Physical Sciences and Mathematics Commons^™

Decision Support Tools To Address Climate Change: Climate Model - Land Surface Models, Zea Mays L. (Corn) Phenology And Evapotranspiration-Yield Sensitivity Models For Nebraska, Usa., Jane A. Okalebo

School of Natural Resources: Dissertations, Theses, and Student Research

Nebraska's climate is highly variable and is expected to change in the future with anthropogenic global warming (AGW), resulting in warmer spring and summer temperatures coupled with more erratic rainfall events. This has strong implications for agriculture in the region, yet it is not clear that current modeling and decision-support tools are adequate to address these looming changes and provide planning, mitigation and adaptation strategies. To address climate change and its implications to agriculture in Nebraska, a set of robust decision support tools are very crucial. This study herein are divided into three chapters, with each chapter addressing a specific …

Catechol Oxidation By Ozone And Hydroxyl Radicals At The Air-Water Interface, Elizabeth A. Pillar, Robert C. Camm, Marcelo I. Guzman

Chemistry Faculty Publications

Anthropogenic emissions of aromatic hydrocarbons promptly react with hydroxyl radicals undergoing oxidation to form phenols and polyphenols (e.g., catechol) typically identified in the complex mixture of humic-like substances (HULIS). Because further processing of polyphenols in secondary organic aerosols (SOA) can continue mediated by a mechanism of ozonolysis at interfaces, a better understanding about how these reactions proceed at the air–water interface is needed. This work shows how catechol, a molecular probe of the oxygenated aromatic hydrocarbons present in SOA, can contribute interfacial reactive species that enhance the production of HULIS under atmospheric conditions. Reactive semiquinone radicals are quickly produced upon …

Vernal Pool: A Participatory Art Project About Place + Precipitation, Karen Miranda Abel, Jessica Marion Barr

The Goose

Produced by Karen Miranda Abel with Jessica Marion Barr, Vernal Pool is an immersive, elemental water installation created as a participatory, contemplative inquiry into our transitory interrelationships with water and landscape. From November 2013 to April 2014, 114 individuals across Canada and abroad gathered snow samples as a form of extrinsic artistic practice about place and precipitation. With the arrival of spring, the reservoir of melted snow was convened for four days at Toronto’s historic Gladstone Hotel to create Vernal Pool.

The Potlib Library Of Potential Energy Functions And A New Global Analytic Pes For The H + O2 Reaction, Ronald Duchovic

Ronald J. Duchovic

No abstract provided.

The Barriers To Adopting Composting Toilets Into Use In Urban And Suburban Locations In The United States, Julia Branstrator

Open Access Theses

The amount of fresh water available in the world is a finite resource. Large quantities of the fresh water are located in remote locations, while more accessible sources of fresh water are disproportionately distributed around the world. Some populations lack reliable access to clean water for daily life, making the routine use of potable water in toilets of upper-income countries a questionable practice in terms of resource responsibility, energy use, and sustainable infrastructure. The innovative nature of composting toilets offers potential solutions to the downfalls of conventional, waterborne toilets. However, the path to adoption of composting toilets has encountered barriers …

Long-Term Protection Of Freshwater Resources Following Co2 Storage, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about the mechanisms being utilized to protect freshwater resources following the subsurface geological storage of CO₂. Outlines the U.S. Department of Energy’s (DOE’s) proactive research to ensure water safety as geologic storage of CO₂ becomes more widespread.

