Physical Sciences and Mathematics Commons^™

Electropolymerization Of B–Cyclodextrin Onto Multi–Walled Carbon Nanotube Composite Films For Enhanced Selective Detection Of Uric Acid, Mulugeta B. Wayu, Luke T. Dipasquale, Margaret A. Schwarzmann, Samuel D. Gillespie, Michael C. Leopold

Chemistry Faculty Publications

An amperometric uric acid (UA) sensor incorporating a multi-walled carbon nanotubes (MWCNT) network in Nafion and electropolymerized β-cyclodextrin (β-CD) layer is investigated. The electrochemical sensor is comprised of a glassy carbon electrode modified with Nafion-MWCNT nanocomposite film, a β-CD polymer inner selective layer, and a Hydrothane polyurethane (HPU) outer selective coating. The surface morphology and electronic structure of the electrode material are characterized using transmission electron microscopy (TEM), scanning electron microscope (SEM), and Fourier transform infrared (FTIR) spectroscopy. The electrocatalytic activity of the sensor is studied using cyclic voltammetry (CV), chronocoulometry (CC) and differential pulse voltammetry (DPV). Analytical performance of …

The Second Quantized Approach To The Study Of Model Hamiltonians In Quantum Hall Regime, Li Chen

Arts & Sciences Graduate Student Theses and Dissertations

The study of model Hamiltonians, whose exact ground states are well known quantum Hall states, have been investigated solely in the literature from the point of view of first quantized approach in the last few decades. However, a second quantized approach to such Hamiltonians has not been taken in the same measure. In this dissertation, we study Haldane pseudopotential, which is the parent Hamiltonian of 1/M Laughlin state, and Trugman-Kivelson pseudopotential, which is the parent Hamiltonian of 2/5 unprojected Jain state. We find that the study of these Hamiltonians in their second quantized forms not only reproduces all properties of …

New Techniques And Optimizations Of Short Echo-Time 1h Mri With Applications In Murine Lung, Jinbang Guo

Arts & Sciences Graduate Student Theses and Dissertations

Although x-ray computed tomography (CT) is a gold standard for pulmonary imaging, it has high ionizing radiation, which puts patients at greater risk of cancer, particularly in a longitudinal study with cumulative doses. Magnetic resonance imaging (MRI) doesn't involve exposure to ionizing radiation and is especially useful for visualizing soft tissues and organs such as ligaments, cartilage, brain, and heart. Many efforts have been made to apply MRI to study lung function and structure of both humans and animals. However, lung is a unique organ and is very different from other solid organs like the heart and brain due to …

Biogenetically Inspired Total Synthesis Of Lingzhiol. Design And Synthesis Of Axially Chiral N-Heterocyclic Carbene Catalysts., Krishna Sharmah Gautam

Arts & Sciences Graduate Student Theses and Dissertations

A stereo- and enantio-selective synthesis of lingzhiol has been achieved, mimicking a proposed biogenetic pathway via Brønsted acid-catalyzed semipinacol rearrangement of a 2,3-epoxy alcohol. A new and improved method was developed for alkylation of anilines using a domestic microwave oven. The resulting racemic chiral anilines were resolved via classical resolution and transformed into axially chiral thiazolylidene-based NHC organocatalysts, which were applied to asymmetric benzoin condensation.

Ongoing And Visually-Evoked Cortical Activity Measured Across Multiple Spatial Scales, Nathaniel Caleb Wright

Arts & Sciences Graduate Student Theses and Dissertations

The visual cortex is a densely-interconnected network of neurons, which receives sensory input from the early visual pathway, and represents information about the visual world in the resulting spatiotemporal activity patterns. These patterns are mediated by cortical interactions that span multiple spatial scales (i.e., neuron-neuron, neuron-population, and population-population). Such interactions are a fundamental property of cortical function, and capture the contribution of the cortex to sensory coding. Yet these interactions are only beginning to be understood, in part because of the challenge of recording ongoing and visually-evoked activity across multiple spatial scales in individual studies. In this thesis, we present …

New Insights Into The Martian Crust And Angrite Parent Body Through Meteorites, Alison R. Santos

Earth and Planetary Sciences ETDs

Petrologic studies of two new, unique meteorites were conducted in order to characterize the samples and provide insights into their parent bodies. The first sample, Northwest Africa 7034, is the first martian meteorite breccia to be discovered. In an effort to understand the martian crustal materials sampled by the breccia, we developed a classification scheme for the breccia clasts based on their texture, mineralogy, and chemistry. We then further investigated two clast groups which contained trends in mineralogy and chemistry that suggested a possible genetic relationship between the two. Our findings suggest they are not related by a simple igneous …

