difference in the skeletal CaCO3 compositions. Our lesson focuses on exploring the activity before ocean acidification is introduced to provide a common conceptual framework to engage students.