Physical Sciences and Mathematics Commons^™

From Access To Excess: Agribusiness, Federal Water Programs, And The Historical Roots Of The California Water Crisis, Tracy Marie Neblina

UNLV Theses, Dissertations, Professional Papers, and Capstones

The purpose of this paper is to show the link between water use, land consolidation, agribusinesses, and the water crisis that California began to experience in 2011. In order to better understand the relationship between the growth of agribusiness in the state and the evolution of water policy, this paper explores the historical context of land policy, the growth of farming in the San Joaquin Valley, and the development of federally funded water projects in the Central Valley. Years of expanding farmland and use of surface and underground water with limited regulation played an important role in exacerbating California’s water …

Continuous Snow Water Equivalent Measurements With Ultra-Wideband Radar: Towards A New Generation Of Real-Time Automated Snow Sensor Arrays, Mark Edward Robertson

Boise State University Theses and Dissertations

Snow accounts for the majority of precipitation in many areas of the Western United States, and accurate measurements of the amount of water contained in the snowpack, known as snow water equivalent (SWE), are therefore important for water resource managers. The National Resources Conservation Service Snow Telemetry (SNOTEL) sites are the current standard remote measurement of SWE, with approximately 800 sites across the Western United States. Measurements at these sites are made by snow pillows, which weigh the overburden pressure of a snowpack, and are relatively expensive to install and maintain. Spring runoff is modeled using a 30-year average of …

A Pes Study Of Factors Influencing Metal Partitioning In Aquatic Systems: “Design Of Experiment As, Cd, Co, Cr, Cu, Pb, Ni, And Zn”, Eid A. Alkhatib, John Rapaglia, Leon Theim

Chemistry & Physics Faculty Publications

Mobility and bioavailability of heavy metals are related to their partitioning amongst suspended sediment and water. A Particle Entrainment Simulator (PES) is used to simulate sediment resuspention in natural surface water systems. The simulations were carried out under various conditions of water/suspended solids conditions. Five factors, each at various levels, are tested collectively: the pH of water at two levels (4 and 8), shear stress on bottom sediment at three levels (0.1, 0.3, and 0.5 N/m2 ) salinity of water at two levels (0.01 and 14.0 ppt), organic matter in sediment at three levels (0.50, 1.93, and 3.80%) and temperature …

Willingness To Pay For Irrigation Water Under Scarcity Conditions, Tyler Robert Knapp

Graduate Theses and Dissertations

Reliance of Arkansas agricultural producers on groundwater for irrigation has led to depletion of the Mississippi River Valley alluvial aquifer. Without intervention, consequences include insufficient groundwater to meet irrigation demand as well as drawdown of the deeper Sparta Aquifer, upon which communities in eastern Arkansas rely for non-agricultural use. Among proposed solutions to combat groundwater decline is the construction of off-farm surface water infrastructure to meet the irrigation needs of producers. Despite the importance of irrigated agriculture to Arkansas, there is little know about the economic value of irrigation water to producers. Thus, we implement a double-bounded dichotomous choice contingent …

Drop By Drop

SIGNED: The Magazine of The Hong Kong Design Institute

In October 2013 Yale University professor Sheila Levrant de Bretteville began exploring the water's edge at four Hong Kong harbours with an interdisciplinary group of students from HKDI. The issues that captured their attention formed the basis of some vivid and emotionally compelling work.

Prospective Doctoral Statement For The University Of Southern California's School Of Cinematic Arts Media Arts + Practice Program, Gabriel Leiner

Gabriel Leiner

After visiting L.A. again and seeing the beautiful fountains on the University of Southern California's campus I am filled with all kinds of ideas about the future and brimming with energy. To all those at the University of Southern California's Cinematic Arts Department, thanks for reading my ideas over the past couple years and helping me to evolve and become a better person and a better writer. Starting a position as a doctoral student in the Media Arts + Practice Program in 2016 is an exciting opportunity. I've got a really positive outlook about Kiss The Water.

Verwiebe's "3-D" Ice Phase Diagram Reworked, Carl W. David

Chemistry Education Materials

The two dimensional phase diagrams of the various forms of ice are difficult to read and understand. A ``3D'' versions appearing ~80 years ago helps understanding of the phases and their inter-conversion into other phases.

