Physical Sciences and Mathematics Commons^™

Kinetic Studies Of The Sulfoxidation Of Aryl Methyl Sulfides By Trans-Dioxoruthenium(Vi) Porphyrin Complexes, Chris Abebrese

Masters Theses & Specialist Projects

The development of an efficient, catalytically active, biomimetic model for cytochrome P-450 enzymes has been an area of intense research activity. Ruthenium porphyrin complexes have been the center of this research and have successfully been utilized, as catalysts, in major oxidation reactions such as the hydroxylation of alkanes, the epoxidation of alkenes and aromatic rings, and the N-oxidation of amines, among others. In this project, the kinetics of two-electron sulfoxidation of para-substituted phenyl methyl sulfides to the corresponding sulfoxides with well-characterized trans-dioxoruthenium(VI) porphyrin complexes were studied by rapid stopped-flow spectroscopy. The substituent effect in sulfides and in dioxoruthenium(VI) complexes were …

Mining Data From Multiple Software Development Projects, Huanjing Wang, Taghi M. Khoshgoftaar, Kehan Gao, Naeem Seliya

Computer Science Faculty Publications

A large system often goes through multiple software project development cycles, in part due to changes in operation and development environments. For example, rapid turnover of the development team between releases can influence software quality, making it important to mine software project data over multiple system releases when building defect predictors. Data collection of software attributes are often conducted independent of the quality improvement goals, leading to the availability of a large number of attributes for analysis. Given the problems associated with variations in development process, data collection, and quality goals from one release to another emphasizes the importance of …

Thermocapillary Effects In Driven Dewetting And Self-Assembly Of Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner

Mathematics Faculty Publications

A mathematical model for the evolution of pulsed laser-irradiated, molten metallic films has been developed using the lubrication theory. The heat transfer problem that incorporates the absorbed heat from a single laser beam or the interfering laser beams is solved analytically. Using this temperature field, we derive the 3D long-wave evolution PDE for the film height. To get insights into dynamics of dewetting, we study the 2D version of the evolution equation by means of a linear stability analysis and by numerical simulations. The stabilizing and destabilizing effects of various system parameters, such as the reflectivity, the peak laser beam …

Ua12/13 Wku Campus Wide Holiday Energy Conservation Plan, Wku Sustainability Committee, Christian Ryan-Downing

Sustainability Publications and Resources

No abstract provided.

From The Bronx Into The Wild! My Adventurous Experience At The Bronx Zoo, Lauren Noll

Student Theses 2001-2013

Many people defend zoos, claiming that they provide great opportunities in education, scientific research, and the overall preservation of wildlife worldwide. However, many people will take the opposing side, arguing that it is wrong to deprive animals of their natural habitats and lifestyles. One of the greatest controversies of our time pertains to the moral issues associated with keeping animals in captivity, such as in zoos and aquariums.

Social Behaviors Of Modern And Indigenous Peoples Impacting The Ecology Of The Amazon Rain Forest In Brazil, Josef W. Schaffer

Earth and Soil Sciences

Human induced disruption of the environment is prevalent in every culture. In Brazil, the effects of massive deforestation have become apparent since the nineteen eighties. However, along with deforestation, and a coinciding loss in an economic resource for the country, is a significant loss of natural habitat and species extinction. The Amazon in Brazil contains a large proportion of the world’s species diversity that is threatened by the socio-economic activities of modern Brazilian culture. Historically and presently, indigenous groups have contributed to insignificant levels of ecological disruption and are themselves threatened by the activities of modern Brazilians. The effects of …

Fisheries Research Report No. 197 - Coastal And Marine Resource Condition Monitoring - Scoping Project, Brett A. Human, Justin I. Mcdonald

Fisheries Research Reports

Final NRM Report – Project 073007

Part 1– Knowledge review and gap analysis: Resource condition monitoring in the Pilbara and Kimberley regions of Western Australia

This report details extensive literature searches for both research and monitoring programs that have been undertaken in the marine and coastal environments of the Pilbara and Kimberley region of northern Western Australia. The Pilbara and Kimberley region is remote and difficult to access, resulting in very little monitoring effort of the marine and coastal environments in that region.