End-Capping Strategies For Triggering End-To-End Depolymerization Of Polyglyoxylates, Bo Fan, John Trant, Elizabeth Gillies

Chemistry Publications

Polymers that undergo end-to-end depolymerization in response to the cleavage of a stimuli-responsive end-cap are promising for diverse applications from drug delivery to responsive coatings and plastics. It is critical that the end-cap is designed to respond to an appropriate stimulus for the application. In the current work, end-caps for triggering the depolymerization of poly(ethyl glyoxylate) (PEtG) were explored. First, a phenylboronate, a disulfi de, and an azobenzene were utilized to impart redox-responsive properties to PEtG. Then, methoxy-substituted trityl groups were used to provide sensitivity to mild acid. A multiresponsive platform was also introduced, allowing PEtG to respond to multiple …

Separation Of Nitrito- And Nitropentamminecobalt (Iii) Chloride By High Performance Liquid Chromatography, Tisha Hutchinson

Seton Hall University Dissertations and Theses (ETDs)

Reversed phase high performance liquid chromatography, chosen because of its ability to collect many data points over a long period of time with minimal involvement, was used to separate pentaamminenitritocobalt(III) chloride and pentaamminenitrocobalt(III) chloride. Pentaamminenitritocobalt(III) chloride was prepared, made into a concentrated solution, divided into aliquots and allowed to isomerize to pentaamminenitrocobalt(III) chloride over a period of twelve to eighteen hours. An injection was made approximately every forty-five minutes. The samples were analyzed at three wavelengths, 254 nm, 460 nm and 490 nm. The absorbance was collected and was used to determine the kinetics of the reaction.

The isomerization from …

Geostationary Operational Environmental Satellite- R Series (Goes-R) 2016, Paige N. Dixon

Student Works

This is a report on the first NOAA GOES-R satellite, launched on November 19th, 2016. This report will cover some of the details of the GOES-R project, as well as discuss the collaborations that made the project possible. This document will also detail some of the new satellite’s capabilities including geostationary lightning detection, and space weather monitoring, and will focus on real-world application of such technology. Additionally, this report will list some of the current and projected GOES-R products, and the potential benefits if testing proves successful.

The Paradox Of Social Media Security: A Study Of It Students’ Perceptions Versus Behavior On Using Facebook, Zahra Y. Alqubaiti

Master of Science in Information Technology Theses

Social media plays an essential role in the modern society, enabling people to be better connected to each other and creating new opportunities for businesses. At the same time, social networking sites have become major targets for cyber-security attacks due to their massive user base. Many studies investigated the security vulnerabilities and privacy issues of social networking sites and made recommendations on how to mitigate security risks. Users are an integral part of any security mix. In this thesis, we explore the relationship between users’ security perceptions and their actual behavior on social networking sites. Protection motivation theory (PMT), initially …

In-Class Versus At-Home Quizzes: Which Is Better? A Flipped Learning Study In A Two-Site Synchronously-Broadcast Organic Chemistry Course, Michael A. Christensen, Alyssia M. Lambert, Louis S. Nadelson, Kami M. Dupree, Trish A. Kingsford

Chemistry and Biochemistry Faculty Publications

We recently shared our design of a two-semester flipped organic chemistry course, in which we gave students in-class quizzes to incentivize attendance and watching the lecture videos in advance. With a second iteration, we planned to make the video-watching experience more engaging. We accordingly hypothesized that if students completed short at-home quizzes while watching the videos, then attentiveness, engagement, and learning would increase. We tested this with a later section of the course, dividing the material into 13 units. For units 1-6, we gave in-class quizzes; for 7-13, quizzes were at home. Although units 1-6 and 7-13 covered different material, …

Groundwater-Flow Model Of The Northern High Plains Aquifer In Colorado, Kansas, Nebraska, South Dakota, And Wyoming, Steven M. Peterson, Amanda T. Flynn, Jonathan (Jp) Traylor

