Physical Sciences and Mathematics Commons^™

Associations Between Iron Concentration And Productivity In Montane Streams Of The Black Hills, South Dakota, Cari-Ann Hayer, Benjamin M. Holocmb, Steven R. Chipps

The Prairie Naturalist

Iron is an important micronutrient found in aquatic systems that can influence nutrient availability (e.g. phosphorus) and primary productivity. In streams, high iron concentrations often are associated with low pH as a result of acid mine drainage, which is known to affect fish and invertebrate communities. Streams in the Black Hills of South Dakota are generally circumneutral in pH, yet select streams exhibit high iron concentrations associated with natural iron deposits. In this study, we examined relationships among iron concentration, periphyton biomass, macroinvertebrate abundance, and fish assemblages in four Black Hills streams. The stream with the highest iron concentration (~5 …

Multi-Robot Task Allocation: A Spatial Queuing Approach, William H. Lenagh

Student Work

Multi-Robot Task Allocation (MRTA) is an important area of research in autonomous multi-robot systems. The main problem in MRTA is to match a set of robots to a set of tasks so that the tasks can be completed by the robots while optimizing a certain metric such as the time required to complete all tasks, distance traveled by the robots and energy expended by the robots. We consider a scenario where the tasks can appear dynamically and the location of tasks are not known a priori by the robots. Additionally, for a task to be completed, it needs to be …

Molecular Dynamics Model Of Carbon Nanotubes In Epon 862/Detda Polymer, Guttormur Arnar Ingvason

Doctoral Dissertations and Master's Theses

The aerospace industry is interested in increasing the strength while reducing the weight of carbon fiber composite materials. Adding single walled carbon nanotubes (SWCNT) to a polymer matrix can achieve that goal by improving delamination properties of the composite. Due to the complexity of polymer molecules and the curing process, few 3-D Molecular Dynamics simulations of a polymer-SWCNT composite have been run. Our model runs on the Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS), with a COMPASS (Condensed phase Optimized Molecular Potential for Atomistic Simulations Studies) potential to represent the interactions between the atoms of the polymer and the SWCNT. This …

Filter-Based Multiscale Entropy Analysis Of Complex Physiological Time Series, Liang Zhao

Dissertations - ALL

The multiscale entropy (MSE) has been widely and successfully used in analyzing the complexity of physiologic time series. In this thesis, we re-interpret the averaging process in MSE as filtering a time series by a filter of a piecewise constant type. From this viewpoint, we introduce the {\it filter-based multiscale entropy} (FME) which filters a time series by filters to generate its multiple frequency components and then compute the {\it blockwise} entropy of the resulting components. By choosing filters adapted to the feature of a given time series, FME is able to better capture its multiscale information and to provide …

For Logs, For Traditional Purposes And For Food: Identification Of Multiple-Use Plant Species Of Northern Amazonia And An Assessment Of Factors Associated With Their Distribution, Anthony Ravindra Cummings

Dissertations - ALL

This dissertation examines the multiplicity of uses associated with tree and palm species of the Rupununi, Southern Guyana and the factors associated with their distribution. As tropical forests continue to decline the most significant response has been to understand the implications for the carbon cycle, with the impacts on forest dwelling peoples and wildlife, inadequately addressed. Multiple-use plants, individual species which at their most critical level provide food for wildlife, non-timber forest products and are commercially logged, provide a suitable lens for appreciating additional ecosystem services that may be compromised as tropical forests decline. I completed a plant inventory in …

Analysis Of Polarimetric Synthetic Aperture Radar And Passive Visible Light Polarimetric Imaging Data Fusion For Remote Sensing Applications, Sanjit Maitra

Theses

The recent launch of spaceborne (TerraSAR-X, RADARSAT-2, ALOS-PALSAR, RISAT) and airborne (SIRC, AIRSAR, UAVSAR, PISAR) polarimetric radar sensors, with capability of imaging through day and night in almost all weather conditions, has made polarimetric synthetic aperture radar (PolSAR) image interpretation and analysis an active area of research. PolSAR image classification is sensitive to object orientation and scattering properties. In recent years, significant work has been done in many areas including agriculture, forestry, oceanography, geology, terrain analysis. Visible light passive polarimetric imaging has also emerged as a powerful tool in remote sensing for enhanced information extraction. The intensity image provides information …