We currently know very little of the condition of marine and coastal natural resources in the Pilbara …

Pair Creation Rates For One-Dimensional Fermionic And Bosonic Vacua, T Cheng, M R. Ware, Q Su, Rainer Grobe

Faculty publications – Physics

We compare the creation rates for particle-antiparticle pairs produced by a supercritical force field for fermionic and bosonic model systems. The rates obtained from the Dirac and Klein-Gordon equations can be computed directly from the quantum-mechanical transmission coefficients describing the scattering of an incoming particle with the supercritical potential barrier. We provide a unified framework that shows that the bosonic rates can exceed the fermionic ones, as one could expect from the Pauli-exclusion principle for the fermion system. This imbalance for small but supercritical forces is associated with the occurrence of negative bosonic transmission coefficients of arbitrary size for the …

Sparql Query Re-Writing For Spatial Datasets Using Partonomy Based Transformation Rules, Prateek Jain, Cory Andrew Henson, Amit P. Sheth, Peter Z. Yeh, Kunal Verma

Kno.e.sis Publications

Often the information present in a spatial knowledge base is represented at a different level of granularity and abstraction than the query constraints. For querying ontology’s containing spatial information, the precise relationships between spatial entities has to be specified in the basic graph pattern of SPARQL query which can result in long and complex queries. We present a novel approach to help users intuitively write SPARQL queries to query spatial data, rather than relying on knowledge of the ontology structure. Our framework re-writes queries, using transformation rules to exploit part-whole relations between geographical entities to address the mismatches between query …

A Local Qualitative Approach To Referral And Functional Trust, Krishnaprasad Thirunarayan, Dharan Althuru, Cory Andrew Henson, Amit P. Sheth

Kno.e.sis Publications

Trust and confidence are becoming key issues in diverse applications such as ecommerce, social networks, semantic sensor web, semantic web information retrieval systems, etc. Both humans and machines use some form of trust to make informed and reliable decisions before acting. In this work, we briefly review existing work on trust networks, pointing out some of its drawbacks. We then propose a local framework to explore two different kinds of trust among agents called referral trust and functional trust, that are modelled using local partial orders, to enable qualitative trust personalization. The proposed approach formalizes reasoning with trust, distinguishing between …

Thermocapillary Effects In Driven Dewetting And Self-Assembly Of Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner

Mathematics Faculty Publications

A mathematical model for the evolution of pulsed laser-irradiated, molten metallic films has been developed using the lubrication theory. The heat transfer problem that incorporates the absorbed heat from a single laser beam or the interfering laser beams is solved analytically. Using this temperature field, we derive the 3D long-wave evolution PDE for the film height. To get insights into dynamics of dewetting, we study the 2D version of the evolution equation by means of a linear stability analysis and by numerical simulations. The stabilizing and destabilizing effects of various system parameters, such as the reflectivity, the peak laser beam …

Off-Metal Synthesis Of Some Aryl Substituted Rhenium N5-Cyclopenta [C] Pyridazyl Complexes, James Leif Neathery

Masters Theses & Specialist Projects

Heterocyclic organic and organometallic compounds (e.g. polypyrrole), and their derivatives, have been of great interest for conductive polymers due to their novel properties and environmental stability as compared to non-aromatic analogs (e.g. polyacetylene). Our current interests focus upon the potential role of pyridazines in next generation electronic devices that utilize organics as the semiconducting material. Pyridazines, 6-membered aromatic rings with two adjacent nitrogens, are promising candidates for a variety of materials and commercial applications. These molecular electronic materials posses several advantages over traditional inorganic semiconducting materials including lower cost of production, higher processibility, and the ability to function on flexible …

Chemistry Of Zirconia And Its Bioanalytical Applications, Oge Anazia

Masters Theses & Specialist Projects

This research studies the chemical nature of zirconia and the complex surface chemistry of zirconia in order to better comprehend its behavior under chromatographic conditions. This research shows how the physical and chemical properties of zirconia depend strongly on the thermal treatment during synthesis. The morphology of the samples was also studied. The absorption capability of Adenosine Triphosphate (ATP) on zirconia was also monitored and spectrally characterized.

The results of this research showed how the properties of zirconia vary with thermal treatment. It was observed that the zirconia prepared at a higher temperature had lower surface area, lower pore size …

Analysis Of Mammoth Cave Pre-Park Communities, Matthew Brunt

Masters Theses & Specialist Projects

Before the creation of Mammoth Cave National Park, this area was home to numerous communities, each with a sense of identity. To prepare for the creation of the National Park, all residents living within these communities were relocated, and many of these communities were lost to the passage of time. Today, public memory of these lost communities is being fostered by the descendents of the pre-park area.

Through the use of a Historical Geographic Information System, 1920 Edmonson County manuscript census data, and statistical analysis, the demographic composition of these lost communities was explored. This project not only brought to …

Heirloom And Hybrid Tomato Yield And Quality In Organic And Conventional Production Systems, Diana J. Edlin

Masters Theses & Specialist Projects

Due to the recent changes in the economy of Kentucky tobacco production, some producers are seeking an alternative crop that will provide similar economic gains to tobacco without needing more acreage. Tomatoes are an existing crop in Kentucky that have been declining in acreage over the last five years. There is evidence to suggest that, through niche and local marketing, tomatoes may be able to fill the void left by tobacco. However, there is concern among producers that they will lose yield and/or quality if they switch to one of these niche production systems or cultivars.

