Physical Sciences and Mathematics Commons^™

Adsorption Driven Regolith-Atmospheric Water Vapor Transfer On Mars: An Analysis Of Phoenix Tecp Data, Holly Nicole Farris

Graduate Theses and Dissertations

NASA’s Phoenix mission allowed for investigations of Martian diurnal water vapor cycles through the collection of temperature, relative humidity, and electric conductivity data by the Thermal and Electric Conductivity Probe (TECP) instrument. Using this data and previous experimental data, we propose a regolith-driven adsorption-desorption regime at the Phoenix landing site, where parameters intrinsic to the regolith are controlling localized relative humidity at the surface. To constrain these parameters, we model adsorption as a function of temperature and relative humidity across various Mars-relevant materials, defined by two layer-based adsorption theories: Langmuir (monolayer) and Brunauer-Emmett-Teller or BET (multilayer). Langmuir serves as an …

Apartment Residents' Understanding Of And Satisfaction With Water Savings Devices, David Farmer

Electronic Theses and Dissertations

As the human population increases, the way we use and manage our supply of drinking water becomes even more important. The purpose of this study was to determine residents’ satisfaction level of and performance rating of new water savings devices installed in their apartments. Specifically the investigation focused on ratings of shower heads, kitchen faucet aerators, bath faucet aerators, and fill valve and flapper systems.

This quantitative survey included residents at 4 apartment complexes in Tennessee using a paper questionnaire (N = 626). The participants were grouped by age, ethnicity, gender, and whether or not they had experienced both nonrestrictive …

Williston Basin Water Treatment Technology Test Bed, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about Energy & Environmental Research Center plan to pilot-test technology to treat high-TDS (total dissolved solids) water. Includes a description of proposed water treatment technology and plan for the testing process. [This item is an outdated or superseded version and retained for historical purposes only. It may no longer reflect current information, policies, or practices.]

Law Library Blog (June 2019): Legal Beagle's Blog Archive, Roger Williams University School Of Law

Law Library Newsletters/Blog

No abstract provided.

Water Systematics Of Samoan Peridotite Xenoliths, Aaron Wolfgang Ashley

Theses and Dissertations

Water influences geodynamic processes such as melting, deformation and rheology. Yet its distribution in the oceanic upper mantle is primarily known indirectly from melt inclusions and glasses of erupted mantle melts (i.e. MORB and OIB). To constrain the mechanisms influencing the distribution of water in the mantle, we analyzed 15 peridotite xenoliths from Savaiʻi and 2 dunite xenoliths from Taʻū (Samoa) for water concentrations (by polarized FTIR) and major/trace elements. Savaiʻi peridotites are among the most melt depleted oceanic xenoliths recovered (degrees of melt depletion ≥15%). They show strong evidence of transient metasomatism by both carbonatite and silicate melts, with …

Molecular Rotation In 3 Dimensions At An Air/Water Interface Using Femtosecond Time Resolved Sum Frequency Generation, Yi Rao, Yuqin Qian, Gang-Hua Deng, Ashlie Kinross, Nicholas J. Turro, Kenneth B. Eisenthal

Chemistry and Biochemistry Faculty Publications

This paper presents the first study of the rotations of rigid molecules in 3 dimensions at the air/water interface, using the femtosecond time resolved sum frequency generation (SFG) technique. For the purpose of this research, the aromatic dye molecule C153 was chosen as an example of a molecule having two functional groups that are SFG active, one being the hydrophilic −−C==O group and the other the hydrophobic −−CF₃ group. From polarized SFG measurements, the orientations of the two chromophores with respect to the surface normal were obtained. On combining these results with the known relative orientation of the two …

Informing Water Use Decision-Making For Waterfowl And Agricultural Production On A Ranch Along The North Platte River, Nebraska, Douglas R. Hallum P.G.

Conservation and Survey Division: Faculty and Staff Publications

In 2014, operators of a ranch along the North Platte River approached Conservation and Survey Division seeking expertise to interpret data collected on their ranch. The interpretations inform ranch decisions to accomplish operators’ goals. This publication documents the work by: 1) characterizing the ranch, 2) summarizing data collected, 3) characterizing hydrogeology of the site and the adjacent reach, and 4) conceptualizing groundwater/surface water interaction.