Group Selection And Key Management Strategies For Ciphertext-Policy Attribute-Based Encryption, Russell F. Martin

Theses

Ciphertext-Policy Attribute-Based Encryption (CPABE) was introduced by Bethencourt, Sahai, and Waters, as an improvement of Identity Based Encryption, allowing fine grained control of access to encrypted files by restricting access to only users whose attributes match that of the monotonic access tree of the encrypted file. Through these modifications, encrypted files can be placed securely on an unsecure server, without fear of malicious users being able to access the files, while allowing each user to have a unique key, reducing the vulnerabilites associated with sharing a key between multiple users.

However, due to the fact that CPABE was designed for …

Permaculture, Roslynn Brain, Blake Thomas

Environment and Society Faculty Publications

No abstract provided.

Analysis Of Energy Flow In Us Globec Ecosystems Using End-To-End Models, J. J. Ruzicka, J. H. Steele, S. K. Gaichas, T. Ballerini, D. J. Gifford, R. D. Brodeur, E. E. Hofmann

CCPO Publications

End-to-end models were constructed to examine and compare the trophic structure and energy flow in coastal shelf ecosystems of four US Global Ocean Ecosystem Dynamics (GLOBEC) study regions: the Northern California Current, the Central Gulf of Alaska, Georges Bank, and the Southwestern Antarctic Peninsula. High-quality data collected on system components and processes over the life of the program were used as input to the models. Although the US GLOBEC program was species-centric, focused on the study of a selected set of target species of ecological or economic importance, we took a broader community-level approach to describe end-to-end energy flow, from …

X-Ray Fluorescence (Xrf) Analyzer - Theory, Utility, And Qa/Qc For Environmental And Commercial Product Samples In Cambodia, Sereyrath Lim

Multidisciplinary Studies Theses

Laboratory facilities in developed countries provide a variety of options for analysis of environmental samples and commercial commodities that could impact human health. The same is not true in developing countries and there is a great need to identify technologies that could be used to provide robust, accurate, cost-effective analysis that minimizes the need for extensive technical training. An X-ray Fluorescence (XRF) analyzer seems to be an analytical technique that could be such a tool for developing countries. Therefore, the objective of this thesis was to assess the performance and utility of a handheld, portable XRF unit in analyzing different …

Remediation Of Copper(Ii) And Lead(Ii) From Aqueous Solution Using Engineered Iron Oxide And Manganese Oxide Nanomaterials, Carlos Tamez Jr.

Theses and Dissertations - UTB/UTPA

Nano-sized Fe3O4, Fe2O3, Mn3O4, and MnO2 were synthesized by titration/precipitation and characterized using powder XRD. pH assays determined that optimum binding occurred at pH 4 for Fe3O4 and Fe2O3 and pH 3 for Mn3O4 and MnO2. Maximum adsorption of Cu(II) and Pb(II) occurred within 20 min or less of contact with the nanomaterials. The synthesized nanomaterials showed a binding preference for Pb(II) over Cu(II) at concentrations above 50 ppm. Batch studies also showed no significant reduction in the binding of copper and lead to either Fe3O4, Fe2O3, Mn3O4, or MnO2 in the presence of Na+ , K+ , Mg2+ or …

Biological Compatibility And Cytotoxicity Studies Of Hepa-1c1c7, Hepg2, And Mcf-7 Cancer Cell Lines Upon Exposure To Silver, Palladium, And Gold Nanoparticles, M. Esther Salinas

Theses and Dissertations - UTB/UTPA

The field of nanomedicine has recently explored potential applications for cancer treatment ranging from drug delivery methods to cancer imaging techniques. Due to potential risks of nanomaterials affecting non-cancerous cells in the body, in vitro toxicity studies are being conducted. The nanoparticles (NPs) were synthesized from potassium tetrachloroaurate (III) hydrate, potassium tetrabromoaurate (III) dihydrate, potassium tetrachloropalladate (II), and silver nitrate. NPs were synthesized using the Turkevich method or through the sodium borohydride reduction. Particles synthesized using sodium borohydride were stabilized with cetyltrimethylammonium bromide (CTAB). The NPs under investigation were used to treat three cancer cell lines. The treated cells were …

