Atmospheric Sciences Commons^™

Growth In Stratospheric Chlorine From Short-Lived Chemicals Not Controlled By The Montreal Protocol, R. Hossaoni, M. P. Chipperfield, A. Saiz-Lopez, J. J. Harrison, R. Von Glasow, R. Sommariva, E. Atlas, M. Navarro, S. A. Montzka, W. Feng, P. F. Bernath

Chemistry & Biochemistry Faculty Publications

We have developed a chemical mechanism describing the tropospheric degradation of chlorine containing very short-lived substances (VSLS). The scheme was included in a global atmospheric model and used to quantify the stratospheric injection of chlorine from anthropogenic VSLS (Cl_y^VSLS) between 2005 and 2013. By constraining the model with surface measurements of chloroform (CHCl₃), dichloromethane (CH₂Cl₂), tetrachloroethene (C₂Cl₄), trichloroethene (C₂HCl₃), and 1,2-dichloroethane (CH₂ClCH₂Cl), we infer a 2013 Cl_y^VSLS mixing ratio of 123 parts per trillion (ppt). Stratospheric injection …

Lower Thermospheric Response To Atmospheric Gravity Waves Induced By The 2011 Tohoku Tsunami, Yonghui Yu, Zhiyu Yan, Michael P. Hickey Ph.D.

Publications

Previous GPS observations have revealed that while ionospheric TIDs were seen propagating in all directions away from the 2011 Tohoku earthquake epicenter, the total electron content (TEC) fluctuations associated with the subsequent tsunami were largest for waves propagating toward the northwest of the epicenter. Ionospheric motions observed approximately 10min after the earthquake were attributed to fast acoustic waves directly produced by the earthquake. Waves that first appeared about 40 min after the tsunami onset in TEC measurements were attributed to atmospheric gravity waves. In this paper, we conjecture that the remarkably different responses observed for the eastward and westward propagating …

Urban Scale Modeling Of Atmospheric Carbon Dioxide And Validation Of Emission Inventories, James E. Powell, Christopher L. Butenhoff, Andrew L. Rice

Student Research Symposium

There exists a pressing need for high resolution emissions inventories for cities. For greenhouse gases, cities and regions need a careful analysis of their carbon footprint to design effective policies to control and mitigate emissions. High resolution emissions inventories can be used in conjunction with meteorology models and atmospheric measurements to place top-down constraints on emissions. High resolution emissions inventories for criteria pollutants like NO_x, CO, and O₃ enable urban-scale air pollution modeling down to the neighborhood level. For example, the Vulcan project estimates CO₂ using county-scale vehicle miles traveled (VMT) from the National Mobile Inventory …

Springtime Melt Onset On Arctic Sea Ice From Satellite Observations And Related Atmospheric Conditions, Angela C. Bliss

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

The timing of snowmelt onset (MO) on Arctic sea ice derived from passive microwave satellite data is examined by determining the melting area (in km²) on a daily basis for the spring and summer melt season months over the 1979 – 2012 data record. The date of MO on Arctic sea ice has important implications for the amount of total solar energy absorbed by the ice-ocean system in a given year. Increasingly early mean MO dates have been recorded over the 34-year data record as evidenced by statistically significant trends of 6.6 days decade^-1 over the extent …

Investigation Of Mountain Waves In The Mesosphere Over The Andes Mountains, Jaime Aguilar Guerrero

Doctoral Dissertations and Master's Theses

An image processing algorithm has been developed to analyze data from a NIR All-Sky Imager of OH airglow emission (from about 87 km altitude), located in the Andes, with the purpose of investigating the atmospheric gravity waves generated when low level wind blows over the high mountains (referred to as Mountain Waves). These types of waves are a special case of atmospheric gravity waves, which carry significant momentum and exert strong forcing to the background upper atmosphere. The imager is located at the Andes Lidar Observatory (ALO) at Cerro Pachón, Chile (30°S, 71°W), which also houses a Na Doppler Lidar …

Numerical Model Derived Altimeter Correction Maps For Non-Standard Atmospheric Temperature And Pressure, Thomas A. Guinn, Frederick R. Mosher

International Journal of Aviation, Aeronautics, and Aerospace

Altimeter corrections for non-standard temperature pose a challenge because accurate calculations require detailed knowledge of the temperature structure of the atmosphere between the surface and the aircraft. By applying basic hypsometric formulae to high resolution numerical model temperature and moisture output, detailed maps of current and forecasted corrected D-values are created. Corrected D-values provide the altitude difference between the true altitude and the indicated altitude from a pressure altimeter. Unlike standard D-values, the corrected D-value corrects for non-standard pressure in addition to non-standard temperature and is therefore useful for flights below class A airspace. Maps of corrected D-value may help …

