Open Access. Powered by Scholars. Published by Universities.®

Chemistry Commons™

Open Access. Powered by Scholars. Published by Universities.®

2021

Discipline
Institution
Keyword
Publication
Publication Type
File Type

Articles 1321 - 1350 of 1742

Full-Text Articles in Chemistry

Optimization For Esterification Of Saturated Palm Fatty Acid Distillate By D-Optimal Design Response Surface Methodology For Biolubricant Production, Majd Jumaah, Nadia Salih, Jumat Salimon Jan 2021

Optimization For Esterification Of Saturated Palm Fatty Acid Distillate By D-Optimal Design Response Surface Methodology For Biolubricant Production, Majd Jumaah, Nadia Salih, Jumat Salimon

Turkish Journal of Chemistry

This work presents a synthesis of palm fatty acid distillate (PFAD)-based esters to produce biolubricant oils through the esterification reaction between saturated palm fatty acid distillate (SFA-PFAD) with different types of high degree polyhydric alcohols such as trimethylolpropane (TMP), di-trimethylolpropane (Di-TMP), pentaerythritol (PE), and di-pentaerythritol (Di-PE) in the presence of sulfuric acid as catalyst. The chemical structures of synthesized SFA PFAD-based esters were characterized and confirmed by using FTIR, NMR (1H and 13C) spectroscopies and GC-FID chromatography. The FTIR spectra of SFA PFAD-based ester products clearly showed the peaks of C=O and C-O of ester group at 1732-1740 cm-1 and …

Go to article

Polycyclic Aromatic Hydrocarbon-Substituted Push-Pull Chromophores: An Investigationof Optoelectronic And Nonlinear Optical Properties Using Experimental And Theoreticalapproaches, Çağatay Dengi̇z Jan 2021

Polycyclic Aromatic Hydrocarbon-Substituted Push-Pull Chromophores: An Investigationof Optoelectronic And Nonlinear Optical Properties Using Experimental And Theoreticalapproaches, Çağatay Dengi̇z

Turkish Journal of Chemistry

A series of new push-pull chromophores were synthesized in moderate to very high yields (65%?97%) by treating TCNE and TCNQ with alkynes substituted by electron-rich diethylaniline and polycyclic aromatic hydrocarbons. Some of the chromophores exhibit strong intramolecular charge-transfer bands in the near-IR region with λmax values between 695 and 749 nm. With the help of experimental and theoretical analysis, it is concluded that the trend in λmax values is affected by PAH substituents sterically, not electronically. Steric constraints led to the increased dihedral angles, reducing conjugation efficiencies. The absorption properties of push-pull compounds have been investigated in solvents possessing different …

Go to article

Antiinfective Properties Of Ursolic Acid-Loaded Chitosan Nanoparticles Againststaphylococcus Aureus, Fatemeh Ghasemzadeh, Ghasem Najafpour, Maedeh Mohammadi Jan 2021

Antiinfective Properties Of Ursolic Acid-Loaded Chitosan Nanoparticles Againststaphylococcus Aureus, Fatemeh Ghasemzadeh, Ghasem Najafpour, Maedeh Mohammadi

Turkish Journal of Chemistry

The present study aimed to synthesize ursolic acid-loaded chitosan nanoparticles (UA-Ch-NPs) as an antiinfective agent against 21 Staphylococcus aureus isolates. The UA-Ch-NPs were synthesized by a simple method and then characterized by TEM, FTIR, DLS-zeta potential, and XRD analyses. According to the characterization results, highly dispersed spherical nanoparticles with a mean diameter of 258 nm and a zeta potential of + 40.1 mV were developed. The antibacterial properties of UA-Ch-NPs were investigated and their inhibitory effect on biofilm formation was demonstrated by AFM. Finally, the expression levels of icaA and icaD were measured using real-time PCR. Results indicated that the …

Go to article

Acetylene Hydrochlorination Over Tin Nitrogen Based Catalysts: Effect Of Nitrogen Carbondotsas Nitrogen Precursor, Yibo Wu, Fuxiang Li, Qingbin Li, Songtian Li, Ganqing Zhao, Xuerong Sun, Peisong Liu, Guoxv He, Yongjun Han, Liping Cheng, Shiying Luo Jan 2021

Acetylene Hydrochlorination Over Tin Nitrogen Based Catalysts: Effect Of Nitrogen Carbondotsas Nitrogen Precursor, Yibo Wu, Fuxiang Li, Qingbin Li, Songtian Li, Ganqing Zhao, Xuerong Sun, Peisong Liu, Guoxv He, Yongjun Han, Liping Cheng, Shiying Luo