Oxidation Of Dibenzothiophene To Dibenzothiophene Sulfone Using Tungsten (Vi) Oxide, Alejandrina Rivera

Theses and Dissertations - UTB/UTPA

The oxidation of dibenzothiophene (DBT) to dibenzothiophene-sulfone has been considered as an alternate method to remove sulfur from crude oil. This study demonstrates that the oxidative desulfurization (ODS) of DBT to DBT-sulfone occurs using WO3 as a catalyst. WO3 was synthesized and characterized using X-ray diffraction to determine the phase of WO3. Each reaction was refluxed and run for four hours using WO3 as a catalyst, dibenzothiphene, and four different solvents: decahydronapthalene, n-dodecane, decalin, and dodecane. The reactions were performed at temperatures ranging from 120 oC to 150 oC. Aliquots were taken at 30 minutes for up to four hours …

A Survey Of Heavy Metals In Water, Soil And The Surrounding Plants In The Lower Rio Grande Valley, Erving W. Morelius

Theses and Dissertations - UTB/UTPA

Heavy metal pollution of the environment in recent years has become a major issue of importance for both human and environmental health. Samples were investigated for the potential pollution of the area as it is a vital produce producing area. During the study plant, soil and water samples were collected from the Donna Reservoir and Canal System to test the concentration of various heavy metals. The heavy metals tested included both potentially toxic and micronutrients in the samples which included arsenic, cadmium, chromium, copper, iron, lead, nickel and sulfur. During the study, a sixty day sampling period was used to …

The Relational Algebra Toolkit: A User-Friendly Approach To Presenting And Processing Relational Algebra Queries On The Web, Jeremy J. Miller

Theses and Dissertations - UTB/UTPA

Relational algebra is the mathematical basis of tools to express and optimize queries on relational data. However, there exists no convenient way to directly use, express, store, render, visualize, and execute relational algebra over the Web. Educators and practitioners are limited to creating relational algebra expressions using TeX or equation editors which cannot execute them. This work presents a solution to this issue: the Relational Algebra Toolkit (RAT). Relational data and queries are represented using purpose-built XML vocabularies, to be both machine-processable and serializable. Encoded relational algebra expressions can be rendered as parenthetical expressions and as syntax trees, translated to …

What You Like In Design Use To Correct Bad-Smells, Marouane Kessentini, Rim Mahaouachi, Khaled Ghedira

Computer Science Faculty Research & Creative Works

Over the past decades, many techniques and tools have been developed to support maintenance activities in order to improve software quality. One of the most efficient ones is software refactoring to eliminate bad smells. A majority of existing work propose "standard" refactoring solutions that can be applied by hand for each kind of defect. However, it is difficult to prove or ensure the generality of these solutions to any kind of bad-smells or software codes. In this paper, we propose an approach to correct bad smells using well-designed code. We use genetic algorithms to generate correction solutions defined as a …

Genetic Algorithm Techniques In Climate Changepoint Problems, Shanghong Li

All Dissertations

The first part of this dissertation studies genetic algorithms as a means of estimating the number of changepoints and their locations in a climatic time series. Such methods bypass classical subsegmentation algorithms, which sometimes yield suboptimal conclusions. Minimum description length techniques are introduced. These techniques require optimizing an objective function over all possible changepoint numbers and location times. Our general objective functions allow for correlated data, reference station aspects, and/or non-normal marginal distributions, all common features of climate time series. As an exhaustive evaluation of all changepoint configurations is not possible, the optimization is accomplished via a genetic algorithm that …

Factors Affecting The Surface-Mediated Reduction Of Plutonium In The Presence Of Pure Mineral Phases, Amy Hixon

All Dissertations

The overall objective of the research is to investigate the mechanistic and kinetic aspects of the surface-mediated reduction of plutonium. The first chapter is a critical review of plutonium sorption to pure mineral phases. The objective is to study if and how the mechanisms by which plutonium interacts with mineral surfaces are connected to mechanisms for the surface-mediated reduction of plutonium. The main conclusion of the review is that advanced spectroscopy, microscopy, and molecular modeling are needed to fully understand not only the surface structure of pure mineral phases, but also the coordination and bonding environment of plutonium surface complexes. …