A two year study …

"All The Crises Reached A Concerted Crescendo" - The Arab Oil Embargo And Why The United States Was Unprepared For It, Jonathan D. Chilcote

Masters Theses & Specialist Projects

During the 2008 spike in oil prices, oil companies and government officials were brought under close scrutiny as many Americans began to question why prices were able to rise so quickly. Americans had become accustomed to living in an economy where cheap oil was the norm, and demanded answers when that situation changed. What most of them did not know is that they were repeating history and mimicking the response to the 1973 oil embargo. Just as in 2008, the United States faced a crisis in 1973 with which it was unprepared to effectively cope. This thesis analyzes the reasons …

Proposed Framework For Understanding Information Security Culture And Practices In The Saudi Context, Mohammed Alnatheer, Karen Nelson

Australian Information Security Management Conference

An examination of Information Security (IS) and Information Security Management (ISM) research in Saudi Arabia has shown the need for more rigorous studies focusing on the implementation and adoption processes involved with IS culture and practices. Overall, there is a lack of academic and professional literature about ISM and more specifically IS culture in Saudi Arabia. Therefore, the overall aim of this paper is to identify issues and factors that assist the implementation and the adoption of IS culture and practices within the Saudi environment. The goal of this paper is to identify the important conditions for creating an information …

Review Of The Evidence Used In The Description Of Currently Recognized Cetacean Subspecies, William F. Perrin, James G. Mead, Robert L. Brownell Jr.

United States Department of Commerce: Staff Publications

We reviewed the subspecies listed by Rice (1998) and those described since (a total of 49, in 19 species), assessing them against the criteria recommended by the recent Workshop on Shortcomings of Cetacean Taxonomy in Relation to Needs of Conservation and Management (Reeves et al., 2004). The workshop suggested that the subspecies concept can be construed to cover two types of entities: a) lineages diverging but not quite far along the continuum of divergence (still having significant gene flow with another lineage or lineages) to be judged as species, and b) lineages that may well be species but for which …

Department Of Chemistry News For Alumni And Friends, December 2009, Illinois State University, Department Of Chemistry

Chem Letter

Newsletter of the Illinois State University Department of Chemistry

Water Resources Year In Review - Winter 2009 Vol 21. No 2, Annis Water Resources Institute

AWRI Reviews

No abstract provided.

Geometry Of Control-Affine Systems, Jeanne N. Clelland, Christopher G. Moseley, George R. Wilkens

University Faculty Publications and Creative Works

Motivated by control-affine systems in optimal control theory, we introduce the notion of a point-affine distribution on a manifold X - i.e., an affine distribution F together with a distinguished vector field contained in F. We compute local invariants for point-affine distributions of constant type when dim(X) = n, rank(F) = n - 1, and when dim(X) = 3, rank(F) = 1. Unlike linear distributions, which are characterized by integer- valued invariants - namely, the rank and growth vector - when dim(X) ≤ 4, we find local invariants depending on arbitrary functions even for rank 1 point-affine distributions on manifolds …

Observations Of Very High Energy Gamma-Ray Emission From Supernova Remnants With Veritas, Mark Theiling

All Dissertations

The nature and source of cosmic rays has been at the core of particle astrophysics since their discovery almost a century ago. The cosmic ray spectrum is best described by a broken power law, and can be better understood as three distinct parts. Theory holds that cosmic rays up to ∼1015 eV – those below the “knee” or steepening in the spectrum – are produced in the shocks of supernova remnants. Direct detection of cosmic rays produced in supernova remnant shocks is impossible, however, as cosmic rays below ∼1018 eV are deflected by the Galactic magnetic field and cannot be …

A Cognitive Model For Problem Solving In Computer Science, Jennifer Parham

All Dissertations

According to industry representatives, computer science education needs to emphasize the processes involved in solving computing problems rather than their solutions. Most of the current assessment tools used by universities and computer science departments analyze student answers to problems rather than investigating the processes involved in solving them. Approaching assessment from this perspective would reveal potential errors leading to incorrect solutions.
This dissertation proposes a model describing how people solve computational problems by storing, retrieving, and manipulating information and knowledge. It describes how metacognition interacts with schemata representing conceptual and procedural knowledge, as well as with the external sources of …

Synthesis And Development Of Novel Fullerene-Based Structures For Photovoltaics, Electronic Applications And Mri Contrast Agents, Manuel Chaur

