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Catalytic Oxidation And Depolymerization Of Lignin In Aqueous Ionic Liquid, Lalitendu Das, Siquan Xu, Jian Shi 2017 University of Kentucky

Catalytic Oxidation And Depolymerization Of Lignin In Aqueous Ionic Liquid, Lalitendu Das, Siquan Xu, Jian Shi

Biosystems and Agricultural Engineering Faculty Publications

Lignin is an integral part of the plant cell wall, which provides rigidity to plants, also contributes to the recalcitrance of the lignocellulosic biomass to biochemical and biological deconstruction. Lignin is a promising renewable feedstock for aromatic chemicals; however, an efficient and economic lignin depolymerization method needs to be developed to enable the conversion. In this study, we investigated the depolymerization of alkaline lignin in aqueous 1-ethyl-3-methylimidazolium acetate [C2C1Im][OAc] under oxidizing conditions. Seven different transition metal catalysts were screened in presence of H2O2 as oxidizing agent in a batch reactor. CoCl2 and …


Seismic Facies Classification Of An Intraslope Minibasin In The Keathley Canyon, Northern Gulf Of Mexico, Lamine Meroudj 2017 University of New Orleans

Seismic Facies Classification Of An Intraslope Minibasin In The Keathley Canyon, Northern Gulf Of Mexico, Lamine Meroudj

LSU New Orleans Theses and Dissertations

This work examines several volume attributes extracted from 3D seismic data with the goal of seismic facies classification and lithology prediction in intraslope minibasins. The study area is in the Keathley Canyon protraction (KC), within the middle slope of the Northern Gulf of Mexico (GOM). It lays within the tabular salt and minibasins province downdip of the main Pliocene and Pleistocene deltaic depocenters. Interaction between sedimentation and mobile salt substrate lead to the emergence of many stratigraphic patterns in the intraslope minibasins. Interest in subsalt formations left above salt formations poorly logged. Facies classification using Artificial Neural Network (ANN) was …


Enhancements In Mass Transfer For Carbon Capture Solvents Part I: Homogeneous Catalyst, Leland R. Widger, Moushumi Sarma, Jonathan J. Bryant, David S. Mannel, Jesse G. Thompson, Cameron A. Lippert, Kunlei Liu 2017 University of Kentucky

Enhancements In Mass Transfer For Carbon Capture Solvents Part I: Homogeneous Catalyst, Leland R. Widger, Moushumi Sarma, Jonathan J. Bryant, David S. Mannel, Jesse G. Thompson, Cameron A. Lippert, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The novel small molecule carbonic anhydrase (CA) mimic [CoIII(Salphen-COO)Cl]HNEt3 (1), was synthesized as an additive for increasing CO2 absorption rates in amine-based post-combustion carbon capture processes (CCS), and its efficacy was verified. 1 was designed for use in a kinetically slow but thermally stable blended solvent, containing the primary amines 1-amino-2-propanol (A2P) and 2-amino-2-methyl-1-propanol (AMP). Together, the A2P/AMP solvent and 1 reduce the overall energy penalty associated with CO2 capture from coal-derived flue gas, relative to the baseline solvent MEA. 1 is also effective at increasing absorption kinetics of kinetically fast solvents, such …


An Economic Analysis Of Residential Photovoltaic Systems With And Without Energy Storage, Rodney Moses Kizito 2017 University of Arkansas, Fayetteville

An Economic Analysis Of Residential Photovoltaic Systems With And Without Energy Storage, Rodney Moses Kizito

Graduate Theses and Dissertations

Residential photovoltaic (PV) systems serve as a source of electricity generation that is separate from the traditional utilities. Investor investment into residential PV systems provides several financial benefits such as federal tax credit incentives for installation, net metering credit from excess generated electricity added back to the grid, and savings in price per kilowatt-hour (kWh) from the PV system generation versus the increasing conventional utility price per kWh. As much benefit as stand-alone PV systems present, the incorporation of energy storage yields even greater benefits. Energy storage (ES) is capable of storing unused PV provided energy from daytime periods of …