Turkish Journal of Chemistry

The catalysts comprising the main active compounds of Sn-Nx were synthesized using trichlorophenylstannane ((C6H5)Cl3Sn), nitrogen carbon-dots (NCDs), and activated carbon (AC) as starting materials, and the activity and stability of catalysts was evaluated in the acetylene hydrochlorination. According to the results on the physical and chemical properties of catalysts (TEM, XRD, BET, XPS and TG), it is concluded that NCDs@AC can increase (C6H5)Cl3Sn dispersity, retard the coke deposition of (C6H5)Cl3Sn/AC and lessen the loss of (C4H5)Cl3Sn, thereby further promoting the stability of (C6H5)Cl3Sn/AC. Based on the characterization results of C2H2- TPD and HCl adsorption experiments, we proposed that the existence …

Go to article

Sn(Ii)/Pn@Ac Catalysts: Synthesis, Physical-Chemical Characterization, And Applications, Yibo Wu, Fuxiang Li, Qingbin Li, Yongjun Han, Li Wang, Wei Ma, Fu Xv Jan 2021

Sn(Ii)/Pn@Ac Catalysts: Synthesis, Physical-Chemical Characterization, And Applications, Yibo Wu, Fuxiang Li, Qingbin Li, Yongjun Han, Li Wang, Wei Ma, Fu Xv

Turkish Journal of Chemistry

In this study, the novel tin-based catalysts (Sn(II)/PN@AC) were prepared using the phosphorus and nitrogen dual-modified activated carbon as support and SnCl2 as active compounds, as well as then evaluated in acetylene hydrochlorination. Under the reaction temperature of 180 °C and an acetylene gas hourly space velocity (GHSV-C2H2) of 30 h?1, the 15%Sn(II)/PN@AC-550 showed the initial acetylene conversion of 100% and vinyl chloride selectivity over 98.5%. Additionally, the deactivation rate of 15%Sn(II)/PN@AC-550 reached 0.47% h-1, which was lower than that of 15%Sn(II)/AC-550 (1.02% h-1), suggesting that PN@AC-550 as novel support can retarded the deactivation of Sn(II)/AC-550 catalysts during acetylene hydrochlorination. …

Go to article

A Survey On Surface Morphology Control Of Cross-Linked Poly(N-Vinylpyrrolidone)Polymer Particle Via Inverse Suspension Polymerization, Uğur Soykan, Sedat Çeti̇n Jan 2021

A Survey On Surface Morphology Control Of Cross-Linked Poly(N-Vinylpyrrolidone)Polymer Particle Via Inverse Suspension Polymerization, Uğur Soykan, Sedat Çeti̇n

Turkish Journal of Chemistry

This study mainly centers on the preparation and characterization of the cross-linked poly(NVP) microspheres by means of inverse suspension polymerization technique. The effect of the cross-linker content, the volumetric ratio of dispersed phase to suspension phase (DP/CP), agitation rate, and the reaction temperature on the characteristics of the microparticles were investigated meticulously using SEM, and the optimum preparation conditions were determined. The findings revealed that the morphological and surface properties of the obtained particles could be controlled easily by changing these parameters. Accordingly, the microparticles having the perfect spherical with smooth surface and good roundness, dumbbell-shaped, snowman besides dented, sunked …

Go to article

Preparation Of G-Cuo Nps And G-Zno Nps With Mallow Leaves, Investigation Of Theirantibacterial Behavior And Synthesis Of Bis(Indolyl)Methane Compounds Under Solventfreemicrowave Assisted Dry Milling Conditions Using G-Cuo Nps As A Catalyst, Mi̇ne Sulak Jan 2021

Preparation Of G-Cuo Nps And G-Zno Nps With Mallow Leaves, Investigation Of Theirantibacterial Behavior And Synthesis Of Bis(Indolyl)Methane Compounds Under Solventfreemicrowave Assisted Dry Milling Conditions Using G-Cuo Nps As A Catalyst, Mi̇ne Sulak

Turkish Journal of Chemistry

In this study, biogenic copper and zinc oxide nanoparticles (G-ZnONPs and G-CuONPs) were synthesized by the green synthesis method using Malva parviflora L. (Millow) leaf extract and the obtained nanoparticles were characterized in detail with UVVis, FTIR, SEM, XRD. The antibacterial properties of the synthesized nanoparticles on gram-positive and gram-negative bacteria were investigated and it was found that the nanoparticles had high antimicrobial activity in the results of the experiments. With the obtained G-CuONPs, the synthesis of bis(indolyl)methanes with the "green" one-pot synthesis using microwave was achieved quickly and with high efficiency, and the thermal behavior of the obtained products …

Go to article

Application Of Inverse Gas Chromatography In The Surface Characterization Of Diethanolamine Modified Polystyrene Based Polymer, Ayşegül Çi̇ğdem Adigüzel, Burak Korkmaz, Fati̇h Çakar, Bahi̇re Fi̇li̇z Şenkal, Özlem Cankurtaran Jan 2021

