Physical Sciences and Mathematics Commons^™

An Ensemble Study Of The Sea Level Rise Impact On Storm Surge And Inundation In The Coastal Bangladesh, Mansur Ali Jisan

Electronic Theses and Dissertations

The hydrodynamic model Delft3D is used to study the impact of Sea Level Rise (SLR) on storm surge and inundation in the coastal region of Bangladesh. To study the present-day inundation scenario, track of two known tropical cyclones (TC) were used: Aila (Category 1; 2009) and Sidr (Category 5; 2007). Model results were validated with the available observations. Future inundation scenarios were generated by using the strength of TC Sidr, TC Aila and an ensemble of historical TC tracks but incorporating the effect of SLR. Since future change in storm surge inundation under SLR impact is a probabilistic incident, that’s …

An Exploratory Study On The Possible Effect Of Hydraulic Fracturing Activities On Air Quality In The Eagle Ford Shale Region Of Texas., Laura B. Fimibama

Electronic Theses and Dissertations

Eagle Ford Shale (EFS) play is one out of five major oil and gas formations in Texas, found in the South-Eastern region with approximately 30 counties. In addition to natural gas, it produces crude oil and petroleum liquids which in recent times has resulted in a surge in drilling due to a new drilling technology – hydraulic fracturing that injects massive quantities of water along with sand and chemical additives into a well to create tiny hairline cracks in rock formations. The success of this technology has made gas extraction more economically feasible. However, this technique has generated an array …

Geologic And Geochemical Characterization Of Cross-Communication Potential Within The Northern Edwards Aquifer System, Texas, Ingrid J. Eckhoff

Electronic Theses and Dissertations

The Edwards Aquifer is a large, complex groundwater system located throughout Central Texas in association with the Balcones Fault Zone. The San Antonio and Barton Spring segments of the Edwards Aquifer have been extensively studied in the past because they provide groundwater resources to the largely urbanized areas of San Antonio and Austin, respectively, and smaller communities along the Interstate 35 corridor. Previous research has been conducted on these southern and central portions of the Edwards Aquifer system, which have characterized the structural, hydrogeological and geochemical variations within the highly karsted region. However, the Northern Segment of the Edwards Aquifer …

Observations And Light Curve Analysis Of Transiting Extra-Solar Planets, Clark M. Holcomb

Electronic Theses and Dissertations

The purpose of this research was to perform the procedures to study transiting exoplanets in their entirety, from the data collection process to determining physical characteristics and orbital properties. The research was conducted with two telescopes of different sizes (16” and 12”) at multiple sites in order to refine the detection process. Both Maxim DL and Mira Pro x64 software were used to process the resulting images. The PHOEBE program was used to model the data to determine the properties of the exoplanets, which were then compared to the results obtained by other astronomers. The data collection process as well …

Zirconium Diboride, Hexagonal Boron Nitride, And Amorphous Alumina Thin Films For High Temperature Applications, David Murdock Stewart

Electronic Theses and Dissertations

The use of microelectronic sensors and actuators in harsh, high temperature environments, such as power plants, turbine engines, and industrial manufacturing, could greatly improve the safety, reliability, and energy efficiency of these processes. The primary challenge in implementing this technology is the breakdown and degradation of thin films used in fabricating these devices when exposed to high temperatures >800 °C and oxidizing atmospheres. Zirconium diboride, hexagonal boron nitride, and amorphous alumina are candidate materials for use as thin film sensor components due to their high melting temperatures and stable phases. Zirconium diboride thin films have metallic-like electrical conductivity and remain …

Sperner's Lemma, The Brouwer Fixed Point Theorem, The Kakutani Fixed Point Theorem, And Their Applications In Social Sciences, Ayesha Maliwal

Electronic Theses and Dissertations

Can a cake be divided amongst people in such a manner that each individual is content with their share? In a game, is there a combination of strategies where no player is motivated to change their approach? Is there a price where the demand for goods is entirely met by the supply in the economy and there is no tendency for anything to change? In this paper, we will prove the existence of envy-free cake divisions, equilibrium game strategies and equilibrium prices in the economy, as well as discuss what brings them together under one heading.

