Physical Sciences and Mathematics Commons^™

Biogenetically Inspired Total Synthesis Of Lingzhiol. Design And Synthesis Of Axially Chiral N-Heterocyclic Carbene Catalysts., Krishna Sharmah Gautam

Arts & Sciences Graduate Student Theses and Dissertations

A stereo- and enantio-selective synthesis of lingzhiol has been achieved, mimicking a proposed biogenetic pathway via Brønsted acid-catalyzed semipinacol rearrangement of a 2,3-epoxy alcohol. A new and improved method was developed for alkylation of anilines using a domestic microwave oven. The resulting racemic chiral anilines were resolved via classical resolution and transformed into axially chiral thiazolylidene-based NHC organocatalysts, which were applied to asymmetric benzoin condensation.

Investigating The Life-Cycle Of Photosystem Ii Using Mass Spectrometry, Daniel Avram Weisz

Arts & Sciences Graduate Student Theses and Dissertations

Photosystem II (PSII) is a protein complex found embedded in the thylakoid membranes of all organisms that perform oxygenic photosynthesis. PSII converts sunlight into chemical energy, filling our atmosphere with molecular oxygen in the process and supporting nearly all life on Earth. PSII undergoes frequent light-induced damage as an unavoidable result of the electron transfer reactions it catalyzes. When damaged, PSII is disassembled, repaired, and reassembled in an intricate, tightly regulated process. The structure and mechanism of function of active PSII are relatively well-understood, due to the available crystal structures of the active complex and many years of biochemical and …

Real-Space Mean-Field Theory Of A Spin-1 Bose Gas In Synthetic Dimensions, Hilary M. Hurst, Justin H. Wilson, J. H. Pixley, I. B. Spielman, Stefan S. Natu

Faculty Research, Scholarly, and Creative Activity

The internal degrees of freedom provided by ultracold atoms give a route for realizing higher dimensional physics in systems with limited spatial dimensions. Non-spatial degrees of freedom in these systems are dubbed "synthetic dimensions". This connection is useful from an experimental standpoint but complicated by the fact that interactions alter the condensate ground state. Here we use the Gross-Pitaevskii equation to study ground state properties of a spin-1 Bose gas under the combined influence of an optical lattice, spin-orbit coupling, and interactions at the mean field level. The associated phases depend on the sign of the spin-dependent interaction parameter and …

Electropolymerization Of B–Cyclodextrin Onto Multi–Walled Carbon Nanotube Composite Films For Enhanced Selective Detection Of Uric Acid, Mulugeta B. Wayu, Luke T. Dipasquale, Margaret A. Schwarzmann, Samuel D. Gillespie, Michael C. Leopold

Chemistry Faculty Publications

An amperometric uric acid (UA) sensor incorporating a multi-walled carbon nanotubes (MWCNT) network in Nafion and electropolymerized β-cyclodextrin (β-CD) layer is investigated. The electrochemical sensor is comprised of a glassy carbon electrode modified with Nafion-MWCNT nanocomposite film, a β-CD polymer inner selective layer, and a Hydrothane polyurethane (HPU) outer selective coating. The surface morphology and electronic structure of the electrode material are characterized using transmission electron microscopy (TEM), scanning electron microscope (SEM), and Fourier transform infrared (FTIR) spectroscopy. The electrocatalytic activity of the sensor is studied using cyclic voltammetry (CV), chronocoulometry (CC) and differential pulse voltammetry (DPV). Analytical performance of …

The Second Quantized Approach To The Study Of Model Hamiltonians In Quantum Hall Regime, Li Chen

Arts & Sciences Graduate Student Theses and Dissertations

The study of model Hamiltonians, whose exact ground states are well known quantum Hall states, have been investigated solely in the literature from the point of view of first quantized approach in the last few decades. However, a second quantized approach to such Hamiltonians has not been taken in the same measure. In this dissertation, we study Haldane pseudopotential, which is the parent Hamiltonian of 1/M Laughlin state, and Trugman-Kivelson pseudopotential, which is the parent Hamiltonian of 2/5 unprojected Jain state. We find that the study of these Hamiltonians in their second quantized forms not only reproduces all properties of …