Application Of Inverse Gas Chromatography In The Surface Characterization Of Diethanolamine Modified Polystyrene Based Polymer, Ayşegül Çi̇ğdem Adigüzel, Burak Korkmaz, Fati̇h Çakar, Bahi̇re Fi̇li̇z Şenkal, Özlem Cankurtaran

Turkish Journal of Chemistry

In the present work, diethanol amine modified polystyrene based polymer (PVBC-Diethanol amine) was synthesized and characterized, then surface properties of the polymer were examined by inverse gas chromatography method at infinite dilution. The retention diagrams obtained based on the interaction of polar and nonpolar probes with the polymer were drawn over a temperature range from 30 to 55 °C. Through the diagrams, the dispersive component of the surface free energy, γSD of the polymer surface, and the specific enthalpy of adsorption, ΔHAS , of probes on the polymer were also calculated. Lewis acid, KA, and Lewis base, KD, parameters of …

Go to article

Pyridine Substituted Bodipys: Synthesis, Characterization And Cholinesterease,α-Glucosidase Inhibitory, Dna Hydrolytic Cleavage Effects, Burak Barut, Hüseyi̇n Baş, Zekeri̇ya Biyiklioğlu Jan 2021

Pyridine Substituted Bodipys: Synthesis, Characterization And Cholinesterease,α-Glucosidase Inhibitory, Dna Hydrolytic Cleavage Effects, Burak Barut, Hüseyi̇n Baş, Zekeri̇ya Biyiklioğlu

Turkish Journal of Chemistry

In this study, the synthesis of new monostyryl (BDPY-2) and distyryl BODIPY dyes (BDPY-4, BDPY-5) containing pyridine groups has been reported for the first time. The acetylcholinesterase from Electrophorus electricus (AChE), butyrylcholinesterase from equine serum (BuChE), α-glucosidase from Saccharomyces cerevisiae and DNA hydrolytic cleavage actions of BDPY-2, BDPY-4, BDPY- 5 were investigated using various techniques. The results indicated that the compounds had varying inhibition properties against AChE, BuChE, and α-glucosidase. BDPY-4 was the most potent compound on AChE with IC50 of 54.78 ± 4.51 μM, and Lineweaver-Burk plots indicated that the compound is bound to a site other than the …

Go to article

Dft (Density Functional Theory) Studies On Cycloisomerization Of 15-Memberedtriazatriacetylenic Macrocycle, Mansooreh Movahedi, Nader Zabarjad Hiraz, Ali Ezabadi, Marjaneh Samadizadeh, Mohamad Reza Talei Bavil Olyai Jan 2021

Dft (Density Functional Theory) Studies On Cycloisomerization Of 15-Memberedtriazatriacetylenic Macrocycle, Mansooreh Movahedi, Nader Zabarjad Hiraz, Ali Ezabadi, Marjaneh Samadizadeh, Mohamad Reza Talei Bavil Olyai

Turkish Journal of Chemistry

The mechanism as well the stereochemistry of cascade cycloisomerization of 15-membered triazatriacetylenic macrocycle was investigated theoretically by using M062X/6-31+G(d,p) and M062X/LANL2DZ calculations. The results showed that the mechanism and outcome of the reaction depended on the absence and presence of a transition metal catalyst. So that, in thermal-induced condition, the reaction had to experience several suprafacial concerted reactions including Ene-reaction (ΔG#=35.38 kcal/mol), Diels-Alder cycloaddition (ΔG# = 17.16 kcal/mol), and sigmatropic H-shift rearrangement (ΔG# = 56.21 kcal/mol) to produce diastereoselective fused cis-tetracyclic aromatic bearing a pyrrole moiety by following kinetic considerations. Also, the [2+2+2] cycloaddition mechanism was neglected in thermal?induced conditions …

Go to article

Cytotoxic And Apoptotic Effects Of Hypericum Androsaemum On Prostate Adenocarcinoma(Pc-3) And Hepatocellular Carcinoma (Hep G2) Cell Lines With Identification Of Secondarymetabolites By Lc-Hrms, Nurdan Yazici Bektaş, Ezgi̇ Ersoy, Mehmet Boğa, Tuğçe Boran, Ercan Çinar, Gül Özhan, Ahmet Ceyhan Gören, Esra Eroğlu Özkan Jan 2021

Cytotoxic And Apoptotic Effects Of Hypericum Androsaemum On Prostate Adenocarcinoma(Pc-3) And Hepatocellular Carcinoma (Hep G2) Cell Lines With Identification Of Secondarymetabolites By Lc-Hrms, Nurdan Yazici Bektaş, Ezgi̇ Ersoy, Mehmet Boğa, Tuğçe Boran, Ercan Çinar, Gül Özhan, Ahmet Ceyhan Gören, Esra Eroğlu Özkan