This paper examines three …

An Analysis Of Gulf Of Maine Cod Metapopulation Structure And Localized Stability, With Application To Area-Based Fisheries Management, Derek Olson

Electronic Theses and Dissertations

The complex metapopulation structure of groundfish stocks in the Gulf of Maine, particularly Atlantic cod (Gadus morhua), is largely ignored under the current system of broad-scale stock assessment and management. This mismatch of biological and administrative scales has contributed to severe overall stock decline and localized serial depletion of Gulf of Maine cod. Such chronic management failure has led to growing calls for a more area-based, finer-scale approach to managing groundfish in the Gulf of Maine. A primary difficulty hindering the development of finer-scale groundfish management has been the challenge of estimating fishing mortality upon local stock components. …

Roles Of Siphon Flows In Suspension Feeding, Kevin Du Clos

Electronic Theses and Dissertations

Benthic marine suspension feeders provide an important link between benthic and pelagic ecosystems. The strength of this link is determined by suspension-feeding rates. Many studies have measured suspension-feeding rates using indirect clearance-rate methods, which are based on the depletion of suspended particles. Direct methods that measure the flow of water itself are less common, but they can be more broadly applied because clearance-rate measurements are affected by properties of the cleared particles. We present pumping rates for three species of suspension feeders, the clams Mya arenaria and Mercenaria mercenaria and the tunicate Ciona intestinalis, calculated using a direct method …

Microstructural Analysis Of Thermoelastic Response, Nonlinear Creep, And Pervasive Cracking In Heterogeneous Materials, Alden C. Cook

Electronic Theses and Dissertations

This dissertation is concerned with the development of robust numerical solution procedures for the generalized micromechanical analysis of linear and nonlinear constitutive behavior in heterogeneous materials. Although the methods developed are applicable in many engineering, geological, and materials science fields, three main areas are explored in this work. First, a numerical methodology is presented for the thermomechanical analysis of heterogeneous materials with a special focus on real polycrystalline microstructures obtained using electron backscatter diffraction techniques. Asymptotic expansion homogenization and finite element analysis are employed for micromechanical analysis of polycrystalline materials. Effective thermoelastic properties of polycrystalline materials are determined and compared …

A Comparison Of Global Climate Reanalysis And Climate Of South Greenland And The North Atlantic, Jeff Auger

Electronic Theses and Dissertations

Global climate reanalysis models are regularly used in many scientific fields concerning climate and atmospheric observation. This thesis utilizes reanalysis models in two chapters in order to gain insight into North Atlantic climate teleconnections and their relation to precipitation across South Greenland. This first chapter of this thesis compares the four most recent reanalysis models – ECMWF Reanalysis Interim (ERA-I), NCEP Climate Forecast System Reanalysis (CFSR), JMA 55-year Reanalysis (JRA-55), and NASA Modern-Era Retrospective Analysis for Research and Applications (MERRA) – and develops from these models a monthly-mean ensemble average of common meteorological variables for the period 1979-2013. Results from …

Embedding Of Hypercube Graphs On Orientable Surfaces, Prateek Kunwar

Electronic Theses and Dissertations

The purpose of this thesis is to study hypercube graphs and their embeddings on orientable surfaces. We use rotation systems to represent these embeddings. We prove some results about the effect of adjacent switches in rotation system and create a rotation system called the ABC rotation system and prove general results about it. Using this rotation system, we give a general theorem about the minimal embedding of $Q_{n}$. We also look at some interesting types of maximal embedding of $Q_{n}$, such as the Eulerian walk embedding and the "big-face embedding". We prove a theorem that gives a recursively constructive way …

Computational Quantum Chemistry Studies Of The Stabilities Of Radical Intermediates Formed During The Oxidation Of Melatonin, Constance E. Warden

Electronic Theses and Dissertations

Melatonin, a nontoxic natural antioxidant, is of interest as a possible spin trap for use in spectroscopic methods to observe and identify short-lived free radicals, which have been linked to oxidative stress that may result in serious health problems. However, the reaction mechanisms for the oxidation of melatonin to form the product N¹-acetyl-N²-formyl-5-methoxykynuramine are still not well understood. Computational quantum chemistry studies have been done on four proposed reaction mechanisms, involving the following major intermediate structures: a dioxetane, an epoxide, a melatonin radical cation, and a spin radical adduct. Molecular geometries were optimized at the …

Characterization And Delineation Of Karst Geohazards Along Rm652 Using Electrical Resistivity Tomography, Culberson County, Texas, Adam F. Majzoub

Electronic Theses and Dissertations

The Delaware Basin of West Texas and southeastern New Mexico is the major western subdivision of the Permian Basin and a northern extension of the Chihuahuan Desert. The major evaporite unit within the Delaware Basin is the Castile Formation, which consists of gypsum/anhydrite and is highly susceptible to dissolution and karsting. Manifestations of karst within the Castile outcrop are abundant and include sinkholes, subsidence features and caves, both epigene and hypogene in origin.

