Condensed Matter Physics Commons^™

Mössbauer Effect Determination Of Relative Recoilless Fractions For Iron Oxides, Sei J. Oh, Desmond C. Cook

Physics Faculty Publications

The relative recoilless fraction (F-value) of each of six iron oxides, defined as the ratio of the recoil-free fractions of two different materials, was experimentally determined relative to hematite at 300 K and 77 K by Mössbauer spectroscopy. Using the relative recoil-free fractions compared to that of hematite, the relative recoilless fractions between all pairs of the seven iron oxides were determined. The F-values can allow conversion of Mössbauer subspectral areas to the relative atomic, molecular, or weight fractions of each iron oxide present in a mixed oxide phase sample.

Time-Resolved Reflection High-Energy Electron Diffraction Study Of The Ge(111)-C(2×8)-(1×1) Phase Transition, Xinglin Zeng, Bo Lin, Ibrahim El-Kholy, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The dynamics of the Ge(111)-c(2×8)-(1×1) phase transition is investigated by 100-ps time-resolved reflection high-energy electron diffraction. A laser pulse heats the surface while a synchronized electron pulse is used to obtain the surface diffraction pattern. Slow heating shows that the adatoms in Ge(111)-c(2×8) start to disorder at ∼510 K and are converted to a disordered adatom arrangement at 573 K. For heating with 100-ps laser pulses, the Ge(111)-c(2×8) reconstructed adatom arrangement starts to disorder at 584±16K, well above the onset temperature of ∼510 K for the disordering of Ge(111)-c(2×8) observed for slow …

Surface Morphology Of Laser-Superheated Pb(111) And Pb(100), Z. H. Zhang, Bo Lin, X. L. Zeng, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The surface step density on the vicinal Pb(111) and the surface vacancy density on Pb(100) after laser superheating and melting are investigated using reflection high-energy electron diffraction. With ∼100-ps laser pulses, Pb(111) surface superheating does not significantly change the density of the steps and step-edge roughness. However, after laser surface melting, the average terrace width and the string length at the step edge become as large as those at room temperature. The average terrace width at 573 K changes from 38±15 to 64±19 Å after laser surface melting, while the average string length at the step edge changes from 90±14 …

Temperature Dependence Of Step Density On Vicinal Pb(111), Z. H. Zhang, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The temperature dependence of step density on the vicinal Pb(111) surface is investigated using reflection high-energy electron diffraction. When the temperature is increased from 323 to 590 K. the average terrace width and the average string length at the step edge decrease from 85±25 to 37±16 Å and from 220±33 to 25±8 Å, respectively. Thermal step collapse on the Pb(111) surface near its bulk melting temperature is not observed. Above 530±7 K, the change in the string length at the step edge with temperature becomes small, and the intensity of the (00) beam is significantly decreased. We conclude that partial …

Femtosecond Photoemission Study Of Ultrafast Electron Dynamics In Single-Crystal Au(111) Films, J. Cao, Y. Gao, H. E. Elsayed-Ali, R. J. D. Miller, D. A. Mantell

Electrical & Computer Engineering Faculty Publications

The energy-dependent relaxation of photoexcited electrons has been measured by time-resolved two-photon photoemission spectroscopy on single-crystal Au(111) films with thickness ranging from 150 to 3000 Å. It is found that the energy-dependent relaxation does not show any significant thickness dependence, which indicates that electron transport is a much slower dynamical process in the near-surface region than expected from bulk properties. Furthermore, lifetimes of the photoexcited electrons can be fitted well by the Fermi-liquid theory with a scaling factor plus an effective upper lifetime. This observation enables separation of electron-electron scattering, and to a lesser extent electron-phonon scattering, processes from electron-transport …

Reflection High-Energy Electron-Diffraction Study Of Melting And Solidification Of Pb On Graphite, Z. H. Zhang, P. Kulatunga, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The melting and solidification of Pb thin films on pyrolytic graphite are investigated in situ by reflection high-energy electron diffraction. Thin films with thicknesses of 4-150 monolayers are investigated. The surface morphology of the thin films were studied by scanning electron microscopy. Superheating of the Pb thin films by 4±2 to 12±2 K is observed from diffraction intensity measurements. Upon cooling the substrate, the Pb on graphite is seen to supercool by ∼69±4 K.