Turkish Journal of Chemistry

The study aims to determine the secondary metabolites of Hypericum androsaemum L. extracts by liquid chromatographyhigh resolution mass spectrometry (LC-HRMS), and investigate the antioxidant and cytotoxic activities of the plant. Cytotoxic activity was evaluated by MTT assay, and apoptosis induction abilities on human prostate adenocarcinoma (PC-3), and hepatocellular carcinoma (Hep G2) cell lines. Accordingly, major secondary metabolites were found as hederagenin (762 ± 70.10 μg/g) in the leaves dichloromethane (LD), herniarin (167 ± 1.50 μg/g) in fruit dichloromethane (FD), (-)-epicatechin (6538 ± 235.36 μg/g) in the leaves methanol (LM), (-)-epigallocatechin gallate (758 ± 20.46 μg/g) in the fruit methanol (FM), …

Go to article

Supramolecular Solvents: A Review Of A Modern Innovation In Liquid-Phase Microextraction Technique, Muhammad Saqaf Jagirani, Mustafa Soylak Jan 2021

Supramolecular Solvents: A Review Of A Modern Innovation In Liquid-Phase Microextraction Technique, Muhammad Saqaf Jagirani, Mustafa Soylak

Turkish Journal of Chemistry

Supramolecular solvents (SUPRASs) have rapidly gained more attention as a potential substitute to organic solvents in the sample preparation and preconcentration process. The essential properties of SUPRAS solvents (e.g., multiple binding sites, different polarity microenvironments, the opportunity to tailor their properties, etc.) these qualities offer numerous opportunities to advance innovative sample preparation and pretreatment platforms compared to the traditional solvents. Among these qualities, certain importance is placed on theoretical and practical knowledge. That has assisted in making significant developments in SUPRAS that advance our understanding of the processes behind SUPRA'S formation. The SUPRA-solute interactions that drive extractions are explored in …

Go to article

Glucosamine Derived Hydrothermal Carbon Electrodes For Aqueous Electrolyte Energy Storage Systems, Burcu Ünal, Rezan Demi̇r Çakan Jan 2021

Glucosamine Derived Hydrothermal Carbon Electrodes For Aqueous Electrolyte Energy Storage Systems, Burcu Ünal, Rezan Demi̇r Çakan

Turkish Journal of Chemistry

Nitrogen-doped porous hard carbons are synthesized by hydrothermal carbonization method (HTC) using glucosamine as biosource and treated at different carbonization temperatures in nitrogen environment (500, 750, 1000 °C). The electrochemical performances of hard carbons electrode materials for aqueous electrolyte sodium ion batteries are examined to observe the effect of two different voltage ranges (-0.8-0.0) V and (0.0-0.8) V in 1.0 M Na2SO4 aqueous electrolyte. The best electrochemical performances are acquired for the 1000 °C treated glucosamine (GA-1000) porous carbon sample that provides ~96 F/g capacitance value in the negative voltage range (between -0.8 and 0.0) V. The sodium diffusion coefficient …

Go to article

Cyclodextrin-Active Natural Compounds In Food Applications: A Review Of Antibacterial, Bingren Tian, Yumei Liu Jan 2021

Cyclodextrin-Active Natural Compounds In Food Applications: A Review Of Antibacterial, Bingren Tian, Yumei Liu

Turkish Journal of Chemistry

Many natural compounds have excellent activity against different bacteria. However, their food use to inhibit the bacteria is often limited by poor water solubility, or instability to light, heat, oxygen, and other environmental factors. Cyclodextrin combines with these natural compounds could not only overcome these shortcomings, but also increase the antibacterial ability of active compounds. This review focuses on the following aspects of active natural compounds in cyclodextrin-based food: the preparation, food applications, and their possible antibacterial mechanisms of different systems. Both cyclodextrin and its derivatives are able to selectively combine with different guest molecules, such as terpenes, phenols and …

Go to article

Antiinflammatory Photodynamic Therapy Potential Of Polyoxyethylene-Substituted Perylene Diimide, Nitrocatechol, And Azo Dye, Özgül Hakli, Kasim Ocakoğlu, Furkan Ayaz Jan 2021

Antiinflammatory Photodynamic Therapy Potential Of Polyoxyethylene-Substituted Perylene Diimide, Nitrocatechol, And Azo Dye, Özgül Hakli, Kasim Ocakoğlu, Furkan Ayaz