Modern Assessment Of The High-Energy Background Environment At Small Atmospheric Depths Using The X-Calibur X-Ray Polarimeter And Its Implications, Rashied Baradaran Amini

Arts & Sciences Graduate Student Theses and Dissertations

Since the discovery of cosmic rays, Earth's upper atmosphere at depths of 1-10 g cm2 has been used for balloon-borne observations probing the high-energy universe. However, the interaction of cosmic rays with the earth atmosphere generates numerous particles, each with their own flux and interaction physics that contribute to instrument background. In Fall 2014, the X-Calibur X-ray polarimeter designed and built at Washington University in St. Louis was launched from Ft. Sumner, New Mexico. While no astrophysical observation was performed as a result of a failure in telescope mechanisms, X-Calibur was able to record hours of instrument background with an …

New Techniques And Optimizations Of Short Echo-Time 1h Mri With Applications In Murine Lung, Jinbang Guo

Arts & Sciences Graduate Student Theses and Dissertations

Although x-ray computed tomography (CT) is a gold standard for pulmonary imaging, it has high ionizing radiation, which puts patients at greater risk of cancer, particularly in a longitudinal study with cumulative doses. Magnetic resonance imaging (MRI) doesn't involve exposure to ionizing radiation and is especially useful for visualizing soft tissues and organs such as ligaments, cartilage, brain, and heart. Many efforts have been made to apply MRI to study lung function and structure of both humans and animals. However, lung is a unique organ and is very different from other solid organs like the heart and brain due to …

Scatterometry Of 50 Nm Half Pitch Features, Ruichao Zhu

Optical Science and Engineering ETDs

Metrology technologies are an essential adjunct to Integrated Circuit (I.C.) Semiconductor manufacturing. Scatterometry, an optical metrology, was chosen to measure 50 nm half pitch feature structures. A bread-board scatterometry system has been assembled to provide a non-contact, non-destructive, accurate and flexible measurement. A real-time, on-line scatterometry system has also been demonstrated and proven to provide a high throughput measurement.

Three different types of samples have been measured using the scatterometry setup. The wire-grid polarizer (WGP) sample has been made by Jet and Flash Nanoimprint Lithography with ~100 nm pitch and ~50 nm wide ~200 nm tall Al gratings on fused …

End-Capping Strategies For Triggering End-To-End Depolymerization Of Polyglyoxylates, Bo Fan, John Trant, Elizabeth Gillies

Chemistry Publications

Polymers that undergo end-to-end depolymerization in response to the cleavage of a stimuli-responsive end-cap are promising for diverse applications from drug delivery to responsive coatings and plastics. It is critical that the end-cap is designed to respond to an appropriate stimulus for the application. In the current work, end-caps for triggering the depolymerization of poly(ethyl glyoxylate) (PEtG) were explored. First, a phenylboronate, a disulfi de, and an azobenzene were utilized to impart redox-responsive properties to PEtG. Then, methoxy-substituted trityl groups were used to provide sensitivity to mild acid. A multiresponsive platform was also introduced, allowing PEtG to respond to multiple …

Geostationary Operational Environmental Satellite- R Series (Goes-R) 2016, Paige N. Dixon

Student Works

This is a report on the first NOAA GOES-R satellite, launched on November 19th, 2016. This report will cover some of the details of the GOES-R project, as well as discuss the collaborations that made the project possible. This document will also detail some of the new satellite’s capabilities including geostationary lightning detection, and space weather monitoring, and will focus on real-world application of such technology. Additionally, this report will list some of the current and projected GOES-R products, and the potential benefits if testing proves successful.