The ranch is a recreation property and a migratory waterfowl refuge with a few general goals: 1) develop and maintain high-quality wet meadow habitat, 2) maximize the extent and duration of surface water on the property …

Climate And Water One-Pager For Resilience, San Diego Regional Climate Collaborative

San Diego Regional Climate Collaborative

Climate change is impacting the way water is managed in the San Diego Region. Precipitation, temperature, and sea level are three primary climate indicators that will affect regional water resources over the next few decades.

Carbon Dioxide Measurement In Irish Blanket Peatlands: An Assessment Of Pool-Soil Flux Variability, Mariya Radomski, Alan Gilmer, Vivienne Byers, Eugene Mcgovern

Articles

Peatlands have been recognised as having a significant role in the mediation of atmospheric carbon dioxide (CO2) levels with direct implications for global climate change. Longitudinal in situ measurement systems for CO2 concentrations in blanket peatland ecosystems are difficult to implement where the nature of terrestrial–aquatic connectivity and hydrodynamics have a significant effect on the carbon cycle. The need for greater data on CO2 concentrations and flux monitoring in these settings has been well recognised. However, applying the most appropriate monitoring approach presents a special challenge. This paper sets out the development of a direct method for field based longitudinal …

Assessment Of Quantity And Quality Of Microplastics In The Sediments, Waters, Oysters, And Selected Fish Species In Key Sites Along The Bombong Estuary And The Coastal Waters Of Ticalan In San Juan, Batangas, Emilyn Q. Espiritu, Sophia Angeli Sn Dayrit, Annabel Soledad O. Coronel, Natasha Sophia C. Paz, Pilar Isabel L. Ronquillo, Virgil Christian G. Castillo, Erwin P. Enriquez

Chemistry Faculty Publications

Microplastics (or MPs; < 5 mm in size) pollution is largely unstudied in the Philippines. From an environmental sustainability standpoint, it is important to understand the characteristics, abundance, and environmental fate of plastic debris of various sizes, and these include microplastics that are not more easily and readily detected. In this study, we assessed the extent of microplastics contamination in the sediments, waters, oysters, and selected fishes found in the rivers and coastal areas of Ticalan, Batangas, which were identified from water quality parameters as Class C and CS, respectively. The microplastics were extracted from these samples by chemical digestion of the matrix, series of filtration, and separation by flotation through a density gradient to finally isolate the microplastics which were not dissolved by chemical digestion. The isolated samples were imaged by optical microscopy and characterized based on their descriptive attributes. The results showed the presence of microplastics in all the samples tested, which were found mostly in the form of filaments, fragments, films, and pellets – with most showing weathered, degraded, or angular and irregular surfaces. Identification was done through spectral matching of the Fourier transform infrared spectra of isolated fragments with that of known plastics, although identification in some cases is made uncertain by possibility of degradation of the plastics in the environment. The majority of the isolates showed signature absorption bands of the C-H stretching vibrations of polyethylene-based plastics.

Preservation Protocols For Maintaining Species Stability Of Arsenic, Chromium, And Selenium In Water Samples, Contessa Lowery

Water Resources Professional Project Reports

Water quality has become an increasing concern in recent years. The environmental challenges surrounding water quality include the presence of dissolved metals and their potential impact on human health and the environment. The challenge is exacerbated because many important metals have multiple oxidation states, which affect the health and environmental behavior of the metal. Many metals are known carcinogens and increased anthropogenic effects have inexorably made metals’ accumulation an imposing threat. Analytical instrumentation has advanced in many areas, making it now possible to measure very low concentrations of multiple elements in water. Current interest is determining the chemical speciation of …

Legislation To Reduce Microplastic Pollution : Understanding The Factors That Facilitated Passage Of The Federal Microbead-Free Waters Act Of 2015, Alyson Kelly Northrup

Legacy Theses & Dissertations (2009 - 2024)

The full environmental impacts of microplastic pollution in aquatic environments remain uncertain, but several detrimental effects have been documented, including adverse health effects in multiple species and the susceptibility of microplastics to adsorb toxins and leach plastic additives. Plastic microbeads from rinse-off personal care products are a source of microplastic pollution that is introduced directly into the environment through runoff, including wastewater treatment plant effluent. In December 2015, the federal Microbead-free Waters Act of 2015 banned the manufacture and sale of all rinse-off personal care products containing plastic microbeads in the United States.