L1 Methods For Shrinkage And Correlation, Jie Shen

All Dissertations

This dissertation explored the idea of L1 norm in solving two statistical problems including multiple linear regression and diagnostic checking in time series. In recent years L1 shrinkage methods have become popular in linear regression as they can achieve simultaneous variable selection and parameter estimation. Their objective functions containing a least squares term and an L1 penalty term which can produce sparse solutions (Fan and Li, 2001). Least absolute shrinkage and selection operator (Lasso) was the first L1 penalized method proposed and has been widely used in practice. But the Lasso estimator has noticeable bias and is inconsistent for variable …

Extremal Results For Peg Solitaire On Graphs, Aaron D. Gray

Electronic Theses and Dissertations

In a 2011 paper by Beeler and Hoilman, the game of peg solitaire is generalized to arbitrary boards. These boards are treated as graphs in the combinatorial sense. An open problem from that paper is to determine the minimum number of edges necessary for a graph with a fixed number of vertices to be solvable. This thesis provides new bounds on this number. It also provides necessary and sufficient conditions for two families of graphs to be solvable, along with criticality results, and the maximum number of pegs that can be left in each of the two graph families.

Synthesis And Characterization Of 2,2-Cis-[Rh2(Nphcoch3)4]•Ncc6h4r Where R = H, 2-Ch3, 3-Ch3, 4-Ch3 And [Rh2(O2cch3)(Nphcocf3)3], Fredricka F. Quarshie

Electronic Theses and Dissertations

Five novel compounds were synthesized and characterized. Crystal structures were determined using Rigaku Mercury 375/MCCD(XtaLAB mini) diffractometer with graphite monochromated MoKα radiation. The crystal structures of [Rh₂(NPhCOCH₃)₄•xNCC₆H₄R where x = 1 or 2 and R=H, 2-CH₃,3-CH₃ and 4-CH₃ were solved to an R₁ value of less than 5 (R₁= Σ||F_o| - |F_c|| / Σ |F_o|). In each of the nitrile complexes, the rhodium is five or six coordinate and possesses pseudo D_4h symmetry. The complexes were …

Co2 Capture On Porous Adsorbents Containing Surface Amino Groups, Odette Amana Esam

Electronic Theses and Dissertations

The potential impact of carbon dioxide as a major source of global warming has led to extensive research in order to mitigate the greenhouse effect. In this work, four adsorbents were synthesized and studied. The adsorbents were obtained by grafting and sol-gel of amino-containing molecules such as bis[3-(trimethoxysilyl)propyl]amine as monoamine and [3-(2-aminoethylamino)propyl]- trimethoxysilane as diamine on the surface of silica gel. CO2 passed through adsorbents at room temperature for its capture, then desorbed at moderate heating, and stored in the form of insoluble BaCO3. The adsorbent synthesized by sol-gel synthesis was found to be more efficient due to its high …

Unified Model Of Charge Transport In Insulating Polymeric Materials, Alec Sim

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Charge transport, charging, and subsequent electrostatic discharge due to interactions with the space environment are primary concerns of spacecraft designers. Developing a physical understanding of the interactions of charge with the multitude of materials that spacecraft are composed of is a critical step in understanding and mitigating both short-term and long-term spacecraft degradation. In particular, the study of charge transport in highly insulating materials is critical as they store charge longer, with higher capacity, and with greater destructive capability than other materials.

The Utah State University Materials Physics Group, with the funding of the NASA James Webb Space Telescope project …

Substrate Binding And Reduction Mechanism Of Molybdenum Nitrogenase, Zhiyong Yang

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

As a key constituent of proteins, nucleic acids, and other biomolecules, nitrogen is essential to all living organisms including human beings. Dinitrogen represents the largest pool of nitrogen, about 79% of the Earth’s atmosphere, yet it is unusable by most living organisms due to its inertness. There are two ways to fix this inert dinitrogen to usable ammonia. One is the industrial Haber-Bosch process, which needs to be conducted at high temperature and pressure. This process uses a lot of the non-renewable fossil fuel as the energy source. The other major pathway is the biological nitrogen fixation carried out by …