Experiments On Tracer Diffusion In Aqueous And Non-Aqueous Solvent Combinations, Duncan M. Frasch, Daniel Spiegel

Physics and Astronomy Faculty Research

Forced Rayleigh scattering is used to study the tracer diffusion of an azobenzene in binary combinations of polar solvents, including water. In the absence of water, the tracer diffusion coefficient D in the mixture lies between the diffusion coefficients within the pure solvents, on a curve that is reasonably close to the prediction of free-volume theory. If water is present, on the other hand, the diffusion coefficient displays a minimum that is less than the smaller of the two pure-solvent values. We attempt to understand the different behavior in water by concentrating on the fairly hydrophobic nature of the solute, …

Polyol Induced Extraction (Pie) Of Water From Organic Solvents, Mithilesh Deshpande

Seton Hall University Dissertations and Theses (ETDs)

Acetonitrile (ACN) is used in huge quantities for Reversed Phase High Performance Liquid Chromatography (RP-HPLC) experiments. For most of the part, these results in waste that is only contaminated with large amounts of water, buffer and trace organic impurities. It would seem worthwhile to purify the ACN from water using a mass separating agent (MSA). In a quest for an MSA, our investigation reveals polyols as a new class of MSAs. It is observed that when a polyol such as glycerol, sorbitol, erythritol, xylitol, Isomalt® or maltitol is added to a mixture of ACN-water, the ACN separates out of the …

Effects Of Ether Vs. Ester Linkage On Lipid Bilayer Structure And Water Permeability., S. Deren Guler, D. Dipon Ghosh, Jianjun Pan, John Mathai, Mark Zeidel, John Nagle, Stephanie Tristram-Nagle

Prof. Stephanie Tristram-Nagle Ph.D.

The structure and water permeability of bilayers composed of the ether-linked lipid, dihexadecylphosphatidylcholine (DHPC), were studied and compared with the ester-linked lipid, dipalmitoylphosphaditdylcholine (DPPC). Wide angle X-ray scattering on oriented bilayers in the fluid phase indicate that the area per lipid A is slightly larger for DHPC than for DPPC. Low angle X-ray scattering yields A=65.1A(2) for DHPC at 48 degrees C. LAXS data provide the bending modulus, K(C)=4.2x10(-13)erg, and the Hamaker parameter H=7.2x10(-14)erg for the van der Waals attractive interaction between neighboring bilayers. For the low temperature phases with ordered hydrocarbon chains, we confirm the transition from a tilted …

Structure And Water Permeability Of Fully Hydrated Diphytanoylpc., Stephanie Tristram-Nagle, Dong Joo Kim, Nadia Akhunzada, Norbert Kucerka, John Mathai, John Katsaras, Mark Zeidel, John Nagle

Prof. Stephanie Tristram-Nagle Ph.D.

Diphytanoylphosphatidylcholine (DPhyPC) is a branched chain lipid often used for model membrane studies, including peptide/lipid interactions, ion channels and lipid rafts. This work reports results of volume measurements, water permeability measurements P(f), X-ray scattering from oriented samples, and X-ray and neutron scattering from unilamellar vesicles at T=30 degrees C. We measured the volume/lipid V(L)=1426+/-1A(3). The area/lipid was found to be 80.5+/-1.5A(2) when both X-ray and neutron data were combined with the SDP model analysis (Kucerka, N., Nagle, J.F., Sachs, J.N., Feller, S.E., Pencer, J., Jackson, A., Katsaras, J., 2008. Lipid bilayer structure determined by the simultaneous analysis of neutron and …

Structure Of Fully Hydrated Fluid Phase Lipid Bilayers With Monounsaturated Chains., Norbert Kucerka, Stephanie Tristram-Nagle, John Nagle

Prof. Stephanie Tristram-Nagle Ph.D.