Delivering Sustained, Coordinated, And Integrated Observations Of The Southern Ocean For Global Impact, Louise Newman, Petra Heil, Rowan Tebilco, Katsuro Katsumata, Andrew Constable, Esmee Van Wijk, Karen Assmann, Joana Beja, Phillippa Bricher, Richard Coleman, Daniel Costa, Steve Diggs, Riccardo Farneti, Sarah Fawcett, Sarah T. Gille, Katharine R. Hendry, Sian Henly, Eileen Hofmann, Ted Maksym, Matthew Mazloff, Andrew Meijers, Michael M. Meredith, Sebastien Moreau, Burcu Ozsoy, Robin Robertson, Irene Schloss, Oscar Schofield, Jiuxin Shi, Elisabeth Sikes, Inga J. Smith, Sebastiaan Swart, Anna Wahlin, Guy Williams, Michael J. M. Williams, Laura Herraiz-Borreguero, Stefan Kern, Jan Lieser, Robert A. Massom, Jessica Melbourne-Thomas, Patricia Miloslavich, Gunnar Spreen

CCPO Publications

The Southern Ocean is disproportionately important in its effect on the Earth system, impacting climatic, biogeochemical, and ecological systems, which makes recent observed changes to this system cause for global concern. The enhanced understanding and improvements in predictive skill needed for understanding and projecting future states of the Southern Ocean require sustained observations. Over the last decade, the Southern Ocean Observing System (SOOS) has established networks for enhancing regional coordination and research community groups to advance development of observing system capabilities. These networks support delivery of the SOOS 20-year vision, which is to develop a circumpolar system that ensures time …

Spatial Patterns Of Particulate Organic Carbon Concentrations And Isotopic Signatures Across A Salinity Gradient In A River Dominated Estuary, Lauren E. Alvaro, John C. Lehrter, Mai Fung

Gulf and Caribbean Research

No abstract provided.

Urban Water Demand In Arid-Regions: Modeling And Forecasting Climatic And Economic Effects, Tallen Ashley Capt

Open Access Theses & Dissertations

Water demand is an ever-growing concern for many municipalities around the world and understanding the driving forces of demand is critical to ensure sustainability. The goal of this research was to develop mechanistic models of urban water demand that could be used as decision support tools for regional water managers. This Dissertation research focused on modeling water consumption in El Paso, Texas at the daily and annual time scale for use in a long-term forecast. The Dissertation is divided into three major chapters: the first two chapters describe independent models on (1) meteorological and (2) economic effects, respectively. The third …

Lead In Tap Water Of Public Schools Near Dayton, Ohio, Baylee Stark

Browse all Theses and Dissertations

Lead (Pb) is a human-health concern, especially with regard to exposures of children. Lead contaminated drinking water is a primary route of exposure for children; however, water sampling for Pb is voluntary in schools with a public water supply. This study examined Pb in tap water from public schools around Dayton, OH. Schools were selected to span a range of ages (construction year) and community socioeconomic status. Of the 28 schools contacted, seven responded "affirmatively" to sampling, two responded "negatively", and 19 did not respond. None of the schools that were sampled had Pb concentrations exceeding the U.S. EPA guidelines …

Sustainably Managing Groundwater - Surface Water Interactions Within The Santa Rosa Plain Basin, Rhianna Frank

Master's Projects and Capstones

In this paper, I designed a strategy for implementation of sustainably managing groundwater-surface water interactions in the Santa Rosa Plain Basin in compliance with the requirements set forth by the Sustainable Groundwater Management Act of 2014. The research objectives for this analysis are: (1) to fully examine the requirements of the Sustainable Groundwater Management Act and the implications that implementation will have on the Santa Rosa Plain Basin, (2) to use technical data gathered regionally coupled with related policy design theory to analyze how groundwater and surface water interactions can be managed to meet the requirements set forth in this …

Assessing Responses Of Betula Papyrifera To Climate Variability In A Remnant Population Along The Niobrara River Valley In Nebraska U.S. Through Dendroecological And Remote Sensing Techniques, Evan Bumann, Tala Awada, Brian Wardlow, Michael Hayes, Jane A. Okalebo, C. Helzer, Anastasios Mazis, J. Hiller, Paolo Cherubini