Land reconnaissance surveys conducted during the summer of 2015 documented abundant karst landforms in close proximity to a major thoroughfare, RM 652, in Culberson County, Texas. 2D …

Comparison Of Two Methods For Developing Aggregate Population-Based Models, Oyebola E. Oyero

Electronic Theses and Dissertations

Aggregate models incorporate the variation between individual parameters of individualbased models to construct a population-based model. This thesis focuses on the comparison of two different methods for creating these population-based models. The first method, the individual parameter distribution technique (IPD) focuses on the similarities and variation of parameters in an individual-based model as calculated using individual data sets [4]. The second method we consider is the nonlinear mixed effect method (NLME), which is primarily used in modeling repeated measurement data. In the NLME approach, both the fixed effects and random effects of the parameter values are estimated in the model …

A Reduced Labeled Samples (Rls) Framework For Classification Of Imbalanced Concept-Drifting Streaming Data., Elaheh Arabmakki

Electronic Theses and Dissertations

Stream processing frameworks are designed to process the streaming data that arrives in time. An example of such data is stream of emails that a user receives every day. Most of the real world data streams are also imbalanced as is in the stream of emails, which contains few spam emails compared to a lot of legitimate emails. The classification of the imbalanced data stream is challenging due to the several reasons: First of all, data streams are huge and they can not be stored in the memory for one time processing. Second, if the data is imbalanced, the accuracy …

Geotechnical Properties Of The Travis Peak (Hosston) Formation In East Texas: A Compressive And Tensile Strength Analysis Using Regression Analysis., Pawan Kakarla

Electronic Theses and Dissertations

The estimation of rock mass strength is a key parameter in geotechnical engineering which is used in the design of geotechnical structures like tunnels, dams and slopes. Geotechnical engineering is the branch of civil engineering which works on the principles of soil and rock mechanics to evaluate subsurface conditions, stability of slopes, foundations of structures and construction of earthworks. The main focus of this study was to calculate the strength of Lower Cretaceous Travis Peak Formation rocks of East Texas and to check the accuracy by comparing it with Regression analysis. The parameters which were used were the Uniaxial Compression …

Speleogenesis And Delineation Of Megaporosity And Karst Geohazards Through Geologic Cave Mapping And Lidar Analyses Associated With Infrastructure In Culberson County, Texas, Jon T. Ehrhart

Electronic Theses and Dissertations

The Gypsum Plain region of the Delaware Basin hosts approximately 1800 km² of the Castile Formation outcrop. A myriad of karstic developments from closed sinkholes to large multi-kilometer cave systems have been documented within the region. Karst studies on the distribution and speleogenetic evolution within Castile strata began within the last decade with ever increasing data resolution. In this study, a combination of both physical field surveys and analyses of high resolution (~30 cm accuracy) LiDAR data was used to create a theoretical model for karst development across the region. This idealized model considers speleogenetic formation type variations (hypogene …

Spreading Speeds Along Shifting Resource Gradients In Reaction-Diffusion Models And Lattice Differential Equations., Jin Shang

Electronic Theses and Dissertations

A reaction-diffusion model and a lattice differential equation are introduced to describe the persistence and spread of a species along a shifting habitat gradient. The species is assumed to grow everywhere in space and its growth rate is assumed to be monotone and positive along the habitat region. We show that the persistence and spreading dynamics of a species are dependent on the speed of the shifting edge of the favorable habitat, c, as well as c^*(∞) and c^*(−∞), which are formulated in terms of the dispersal kernel and species growth rates in both directions. When …

Investigating High Speed Localization Microscopy Through Experimental Methods, Data Processing Methods, And Applications Of Localization Microscopy To Biological Questions, Andrew J. Nelson