The Paradox Of Social Media Security: A Study Of It Students’ Perceptions Versus Behavior On Using Facebook, Zahra Y. Alqubaiti

Master of Science in Information Technology Theses

Social media plays an essential role in the modern society, enabling people to be better connected to each other and creating new opportunities for businesses. At the same time, social networking sites have become major targets for cyber-security attacks due to their massive user base. Many studies investigated the security vulnerabilities and privacy issues of social networking sites and made recommendations on how to mitigate security risks. Users are an integral part of any security mix. In this thesis, we explore the relationship between users’ security perceptions and their actual behavior on social networking sites. Protection motivation theory (PMT), initially …

Separation Of Nitrito- And Nitropentamminecobalt (Iii) Chloride By High Performance Liquid Chromatography, Tisha Hutchinson

Seton Hall University Dissertations and Theses (ETDs)

Reversed phase high performance liquid chromatography, chosen because of its ability to collect many data points over a long period of time with minimal involvement, was used to separate pentaamminenitritocobalt(III) chloride and pentaamminenitrocobalt(III) chloride. Pentaamminenitritocobalt(III) chloride was prepared, made into a concentrated solution, divided into aliquots and allowed to isomerize to pentaamminenitrocobalt(III) chloride over a period of twelve to eighteen hours. An injection was made approximately every forty-five minutes. The samples were analyzed at three wavelengths, 254 nm, 460 nm and 490 nm. The absorbance was collected and was used to determine the kinetics of the reaction.

The isomerization from …

New Insights Into The Martian Crust And Angrite Parent Body Through Meteorites, Alison R. Santos

Earth and Planetary Sciences ETDs

Petrologic studies of two new, unique meteorites were conducted in order to characterize the samples and provide insights into their parent bodies. The first sample, Northwest Africa 7034, is the first martian meteorite breccia to be discovered. In an effort to understand the martian crustal materials sampled by the breccia, we developed a classification scheme for the breccia clasts based on their texture, mineralogy, and chemistry. We then further investigated two clast groups which contained trends in mineralogy and chemistry that suggested a possible genetic relationship between the two. Our findings suggest they are not related by a simple igneous …

Groundwater-Flow Model Of The Northern High Plains Aquifer In Colorado, Kansas, Nebraska, South Dakota, And Wyoming, Steven M. Peterson, Amanda T. Flynn, Jonathan (Jp) Traylor

United States Geological Survey: Water Reports and Publications

The High Plains aquifer is a nationally important water resource underlying about 175,000 square miles in parts of eight states: Colorado, Kansas, Oklahoma, Nebraska, New Mexico, South Dakota, Texas, and Wyoming. Droughts across much of the Northern High Plains from 2001 to 2007 have combined with recent (2004) legislative mandates to elevate concerns regarding future availability of groundwater and the need for additional information to support science-based water-resource management. To address these needs, the United States Geological Survey (USGS) began the High Plains Groundwater Availability Study to provide a tool for water-resource managers and other stakeholders to assess the status …

Distributed All-Ip Mobility Management Architecture Supported By The Ndn Overlay, Zhiwei Yan, Guanggang Geng, Sherali Zeadally, Yong-Jin Park

Information Science Faculty Publications

Two of the most promising candidate solutions for realizing the next-generation all-IP mobile networks are Mobile IPv6 (MIPv6), which is the host-based and global mobility supporting protocol, and Proxy MIPv6 (PMIPv6), which is the network-based and localized mobility supporting protocol. However, the unprecedented growth of mobile Internet traffic has resulted in the development of distributed mobility management (DMM) architecture by the Internet engineering task force DMM working group. The extension of the basic MIPv6 and PMIPv6 to support their distributed and scalable deployment in the future is one of the major goals of the DMM working group. We propose an …

In-Class Versus At-Home Quizzes: Which Is Better? A Flipped Learning Study In A Two-Site Synchronously-Broadcast Organic Chemistry Course, Michael A. Christensen, Alyssia M. Lambert, Louis S. Nadelson, Kami M. Dupree, Trish A. Kingsford

Chemistry and Biochemistry Faculty Publications

We recently shared our design of a two-semester flipped organic chemistry course, in which we gave students in-class quizzes to incentivize attendance and watching the lecture videos in advance. With a second iteration, we planned to make the video-watching experience more engaging. We accordingly hypothesized that if students completed short at-home quizzes while watching the videos, then attentiveness, engagement, and learning would increase. We tested this with a later section of the course, dividing the material into 13 units. For units 1-6, we gave in-class quizzes; for 7-13, quizzes were at home. Although units 1-6 and 7-13 covered different material, …

Trending @ Rwu Law: Julia Wyman's Post: The Threat Of Marine Debris 12-13-2016, Julia Wyman

Law School Blogs

No abstract provided.