Quantitative structures are obtained at 30 degrees C for the fully hydrated fluid phases of palmitoyloleoylphosphatidylcholine (POPC), with a double bond on the sn-2 hydrocarbon chain, and for dierucoylphosphatidylcholine (di22:1PC), with a double bond on each hydrocarbon chain. The form factors F(qz) for both lipids are obtained using a combination of three methods. (1) Volumetric measurements provide F(0). (2) X-ray scattering from extruded unilamellar vesicles provides /F(qz)/ for low q(z). (3) Diffuse X-ray scattering from oriented stacks of bilayers provides /F(qz)/ for high q(z). Also, data using method (2) are added to our recent data for dioleoylphosphatidylcholine (DOPC) using methods …

Development And Applications Of The Expanded Equivalent Fluid Method, Bharath Kumar Kandula

Dissertations

Ocean acoustics is the study of sound in the oceans. Electromagnetic waves attenuate rapidly in the water medium. Sound is the best means to transmit information underwater. Computational numerical simulations play an important role in ocean acoustics. Simulations of acoustic propagation in the oceans are challenging due to the complexities involved in the ocean environment. Different methods have been developed to simulate underwater sound propagation. The Parabolic-Equation (PE) method is the best choice in several ocean acoustic problems. In shallow water acoustic experiments, sound loses some of its energy when it interacts with the bottom. An equivalent fluid technique was …

Volunteered Geographic Information For Water Management: A Prototype Architecture, Maria Antonia Brovelli, Luca Dotti, Marco Minghini, Massimo Pancaldi, Giorgio Zamboni

International Conference on Hydroinformatics

Driven by Web 2.0 technology and the almost ubiquitous presence of mobile devices, Volunteered Geographic Information (VGI) is knowing an unprecedented growth. These notable technological advancements have opened fruitful perspectives also in the field of water management and protection, raising the demand for a reconsideration of policies which also takes into account the emerging trend of VGI. This research investigates the opportunity of leveraging such technology to involve citizens equipped with common mobile devices (e.g. tablets and smartphones) in a campaign of report of water-related phenomena. The work is carried out in collaboration with ADBPO - Autorità di bacino del …

Development Of A Public Education Website: Building Bridges Over Water, Angelina Mckee

Agricultural Education and Communication

Website created by Angelina McKee to educate the public about water resource issues. Water is the basic unit of life, water resources are the basis for what societies and ecosystems are founded upon. Water shortages and droughts are more prevalent in our ever-changing world. It is no shock that there are discrepancies between various stockholders on either sides of the dry riverbed. This senior project resulted in the development of a website that addresses global water resources, water use in California, water conservation, and water allocation. The website informs the public on water resources and related issues and will hopefully …

2014 Martz Summer Conference Poster Session, University Of Colorado Boulder. Getches-Wilkinson Center For Natural Resources, Energy, And The Environment, University Of Colorado Boulder. Airwatergas Sustainability Research Network

Water and Air Quality Issues in Oil and Gas Development: The Evolving Framework of Regulation and Management (Martz Summer Conference, June 5-6)

1 page.

This Conference is presented by the Getches-Wilkinson Center for Natural Resources, Energy, and the Environment, in conjunction with the Air-Water-Gas Sustainability Research Network. Technological advances for extracting oil and gas from shale deposits have ushered in a new era of energy development in key resource-rich pockets throughout the US. In this event, we review the ongoing efforts of governments and industry to develop the regulatory and management practices necessary to protect water and air resources, drawing on the latest scientific research to tackle areas of uncertainty and to inform future action.

Water In The 21st Century, Grayson Michael Shor

Social Sciences

The aim of this research project is to provide a comprehensive and global analysis of water use in order to provide the reader with a comprehensive grasp of current and impending issues. The included five (5) chapters discuss water distribution, conservation, purification, law, international development, economic debates, ethical consideration, as well as educated estimations of the effects water related issues may cause in the next one-hundred years.