Water-Assisted Oxygen Activation During Selective Oxidation Reactions, Hung-Vu Tran, Hieu A. Doan, Bert D. Chandler, Lars C. Grabow

Chemistry Faculty Research

The selective functionalization of hydrocarbons with oxygen to produce valuable commodity chemicals is inherently challenging, because of the thermodynamic stability of the complete combustion products. Emerging green synthesis routes and sustainable energy production also rely on the success of selective oxidation reactions. As one of the unselective by-products, water is always present under reaction conditions and numerous studies indicate that the catalytic activity and selectivity of selective oxidation reactions may be tuned by judiciously controlling the water content during the reaction. Some experimentally verified examples include the preferential oxidation of carbon monoxide, direct hydrogen peroxide synthesis, propene epoxidation and alcohol …

Qualitative Detection Of Selected Designer Drugs And Relevant Metabolites In Environmental Water Samples, Marley Pruyn

FIU Electronic Theses and Dissertations

Designer drugs are compounds which have been synthetically derived from illicit drugs. After consumption, drugs and their metabolites are introduced into the sewage water which is treated and disposed into the environment. A combined target, suspect and non-target workflow was created to detect designer drugs in environmental water samples. Multiple water samples were spiked with an unknown mixture of drugs and metabolites to assess the efficiency of the method. Samples were collected from sewage influent and effluent pipes, downstream from a sewage outfall and reclaimed water. Analysis was conducted with high resolution MS using the QExactive Orbitrap. Screening was performed …

Developing A Sustainable Water Supply In The American West: The Case Of Rio Rancho, New Mexico, Hubert B. Stroud, Mary K. Kilmer

Suburban Sustainability

Suburban and urban communities in the American West are challenged by rapid population growth combined with limited natural resources. Supporting sustainable development is of great concern in this region and in similar regions throughout the world. This research examines the sustainability of the water supply within a rapidly growing suburban city in the American West. The city, Rio Rancho, New Mexico, began as an interstate land sales operation and rapidly became a “boom” town, in part because of its location near metropolitan Albuquerque.

Because of a very limited water supply and an increasing demand for water associated with population growth, …

Agenda: Indigenous Water Justice Symposium, University Of Colorado Boulder. Getches-Wilkinson Center For Natural Resources, Energy, And The Environment

Indigenous Water Justice Symposium (June 6)

Indigenous peoples throughout the world face diverse and often formidable challenges of what might be termed “water justice.” On one hand, these challenges involve issues of distributional justice that concern Indigenous communities’ relative abilities to access and use water for self-determined purposes. On the other hand, issues of procedural justice are frequently associated with water allocation and management, encompassing fundamental matters like representation within governance entities and participation in decision-making processes. Yet another realm of water justice in which disputes are commonplace relates to the persistence of, and respect afforded to, Indigenous communities’ cultural traditions and values surrounding water—more specifically, …

Impacts To Anadromous Fish Through Groundwater Extraction, Aaron Hebert

Master's Projects and Capstones

California uses more groundwater than any other state in the United States in order to meet agricultural demand during the growing season when water is naturally least available due to the state’s Mediterranean climate. The state also hosts populations of anadromous fish that are otherwise found exclusively in the wetter Pacific northwest. Groundwater has historically helped maintain baseflow in the summer and fall low-flow periods and acted as a natural buffer against the regular droughts that occur in California. Today, groundwater provides 30-40% of the state’s water supply, but the pumping in many cases has reduced groundwater discharge and baseflow, …

Environmental Fullerene Chemistry: Elucidating Critical Reaction Pathways And Resulting Products In The Aqueous Phase, Jiewei Wu

McKelvey School of Engineering Theses & Dissertations

As the production of fullerenes and fullerene-based materials approaches industrial scale, there are increasing interests/concerns regarding their (potential) environmental impact(s) upon release. To date, a number of critical, aqueous-based fullerene transformation pathways under environmentally relevant conditions remain poorly understood. Comprehensive, fundamental, and quantitative understanding of the potential (major) reaction pathways and resulting products of fullerene materials, particularly in aquatic systems, is now crucial for their accurate fate, transport, life cycle, risk assessment(s), and thus ultimate material sustainability.