Turkish Journal of Chemistry

Photodynamic therapy (PDT) applications enable light-controlled activation of drug candidates instead of their constitutive activities to prevent undesired side effects associated with their constant activities. A specific wavelength of light is utilized to enable electron mobility in the chemical structure, which results in differential activities that may alter cell viability and cellular functions. Canonical photodynamic therapy applications mostly focus on cytotoxicity-based antimicrobial and anticancer properties of the PDT agents. In this study, we focused on subtoxic concentrations of three different molecules containing polyoxyethylene group and examined their antiinflammatory activities on stimulated mammalian macrophages. Stimulated macrophages produce proinflammatory cytokines TNF and …

Go to article

Structural, Surface Morphological, Optical And Electrical Properties Of Inxsey Thin Films, An Absorber Layer For Photovoltaic Cells Fabricated By M-Cbd Method Using Different Variables, Fati̇h Ünal, Serkan Demi̇r, Hasan Mammadov Jan 2021

Structural, Surface Morphological, Optical And Electrical Properties Of Inxsey Thin Films, An Absorber Layer For Photovoltaic Cells Fabricated By M-Cbd Method Using Different Variables, Fati̇h Ünal, Serkan Demi̇r, Hasan Mammadov

Turkish Journal of Chemistry

Mixed-phased InxSey thin film containing InSe, In2Se3 and In6Se7 phases was prepared by M-CBD method and characterized by X-ray diffraction, AFM, optical spectroscopy and J-V measurements. Structural, optical and electrical conductance properties were modified by annealing the films at different temperatures. Optical and morphological properties were also investigated dependently on temperature and concentration of cationic precursor solution. It has been observed with annealing that, the compositions of the phases changed, particle sizes increased, energy band gaps decreased and electrical conductivity increased. The photoconductivity of thin film was revealed by J-V measurements and slightly increased by annealing. From temperature-dependent J-V measurements, …

Go to article

Determination Of Characterization, Antibacterial And Drug Release Properties Of Poss-Based Film Synthesized With Sol-Gel Technique, İdi̇l Karaca Açari, Süleyman Köytepe, Burhan Ateş, İsmet Yilmaz, Turgay Seçki̇n Jan 2021

Determination Of Characterization, Antibacterial And Drug Release Properties Of Poss-Based Film Synthesized With Sol-Gel Technique, İdi̇l Karaca Açari, Süleyman Köytepe, Burhan Ateş, İsmet Yilmaz, Turgay Seçki̇n

Turkish Journal of Chemistry

In the study, antibacterial film synthesis was aimed using sol-gel technique from POSS structure with various functional groups. For this purpose, antibacterial properties have been acquired by metronidazole to the films to be synthesized. The films obtained were coated on glass surface samples by dip coating method. Antibacterial activities of surface coated glass samples were observed in E.coli and S. aureus bacteria. Metronidazole release studies in the film samples were followed by UV spectrophotometer. It was observed that drug release reached 68.90% at the end of the 24th h. As a result, it is thought that the synthesized film will …

Go to article

Study Of The Effectiveness Of A Presoaking Process For Reducing The Additives Migration From Babies Toys, Mohand Ouidir Boussoum, Aicha Kentaoui, Beatrice George, Stephane Dumarcay, Ahmed Boucherit, Hassiba Laribi Habchi Jan 2021

Study Of The Effectiveness Of A Presoaking Process For Reducing The Additives Migration From Babies Toys, Mohand Ouidir Boussoum, Aicha Kentaoui, Beatrice George, Stephane Dumarcay, Ahmed Boucherit, Hassiba Laribi Habchi

Turkish Journal of Chemistry

This research aims to study a process of steeping in the n-heptane, used for reducing the migration of additives contained initially in toys for babies plasticized with di-octylphtalate (DOP) based on poly (vinyl chloride) (PVC) and stabilized with epoxidized sunflower oil (ESO). Two formulations were carried out at different levels of DOP plasticizers (15% and 45%). The migration tests were conducted in the synthetic saliva in the absence and in the presence of α-amylase with or without agitation at 37° C for 1, 3, and 6 h. The migration phenomenon was studied on the basis of preliminary studies based on …

Go to article

Microwave Irradiated Synthesis Of Schiff Bases Of 4-(Arylideneamino)-5-Alkyl-2,4-Dihydro-1,2,4-Triazole-3-Thione Containing 1,2,4-Triazole Segment, Mahdi Shirmohammadi, Saeid Souzangarzadeh, Dadkhoda Ghazanfari, Mohsen Ghodratbeigi, Mohammad Reza Akhgar Jan 2021

Microwave Irradiated Synthesis Of Schiff Bases Of 4-(Arylideneamino)-5-Alkyl-2,4-Dihydro-1,2,4-Triazole-3-Thione Containing 1,2,4-Triazole Segment, Mahdi Shirmohammadi, Saeid Souzangarzadeh, Dadkhoda Ghazanfari, Mohsen Ghodratbeigi, Mohammad Reza Akhgar

Turkish Journal of Chemistry

Novel compounds based on the 1,2,4-triazole skeleton were synthesized. A class of 4-amino-5-alkyl-4H-1,2,4-triazole-3- thione created by reaction of thiocarbohydrazide with long-chain aliphatic carboxylic acids, and then the Schiff bases were obtained in the media of heat and microwave waves, in the presence and the absence of a catalyst. Their chemical structures were assayed by elemental analysis, also device spectroscopic methods.