3d Flowerlike Micro/Nanocomposite Ceria To Remove Arsenic And Chromium In Drinking Water, Taera Kim

Honors Theses

Ceria has received great attention for the removal of water contaminants due to its high oxygen storage capacity, marked oxygen ion conductivity, and tunable catalytic activity. Zhong et al. suggested that ceria (cerium oxide) microspheres with nanoscale 3D flowerlike morphology represent a promising inorganic synthetic material to remove water contaminants such as As(V) and Cr(VI) from drinking water. The 3D flowerlike micro/nanocomposite ceria offer key advantages over other nanoparticle based remediation systems as they can be easily removed via conventional microfiltration. The goals of this thesis project were to test the reproducibility of the synthesis of the 3D flowerlike ceria, …

Green Infrastructure: A New Way Of Addressing Water Quality Issues Within A Growing Population., Marlin Martes

2014 Student Theses

Abstract

Beneath the great metropolis known as New York City, underlies an intricate system of water networks linking all of New York City’s five boroughs. In the same manner that veins function as vessels for the transportation of blood in the circulatory system, NYC’s water system interconnects all of the diverse communities found at multiple levels of society within the city. Regardless of origin or background, today all NYC residents and visitors share NYC’s tap water as a natural resource without fearing water scarcity tomorrow. However, as the estimated population in New York City is expected to rise above 9 …

Water Water Everywhere: Analyzing Long Island's Water Issues And Finding Solutions For A Sustainable Future, Anthony T. Becker

2014 Student Theses

Over three million people call Long Island their home. With access to beautiful landscapes, world-renowned beaches, and proximity to New York City, it is no wonder that so many proudly call this geographic stretch of glacial till their home. However, throughout the years our actions do not necessarily reflect this affection we have to our home. Years of sprawl and human infestation across the island have resulted in widespread environmental degradation. Specifically, the water we drink and the beaches we enjoy have become endangered. I plan on studying the urban ecology of how intensified population growth led to the eutrophication …

Spatial Co-Variation Between Distance From Mining Activity And Water Chemistry On East Tennessee's Northern Cumberland Plateau, Bryan Benjamin Bozeman

Chancellor’s Honors Program Projects

No abstract provided.

Tap Versus Bottle: A Mixed Methods Analysis Of Public Water Supply And The Bottled Water Industry In The United States, Catherine Simons

Theses and Dissertations

Discrepancies exist between the regulation of public tap water by the EPA and bottled water by the FDA. The Safe Drinking Water Act mandates the EPA to set national contaminant standards for drinking water as well as regulations to ensure source water protection, treatment, monitoring, compliance, enforcement, waste water, and public access to water quality information. Bottled water is subject to a differing mandate. As a food product regulated by the FDA, bottled water is required to comply with FDA food regulations as well as specific bottled water regulation regarding standards of identity, quality and cGMP. As a result of …

Regional Carbon Sequestration Partnership Water Working Group, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet about the U.S. Department of Energy (DOE) Regional Carbon Sequestration Partnership’s (RCSP) Water Working Group (WWG). Includes information on the role of water in carbon capture and storage (CCS), and describes the function of the WWG in addressing stakeholder concerns regarding the development of that technology.

Monitoring, Verification, And Accounting Plans Of Water Resources During The Geologic Storage Of Carbon Dioxide, University Of North Dakota. Energy And Environmental Research Center

EERC Brochures and Fact Sheets

Fact sheet developed by the U.S. Department of Energy’s (DOE’s) Water Working Group (WWG), which examines the monitoring aspects of the CO₂ monitoring, verification, and accounting (MVA) framework as it pertains to geologic storage (GS) sites. Highlights measures taken to protect water resources.

Collective Librations Of Water Molecules In The Crystal Lattice Of Rubidium Bromide: Experiment And Simulation, L M. Lepodise, J Horvat, Roger A. Lewis

Josip Horvat

Terahertz spectroscopy of RbBr reveals four prominent absorption lines at room temperature and a further 15 lines at 10 K. Via density-functional-theory (DFT) numerical modelling using the PBE0 hybrid GGA functional, all the absorptions are identified as correlated librations of water molecules in the RbBr lattice. Each libration mode is a combination of rocking, wagging and twisting motions of the water molecules. The number of libration lines and numerical modelling show that the C2v symmetry of water in RbBr is broken. Our modelling shows that the distribution of libration amplitudes and phases for different water molecules in the RbBr unit …