School of Natural Resources: Faculty Publications

Remnant populations of Betula papyrifera have persisted in the Great Plains after the Wisconsin Glaciation along the Niobrara River Valley, Nebraska. Population health has declined in recent years, and has been hypothesized to be due to climate change. We used dendrochronological techniques to assess the response of B. papyrifera to microclimate (1950-2014), and satellite imagery [Landsat 5 TM (1985-2011) and MODIS (2000-2014)] derived NDVI as a proxy for population health. Growing-season streamflow and precipitation were positively correlated with raw and standardized tree-ring widths and basal area increment increase. Increasing winter and spring temperatures were unfavorable for tree growth while increasing …

Impact Of Bubble Baths On Stainless Steel Sphere Water Entry, Wesley Robinson

Physics Capstone Projects

Soap Bubbles on the water surface would seem to be an intuitive means for splash suppression, but their presence appears to be a double edged sword. We present on the water entry of hydrophilic spheres where the liquid surface is augmented by the presence of a bubble layer, similar to a bubble bath. While the presence of a bubble layer can diminish splashing upon impact at low Weber numbers, it also induces cavity formation at speeds below the critical velocity. The formation of a cavity generally results in larger Worthington jets and thus, larger amounts of ejected liquid. Bubble layers …

Toward Real-Time Flip Fluid Simulation Through Machine Learning Approximations, Javid Kennon Pack

Theses and Dissertations

Fluids in computer generated imagery can add an impressive amount of realism to a scene, but are particularly time-consuming to simulate. In an attempt to run fluid simulations in real-time, recent efforts have attempted to simulate fluids by using machine learning techniques to approximate the movement of fluids. We explore utilizing machine learning to simulate fluids while also integrating the Fluid-Implicit-Particle (FLIP) simulation method into machine learning fluid simulation approaches.

Energy And Water Assessment And Plausibility Of Reuse Of Spent Caustic Solution In A Midwest Fluid Milk Processing Plant, Carly Rain Adams

Department of Food Science and Technology: Dissertations, Theses, and Student Research

The Food Energy and Water Nexus (FEW Nexus) is the inseparable connection linking these resources. The concept of the FEW Nexus within the food industry addresses the connection of water and energy as key members of food production. The steady increase in population and the increase in food demand are directly related, therefore, the need for water and energy. Immediately taking on this critical challenge will lead to tangible impacts on the water and energy crisis facing the food system. To reduce the distance between process productivity and resource efficiency it must first be determined, within food processing, where water …

Fluted Films, Nathan B. Spiers, Mohammad M. Mansoor, Jesse Belden, Randy Craig Hurd, Zhao Pan, Tadd T. Truscott

Mechanical and Aerospace Engineering Faculty Publications

This paper is associated with a poster winner of a 2017 APS/DFD Milton van Dyke Award for work presented at the DFD Gallery of Fluid Motion. The original poster is available from the Gallery of Fluid Motion, https://doi.org/10.1103/APS.DFD.2017.GFM.P0030

To Rebate Or Not To Rebate: The Influences And Deterrents For Residential Customers To Participate In Water Authority Rebates, Meagan Virginia Oldham

Water Resources Professional Project Reports

The depletion of aquifers and reduced surface water flows are a growing concern for water managers. Educational outreach and incentives to promote conservation have been a growing trend over the past couple of decades in the arid Southwestern United States, including Albuquerque, New Mexico. Rebates for the installation of water efficient appliances and xeric landscape conversions are a couple of ways that water authorities incentivize their residential consumers to do their part at home to conserve water. This study involves a survey sent to a random sample of 2,215 Albuquerque Bernalillo County Water Utility Authority residential customers, with a 31% …

Enhanced Acidity Of Acetic And Pyruvic Acids On The Surface Of Water, Alexis J. Eugene, Elizabeth A. Pillar, Agustín J. Colussi, Marcelo I. Guzman

Chemistry Faculty Publications

Understanding the acid–base behavior of carboxylic acids on aqueous interfaces is a fundamental issue in nature. Surface processes involving carboxylic acids such as acetic and pyruvic acids play roles in (1) the transport of nutrients through cell membranes, (2) the cycling of metabolites relevant to the origin of life, and (3) the photooxidative processing of biogenic and anthropogenic emissions in aerosols and atmospheric waters. Here, we report that 50% of gaseous acetic acid and pyruvic acid molecules transfer a proton to the surface of water at pH 2.8 and 1.8 units lower than their respective acidity constants pK_{a …}