A Laboratory-Scale Study On The Production Of High-Value Products From Broiler Litter Involving Solid-State Anaerobic Digestion And Mushroom Cultivation, Joe Barrett Carter III 2017 University of Arkansas, Fayetteville

A Laboratory-Scale Study On The Production Of High-Value Products From Broiler Litter Involving Solid-State Anaerobic Digestion And Mushroom Cultivation, Joe Barrett Carter Iii

Graduate Theses and Dissertations

There is a need to investigate alternate uses and treatments of broiler litter that lessen environmental impacts and decrease costs associated with its disposal. Anaerobic digestion is a biological process in which organic material is converted to a renewable fuel source. However, the substrate for anaerobic digestion often requires some form or pretreatment. Certain types of fungus have been investigated as a pretreatment for anaerobic digestion, one of which is Pleurotis ostreatus or the oyster mushroom, which also produces an edible fruiting body. Thus, this study was performed to investigate the use of broiler litter for oyster mushroom cultivation and …


Evaluating One-Step Catalytic Free Method Including Hydrolysis, Esterification, Transesterification, And Degradation Reactions To Produce Biodiesel From Soybean Oil, Mahmood Gheni Jebur 2017 University of Arkansas, Fayetteville

Evaluating One-Step Catalytic Free Method Including Hydrolysis, Esterification, Transesterification, And Degradation Reactions To Produce Biodiesel From Soybean Oil, Mahmood Gheni Jebur

Graduate Theses and Dissertations

Due to the environmental and economic impacts of diesel fuel based on petroleum, several studies have been done to find an alternative source of energy. Biodiesel is considered one of these alternative sources. It is a renewable source of energy produced from vegetable oils and animal fats. There are two main reaction routes used to produce biodiesel (fatty acid methyl esters). Transesterification reaction is the first route used to convert triglycerides to fatty acid methyl esters (FAMEs), while hydrolysis followed by esterification reactions are the second route employed to convert triglycerides to free fatty acids (FFA) and then further converted …


The Impact Weather Has On Nyc Citi Bike Share Company Activity, Mark Martinez 2017 Colby College

The Impact Weather Has On Nyc Citi Bike Share Company Activity, Mark Martinez

Journal of Environmental and Resource Economics at Colby

This paper seeks to figure out the effect weather has on individuals’ behavior. A more focused approach to determining this effect is seeing how different weather conditions ranging from the temperature, the precipitation, the amount of inches of snowfall and the wind speed effect the ridership of Citi Bikes throughout all four seasons. The approach of this research paper is using data from the National Climatic Data Center that focuses in on the weather found in Manhattan, New York and correlates each of the weather conditions to the total number of trips per day that is provided by the Citi …


Electricity Demand Due To Policy Change In The U.K., Kevin W. Doherty 2017 Colby College

Electricity Demand Due To Policy Change In The U.K., Kevin W. Doherty

Journal of Environmental and Resource Economics at Colby

This paper examines United Kingdom Electricity Demand with regards to the Climate Change Act, which was enacted in November of 2008. Through actual demand data obtained from Nationalgrid, a U.K. based gas and electric utility company, this paper seeks to find out if the Climate Change Act has started to achieve its goal of reducing carbon emissions by looking at trends of electricity demand. Burning fossil fuels to produce electricity is a major contributor to global warming in the U.K. and policies enacted do not always live up to their ultimate goals. This paper tests how on track the Climate …


The Demographic Drivers Of California’S Environmental Voting, Lukas Yasuda 2017 Colby College

The Demographic Drivers Of California’S Environmental Voting, Lukas Yasuda

Journal of Environmental and Resource Economics at Colby

This study examines the demographics of California’s 53 congressional districts and the relationship with the voting patterns on three environmentally focused propositions in the 2008 and 2010 elections. Previous literature on the topic is mixed as some studies suggest that select attributes are found among environmental voting centers, yet other research describes the relationship as more complex than simple characteristics. Previous literature on the topic is mixed, with some studies suggesting that select attributes are found among environmental vote support hubs, whereas alternative research suggests the problem is more complex than simple characteristics. I collected data on income, education, age, …