United States Geological Survey: Water Reports and Publications

The High Plains aquifer is a nationally important water resource underlying about 175,000 square miles in parts of eight states: Colorado, Kansas, Oklahoma, Nebraska, New Mexico, South Dakota, Texas, and Wyoming. Droughts across much of the Northern High Plains from 2001 to 2007 have combined with recent (2004) legislative mandates to elevate concerns regarding future availability of groundwater and the need for additional information to support science-based water-resource management. To address these needs, the United States Geological Survey (USGS) began the High Plains Groundwater Availability Study to provide a tool for water-resource managers and other stakeholders to assess the status …

Distributed All-Ip Mobility Management Architecture Supported By The Ndn Overlay, Zhiwei Yan, Guanggang Geng, Sherali Zeadally, Yong-Jin Park

Information Science Faculty Publications

Two of the most promising candidate solutions for realizing the next-generation all-IP mobile networks are Mobile IPv6 (MIPv6), which is the host-based and global mobility supporting protocol, and Proxy MIPv6 (PMIPv6), which is the network-based and localized mobility supporting protocol. However, the unprecedented growth of mobile Internet traffic has resulted in the development of distributed mobility management (DMM) architecture by the Internet engineering task force DMM working group. The extension of the basic MIPv6 and PMIPv6 to support their distributed and scalable deployment in the future is one of the major goals of the DMM working group. We propose an …

Formulation Of Colloidal Suspensions Of 3-Mercaptopropionic Acid Capped Pbs Quantum Dots As Solution Processable Qd "Inks" For Optoelectronic Applications, Chase Collier Reinhart

Dissertations and Theses

The use of colloidal quantum dots (QDs) for photovoltaic energy conversion is a nascent field that has been dominated for well over a decade by the use of 3-mercaptopropionic acid (3-MPA) capped PbS QDs. These QDs are routinely deposited via an in situ solid state ligand exchange process that displaces the native oleate ligand on the PbS QD surface. This ligand exchange procedure is wasteful of material and has been demonstrated to leave numerous impurities that limit electronic performance of the as-deposited QD devices. Until the last few years there was very little understanding in chemical literature as to many …

Trending @ Rwu Law: Julia Wyman's Post: The Threat Of Marine Debris 12-13-2016, Julia Wyman

Law School Blogs

No abstract provided.

The Evolution Of Zero-Tolerance Policies, Stephanie D. Stahl

CrissCross

Most Americans today have a largely negative image of zero-tolerance policies (ZTP) enacted to stop and prevent violence in the United States school system. According to the U.S. Department of Education Office of Educational Research and Improvement, zero-tolerance procedures are policies that mandate predetermined consequences or punishments for specific offenses (Walker). These policies specifically targeted actions considered violent and threatening, such as possession of a firearm or weapon. The concept of zero-tolerance policies was introduced into the education system during the 1980s as part of the failed War on Drugs as an attack on drug usage and violence in schools. …

The Labyrinth Of The Mind: The Psychology Of War Stories In Tim O’Brien’S Going After Cacciato, Rebekah Smith

CrissCross

This paper explores and analyzes the psychological reasons for storytelling by soldiers and veterans both during and after their deployments in war. It brings in multiple works by author-veterans as well as critical writing about these books with a specific focus on Going After Cacciato by Tim O'Brien. Paul Berlin, the novel's protagonist, imagines a fictional quest leaving Vietnam and going all the way to Paris following the desertion of a fellow soldier gone AWOL. He creates this journey to create order, find meaning, generate understanding, and focus on the good rather than the bad. This paper also explores the …

American Spring, Sam Mullooly, Tom Mullooly

CrissCross

Composer's Notes

I composed American Spring during the 2015-2016 school year, my final year as an undergraduate at Illinois Wesleyan University, in connection with the 150th anniversary of the end of the Civil War. This opera takes place mostly in April 1865, the year Richmond burned and Lincoln died, and deals with America’s feelings of pride and shame in war. The opera’s main character is Varina Davis, the wife of confederate President Jefferson Davis. Varina offers the 1860’s Southern perspective on slavery and the war, one glossed over in most readings of our history because it is so obviously repugnant …

Birthing Center Versus Hospitalized Birth, Nicolette Larsen

CrissCross

There are many risks and benefits of giving birth at a birthing center versus a hospital. Determining the location of birth is an important decision, as women in the world today have many options of where to have their child. Hospitals and birthing centers are two places where medical professionals provide prenatal, labor and delivery, and postpartum care for the mother and fetus during this memorable time. While hospital nurses and physicians provide advanced medical care, birthing centers focus on holistic care of the family unit emphasizing mental, spiritual, and physical health. Doctors often perform cesarean sections (C-sections) for non-medical …

A Park Story, David Flowers, Evan Dolan

CrissCross

Composer's Note

A Park Story was written to be an honest and objective portrayal of the struggles that both characters experience throughout their collective story. Christopher and his mother both end up fighting two dominating perspectives of their identity: their family roles, and how they identify themselves. Their self-identities collide with each other in an irreconcilable manner; while both of them strongly desire the family bond they have, the mother’s convictions become the line that neither of them have any desire to cross.