Comparative Microbial Community Dynamics In A Karst Aquifer System And Proximal Surface Stream In Northwest Arkansas, Josue Rodriguez

Graduate Theses and Dissertations

Northwest Arkansas has well-developed karst systems, with numerous sinking streams and springs. Karst conduits make it easy for contaminants to enter groundwater systems, degrading the water quality and destroying fragile karst ecosystems. With the increase of urbanization, potential threats in the form of fecal contamination may prove to be more of a problem. The purpose of this research is to compare the difference between microbial communities within two different settings, a karst aquifer and a surface stream. The microbial communities within Blowing Spring Cave and Little Sugar Creek were detected and identified in water and sediment samples. Samples were also …

Adaptive Fluid Simulation Using A Linear Octree Structure, Sean A. Flynn

Theses and Dissertations

An Eulerian approach to fluid flow provides an efficient, stable paradigm for realistic fluid simulation. However, its traditional reliance on a fixed-resolution grid is not ideal for simulations that simultaneously exhibit both large and small-scale fluid phenomena. Octree-based fluid simulation approaches have provided the needed adaptivity, but the inherent weakness of a pointer-based tree structure has limited their effectiveness. We present a linear octree structure that provides a significant runtime speedup using these octree-based simulation algorithms. As memory prices continue to decline, we leverage additional memory when compared to traditional octree structures to provide this improvement. In addition to reducing …

Single-Stage, Venturi-Driven Desalination System, Brandon Proetto

Mechanical & Aerospace Engineering Theses & Dissertations

Water demand is increasing at a rapid pace due to population increase, industrial expansion, and agricultural development. The use of desalination technology to meet the high water demands has increased global online desalination capacity from 47 million m^3/d in 2007 to 92.5 million m^3/d as of June 2017 [49]. Membrane and thermal processes are the two mainstream desalination categories used worldwide for desalination plants. Reverse Osmosis (RO) is the most widely used membrane process and it has become the dominant technology for building desalination plants over recent decades. Thermal distillation, however, has become less and less competitive due to its …

Microtextural Studies Of Feldspar In Ordinary Chondrites, Jonathan A. Lewis

Earth and Planetary Sciences ETDs

Ordinary chondrites contain an important record of events that took place during the earliest period of solar system evolution. These include primary processes, such as chondrule formation, and secondary processes, those that affected asteroids after accretion and modified primary components. Secondary processes include aqueous alteration, thermal metamorphism, and shock effects from impact events. Secondary minerals can provide insight into the chemical and physical conditions that affected their parent asteroids. Feldspar is known to be a secondary mineral that crystallized during thermal metamorphism. The goal of this work is to use the formation and evolution of feldspar to elucidate the conditions …

Crown Ether Effects On The Location Of Charge Carriers In Electrospray Droplets: Implications For The Mechanism Of Protein Charging And Supercharging., Haidy Metwally, Lars Konermann

Chemistry Publications

"Native" electrospray ionization (ESI) mass spectrometry (MS) aims to transfer proteins from solution into the gas phase while maintaining solution-like structures and interactions. The ability to control the charge states of protein ions produced in these experiments is of considerable importance. Supercharging agents (SCAs) such as sulfolane greatly elevate charge states without significantly affecting the protein structure in bulk aqueous solution. The origin of native ESI supercharging remains contentious. According to one model, SCAs trigger unfolding within ESI droplets. In contrast, the "charge trapping model" envisions that SCAs impede the ejection of charge carriers (e.g., NH₄⁺ or Na …

Application Of Ultraviolet Light Emitting Diodes For The Advanced Oxidation Of Guar Gum, Andrew W. Davenport

Theses and Dissertations

Guar Gum (GG) is one of the problematic water pollutants connected to hydraulic fracturing. There is a pressing need to investigate appropriate unit operations that can be employed to protect the aquatic environment. This study investigated the use of light-emitting diodes (LEDs) in the advanced oxidation process (AOP) of GG. Chemical oxygen demand (COD) removal provided mixed results, depending on the concentration of hydrogen peroxide (H₂O₂) in solution, and was between (0-95%) for H₂O₂-to-GG ratios between 7.0 and 176.3 g H₂O₂/g GG. COD removal was greatest at the …