Determining The Dynamics Of Agricultural Water Use: Cases From Asia And Africa, Lisa-Maria Rebelo, Robyn Johnston, Poolad Karimi, Peter G. Mccornick

Daugherty Water for Food Global Institute: Faculty Publications

Across Africa and Asia, water resources are being affected by a complex mixture of social, economic, and environmental factors. These include climate change and population growth, food prices, oil prices, financial disruptions, and political fluctuations. The need to produce more food will have one of the largest impacts on water and will continue to reshape the patterns of agricultural water use in major food-growing regions. With this increasing demand on water for agriculture, from large-scale irrigation to intensification of rainfed systems, it is becoming increasingly important to ensure that water resources decision-making has access to information that captures the spectrum …

Influence Of Chemical Composition And Water On The Bulk Modulus Of Pyrope, Shu Huang

FIU Electronic Theses and Dissertations

Garnets are major silicates from the upper mantle to the transition zone. Elastic properties of garnets are essential to interpret the variation of seismic velocities at different depths and construct a model of the Earth’s composition. Due to the chemical flexibility at octahedron sites of the crystal structures, garnets usually exist with multiple components and have many composition variations. Pyrope is an important member in the garnet group. Fe²⁺-Mg²⁺ substitution in pyrope is one of the common solid solutions. We have synthesized and measured three synthetic solid solutions samples (Py₈₃Alm₁₇, Py₅₄Alm …

Agenda: Fracking, Water Quality And Public Health: Examining Current Laws And Regulations, Network For Public Health Law, American Society Of Law, Medicine & Ethics, Public Health Law Research Program

Fracking, Water Quality and Public Health: Examining Current Laws and Regulations (March 20)

Improved technology developments in directional drilling and hydraulic fracturing, more commonly known as "fracking," have resulted in an oil and gas production boom nationwide. Fracking involves pumping pressurized water, sand, and chemicals down wells to crack bedrock, freeing petroleum and natural gas. Wastewater discharges, hydraulic fracturing fluid releases, and other accidental spills pose potential water quality risks, sparking concern for public health.

This webinar will examine the laws and regulations governing water quality issues related to fracking, recent state court decisions affecting regulations, and implications for public health.

Agriculture, Environmental Restoration And Ecosystem Services: Assessing The Costs Of Water Storage On Agricultural Lands In South Florida, Kayla Ouellette

USF Tampa Graduate Theses and Dissertations

A large part of the environmental restoration required by the Comprehensive Everglades Restoration Plan calls for more water-storage on lands south of Lake Okeechobee in order to restore the natural water flows of the Everglades watershed. The Everglades Agricultural Area (EAA) can be used for increased water storage in order to relieve coastal estuaries of excess water in the rainy season. This water storage can deliver additional ecosystem services of soil retention and reduced CO2 emissions that could compensate farmers for the cost of water storage by increasing long term farm profitability. The goals of this study were 1) to …

A Light-Assisted, Polymeric Water Oxidation Catalyst That Selectively Oxidizes Seawater With A Low Onset Potential, Jun Chen, Pawel W. Wagner, Lei Tong, Danijel Boskovic, Weimin Zhang, David L. Officer, Gordon G. Wallace, Gerhard F. Swiegers

Gordon Wallace

Vapour phase polymerisation (vpp) of PEDOT to incorporate high levels of a sulphonated manganese porphyrin yields a vivid green conducting polymer that, under illumination, catalyzes selective oxidation of water from seawater from ca. 0.40 V (vs. NHE; Pt counter electrode) without observable chlorine formation. This onset potential is comparable to that of certain metal oxide semiconductors that achieve higher photocurrents but are not capable of selectively oxidising the water in seawater.

Dynamics Of Breakpoint Chlorination, Irvine Wei, J. Carrell Morris

Irvine W. Wei

No abstract provided.