Formulation Of Colloidal Suspensions Of 3-Mercaptopropionic Acid Capped Pbs Quantum Dots As Solution Processable Qd "Inks" For Optoelectronic Applications, Chase Collier Reinhart

Dissertations and Theses

The use of colloidal quantum dots (QDs) for photovoltaic energy conversion is a nascent field that has been dominated for well over a decade by the use of 3-mercaptopropionic acid (3-MPA) capped PbS QDs. These QDs are routinely deposited via an in situ solid state ligand exchange process that displaces the native oleate ligand on the PbS QD surface. This ligand exchange procedure is wasteful of material and has been demonstrated to leave numerous impurities that limit electronic performance of the as-deposited QD devices. Until the last few years there was very little understanding in chemical literature as to many …

The Evolution Of Zero-Tolerance Policies, Stephanie D. Stahl

CrissCross

Most Americans today have a largely negative image of zero-tolerance policies (ZTP) enacted to stop and prevent violence in the United States school system. According to the U.S. Department of Education Office of Educational Research and Improvement, zero-tolerance procedures are policies that mandate predetermined consequences or punishments for specific offenses (Walker). These policies specifically targeted actions considered violent and threatening, such as possession of a firearm or weapon. The concept of zero-tolerance policies was introduced into the education system during the 1980s as part of the failed War on Drugs as an attack on drug usage and violence in schools. …

The Labyrinth Of The Mind: The Psychology Of War Stories In Tim O’Brien’S Going After Cacciato, Rebekah Smith

CrissCross

This paper explores and analyzes the psychological reasons for storytelling by soldiers and veterans both during and after their deployments in war. It brings in multiple works by author-veterans as well as critical writing about these books with a specific focus on Going After Cacciato by Tim O'Brien. Paul Berlin, the novel's protagonist, imagines a fictional quest leaving Vietnam and going all the way to Paris following the desertion of a fellow soldier gone AWOL. He creates this journey to create order, find meaning, generate understanding, and focus on the good rather than the bad. This paper also explores the …

American Spring, Sam Mullooly, Tom Mullooly

CrissCross

Composer's Notes

I composed American Spring during the 2015-2016 school year, my final year as an undergraduate at Illinois Wesleyan University, in connection with the 150th anniversary of the end of the Civil War. This opera takes place mostly in April 1865, the year Richmond burned and Lincoln died, and deals with America’s feelings of pride and shame in war. The opera’s main character is Varina Davis, the wife of confederate President Jefferson Davis. Varina offers the 1860’s Southern perspective on slavery and the war, one glossed over in most readings of our history because it is so obviously repugnant …

Birthing Center Versus Hospitalized Birth, Nicolette Larsen

CrissCross

There are many risks and benefits of giving birth at a birthing center versus a hospital. Determining the location of birth is an important decision, as women in the world today have many options of where to have their child. Hospitals and birthing centers are two places where medical professionals provide prenatal, labor and delivery, and postpartum care for the mother and fetus during this memorable time. While hospital nurses and physicians provide advanced medical care, birthing centers focus on holistic care of the family unit emphasizing mental, spiritual, and physical health. Doctors often perform cesarean sections (C-sections) for non-medical …

A Park Story, David Flowers, Evan Dolan

CrissCross

Composer's Note

A Park Story was written to be an honest and objective portrayal of the struggles that both characters experience throughout their collective story. Christopher and his mother both end up fighting two dominating perspectives of their identity: their family roles, and how they identify themselves. Their self-identities collide with each other in an irreconcilable manner; while both of them strongly desire the family bond they have, the mother’s convictions become the line that neither of them have any desire to cross.