The Long-Term Effect Of State Renewable Energy Incentive Programs, Fred Bower 2017 Colby College

The Long-Term Effect Of State Renewable Energy Incentive Programs, Fred Bower

Journal of Environmental and Resource Economics at Colby

Abstract: Renewable energy is praised for its environmental benefits and long run energy savings, however, for the average consumer, the up-front cost of this infrastructure deters investment. On the Federal and state level, incentive programs have been implemented to break down these initial barriers and give easier access to renewable energy. Studies have shown that these incentive programs have been successful at the consumer level (Crago, 2014). What policy makers and government officials should maybe be more concerned with though, is the long-term effect of these programs. This paper will analyze the long-term effect of renewable energy incentive programs beyond …


The Effects From Public Transportation On Property Values: A Closer Look At Scituate, Hanover, And Norwell, Massachusetts, Alexandra Taylor Perticone, Christine S. Coveney 2017 Colby College

The Effects From Public Transportation On Property Values: A Closer Look At Scituate, Hanover, And Norwell, Massachusetts, Alexandra Taylor Perticone, Christine S. Coveney

Journal of Environmental and Resource Economics at Colby

Prior studies have expressed the value of location in real estate, but more recent studies have explored the influence that public transportation has had on housing prices. Access to public transportation is understood to increase the value of homes. Easier access to public transportation allows for shorter and more convenient commutes into or within cities. However, other studies have found that proximity to public transportation can also have adverse effects on property values. This paper investigates whether the implementation of the Greenbush Commuter line in Massachusetts in October 2007 increased the housing prices in Scituate, Ma--the furthest town from the …


When Trash Costs Money: Analyzing The Impact Of Pay-As-You-Throw Programs In Massachusetts, Thomas W. Barry IV 2017 Colby College

When Trash Costs Money: Analyzing The Impact Of Pay-As-You-Throw Programs In Massachusetts, Thomas W. Barry Iv

Journal of Environmental and Resource Economics at Colby

This paper evaluates whether municipalities with Pay-As-You-Throw (PAYT) programs dispose of less trash per household than municipalities without them. Given how much trash U.S. residents produce, the negative environmental effects associated with trash disposal, as well as how much the U.S. Environmental Protection Agency advocates for PAYT, it is important to closely analyze whether these programs actually do their job. This paper formally analyzes the effects of PAYT programs using the Massachusetts Department of Environmental Protection’s trash disposal data from 2011-2015. After controlling for municipality and time heterogeneity, my analysis shows that PAYT programs reduce trash per household by a …


Invited Introduction To Jerec, Matthew Kahn 2017 University of Southern California and NBER

Invited Introduction To Jerec, Matthew Kahn

Journal of Environmental and Resource Economics at Colby

No abstract provided.


Welcome By The Editor, Nathan W. Chan 2017 Colby College

Welcome By The Editor, Nathan W. Chan

Journal of Environmental and Resource Economics at Colby

No abstract provided.


Book Review: Peak Oil: Apocalyptic Environmentalism And Libertarian Political Culture, Matthew Schneider-Mayerson, The University Of Chicago Press, Chicago And London (2015), Corrie Grosse 2017 College of Saint Benedict/Saint John's University

Book Review: Peak Oil: Apocalyptic Environmentalism And Libertarian Political Culture, Matthew Schneider-Mayerson, The University Of Chicago Press, Chicago And London (2015), Corrie Grosse

Environmental Studies Faculty Publications

No abstract provided.


One-Step Laser-Induced Hydrogen Generation From Coal Powders In Water, Dovletgeldi Seyitliyev 2017 Western Kentucky University

One-Step Laser-Induced Hydrogen Generation From Coal Powders In Water, Dovletgeldi Seyitliyev

Masters Theses & Specialist Projects

This study presents a simple way of obtaining hydrogen gas (H2) from various ranks of coal, coke, and graphite using nanosecond laser pulses. Powder samples of coal and graphite with and without water were irradiated with 1064 nm and 532 nm pulses from an Nd: YAG laser for 45 minutes under air and argon atmospheres. It was observed that 532 nm laser pulses were more effective than 1064 nm pulses in gas generation and both were nonlinearly correlated with respect to the laser energy density. Mainly hydrogen (H2) and carbon monoxide (CO) were observed. The H2 to CO ratio shows …