All Dissertations

Metallic nitride endohedral metallofullerenes (EMFs) are one of the most interesting types of metallofullerenes due to their high yields and interesting electronic properties. The synthesis of these compounds allows the encapsulation of different metals inside fullerenes making it possible to combine the properties of the metal with those of the fullerene. Their interesting electrochemical and optical features make them potential candidates for several applications such as molecular electronics, biomedical imaging, non-linear optical devices, and magnetic resonance imaging (MRI) agents. This thesis reports the synthesis of novel metallic nitride EMFs based on Gd, Nd, Pr, Ce and La. These families of …

Functional Characterization Of Calcium Dependent Protein Kinase 32 From Arabidopsis, Rucha Karve

All Dissertations

Calcium-dependent protein kinases (CPKs) are major plant Ca2+ sensors, many of which have roles in plant stress responses. The Arabidopsis genome encodes 34 CPK isoforms. Here we report characterization of AtCPK32 gene function. Analysis of transgenic plants expressing pCPK32-GUS shows that CPK32 is highly expressed in roots, pollen and embryo, as well as leaf hydathodes, and the abscission zone of mature siliques. Real time RT-PCR and promoter expression patterns show that CPK32 is responsive to abiotic and biotic stresses. Plants treated with salt, ABA, osmotic stress (PEG), wounding, and flagellin 22 peptide show up-regulation of CPK32 upon these stress treatments. …

An Evaluation Of Potential Technologies For A Web Based Development Environment For Cs1 Students, Manuel Garcia

Computer Science and Software Engineering

The goal of this senior project was to design a web-based integrated development environment that would incorporate Web-CAT. Web-CAT is an automated testing tool designed by Stephen Edwards at Virginia Tech University, to help beginning students learn test-driven development. This tool runs on a server where a professor assigns usernames and passwords to students so they can submit code. This program can assist professors in grading, and students in showing errors in code. The development environment design waskept simple to create less confusion for beginning programming students. This development environment will be online to give all students universal access and …

Exercise Power Grid Display And Web Interface, Alexander (Alex) Chernetz

Computer Engineering

The 2008-2009 expansion of the Recreation Center at Cal Poly includes three new rooms with cardiovascular fitness equipment. As part of its ongoing commitment to sustainable development, the new machines connect to the main power grid and generate power during a workout. This document explains the process of quantifying and expressing the power generated using two interfaces: an autonomous display designed for a television with a text size and amount of detail adaptable to multiple television sizes and viewing distances, and an interactive, more detailed Web interface accessible with any Java-capable computer system or browser.

Towards Reasoning Pragmatics, Pascal Hitzler

Computer Science and Engineering Faculty Publications

The realization of Semantic Web reasoning is central to substantiating the Semantic Web vision. However, current mainstream research on this topic faces serious challenges, which force us to question established lines of research and to rethink the underlying approaches.

Spatial Distribution Of Petroleum Hydrocarbons In Sediment Cores From Blind Pass, St. Pete Beach, Florida, Charles M. Featherstone, John Proni, Thomas P. Carsey, Cheryl J. Brown, Madeleine M. Adler, Patricia Blackwelder, Husain Alsayegh, Teresa A. Hood, Christina Piela, Donald S. Mccorquodale Jr.

Marine & Environmental Sciences Faculty Reports

One hundred and one sediment cores were collected to characterize the spatial distribution of petroleum hydrocarbons within and just outside Blind Pass, St. Pete Beach, Florida. Twenty-five percent of the cores exhibited levels of petroleum hydrocarbons above detection limits of the gas chromatograph/flame ionization detector (GC/FID) (0.01 mg/Kg), but at generally low concentrations. Petroleum hydrocarbon speciation studies of these samples (gas chromatography/mass spectroscopy [GC/MS]) indicate above-detection level (1 μg/Kg) petroleum hydrocarbons are similar to the non-volatile petroleum hydrocarbons found in a Bouchard 155 reference sample collected after the 1993 oil spill in the area, but are in a much degraded …

Extraction And Analysis Of Coral Reef Core Samples From Broward County, Florida., Anastasios Stathakopoulos

HCNSO Student Theses and Dissertations

The reefs off Broward County exist as three shore-parallel, sequentially deeper terraces named the "inner", "middle", and "outer" reefs and also a shallower, nearshore ridge complex. These structures span the continental coast of southeast Florida from Palm Beach County to southern Miami-Dade County and were characterized as relict, early Holocene shelf-edge and mid-shelf reefs along with limestone ridges. Presently, the reefs are colonized by a fauna characteristic of West Atlantic/Caribbean reef systems. Scleractinian coral cover is low except for a few dense patches of Acropora cervicornis, while Acropora palmata is absent except for a few individual living colonies.

Coral …