A Full-Wave Model For A Binary Gas Thermosphere: Effects Of Thermal Conductivity And Viscosity, Michael P. Hickey Ph.D., R. L. Walterscheid, G. Schubert

Publications

The thermosphere is diffusively separated and behaves as a multiconstituent gas wherein individual species in static equilibrium are each stratified according to their individual scale heights. Gravity waves propagating in the thermosphere cause individual gases to oscillate with different amplitudes and phases. We use a two-gas (N2 and O) full-wave model to examine the roles of thermal conductivity, viscosity, and mutual diffusion on the wave-induced characteristics of both gases. In the lower thermosphere, where the gases are relatively tightly coupled, the major gas (N2) controls the minor gas (O) response. At higher altitudes, the gases become thermally and inertially decoupled, …

Twentieth Century Dust Lows And The Weakening Of The Westerly Winds Over The Tibetan Plateau, Bjorn Grigholm, P. A. Mayewski, S. Kang, Y. Zhang, U. Morgenstern, M. Schwikowski, Susan D. Kaspari, V. Aizen, E. Aizen, N. Takeuchi, K. A. Maasch, S. Birkel, M. Handley, S. Sneed

All Faculty Scholarship for the College of the Sciences

Understanding past atmospheric dust variability is necessary to put modern atmospheric dust into historical context and assess the impacts of dust on the climate. In Asia, meteorological data of atmospheric dust is temporally limited, beginning only in the 1950s. High‐resolution ice cores provide the ideal archive for reconstructing preinstrumental atmospheric dust concentrations. Using a ~500 year (1477–1982 A.D.) annually resolved calcium (Ca) dust proxy from a Tibetan Plateau (TP) ice core, we demonstrate the lowest atmospheric dust concentrations in the past ~500 years during the latter twentieth century. Declines in late nineteenth to twentieth century Ca concentrations significantly correspond with …

Observations Of Mesospheric Gravity Waves Over The Andes, Jonathan Pugmire, Michael Taylor, Yucheng Zhao

Student Research Symposium

Focusing on data from an imager and the SABER instrument aboard the TIMED satellite temperature variances are determined to quantify small-scale gravity waves. IDL software was used to extract all the temperature profile measurements that were measured by SABER within a limited geographical area, centered on our ground-based optical imager at Cerro Pachon, Chile (30.3°S, 70.7°S). Large-scale tidal waves, with wavenumbers 0-6, were removed from each profile revealing the gravity wave perturbations. Temperature variances reveal possible increased wave activity due to mountain waves. Mountain waves in the mesosphere are a relatively unexplored field in aeronomy. They are generated predominantly in …

Characterizing The Tgf-Lightning Relationship Using Entln, Kareem Omar

Research Horizons Day Posters

No abstract provided.

River Discharge As Affected By Precipitation, Temperature And Soil Characteristics, Susan Kotikot, Kelly Hodgskins

Research Horizons Day Posters

No abstract provided.

Comparing The Model-Simulated Global Warming Signal To Observations Using Empirical Estimates Of Unforced Noise, Patrick T. Brown, Wenhong Li, Eugene C. Cordero, Steven A. Mauget

Faculty Publications, Meteorology and Climate Science

The comparison of observed global mean surface air temperature (GMT) change to the mean change simulated by climate models has received much public and scientific attention. For a given global warming signal produced by a climate model ensemble, there exists an envelope of GMT values representing the range of possible unforced states of the climate system (the Envelope of Unforced Noise; EUN). Typically, the EUN is derived from climate models themselves, but climate models might not accurately simulate the correct characteristics of unforced GMT variability. Here, we simulate a new, empirical, EUN that is based on instrumental and reconstructed surface …

Laboratory Studies On The Production Of Alpha-Pinene-Derived Organic Nitrates And Their Atmospheric Fate, Joel David Rindelaub

Open Access Dissertations

Currently, the formation yields of organic nitrates from the oxidation of biogenic volatile organic compounds, such as α-pinene, is highly uncertain, negatively impacting our knowledge on tropospheric ozone production and the fate of atmospheric NO_x. To lower this uncertainty, we quantified the organic nitrate yield from the OH radical oxidation of α-pinene under high NO_x conditions. The α-pinene- derived nitrates created in chamber experiments readily partitioned to the aerosol phase and underwent particle phase hydrolysis, indicating that these processes are likely a sink for atmospheric NO_x. The hydrolysis of organic nitrates was found to be …

Drougthscape, Spring 2015, Kelly Smith

DroughtScape: Quarterly Newsletter of the National Drought Mitigation Center (2007–2023)

Contents

Director’s column.