Herein, this dissertation is focused on identifying and elucidating aqueous transformation pathways of fullerene materials, focused on C60 as a model fullerene, under …

Performance Analysis Of A Rankine Cycle Integrated With The Goswami Combined Power And Cooling Cycle, Ricardo Vasquez Padilla, Antonio Ramos Archibold, Gokmen Demirkaya, Saeb Besarati, D Yogi Goswami, Muhammad M. Rahman, Elias L. Stefanakos

Dr Ricardo Vasquez Padilla

Improving the efficiency of thermodynamic cycles plays a fundamental role in reducing the cost of solar power plants. These plants work normally with Rankine cycles which present some disadvantages due to the thermodynamic behavior of steam at low pressures. These disadvantages can be reduced by introducing alternatives such as combined cycles which combine the best features of each cycle. In this paper, a combined Rankine–Goswami cycle (RGC) is proposed and a thermodynamic analysis is conducted. The Goswami cycle, used as a bottoming cycle, uses ammonia–water mixture as the working fluid and produces power and refrigeration while power is the primary …

Barays, Boeungs And Bassins: Reservoirs And The Capacity For Life And Change In Cambodia, Kevin D. Curry

Bridgewater Review

No abstract provided.

Applying The Water Governance Framework On Rural Water Development Projects In Guatemala, Muhanad M. Alkharaz

Theses and Dissertations

According to the Organization for Economic Cooperation and Development (OECD), ‘Water crisis is mainly a governance crisis’, (OECD, 2013). Many water experts, as individuals, organizations and even governmental bodies have developed water governance frameworks to overcome water challenges on local, national, and international levels such as Integrated Water Resource Management. In rural areas, especially in developing countries, access to safe drinking water is a daily challenge due to a variety of political, economic, and social constraints. For in-stance, some developing countries have a strong centralized governance system. Due to lack of capacity and resources, central governments are incapable of providing …

Benchmarking Ab Initio Computational Methods For The Quantitative Prediction Of Sunlight-Driven Pollutant Degradation In Aquatic Environments, Kasidet Trerayapiwat

Honors Projects

Understanding the changes in molecular electronic structure following the absorption of light is a fundamental challenge for the goal of predicting photochemical rates and mechanisms. Proposed here is a systematic benchmarking method to evaluate accuracy of a model to quantitatively predict photo-degradation of small organic molecules in aquatic environments. An overview of underlying com- putational theories relevant to understanding sunlight-driven electronic processes in organic pollutants is presented. To evaluate the optimum size of solvent sphere, molecular Dynamics and Time Dependent Density Functional Theory (MD-TD-DFT) calculations of an aniline molecule in di↵erent numbers of water molecules using CAM-B3LYP functional yielded excited …

Modeling The Influence Of The Heterogeneous Substrate On The Transport Of The Jet Fuel Solute Plume, Kirtland Air Force Base, Albuquerque, New Mexico, Hannah Sarah Gatz-Miller

Earth and Planetary Sciences ETDs

A subsurface model was developed to characterize the influence of heterogeneity on solute phase plume migration of the Jet Fuel spill of Kirtland Air Force Base. Core –logs from KAFB boreholes were compiled, and lithology was interpolated across the study area using transition probability geostatistics (T-PROGS). High conductivity materials in the travel path resulted in a faster than average breakthrough time while, if low conductivity materials were placed in the travel path, particles were either forced to divert around the low K material, which added time and changed the direction of travel, or were forced by the hydraulic gradient to …

Mineral Physics Modeling Of The Effect Of Water On Crustal Seismic Velocity Ratios, Eric Lyman

Physics Capstone Projects

This research explores the relationship between the presence of water (H2O) in the make up of rocks and minerals (specifically quartz) at different levels in the crust. The relationships were calculated using Perple_x software to adjust the level of the different chemical and mineral make up of the rock. The densities were calculated using the velocity of primary waves and shear waves as collected by Tony Lowry. There seems to be at least a casual link between water content and quartz content.

Extent Of Capillary Rise In Sands And Silts, Rachel Lynn Salim

Masters Theses

The values reported in literature for the height of capillary rise in fine sands, silts, and clays are contradictory. Most of the values were based on mathematical models, which used estimated rather than measured input data. This work measured capillary rise values in laboratory experiments in fine-grained sands and silts.