Femtosecond Photoemission Study Of Ultrafast Electron Dynamics On Cu(100), J. Cao, Y. Gao, R. J. D. Miller, Hani E. Elsayed-Ali, D. A. Mantell

Electrical & Computer Engineering Faculty Publications

The energy dependence of the relaxation of photoexcited electrons in copper was measured using femtosecond time-resolved photoemission spectroscopy to within 0.3 eV above the Fermi level. By performing lifetime measurements under different surface conditions, several surface dynamical processes were investigated. In particular, an anomalous long lifetime feature, which cannot be explained with Fermi-liquid theory, was observed in the lifetime-energy curve. This feature was found originating from the photoexcitation of the strongly localized Cu 3d electrons. ©1997 American Physical Society

Mechanical Alloying Of Nitrogen Into Iron Powders, J. Rawers, D. Govier, D. C. Cook

Physics Faculty Publications

Mechanical alloying of nitrogen into bcc-fe powder is a very effective and efficient means of obtaining very high concentration of nitrogen in micron-size iron particles. Mechanical alloying increases the concentration of nitrogen in the iron powder far in excess of the bcc-Fe lattice low nitrogen solubility, however most of the infused nitrogen resides on the nano-size grain boundaries and in nano-size bct-fe that forms during mechanical alloying.

Measurement Of Nuclear Quadrupole Interactions Using Mössbauer Spectroscopy, Desmond C. Cook

Physics Faculty Publications

Mössbauer spectroscopy is a useful probe for investigating nuclear quadrupole interactions. It enables the magnitude, sign and asymmetry of the electric quadrupole coupling constant to be determined. It is especially important for its ability to measure these parameters for excited nuclear states. The Mössbauer effect is used to measure excited state quadrupole moments in materials whose electric field gradient (EFG) is known. More commonly however, it is used to determine the EFG from which atomic bonding and electronic structure are determined. The technique also allows temperature dependent orientation of sublattice magnetization to be measured using the direction of the electric …

Nuclear Forward-Scattering Of Synchrotron Radiation From Krypton: First Observation And Application To The Study Of Lattice Dynamics In Near-Monolayer Krypton-On-Graphite, David Eric Johnson

Physics Theses & Dissertations

Since 1985 nuclear-resonant scattering, and in particular nuclear forward-scattering, of synchrotron radiation has been observed in a select few Mossbauer isotopes including: ⁵⁷Fe, ¹¹⁹Sn, ¹⁶⁹Tm. For the first time, nuclear forward-scattering from the 9.4 keV Mossbauer level in ⁸³Kr has been observed. A large resonance effect, comparable to that in ⁵⁷Fe, has been observed in a variety of systems containing Kr including bulk crystals and physisorbed Kr-on-exfoliated graphite. Previous nuclear-resonant scattering experiments using synchrotron radiation have consisted of demonstration experiments. Nuclear forward-scattering from Kr has been applied to study the lattice dynamics of near-monolayer Kr-on-graphite …

Compensation And Characterization Of Gallium Arsenide, Randy A. Roush

Electrical & Computer Engineering Theses & Dissertations

The properties of transition metals in gallium arsenide have been previously investigated extensively with respect to activation energies, but little effort has been made to correlate processing parameters with electronic characteristics. Diffusion of copper in gallium arsenide is of technological importance due to the development of GaAs:Cu bistable photoconductive devices. Several techniques are demonstrated in this work to develop and characterize compensated gallium arsenide wafers. The material is created by the thermal diffusion of copper into silicon-doped GaAs. Transition metals generally form deep and shallow acceptors in GaAs, and therefore compensation is possible by material processing such that the shallow …

Scanning-Tunneling-Microscopy Study Of Pb On Si(111), D. Tang, H. E. Elsayed-Ali, J. Wendelken, J. Xu

Electrical & Computer Engineering Faculty Publications

Scanning-tunneling microscopy has been used to study temperature and coverage dependence of the structure of lead on the Si(111)-7×7 surface. For low Pb coverage, the Pb atoms favored the faulted sites. The ratio between the number of Pb atoms on faulted to unfaulted sites increased after sample annealing. An energy difference of 0.05 eV associated with a Pb atom on these two sites is estimated. The mobility of Pb atoms on Si(111) was observed at a temperature as low as 260°C for a coverage of 0.1 and 1 ML. © 1995 The American Physical Society.

Reflection High-Energy Electron-Diffraction Study Of Surface Disorder And Anomalous Expansion Of Pb(100), D. Tang, H. E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

The temperature-dependent surface structural behavior of Pb(100) is studied using reflection high-energy electron diffraction. Anomalous surface expansion for temperatures between room temperature to about 500 K is observed. A high density of surface vacancies appears at temperatures above ~ 500 K. © 1994 The American Physical Society.