Electronic Theses and Dissertations

Fluorescence Photoactivation Localization Microscopy(FPALM) and other super resolution localization microscopy techniques can resolve structures with nanoscale resolution. Unlike techniques of electron microscopy, they are also compatible with live cell and live animal studies, making FPALM and related techniques ideal for answering questions about the dynamic nature of molecular biology in living systems. Many processes in biology occur on rapid sub second time scales requiring the imaging technique to be capable of resolving these processes not just with a high enough spatial resolution, but with an appropriate temporal resolution. To that end, this Dissertation in part investigates high speed FPALM as …

Declining Dissolved Oxygen In The Central California Current Region, Alice Ren

Electronic Theses and Dissertations

A potential consequence of climate change is a global decrease in dissolved oxygen at depth due to changes in the balance of ventilation, mixing, respiration, and photosynthesis in the oceans. Regionally, the California Current has experienced dissolved oxygen declines since the late 1980s with observations from Oregon and the Southern California Bight. Here, we present observations of declining dissolved oxygen along CalCOFI Line 67 off of Monterey Bay, in the Central California Current region, and investigate likely mechanisms. The hydrographic cruises obtained dissolved oxygen measurements 50-300 km from shore between 1998 and 2013, with quasi-seasonal sampling resolution. Dissolved oxygen decreased …

A Multi-Indexed Logistic Model For Time Series, Xiang Liu

Electronic Theses and Dissertations

In this thesis, we explore a multi-indexed logistic regression (MILR) model, with particular emphasis given to its application to time series. MILR includes simple logistic regression (SLR) as a special case, and the hope is that it will in some instances also produce significantly better results. To motivate the development of MILR, we consider its application to the analysis of both simulated sine wave data and stock data. We looked at well-studied SLR and its application in the analysis of time series data. Using a more sophisticated representation of sequential data, we then detail the implementation of MILR. We compare …

Diazonium 4-(Trifluorovinyloxy) Perfluorobutanesulfonyl Benzenesulfonimide Zwitterionic Monomer Synthesis, Isaac D. Addo

Electronic Theses and Dissertations

3-Diazonium- 4-(trifluorovinyloxy) - perfluorobutanesulfonyl benzenesulfonimide zwitterionic monomer (see figure 1) is proposed to be polymerized and further act as a new electrolyte for Polymer exchange membrane fuel cells (PEMFCs). One reason is that, the aromatic trifluorovinyl aryl ether (TFVE) group can easily be homopolymerized to aromatic perfluorocyclobutane (PFCB) polymer. Furthermore, the diazonium moiety in the monomer is expected to covalently attach the electrolyte to the carbon electrodes support. The perfluoroalkyl(aryl) sulfonimide (PFSI) pendant provides good chemical and mechanical stability as well as better proton conductivity. Several multi-step synthetic schemes are designed to obtain such monomer from perfluoroalkyl(aryl) sulfonimide (PFSI). Among …

Improving The Performance Of Ice Sheet Modeling Through Embedded Simulation, Christopher G. Dufour

Electronic Theses and Dissertations

Understanding the impact of global climate change is a critical concern for society at large. One important piece of the climate puzzle is how large-scale ice sheets, such as those covering Greenland and Antarctica, respond to a warming climate. Given such ice sheets are under constant change, developing models that can accurately capture their dynamics represents a significant challenge to researchers. The problem, however, is properly capturing the dynamics of an ice sheet model requires a high model resolution and simulating these models is intractable even for state-of-the-art supercomputers.

This thesis presents a revolutionary approach to accurately capture ice sheet …

Social Ecological Food Systems: Sustainability Lessons From Maine Dairy Networks, Julia B. Mcguire

Electronic Theses and Dissertations

Milk production has played an integral role in the culture, landscape, and economy of Maine’s agriculture. Maine dairy farmers have faced numerous sustainability challenges to economic, environmental, and social aspects of their industry. Like many other complex social ecological systems, the Maine dairy industry faces a gap between scientific knowledge and actionable management or policy. A cultural dichotomy exists between conventional and organic farming. Shifting the focus from this binary, metrics such as social capital may play a key role in solving sustainability issues. Difficulties arise in the governance of complex social ecological systems when the scales of assessment, management, …

Shortnose Sturgeon (Acipenser Brevirostrum) Spawning Potential In The Penobscot River, Maine: Considering Dam Removals And Emerging Threats, Catherine Johnston