Two uniform sands with grains 0.35--0.7 mm in diameter and 0.3-0.6 mm in diameter, silt with an average grain size below 40 microns, and 0.35--0.7 mm sand coated with a water-repellant spray were carefully packed into two-inch diameter glass columns. These columns were placed into clear plastic tanks with water …

Double-Stranded Water On Stepped Platinum Surfaces, Manuel J. Kolb, Rachael G. Farber, Jonathan Derouin, Cansin Badan, Federico Calle-Vallejo, Ludo B. F. Juurlink, Daniel Killelea, Marc T. M. Koper

Chemistry: Faculty Publications and Other Works

The interaction of platinum with water plays a key role in (electro)catalysis. Herein, we describe a combined theoretical and experimental study that resolves the preferred adsorption structure of water wetting the Pt(111)-step type with adjacent (111) terraces. Double stranded lines wet the step edge forming water tetragons with dissimilar hydrogen bonds within and between the lines. Our results qualitatively explain experimental observations of water desorption and impact our thinking of solvation at the Pt electrochemical interface.

The Household Water Management System In The Village Of Falifah, Gambia: A Case Study In Sustainable Local Development, Baboucar Jobe

USF Tampa Graduate Theses and Dissertations

Access to safe and clean water is a problem in many countries in the world, especially sub-Saharan Africa. The urgency of the was recognized by the United Nations through its 2008 Millennium Development Goals, which were recently replaced by the new Sustainable Development Goals. Lack or poor access to clean water not only creates conflicts and rifts among the people, but also makes them more susceptible to a wide assortment of water borne diseases.

The purpose of this dissertation is to complete a pilot study of ways of thinking and actions of a small group of people from Falifah, a …

Satisfaction, Water And Fertilizer Use In The American Residential Macrosystem, Peter M. Groffman, J Morgan Grove, Colin Polsky, Neil D. Bettez, Jennifer L. Morse, Jeanine Cavender-Bares, Sharon J. Hall, James B. Heffernan, Sarah E. Hobbie, Kelli L. Larson, Christopher Neill, Kristen Nelson, Laura Ogden, Jarlath O'Neil-Dunne, Diane Pataki, Rinku Roy Chowdhury, Dexter H. Locke

Advanced Science Research Center

Residential yards across the US look remarkably similar despite marked variation in climate and soil, yet the drivers of this homogenization are unknown. Telephone surveys of fertilizer and irrigation use and satisfaction with the natural environment, and measurements of inherent water and nitrogen availability in six US cities (Boston, Baltimore, Miami, Minneapolis-St. Paul, Phoenix, Los Angeles) showed that the percentage of people using irrigation at least once in a year was relatively invariant with little difference between the wettest (Miami, 85%) and driest (Phoenix, 89%) cities. The percentage of people using fertilizer at least once in a year also ranged …

Fy 2016 Umass Amherst Water & Steam Data By Building, Ezra Small

Campus Data

Each year, UMass Amherst Utilities publishes this spreadsheet which has the monthly and annual building water and steam consumption of each metered building on campus.

An Ecotoxicological Survey Of Tributaries Of The Selenge River, Mongolia, August 2010, Viktor T. Komov, Ch. Javzan, William G. Brumbaugh

Erforschung biologischer Ressourcen der Mongolei / Exploration into the Biological Resources of Mongolia, ISSN 0440-1298

The biodiversity of the Selenga river basin and the receiving waters of the lake Baikal, are among the greatest in the world with over 1,700 known endemic species of plants and animals. Mining activities along the Selenga river and its tributaries pose a major threat of chemical contamination, potentially reducing habitat quality and suitability for aquatic species. Moreover, the Selenga river serves as a major water source for the lake Baikal. Little information exists on the chemical contaminant concentrations in the Selenga river basin. Thus, the objectives of our study were to evaluate the concentrations of metals in soil, sediment, …

Aqueous Electrosynthesis Of An Electrochromic Material Based Water-Soluble Edot-Menh2 Hydrochloride, Hui Sun, Long Zhang, Liqi Dong, Xiaofei Zhu, Shouli Ming, Youshan Zhang, Huakun Xing, Xuemin Duan, Jingkun Xu