Tracking The Elephant (Lexodonta Africana) Corridor And The Human-Wildlife Conflict In Selela Village, Nicole Chlebek, Laura Stalter

CrissCross

The beastly journey of long-distance migration for the African Elephant (Lexodonta Africana) is important for upholding their connections between diminishing protected areas, especially in northeastern Tanzania. However, human development is encroaching into these corridors, creating a human-elephant conflict, which can ruin livelihoods of villagers, depending on the extent of conflict. This study focused on exploring the hypothesized human-elephant conflict on the Selela corridor, specifically in Selela village, as well as GPS (Global Positioning System) mapping evidence of elephant travel along the projected Selela elephant corridor connecting Ngorongoro Conservation Area (NCA), to Selela Forest Reserve (SFR), and finally to …

How Shape Of Simulated Graphene Sheets Affects Debye Scattering Patterns, Lindsay Lesh

Honors Projects

This research is about understanding the structure of a subset of graphitic stardust found in primitive meteorites (e.g. the Murchison meteorite). The carbon grains of interest exhibit a core-rim structure, where the core – with a density less than that of the graphitic rim – comprises the majority of the grain. Previous studies have shown that the cores are comprised primarily of unlayered graphene, and it has been hypothesized that the cores are the result of the rapid freezing (quenching) of a liquid carbon droplet. Electron diffraction is sensitive to small differences in crystal structure and simulated electron diffraction powder …

Ironstone Gravel Types In Western Australia: Re-Purposing A Geological Survey To Improve Soil Management, Edward A. Griffin, Karen Holmes, Tim Overheu

Conference papers and presentations

The deeply laterised landscapes of Western Australia’s wheatbelt contain large amounts of ferruginous concretions or pisoliths, referred to locally as ironstone gravel. Soil surveys over the years have described ironstone gravel presence and abundance, and the state soil classification system recognises their importance in agriculture by designating ‘ironstone gravel soils’ at the highest level of the classification hierarchy. These gravels have generally been assumed inert in agricultural soils; however, farm trials and anecdotal experience suggest they may play a more active role in nutrient and water retention than previously recognised. Gravelly soil performance under dryland agriculture varies dramatically across the …

Anomaly Detection From Hyperspectral Remote Sensing Imagery, Qiandong Guo, Ruiliang Pu, Jun Cheng

School of Geosciences Faculty and Staff Publications

Hyperspectral remote sensing imagery contains much more information in the spectral domain than does multispectral imagery. The consecutive and abundant spectral signals provide a great potential for classification and anomaly detection. In this study, two real hyperspectral data sets were used for anomaly detection. One data set was an Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data covering the post-attack World Trade Center (WTC) and anomalies are fire spots. The other data set called SpecTIR contained fabric panels as anomalies compared to their background. Existing anomaly detection algorithms including the Reed–Xiaoli detector (RXD), the blocked adaptive computation efficient outlier nominator (BACON), the …

Bgsu Minecraft Initiative Website, Jacob Gusching

Honors Projects

A website for the BGSU Minecraft Initiative, a program that uses Minecraft as an educational tool to engage younger students to learn. This website is a communication tool to showcase the work of BGSU students and to spread the knowledge and lesson to plans to interested parties.

Algorithm For Premature Ventricular Contraction Detection From A Subcutaneous Electrocardiogram Signal, Iris Lynn Shelly

Dissertations and Theses

Cardiac arrhythmias occur when the normal pattern of electrical signals in the heart breaks down. A premature ventricular contraction (PVC) is a common type of arrhythmia that occurs when a heartbeat originates from an ectopic focus within the ventricles rather than from the sinus node in the right atrium. This and other arrhythmias are often diagnosed with the help of an electrocardiogram, or ECG, which records the electrical activity of the heart using electrodes placed on the skin. In an ECG signal, a PVC is characterized by both timing and morphological differences from a normal sinus beat.

An implantable cardiac …

Development Of An Hplc-Based Oligosaccharide Synthesizer, Salvatore Pistorio

Dissertations

Carbohydrates are the most abundant molecules on Earth. They are involved in a wide range of fundamental biological processes: anti-inflammation, immune response, joint lubrication, cell growth, antigenic determination. Carbohydrates are also held responsible for many damaging cellular processes, such as bacterial and viral infections, development of tumors, etc.. Therefore, the development of effective methods for the synthesis of complex carbohydrates has become a critical area of glycosciences. One challenge that stands out is the stereocontrol in the synthesis of glycosidic bonds, the linkage that serves as the only means to connect simple monosaccharides into complex oligomeric networks. Beyond this, the …