South Plains ranch workshops 3

First quarter drought summary

First quarter impacts summary

Gary’s favorite pond, D1-4

NDMC’s Haigh leads U2U pubs

SW Montana watersheds convene

Wind River monitors drought

Morocco’s new drought index

Northeast Brazil drought monitoring

EU’s drought initiative

U.S. Drought Monitor Forum

How Colorado tourism coped in 2012

Impact Of Biogenic Volatile Organic Compounds On Peroxyacetyl Nitrate Production In The Southeast United States, Christopher John Groff

Open Access Theses

Our atmosphere is arguably the fundamental entity that has made life on Earth possible. Knowledge of the delicate nature of our atmosphere continues to spread as "green" initiatives promote awareness of human influence on the environment. However, many climate scientists fear that unless immediate mitigation occurs, the reversal of human impact on our planet will be impossible, leading to unknown consequence. Perturbations to natural processes are likely to cause drastic change to the planet as we know it and ultimately result in significant health issues. It is important to push the boundaries of our understanding of atmospheric processes with intent …

Studies Of The Interaction Of Biogenic Volatile Organic Compounds And Nox In Forest Environments, Kevin M. Mcavey

Open Access Dissertations

Ozone is a pollutant that causes crop damage, adverse health effects, and is a contributor to global climate change. Ozone concentrations are predicted to rise over the next half-century along with global temperature. Ozone production is controlled by the chemistry between biogenic volatile organic compounds and NO_x (NO + NO₂), and therefore, a greater understanding of NO_x + BVOC chemistry along with their sources and sinks is needed. One large uncertainty in understanding NO_x + BVOC chemistry is the production of organic nitrates (RONO₂), which act as a radical termination step in the …

Spectroscopic Characterization And Photochemistry Of Nitrogen-Containing Molecules Relevant To Titan's Atmosphere, Deepali N. Mehta-Hurt

Open Access Dissertations

Titan's atmospheric chemistry has been the source of intrigue since the planetary body's discovery. Though there is a growing understanding of the atmospheric chemistry of small molecules on Titan, much less is known about larger molecule formation, and particularly about nitrile chemistry. This dissertation characterizes nitrile/isonitrile intermediates that are postulated to be important in Titan's atmosphere, adding to the necessary foundation for understanding Titan's atmospheric chemistry. The vibronic spectroscopy of para-diisocyanobenzene (pDIB, C≡N-Ph-N≡C) has been characterized as a first step towards photochemical studies that can test the transformation of the isonitrile group to other nitrogen-based functionalities.p …

Comparing Different Methods For Estimating Total Open Heliospheric Magnetic Flux, Samantha J. Wallace

Doctoral Dissertations and Master's Theses

There are extended periods over the solar cycle where significant discrepancies occur between the observed open magnetic flux (i.e., those based on spacecraft observations) and that determined from coronal models. One explanation for the source of these discrepancies is the magnetic fields in CMEs, which have yet to magnetically disconnect from the Sun. These “closed” flux sources can be included in open flux estimates, because open and closed magnetic field lines are not easily distinguished in spacecraft data. Another possibility is that a portion of the open flux measured by in situ spacecraft originates from the time-dependent evolution of solar …

Utilizing Four Dimensional Lightning And Dual-Polarization Radar To Develop Lightning Initiation Forecast Guidance, Andrew J. Travis

Theses and Dissertations

Lightning initiation is a major forecast challenge faced by Air Force's 45th Weather Squadron (45 WS), which provides weather support to Cape Canaveral Air Force Station and Kennedy Space Center (KSC). Prior studies by Thurmond (2014) and Woodard (2011) have shown that dual-polarization (DP) radar can be used to identify the presence of hydrometeors indicative of cloud charging, leading to improved lightning initiation forecasts. The 45 WS currently employs empirical lightning initiation forecast rules which state that in-cloud lightning is likely when radar reflectivity meets or exceeds 37.0 dBZ above the -10°C height. This study examined 249 convective cells from …

A Study Of Thunderstorm Microphysical Properties And Lightning Flash Counts Associated With Terrestrial Gamma-Ray Flashes, D. E. Barnes, M. E. Splitt, J. R. Dwyer, S. Lazarus, D. M. Smith, H. K. Rassoul

Aerospace, Physics, and Space Science Faculty Publications

The terrestrial gamma ray flash (TGF) is an emission of highly energetic radiation produced by or at least in close association with lightning. Previous investigations attempted to isolate the production mechanisms and production altitude(s) of TGFs as well as macrophysical characteristics, while thunderstorm microphysical characteristics were largely ignored. This investigation into thunderstorms and their hydrometeor and flash characteristics utilize temporal and spatial coincident satellite passes between the Reuven Ramaty High Energy Solar Spectroscopic Imager and the Tropical Rainfall Measuring Mission to determine the bulk (or footprint) microphysical properties of two types of study events, the thunderstorm complexes which are associated …