Tracking The Elephant (Lexodonta Africana) Corridor And The Human-Wildlife Conflict In Selela Village, Nicole Chlebek, Laura Stalter

CrissCross

The beastly journey of long-distance migration for the African Elephant (Lexodonta Africana) is important for upholding their connections between diminishing protected areas, especially in northeastern Tanzania. However, human development is encroaching into these corridors, creating a human-elephant conflict, which can ruin livelihoods of villagers, depending on the extent of conflict. This study focused on exploring the hypothesized human-elephant conflict on the Selela corridor, specifically in Selela village, as well as GPS (Global Positioning System) mapping evidence of elephant travel along the projected Selela elephant corridor connecting Ngorongoro Conservation Area (NCA), to Selela Forest Reserve (SFR), and finally to …

How Shape Of Simulated Graphene Sheets Affects Debye Scattering Patterns, Lindsay Lesh

Honors Projects

This research is about understanding the structure of a subset of graphitic stardust found in primitive meteorites (e.g. the Murchison meteorite). The carbon grains of interest exhibit a core-rim structure, where the core – with a density less than that of the graphitic rim – comprises the majority of the grain. Previous studies have shown that the cores are comprised primarily of unlayered graphene, and it has been hypothesized that the cores are the result of the rapid freezing (quenching) of a liquid carbon droplet. Electron diffraction is sensitive to small differences in crystal structure and simulated electron diffraction powder …

Ironstone Gravel Types In Western Australia: Re-Purposing A Geological Survey To Improve Soil Management, Edward A. Griffin, Karen Holmes, Tim Overheu

Conference papers and presentations

The deeply laterised landscapes of Western Australia’s wheatbelt contain large amounts of ferruginous concretions or pisoliths, referred to locally as ironstone gravel. Soil surveys over the years have described ironstone gravel presence and abundance, and the state soil classification system recognises their importance in agriculture by designating ‘ironstone gravel soils’ at the highest level of the classification hierarchy. These gravels have generally been assumed inert in agricultural soils; however, farm trials and anecdotal experience suggest they may play a more active role in nutrient and water retention than previously recognised. Gravelly soil performance under dryland agriculture varies dramatically across the …

Anomaly Detection From Hyperspectral Remote Sensing Imagery, Qiandong Guo, Ruiliang Pu, Jun Cheng

School of Geosciences Faculty and Staff Publications

Hyperspectral remote sensing imagery contains much more information in the spectral domain than does multispectral imagery. The consecutive and abundant spectral signals provide a great potential for classification and anomaly detection. In this study, two real hyperspectral data sets were used for anomaly detection. One data set was an Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data covering the post-attack World Trade Center (WTC) and anomalies are fire spots. The other data set called SpecTIR contained fabric panels as anomalies compared to their background. Existing anomaly detection algorithms including the Reed–Xiaoli detector (RXD), the blocked adaptive computation efficient outlier nominator (BACON), the …

Bgsu Minecraft Initiative Website, Jacob Gusching

Honors Projects

A website for the BGSU Minecraft Initiative, a program that uses Minecraft as an educational tool to engage younger students to learn. This website is a communication tool to showcase the work of BGSU students and to spread the knowledge and lesson to plans to interested parties.

Algorithm For Premature Ventricular Contraction Detection From A Subcutaneous Electrocardiogram Signal, Iris Lynn Shelly

Dissertations and Theses

Cardiac arrhythmias occur when the normal pattern of electrical signals in the heart breaks down. A premature ventricular contraction (PVC) is a common type of arrhythmia that occurs when a heartbeat originates from an ectopic focus within the ventricles rather than from the sinus node in the right atrium. This and other arrhythmias are often diagnosed with the help of an electrocardiogram, or ECG, which records the electrical activity of the heart using electrodes placed on the skin. In an ECG signal, a PVC is characterized by both timing and morphological differences from a normal sinus beat.