Solvent Degradation And Emissions From A 0.7mwe Pilot Co2 Capture System With Two-Stage Stripping, Jesse Thompson, Heather Nikolic, Megan Combs, Saloni Bhatnagar, Jonathan Pelgen, Keemia Abad, Kunlei Liu 2017 University of Kentucky

Solvent Degradation And Emissions From A 0.7mwe Pilot Co2 Capture System With Two-Stage Stripping, Jesse Thompson, Heather Nikolic, Megan Combs, Saloni Bhatnagar, Jonathan Pelgen, Keemia Abad, Kunlei Liu

Center for Applied Energy Research Faculty and Staff Publications

The UKy-CAER team successfully tested an advanced 0.7 MWe post-combustion CO2 capture system on a coal-fired power plant using a heat integration process combined with two-stage stripping to enhance the CO2 absorber performance. One of the unique feature of the UKy-CAER integrated process is a two-stage stripping unit for solvent regeneration. The secondary stripper is empowered by the heat rejection from a conventional steam-heated (primary) stripper. The secondary stripper outlet stream at the commercial scale can be used as boiler secondary combustion air, consequently enriching the flue gas with CO2, resulting in less energy penalty required …


Extraction Of Oil From The Bakken Shales With Supercritical Co2, Lu Jin, Steven B. Hawthorne, James A. Sorensen, Bethany A. Kurz, Steven A. Smith, Loreal V. Heebink, Nicholas W. Bosshart, José A. Torres, Chantsalmaa Dalkhaa, Charles D. Gorecki, Edward N. Steadman, John A. Harju 2017 University of North Dakota. Energy and Environmental Research Center

Extraction Of Oil From The Bakken Shales With Supercritical Co2, Lu Jin, Steven B. Hawthorne, James A. Sorensen, Bethany A. Kurz, Steven A. Smith, Loreal V. Heebink, Nicholas W. Bosshart, José A. Torres, Chantsalmaa Dalkhaa, Charles D. Gorecki, Edward N. Steadman, John A. Harju

EERC Publications, Papers, & Presentations

Results from 20 samples showed that supercritical CO2 enables extraction of a considerable portion (15%–65%) of the hydrocarbons from the Bakken shales within 24 hours. The results may be used to improve modeling and forecasting the effects of CO2 enhanced oil recovery (EOR) and suggest the possibility for increasing ultimate recovery, and possibly CO2 storage, in some areas of the Bakken Formation.


Pore Resolved Simulations Of Char Particle Gasification, Greg Hingwah Fong 2017 Marquette University

Pore Resolved Simulations Of Char Particle Gasification, Greg Hingwah Fong

Master's Theses (2009 -)

Coal is a significant source of energy in today’s world and many studies have been conducted in order to better understand and optimize its use. To address greenhouse effects associated with coal combustion, cleaner methods for harnessing its energy are being explored. One such method is gasification, a process which converts coal into syngas, a mixture consisting primarily of H2 and CO. Syngas can be used to generate electricity or to produce hydrocarbons that can be used as fuels. To better understand and optimize the process, simulations can be used to study the gasification of individual porous char particles that …


Carbon And Nutrient Balances In Microalgal Bioenergy System, Eunyoung Lee 2017 University of South Florida

Carbon And Nutrient Balances In Microalgal Bioenergy System, Eunyoung Lee

USF Tampa Graduate Theses and Dissertations

This research investigated life cycle environmental impacts and benefits of an integrated microalgae system with wastewater treatment system using an integrated process modeling approach combined with experimentation. The overall goal of this research is to understand energy, carbon and nutrient balances in the integrated system and to evaluate the environmental impacts and benefits of the integrated system from a carbon, nutrient, and energy perspective. In this study, four major research tasks were designed to contribute to a comprehensive understanding of the environmental and economic sustainability of the integrated system, which included development of an integrated co-limitation kinetic model for microalgae …


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