Direct Measurements Of The Transport Of Nonequilibrium Electrons In Gold Films With Different Crystal Structures, T. Juhasz, H. E. Elsayed-Ali, G. O. Smith, C. Suárez, W. E. Bron

Electrical & Computer Engineering Faculty Publications

The transport of femtosecond-laser-excited nonequilibrium electrons across polycrystalline and single-crystalline gold films has been investigated through time-of-flight measurements. The thicknesses of the films range from 25 to 400 nm. Ballistic electrons as well as electrons interacting with other electrons and/or with the lattice have been observed. The ballistic component dominates the transport in the thinner films, whereas the interactive transport mechanism is dominant at the upper end of the thickness range. A slower effective velocity of the interactive component is observed in the polycrystalline samples, and is assumed to arise from the presence of grain boundaries. The reflection coefficient of …

Study Of The Heavy Fermion/Spin-Glass System, Ce1-X GdX Al3, Using 155Gd Mossbauer Spectroscopy, Nicholas G. Ruggiero

Physics Theses & Dissertations

The magnetic properties of Ce_1-xGd_x.Al₃ have been studied using ¹⁵⁵Gd Mossbauer spectroscopy. It has been shown that the magnetic moments of the host GdAl₃ are constrained to the basal plane. The magnetic properties of GdAl₃ can best be described in the framework of RKKY theory. Prior studies of Ce_1-xGd_xAl₃, have revealed complex magnetic behavior throughout the series. As observed with Mossbauer spectroscopy magnetic ordering occurs for x ≥ 0.5, though not at the reported spin glass temperatures. For x = 0.23 and x = 0.18, the …

Magnetic-Field Distributions In Zinc-Nickel Ferrite, T. A. Dooling, Desmond C. Cook

Physics Faculty Publications

The Mössbauer effect has been used to study the microscopic magnetic properties of the cubic microwave ferrite (Zn_0.41Ni_0.59)Fe₂O₄ at 300 K. The magnetically split spectrum is broad and unresolved due to the overlap of the hyperfine magnetic fields at the tetrahedral and octahedral sites. This is caused by a distribution of magnetic fields at each site. The distribution is especially large and asymmetric at the octahedral site and is due to the fact that the iron atoms at this site are influenced by the presence of both iron and zinc at the tetrahedral …

Phase Changes In Plasma‐Sprayed Zinc‐Nickel Ferrite, T. A. Dooling, Desmond C. Cook

Physics Faculty Publications

The magnetic and crystalline properties of a plasma‐sprayed coating of the microwave absorbing zinc‐nickel ferrite, (Zn_0.41Ni_0.59 )Fe₂O₄ have been studied at 300 K using the Mössbauer effect and x‐ray diffraction (XRD). Both techniques indicate that the plasma‐sprayed material separated into two phases. The first is a nickel‐rich phase with magnetic fields of 47.5 and 44.5 T at the tetrahedral and octahedral sites, respectively. The second is a zinc‐rich phase, zinc meta‐ferrite, having a small magnetic field of 4.2 T. The quadrupole splitting of this second phase is ΔE=0.34 mm s⁻¹, …

The Study Of Oxygen Transport Through Polycrystalline, Single Crystal And Alloyed Silver, Dongchuan Wu

Physics Theses & Dissertations

The permeation of oxygen through large grain polycrystalline silver, through the (110), (111) and (100) single crystals of silver and through Ag0.05Zr alloy have been studied over the temperature range of 400 - 800 °C. In addition, studies were also conducted using glow discharge dissociation of the supply side ( upstream ) molecular oxygen in order to examine whether normal dissociative adsorption is a limiting step in the overall transport process.

The permeability of oxygen through polycrystalline silver was found to be quite linear and quite repeatable. The diffusivity measurements were found to exhibit two distinct linear regions, one above …

Mössbauer Spectroscopic Studies Of Hemoglobin And Its Isolated Subunits, G. R. Hoy, D. C. Cook, R. L. Berger, F. K. Friedman

Physics Faculty Publications

Samples of 90% enriched ⁵⁷Fe hemoglobin and its isolated subunits have been prepared. Mössbauer spectroscopic measurements have been made on three such samples. Sample one contained contributions of oxyhemoglobin, deoxyhemoglobin, and carbonmonoxyhemoglobin. This sample was studied from a temperature of 90 K down to 230 mK. Measurements were also made at 4.2 K using a small applied magnetic field of 1.0 T. In general, the measured quadrupole splittings and isomer shifts for each component agreed with previous measurements on single component samples in the literature, and thus demonstrated that chemically enriched hemoglobin has not been altered. The second and …

Feasibility Studies Of Conversion Electron Mössbauer Spectroscopy (Cems) Of Iron-Doped Inp, Gilbert R. Hoy, Desmond C. Cook, Edward Agyekum

Physics Faculty Publications

An electron detector for conversion electron Moessbauer spectroscopy CEMS has been designed and built. Tests have been performed to study the effects on the detector resolution with respect to high voltage, gas flow rate, and counting rate. These parameters have been optimized to detect the 7.3keV conversion electrons emitted following resonant absorption of the 14.4keV source gamma rays associated with the Moessbauer effect using Fe57. CEMS spectra have been obtained using standard Fe57 enriched and natural iron samples. CEMS spectra have also been obtained for InPFe samples supplied by the Naval Research Laboratory. So far we have only been successful …