Go to article

The Hydrothermal Synthesis Of Blue-Emitting Boron-Doped Cqds And Its Application For Improving The Photovoltaic Parameters Of Organic Solar Cell, Tuğbahan Yilmaz Jan 2021

The Hydrothermal Synthesis Of Blue-Emitting Boron-Doped Cqds And Its Application For Improving The Photovoltaic Parameters Of Organic Solar Cell, Tuğbahan Yilmaz

Turkish Journal of Chemistry

In this work, boron-doped CQDs (B-CQDs) were synthesized by using boric acid, urea, and citric acid via hydrothermal method to use as a novel additive material for poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) based organic solar cells. The OSCs with an inverted device structure were fabricated on titanium dioxide (TiO2) thin film. It was showed the crystallinity, morphological and optical properties of P3HT:PCBM films improved after B-CQDs additive. The best performance was obtained to be a 39.65% of FF, a 546 mV of Voc, an 8.606 mA cm-2 of Jsc after 3 vol.% B-CQDs addition in P3HT:PCBM blend. The power …

Go to article

Synthesis, Characterization, Cox1/2 Inhibition And Molecular Modeling Studies On Novel 2-Thio-Diarylimidazoles, Zafer Şahi̇n, Meli̇ke Kalkan, Barkin Berk, Leyla Yurttaş, Ceysu Bender, Sevde Nur Bi̇lteki̇n Kaleli̇, Şeref Demi̇rayak Jan 2021

Synthesis, Characterization, Cox1/2 Inhibition And Molecular Modeling Studies On Novel 2-Thio-Diarylimidazoles, Zafer Şahi̇n, Meli̇ke Kalkan, Barkin Berk, Leyla Yurttaş, Ceysu Bender, Sevde Nur Bi̇lteki̇n Kaleli̇, Şeref Demi̇rayak

Turkish Journal of Chemistry

Heterocyclic compounds with diaryl substituents have been a milestone approach for selective cyclooxygenase 2 (COX 2) inhibition by bioisosteric replacements and modifications. It is also known that thiazole derivatives have different pharmacological activities. In this study, nine novel 2-[(1,5-diphenyl-1H-imidazole-2-yl)thio]-N-(thiazole-2-yl)acetamide derivatives (Compound 1-9) were synthesized via the reaction of 1,5-disubstitued phenyl-imidazole-2-thiole and N-thiazole acetamide. The inhibitory effects of COX-1 and COX-2 enzymes were tested for the synthesized compounds. Enzyme-ligand interactions of the most active compound on COX subtypes were elucidated by molecular modeling studies. The percent inhibitory effect for compound 1, which is the naked derivative among all the compounds, was …

Go to article

The Removal Of Chromium (Vi) From Tannery Waste Using Spirulina Sp. Immobilized Silica Gel, Nais Pinta Adetya, Uma Fadzilia Arifin, Emiliana Anggriyani Jan 2021

The Removal Of Chromium (Vi) From Tannery Waste Using Spirulina Sp. Immobilized Silica Gel, Nais Pinta Adetya, Uma Fadzilia Arifin, Emiliana Anggriyani

Turkish Journal of Chemistry

The use of microalgae biomass is an alternative solution to the problem of environmental pollution due to heavy metals, one of which is Cr metal in leather tanning liquid waste. However, the ability of biomass to adsorb heavy metals has limitations. Therefore, the algal biomass is immobilized with silica gel in order to obtain a stable structure. This research aims to study the absorption efficiency of Cr (VI) metal by the biomass of Spirulina sp. which is immobilized with silica gel from the tannery liquid waste. The preparation stages in this study were adsorbent preparation, immobilization of biomass with silica …

Go to article

A Flame Retardant-Hardener For Epoxy Resins: Synthesis, Structural, And Dft Studies Of The [Cu(H2nc2h4nh2)2 (H2o)Cl]Cl Complex, Borys Mykhalichko, Helen Lavrenyuk, Oleg Mykhalichko Jan 2021