An implantable cardiac …

Development Of An Hplc-Based Oligosaccharide Synthesizer, Salvatore Pistorio

Dissertations

Carbohydrates are the most abundant molecules on Earth. They are involved in a wide range of fundamental biological processes: anti-inflammation, immune response, joint lubrication, cell growth, antigenic determination. Carbohydrates are also held responsible for many damaging cellular processes, such as bacterial and viral infections, development of tumors, etc.. Therefore, the development of effective methods for the synthesis of complex carbohydrates has become a critical area of glycosciences. One challenge that stands out is the stereocontrol in the synthesis of glycosidic bonds, the linkage that serves as the only means to connect simple monosaccharides into complex oligomeric networks. Beyond this, the …

The Creation Of A Video Review Guide For The Free-Response Section Of The Advanced Placement Calculus Exam, Jeffrey Brown

Honors Theses

The Creation of a Video Review Guide for the Free-Response Section of the Advanced Placement Calculus Exam follows the creation of a resource to help students prepare for the College Board’s Advanced Placement Calculus Exam. This project originated out of the authors personal experiences in preparing for this exam. The goal of the project was to create an accessible resource that reviews content, provides insights into the Advanced Placement exam, and creates successful habits in student responses. This paper, chronologically, details the development of the resource and a reflection on the final product and future uses.

Sdss-Iv Manga – The Spatially Resolved Transition From Star Formation To Quiescence, Francesco Belfiore, Roberto Maiolino, Claudia Maraston, Eric Emsellem, Matthew A. Bershady, Karen L. Masters, Dmitry Bizyaev, Médéric Boquien, Joel R. Brownstein, Kevin Bundy, Aleksandar M. Diamond-Stanic, Niv Drory, Timothy M. Heckman, David R. Law, Olena Malanushenko, Audrey Oravetz, Kaike Pan, Alexandre Roman-Lopes, Daniel Thomas, Anne-Marie Weijmans, Kyle B. Westfall, Renbin Yan

Physics and Astronomy Faculty Publications

Using spatially resolved spectroscopy from SDSS-IV MaNGA we have demonstrated that low ionization emission-line regions (LIERs) in local galaxies result from photoionization by hot evolved stars, not active galactic nuclei, hence tracing galactic region hosting old stellar population where, despite the presence of ionized gas, star formation is no longer occurring. LIERs are ubiquitous in both quiescent galaxies and in the central regions of galaxies where star formation takes place at larger radii. We refer to these two classes of galaxies as extended LIER (eLIER) and central LIER (cLIER) galaxies, respectively. cLIERs are late-type galaxies primarily spread across the green …

The Rate Of Binary Black Hole Mergers Inferred From Advanced Ligo Observations Surrounding Gw150914, B. P. Abbott, R. Abbott, T. D. Abbott, M. R. Abernathy, F. Acernese, K. Ackley, C. Adams, T. Adams, P. Addesso, R. X. Adhikari, V. B. Adya, C. Affeldt, M. Agathos

Physics & Astronomy Faculty Publications

A transient gravitational-wave signal, GW150914, was identified in the twin Advanced LIGO detectors on 2015 September 2015 at 09:50:45 UTC. To assess the implications of this discovery, the detectors remained in operation with unchanged configurations over a period of 39 days around the time of the signal. At the detection statistic threshold corresponding to that observed for GW150914, our search of the 16 days of simultaneous two-detector observational data is estimated to have a false-alarm rate (FAR) of <4.9×10−6yr−1, yielding a p-value for GW150914 of <2×10−7. Parameter estimation follow-up on this trigger identifies its source as a binary black hole (BBH) merger with component masses (m1,m2)=(36−4+5,29−4+4)M⊙ at redshift z=0.09−0.04+0.03 (median and 90% credible range). Here, we report on the constraints these observations place on the rate of BBH coalescences. Considering only GW150914, assuming that all BBHs in the universe have the same masses and spins as this event, imposing a search FAR threshold of 1 per 100 years, and assuming that the BBH merger rate is constant in the comoving frame, we infer a 90% credible range of merger rates between 2--53Gpc−3yr−1 (comoving frame). Incorporating all search triggers that pass a much lower threshold while accounting for the uncertainty in the astrophysical origin of each trigger, we estimate a higher rate, ranging from 13--600Gpc−3yr−1 depending on assumptions about the BBH mass distribution. All together, our various rate estimates fall in the conservative range 2--600Gpc−3yr−1.