Physical Sciences and Mathematics Commons^™

Kentucky Karst Dye Trace Database, Sarah M. Arpin, Benjamin W. Tobin, Maaz Fareedi, Adam Link, James C. Currens

Research Data--KGS

This dataset provides the geographical locations of karst groundwater basins, groundwater flowpaths, and dye injection/recovery points in Kentucky. Dye tracing is a common method used for understanding groundwater movement. Dye is poured (or injected) into a sinking stream, well, sinkhole, or body of water, where it is carried down-gradient by flowing water. The locations at which dye is recovered (typically at artesian springs) indicates a connection from injection to recovery site. This connection is refered to as a groundwater flowpath. Conducting multiple dye traces across an area allows for the interpretation of regional groundwater flow by assessing where flowpaths either …

Phosphorus Transfer To River Water From Grassland Catchments In Ireland, H. Tunney, P. Jordan, G. Kiely, R. Moles, G. Morgan, P. Byrne, W. Menary, K. Daly

IGC Proceedings (1997-2023)

In Ireland it is estimated that at least half of phosphorus (P) loss to water is from agricultural sources and National and European Union policy and legislation aim at reducing phosphorus (P) loss to water in order to reduce eutrophication. In Ireland, the average soil test P (STP) levels increased ten-fold, from less than 1 to over 8 mg Morgan P per l soil over the past 50 years, reflecting increased P inputs in fertiliser and animal feed. One of the main objectives of this three-year research programme, started in 2001, was to investigate P loss to water in grassland …

Hydrology Data For Fern Cave, Alabama (2020-2022), Benjamin Tobin, Benjamin V. Miller, Matthew Niemiller, Andrea Erhardt

Research Data--KGS

Dataset includes water level from four sites within Fern Cave in Jackson County Alabama. Additionally, it includes chemistry of water, sediments and cave-adapted isopods.

Grasslands1 For Production And The Environment, David R. Kemp, David L. Michalk

IGC Proceedings (1997-2023)

1. To manage grasslands for production and enhanced environmental values requires a redefinition of the frameworks within which management decisions are made, and a tailoring of practices to suit the ways that farmers operate.
2. Improving the perenniality and permanence of grasslands usually leads to better environmental and production outcomes.
3. There is a case for a more conservative approach to utilising grasslands in order to sustain the functioning of local ecosystems and to improve water quality, nutrient and energy cycling and biodiversity.
4. A landscape rather than paddock focus is more appropriate for meeting current grassland management objectives. Grasslands can be triaged to …

Phosphorus Transfer To River Water From Grassland Catchments In Ireland, H. Tunney, P. Jordan, G. Kiely, R. Moles, G. Morgan, P. Byrne, W. Menary, K. Daly

IGC Proceedings (1997-2023)

In Ireland it is estimated that at least half of phosphorus (P) loss to water is from agricultural sources and National and European Union policy and legislation aim at reducing phosphorus (P) loss to water in order to reduce eutrophication. In Ireland, the average soil test P (STP) levels increased ten-fold, from less than 1 to over 8 mg Morgan P per l soil over the past 50 years, reflecting increased P inputs in fertiliser and animal feed. One of the main objectives of this three-year research programme, started in 2001, was to investigate P loss to water in grassland …

Grasslands For Production And The Environment, David R. Kemp, David L. Michalk

IGC Proceedings (1997-2023)

Key points

1. To manage grasslands for production and enhanced environmental values requires a redefinition of the frameworks within which management decisions are made, and a tailoring of practices to suit the ways that farmers operate.

2. Improving the perenniality and permanence of grasslands usually leads to better environmental and production outcomes.

3. There is a case for a more conservative approach to utilising grasslands in order to sustain the functioning of local ecosystems and to improve water quality, nutrient and energy cycling and biodiversity.

4. A landscape rather than paddock focus is more appropriate for meeting current grassland management …

Manipulation Of The Spatial Grazing Behaviour Of Livestock In Extensive Grassland Systems, Derek W. Bailey, Mitch B. Stephenson, Milton G. Thomas, Juan F. Medrano, Gonzalo Rincon

IGC Proceedings (1997-2023)

Spatial behaviour of livestock is a critical factor in grassland management. Recent and ongoing research suggests that new approaches can be used to manipulate where cattle graze. The combination of strategic supplement placement and low-stress herding can be used to target cattle grazing and potentially may be useful for managing fine fuels. A phenotype to genotype association study of cattle spatial behavior suggests that use of rugged terrain and areas far from water is inherited. Although more research is needed, selection for animals specifically adapted for mountainous terrain or extensive paddocks may be an alternative for managing grasslands in the …

Enhanced Acidity Of Acetic And Pyruvic Acids On The Surface Of Water, Alexis J. Eugene, Elizabeth A. Pillar, Agustín J. Colussi, Marcelo I. Guzman

Chemistry Faculty Publications

Understanding the acid–base behavior of carboxylic acids on aqueous interfaces is a fundamental issue in nature. Surface processes involving carboxylic acids such as acetic and pyruvic acids play roles in (1) the transport of nutrients through cell membranes, (2) the cycling of metabolites relevant to the origin of life, and (3) the photooxidative processing of biogenic and anthropogenic emissions in aerosols and atmospheric waters. Here, we report that 50% of gaseous acetic acid and pyruvic acid molecules transfer a proton to the surface of water at pH 2.8 and 1.8 units lower than their respective acidity constants pK_{a …}

Oxidation Of Substituted Catechols At The Air-Water Interface: Production Of Carboxylic Acids, Quinones, And Polyphenols, Elizabeth A. Pillar, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are converted into the respective phenols, cresols, and methoxyphenols by fast gas-phase reaction with hydroxyl radicals (HO(•)). Further processing of the latter species by HO(•) decreases their vapor pressure as a second hydroxyl group is incorporated to accelerate their oxidative aging at interfaces and in aqueous particles. This work shows how catechol, pyrogallol, 3-methylcatechol, 4-methylcatechol, and 3-methoxycatechol (all proxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasing O3(g) during τc ≈ 1 μs contact time and contrasts their …

Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic emissions of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of humic-like substances (HULIS). Because further processing of polyphenols in secondary organic aerosols (SOA) can continue mediated by a mechanism of ozonolysis at interfaces, a better understanding about how these reactions proceed at the air–water interface is needed. This work shows how catechol, a molecular probe of the oxygenated aromatic hydrocarbons present in SOA, can contribute interfacial reactive species that enhance the production of HULIS under atmospheric conditions. Reactive semiquinone radicals are quickly produced upon …

Use Of Boron Compounds To Precipitate Uranium From Water, David A. Atwood

Chemistry Faculty Patents

A method is provided for removing uranium from water. The method includes the mixing of a boron reagent with water contaminated with uranyl dication ions, leading to removal of the uranium from that water.

Water Well And Spring Map Of The Hazard 30 X 60 Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Elizabethtown 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Corbin 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Madisonville 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Paducah 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Williamson 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Pikeville 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Huntington 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Tompkinsville 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Tell City 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Morehead 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Hopkinsville 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Murray 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Lexington 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Harrodsburg 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Louisville 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Falmouth, Cincinnati, And Madison 30 X 60 Minute Quadrangles, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Somerset 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.

Water Well And Spring Map Of The Bowling Green 30 X 60 Minute Quadrangle, Kentucky, Bart Davidson

Map and Chart--KGS

No abstract provided.