A Flame Retardant-Hardener For Epoxy Resins: Synthesis, Structural, And Dft Studies Of The [Cu(H2nc2h4nh2)2 (H2o)Cl]Cl Complex, Borys Mykhalichko, Helen Lavrenyuk, Oleg Mykhalichko

Turkish Journal of Chemistry

The aqua-bis(ethylenediamine)-chloro-copper(II) chloride complex, [Cu(en)2 (H2O)(Cl)]Cl (1), was synthesized by direct interaction of CuCl2×2H2O with pepa (pepa is a polyethylenepolyamine containing ethylenediamine (en)). The crystalline complex 1 was characterized by IR spectra and structurally studied. Crystals of this complex consist of the [Cu(en)2(H2O)(Cl)] + discrete cations, whose Cu2+ ion is chelated by two en molecules. The Cu(II) coordination polyhedron has the shape of an elongated square bipyramid, in which four nitrogen atoms of the -NH2 groups of en molecules form the base of this bipyramid, and the oxygen atom of the water molecule and Cl- are in its apical positions. …

Go to article

Novel Vic-Dioximes: Synthesis, Structure Characterization, And Antimicrobial Activity Evaluation, Dumitru Ureche, Ion Bulhac, Alexandru Ciocarlan, Daniel Roshca, Lucian Lupascu, Paulina Bourosh Jan 2021

Novel Vic-Dioximes: Synthesis, Structure Characterization, And Antimicrobial Activity Evaluation, Dumitru Ureche, Ion Bulhac, Alexandru Ciocarlan, Daniel Roshca, Lucian Lupascu, Paulina Bourosh

Turkish Journal of Chemistry

The vic-dioximes are compounds with various industrial uses and scientific applications. Many coordination compounds have been synthesized based on vic-dioximes. This study presents the synthesis and full characterization of two vic-dioximes based on dichloroglyoxime, p-aminobenzoic acid, and p-aminotoluene. Their structures were proved by IR, 1H, 13C and 15N NMR spectral analysis, and single crystal X-ray diffraction. One of the reported vic-dioximes, bis(di-p-aminotoluene)glyoxime mono-p-aminotoluene trihydrate showed good to moderate antimicrobial activity against both nonpathogenic gram-positive and gram-negative bacteria (Bacillus subtilis and Pseudomonas fluorescens), phytopathogenic (Xanthomonas campestris, Erwinia amylovora, E. carotovora) and the fungi (Candida utilis and Saccharomyces cerevisiae) at MIC - …

Go to article

Preparation And Characterization Of Nano Mno-Cals As A Green Catalyst For Oxidation Of Styrene, Mahdi Arian, Hoda Mollabagher, Salman Taheri, Ali Zamanian, Seyed Amir Hossein Seyed Mousavi Jan 2021

Preparation And Characterization Of Nano Mno-Cals As A Green Catalyst For Oxidation Of Styrene, Mahdi Arian, Hoda Mollabagher, Salman Taheri, Ali Zamanian, Seyed Amir Hossein Seyed Mousavi

Turkish Journal of Chemistry

Hydrophilic nano MnO is shown to have significant stability in aqueous media for oxidation of styrene. Different catalysts have been used to synthesis styrene oxide, but MnO-CaL is considered the efficient and selective catalyst to produce styrene oxide. In general, this paper reported especial strategy for synthesis of novel nano MnO that stabilized with oleic acid in chloroform and changing nature of its stabilizer by exchanging oleic acid with lignosulfunate and displays its catalytic activity towards selective oxidation of styrene. The catalyst has shown good selectivity in oxidation of styrene by changing temperature. Finding the optimal conditions for reaction and …

Go to article

A Facile Approach For The Synthesis Of Porous Hematite And Magnetite Nanoparticles Through Sol-Gel Self-Combustion, Imene Gritli, Afrah Bardaoui, Jamila Ben Naceur, Salah Ammar, Mohammad Abu Haija, Sherif Mohamed Abdel Salam Keshk, Radhouane Chtourou Jan 2021

A Facile Approach For The Synthesis Of Porous Hematite And Magnetite Nanoparticles Through Sol-Gel Self-Combustion, Imene Gritli, Afrah Bardaoui, Jamila Ben Naceur, Salah Ammar, Mohammad Abu Haija, Sherif Mohamed Abdel Salam Keshk, Radhouane Chtourou

Turkish Journal of Chemistry

Porous magnetite (Fe3O4) and hematite (α-Fe2O3) nanoparticles were prepared via the sol-gel auto-combustion method. The gels were prepared by reacting ferric nitrates (as oxidants) with starch (as fuel) at an elevated temperature of 200 °C. Different ratios (Φ) of ferric nitrates to starch were used for the synthesis (Φ = fuel/oxidant). The synthesized iron oxides were characterized by Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, X-ray diffraction (XRD) spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), Brunauer-Emmet-Teller (BET) and vibrating sample magnetometer (VSM) analysis techniques. The crystal structure, morphology, and specific surface area of the iron oxide nanoparticles (Fe3O4 …