Quantum Dot Enhanced Epitaxial Lift-Off Solar Cells, Mitchell F. Bennett

Theses

Embedded nanostructures such as quantum dots (QDs) have been studied for many applications in solar cells including enhanced mini-band absorption in intermediate-band solar cells and current matching in multi junction cells. The major drawbacks of using such techniques to decrease intrinsic solar cell loss mechanisms are twofold: first, it is difficult to maintain partially populated states using QDs due to a quick thermal extraction of carriers; second, QDs have a weak absorption which necessitates a near-perfect control of QD growth mechanisms to carefully ensure a balance between dot size and density. One avenue for improving absorption into QDs is to …

Manufacture And Investigation Of Organic Composite Polymer Based Films For Advanced Flexible Solar Cells, Raffie Arshak

Masters

Modern society has created big challenges in the area of sustainable supply of energy to satisfy the needs of growing population and to account for depleting fossil fuel resources. The Irish Government has set targets for the energy sector by 2020, with 33% of electricity to be generated from renewable sources. Organic photovoltaic devices offer several advantages over expensive silicon solar cells, including deposition of ultra-thin films by spin-coating, printing and spray-coating. This in turn provides for the exciting possibility to make lightweight, flexible solar cells for a broad range of existing and emerging applications for security, military and medicine. …

Determining The Feasibility Of Implementing An Effective Fungiculture Program With The Peace Garden At Illinois Wesleyan University, Mackenzie Rivkin '14

Outstanding Senior Seminar Papers

The Peace Garden at Illinois Wesleyan University (IWU), the organic garden at the small liberal-arts university in Bloomington, Illinois, is devoted to growing nutritious, pesticide-free food to be sold locally in an attempt to counterbalance the various food-related issues which stem from conventional food systems. Mushrooms, fungi with many nutritional benefits, are not currently produced by the Peace Garden. However, the unique nature of mushrooms may be attractive to certain consumers and could further contribute to the Peace Garden's mission if produced. This study, conducted September to December 2013 is guided by the following question: What is the feasibility of …

Multiple Solutions Of A P(X)-Laplacian Equation Involving Critical Nonlinearities, Yuan Liang, Xianbin Wu, Qihu Zhang, Chunshan Zhao

Mathematical Sciences: Faculty Publications

In this paper, we consider the existence of multiple solutions for the following p(x)-Laplacian equations with critical Sobolev growth conditions

−div(|∇u| p(x)−2 ∇u) + |u| ^p(x)−2 u = f(x, u) in Ω,

u = 0 on ∂Ω.

We show the existence of infinitely many pairs of solutions by applying the Fountain Theorem and the Dual Fountain Theorem respectively. We also present a variant of the concentration-compactness principle, which is of independent interest.

Synergy Of The Developed 6d Bim Framework And Conception Of The Nd Bim Framework And Nd Bim Process Ontology, Shawn Edward O'Keeffe

Dissertations

The author developed a unified nD framework and process ontology for Building Information Modeling (BIM). The research includes a framework developed for 6D BIM, nD BIM, and nD ontology that defines the domain and sub-domain constructs for future nD BIM dimensions. The nD ontology defines the relationships of kinds within any new proposed dimensional domain for BIM. The developed nD BIM framework and ontology takes into account the current 2D-5D BIM dimensions. There is a synergy between the 6D and nD framework that allows the nD framework and ontology to be utilized as a unified template for future dimensional development. …

Gene Regulatory Network Analysis And Web-Based Application Development, Yi Yang

Dissertations

Microarray data is a valuable source for gene regulatory network analysis. Using earthworm microarray data analysis as an example, this dissertation demonstrates that a bioinformatics-guided reverse engineering approach can be applied to analyze time-series data to uncover the underlying molecular mechanism. My network reconstruction results reinforce previous findings that certain neurotransmitter pathways are the target of two chemicals - carbaryl and RDX. This study also concludes that perturbations to these pathways by sublethal concentrations of these two chemicals were temporary, and earthworms were capable of fully recovering. Moreover, differential networks (DNs) analysis indicates that many pathways other than those related …