Electronic Theses and Dissertations

Dam removals from the Penobscot River in Maine restored access to freshwater habitat critical for the life cycle of endangered shortnose sturgeon. Prior to the dam removals, shortnose sturgeon spawning activity had not been documented. Instead, evidence suggested that individuals emigrated from the Penobscot River to spawn in the Kennebec complex, 140 km away. A central question of this thesis was whether spawning activity would commence in the first two years following dam removal. Consistent with pre-dam removal movement patterns determined using acoustic telemetry, the majority (78%) of tagged individuals emigrated from the Penobscot River at some point over the …

Sediment Accumulations Patterns In The Damariscotta River Estuary, Emily A. Chandler

Electronic Theses and Dissertations

The tidally dominated Damariscotta River estuary is located on the south-central Maine coast. The elongate, north-south orientation of the estuary is characteristic of the indented shoreline in this region and a consequence of the bedrock structural framework, comprised of Paleozoic high-grade metasedimentary rocks. Pegmatite sills form bedrock constriction points that divide the estuary into seven distinct basins. The narrow, bending geometry and sill and basin morphology impact the distribution of sediment within the estuary and the hydrodynamics of the system. This study employs multibeam bathymetry surveys, sediment grab samples and radionuclide analysis (²¹⁰Pb and ¹³⁷Cs) of sediment …

Size As A Trait For Understanding The Role Of Zooplankton In The Biological Carbon Pump, Karen Stamieszkin

Electronic Theses and Dissertations

Living organisms impact carbon transport between the atmosphere and the ocean through the biological carbon pump. Some plankton communities augment carbon export from the ocean’s surface, and are thought to have a major role in global climate. These export communities are often characterized by larger organisms that sink to depths where the carbon they contain is sequestered from the atmosphere. Zooplankton can enhance export by aggregating prey into larger sinking fecal pellets; however fecal pellet flux is a highly variable component of the biological carbon pump. Relating plankton trophic dynamics to changes in particulate carbon flux is an important step …

Silver-Polymer Nanocomposites, Anita N. Paul

Electronic Theses and Dissertations

The objective of this research was the development of an efficient method for the preparation of silver-polymer nanocomposites containing finely dispersed silver nanoparticles. The surface of nanosilver was functionalized by thiolation with 2-aminoethanethiol. Amino-modified nanosilver was covalently bonded to polyacrylic acid, biodegradable polymers like acid terminated polylactic acid, ester terminated poly(DL-lactide-co-glycolide) and acid terminated poly(DL lactide-co-glycolide) in the presence of diisopropylcarbodiimide by carbodiimide method. Esterification of the carboxyl groups of Ag-polyacrylic acid by hydrochloric acid in methanol resulted in the formation of a stable colloidal dispersion of Ag nanoparticles in the polymer matrix. It was observed that not just acid …

Molecular Docking, Synthesis And Evaluation Of Pyrrolo[2,1-C][1,4]Benzodiazepines Derivatives As Non-Β-Lactam Β-Lactamases Inhibitors, Joseph Osamudiamen Osazee

Electronic Theses and Dissertations

Our research aim was to design, synthesize, and study the competitive enzyme inhibition kinetics of pyrrolo[2,1-c][1,4]benzodiazepine (PBD) derivatives as potential non-²-lactam ²-lactamase inhibitors. All compounds (1-13) passed the Lipinski’s rule of 5 test and were docked into the active site of TEM-1 ²-lactamase. PBD derivatives 1-7 were synthesized in high yields and tested for their potency against TEM-1 and P99 ²-lactamases. Kinetic data showed that compounds 1, 4, 5, and 7 possessed inhibitory activity against TEM-1 ranging from 4-34 %. Docking results revealed significant interactive spanning of the active site of TEM-1 by PBDs. …

Tornado Density And Return Periods In The Southeastern United States: Communicating Risk And Vulnerability At The Regional And State Levels, Michelle Bradburn

Electronic Theses and Dissertations

Tornado intensity and impacts vary drastically across space, thus spatial and statistical analyses were used to identify patterns of tornado severity in the Southeastern United States and to assess the vulnerability and estimated recurrence of tornadic activity. Records from the Storm Prediction Center's tornado database (1950-2014) were used to estimate kernel density to identify areas of high and low tornado frequency at both the regional- and state-scales. Return periods (2-year, 5-year, 10-year, 25-year, 50-year, and 100-year) were calculated at both scales as well using a composite score that included EF-scale magnitude, injury counts, and fatality counts. Results showed that the …