Go to article

Synthesis And Application Of Colloidal Cds Quantum Dots As Interface Modification Material In Perovskite Solar Cells, Esma Yenel Jan 2021

Synthesis And Application Of Colloidal Cds Quantum Dots As Interface Modification Material In Perovskite Solar Cells, Esma Yenel

Turkish Journal of Chemistry

In this study, colloidal CdS quantum dots were synthesized, structurally characterized, and their effect on performance of perovskite solar cells was observed by using them as interface modification agent between TiO2/perovskite. Colloidal CdS quantum dots were synthesized based on two-phase method and characterized by X-ray diffraction and Transmission Electron Microscopy techniques. The average particle size of CdS quantum dots have found to be around 5 nm. Oleic acid was used as capping agent during synthesis to lead solubility in organic solvents. Obtained quantum dots are coated on compact TiO2 layer for surface modification. A decrease was observed when oleic acid …

Go to article

Reductant Free Green Synthesis Of Magnetically Recyclable Mnfe2o4@Sio2-Ag Core-Shell Nanocatalyst For The Direct Reduction Of Organic Dye Pollutants, Ali̇ Serol Ertürk, Gökhan Elmaci, Mustafa Ulvi̇ Gürbüz Jan 2021

Reductant Free Green Synthesis Of Magnetically Recyclable Mnfe2o4@Sio2-Ag Core-Shell Nanocatalyst For The Direct Reduction Of Organic Dye Pollutants, Ali̇ Serol Ertürk, Gökhan Elmaci, Mustafa Ulvi̇ Gürbüz

Turkish Journal of Chemistry

The present paper describes in situ green immobilization of silver nanoparticles on MnFe2O4@SiO2-Ag nanospheres using Epilobium parviflorum (EP) without using any other toxic chemicals and reducing or stabilizing agents. The morphology, composition, and magnetic properties of the resulting MnFe2O4@SiO2-Ag core-shell nanocatalyst were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR). The catalytic performance of the synthesized MnFe2O4@SiO2-Ag was employed on the organic pollutants dyes such as rhodamine B (RhB) and methylene blue (MB). The results revealed significant reduction performances for …

Go to article

A Four-Component Modified Biginelli Reaction: A Novel Approach For C-2 Functionalizeddihydropyrimidines, Harsha Narkhede, Avinash Dhake, Vaidhyanathan Balasubramaniyan Jan 2021

A Four-Component Modified Biginelli Reaction: A Novel Approach For C-2 Functionalizeddihydropyrimidines, Harsha Narkhede, Avinash Dhake, Vaidhyanathan Balasubramaniyan

Turkish Journal of Chemistry

A novel four component modified Biginelli reaction for the synthesis of C-2 functionalized dihydropyrimidines has been established. The approach uses assembly of less explored acetyl acetone with aromatic aldehyde, thiourea, and dimethyl sulphate to construct a novel 5-acetyl 2-methylthio dihydropyrimidine system, which works as an efficient well-designed intermediate for generating C-2 modified Biginelli libraries with nitrogen nucleophiles. Phenyl hydrazine, semicarbazide, and aryl semicarbazides are successfully used as N-nucleophiles to generate C-2 functionalized dihydropyrimidine derivatives, which fulfil the demands of active pharmacophore. Time economy, step economy, and a single pot reaction with moderate to excellent yield are the major advantages of …

Go to article

Silk Fiber-Based Composite Nanofiber Tissue Scaffold Produced With Electrospinning Method, Meti̇n Yüksek, Mehmet Akalin, Erhan Sancak, Erkan İşgören, Onur Atak, Derya Saltik Çi̇rki̇n, Ali̇ Beyi̇t Jan 2021

Silk Fiber-Based Composite Nanofiber Tissue Scaffold Produced With Electrospinning Method, Meti̇n Yüksek, Mehmet Akalin, Erhan Sancak, Erkan İşgören, Onur Atak, Derya Saltik Çi̇rki̇n, Ali̇ Beyi̇t

Turkish Journal of Chemistry

Wound dressings are one of the most rapidly expanding areas in medical textiles. In recent years, a large number of functional wound dressing has been developed. The aims of these products are to speed up the wound healing process and to provide maximum comfort for patients. Today, the multidisciplinary studies are required to improve further existed wound dressings. The results of such research studies are also promised new hopes for the Turkish textile industry weakened by the global competition. For this purpose, three different polymers were selected as silk fibroin (SF) / polycaprolactone (PCL) / polyethylene oxide (PEO). The productions …

Go to article

First Prev Next Last