Australian Institute for Innovative Materials - Papers

2'-Aminomethyl-3,4-ethylenedioxythiophene (EDOT-MeNH2) showed unsatisfactory results when its polymerization occurred in organic solvent in our previous report. Therefore, a water-soluble EDOT derivative was designed by using hydrochloric modified EDOT-MeNH2 (EDOT-MeNH2·HCl) and electropolymerized in aqueous solution to form the corresponding polymer with excellent electrochromic properties. Moreover, the polymer was systematically explored, including electrochemical, optical properties and structure characterization. Cyclic voltammetry showed low oxidation potential of EDOT-MeNH2·HCl (0.85 V) in aqueous solution, leading to the facile electrodeposition of uniform the polymer film with outstanding electroactivity. Compared with poly(2′-aminomethyl- 3,4-ethylenedioxythiophene) (PEDOT-MeNH2), poly(2′-aminomethyl-3,4-ethylenedioxythiophene salt) (PEDOT-MeNH3 +A-) revealed higher efficiencies (156 cm2 C-1), lower bandgap (1.68 …

Synthesis, Characterization, And Functional Evaluation Of Nanocomposites For Water Purification, Julio Eduardo Padilla

Open Access Theses & Dissertations

The United Nations estimate that around 780 million people do not have access to clean and safe water and around 2.5 billion people do not have proper water sanitation. As a result, around 6-8 million people die each year due to water related diseases, such as cholera and dysentery, and disasters. As population increases the water problem will become more difficult to solve. Furthermore, climate change threatens to intensify water scarcity. The design of functional materials at the nanoscale offer unique solutions in molecular sorbents and catalytic systems that can develop into cost-effective solutions in water treatment by reducing the …

Drinking Water And Autism: Using Spatial Cluster Detection To Explore Patterns Of Autism Cases In Lane County, Oregon, Sherry Sandreth

Walden Dissertations and Doctoral Studies

Autism Spectrum Disorders (ASD) are a complex array of neurological disorders with a diverse presentation, multiple etiologies, and long-term ramifications. Prevalence of ASD in the United States is about 1 in 50 children as of 2013, making it a significant public health problem. The etiology is not understood, and it is widely accepted that it is multicausal, with genetic and environmental influences. Prior research suggests an association between water source and ASD. Contaminants such as lead, arsenic, mercury, pharmaceuticals and pesticides found in water are associated with developmental disorders suggesting that a systematic review focused on water source was warranted. …

Resolving The Hono Formation Mechanism In The Ionosphere Via Ab Initio Molecular Dynamic Simulations, Rongxing He, Lei Li, Jie Zhong, Chongqin Zhu, Joseph S. Francisco, Xiao Cheng Zeng

Xiao Cheng Zeng Publications

Solar emission produces copious nitrosonium ions (NO⁺) in the D layer of the ionosphere, 60 to 90 km above the Earth’s surface. NO⁺ is believed to transfer its charge to water clusters in that region, leading to the formation of gaseous nitrous acid (HONO) and protonated water cluster. The dynamics of this reaction at the ionospheric temperature (200–220 K) and the associated mechanistic details are largely unknown. Using ab initio molecular dynamics (AIMD) simulations and transition-state search, key structures of the water hydrates—tetrahydrate NO⁺(H₂O)₄ and pentahydrate NO⁺(H₂O)_{5 …}

Simple And Rapid Voltammetric Determination Of Boron In Water And Steel Samples Using A Pencil Graphite Electrode, Lokman Li̇v, Nuri̇ Naki̇boğlu

Turkish Journal of Chemistry

This paper presents a simple, rapid, and accurate voltammetric method for determination of boron in water and steel samples using a disposable pencil graphite electrode. The oxidation of Tiron in the boron-Tiron complex in phosphate buffer at pH 7.5 was measured as a response. Type and concentration of supporting electrolyte, pH, ionic strength, Tiron concentration, scan rate, step amplitude, pulse amplitude, and pencil grade were investigated as the parameters affecting the peak current. The limit of detection (3s) was estimated as 84 $\mu $g/L. The relative standard deviation of the method was 4.6 for 1 mg B/L (N = 7). …