Physical Sciences and Mathematics Commons^™

Patterning-Induced Surface Chirality And Modulation Of Director Twist In A Nematic Cell, Yoonseuk Choi, Timothy J. Atherton, Sameh Ferjani, Rolfe G. Petschek, Charles Rosenblatt

Faculty Scholarship

A substrate coated with a polyimide alignment layer is scribed bidirectionally with the stylus of an atomic force microscope to create an easy axis for liquid-crystal orientation. The resulting noncentrosymmetric topography breaks two-dimensional inversion symmetry and results in a spatial amplitude modulation of an imposed twisted nematic state. This is observed optically as spatially periodic light and dark stripes. When the alignment layer is scribed unidirectionally the centrosymmetric topography maintains inversion symmetry, and no stripes are observed. The appearance of the twist modulation is consistent with a chiral term in the free energy.

An Adaptive Bayesian Approach To Dose-Response Modeling, Thomas J. Leininger

Theses and Dissertations

Clinical drug trials are costly and time-consuming. Bayesian methods alleviate the inefficiencies in the testing process while providing user-friendly probabilistic inference and predictions from the sampled posterior distributions, saving resources, time, and money. We propose a dynamic linear model to estimate the mean response at each dose level, borrowing strength across dose levels. Our model permits nonmonotonicity of the dose-response relationship, facilitating precise modeling of a wider array of dose-response relationships (including the possibility of toxicity). In addition, we incorporate an adaptive approach to the design of the clinical trial, which allows for interim decisions and assignment to doses based …

Biological Sequence Simulation For Testing Complex Evolutionary Hypotheses: Indel-Seq-Gen Version 2.0, Cory L. Strope

School of Computing: Dissertations, Theses, and Student Research

Reconstructing the evolutionary history of biological sequences will provide a better understanding of mechanisms of sequence divergence and functional evolution. Long-term sequence evolution includes not only substitutions of residues but also more dynamic changes such as insertion, deletion, and long-range rearrangements. Such dynamic changes make reconstructing sequence evolution history difficult and affect the accuracy of molecular evolutionary methods, such as multiple sequence alignments (MSAs) and phylogenetic methods. In order to test the accuracy of these methods, benchmark datasets are required. However, currently available benchmark datasets have limitations in their sizes and evolutionary histories of the included sequences are unknown. These …

A New Process For Organizing Assessments Of Social, Economic, And Environmental Outcomes: Case Study Of Wildland Fire Management In The Usa, Randall Jf Bruins, Wayne R. Munns Jr., Stephen J. Botti, Steve Brink, David Cleland, Larry Kapustka, Danny Lee, Valerie Luzadis, Laura Falk Mccarthy, Naureen Rana, Douglas B. Rideout, Matt Rollins, Peter Woodbury, Mike Zupko

United States Environmental Protection Agency: Publications

Ecological risk assessments typically are organized using the processes of planning (a discussion among managers, stakeholders, and analysts to clarify ecosystem management goals and assessment scope) and problem formulation (evaluation of existing information to generate hypotheses about adverse ecological effects, select assessment endpoints, and develop an analysis plan). These processes require modification to be applicable for integrated assessments that evaluate ecosystem management alternatives in terms of their ecological, economic, and social consequences.We present 8 questions that define the steps of a new process we term integrated problem formulation (IPF), and we illustrate the use of IPF through a retrospective case …

Interview With Jim Quinn, Metro's Hazardous Waste Program, 2009 (Audio), Jim Quinn

All Sustainability History Project Oral Histories

Interview of Jim Quinn by Sean Quigley at Metro in Portland, Oregon on December 2nd, 2009.

The interview index is available for download.

Isolation And X-Ray Structural Characterization Of A Dicationic Homotrimer Of 2,3,6,7-Tetramethoxy-9,10-Dimethylanthracene Cation Radical, Matthew J. Modjewski, Ruchi Shukla, Sergey V. Lindeman, Rajendra Rathore

Chemistry Faculty Research and Publications

Electrochemical oxidation of 2,3,6,7-tetramethoxy-9,10-dimethylanthracene (1) showed that it undergoes a highly reversible electrochemical oxidation (E_ox = 0.81 V vs SCE) and forms a modestly stable cation-radical salt in solution. X-ray crystallography established that 1⁺SbCl₆^- crystallizes as a (centrosymmetric) dicationic homotrimer via a close cofacial association of a pair of cationic and one neutral molecule of 1 with an interplanar separation of ∼3.2 Å. The structure of the dicationic homotrimer was also reproduced by DFT calculations. Furthermore, the structure of a dicationic spiro adduct, formed by a slow decomposition of a solution of 1^{+ …}

College Of Engineering Senior Design Competition Fall 2009, University Of Nevada, Las Vegas

Fred and Harriet Cox Senior Design Competition Projects

Each student in his or her senior year chooses, plans, designs, and prototypes a product in this required element of the curriculum. The senior design project encourages the student to use everything learned in the engineering program to create a practical, real-world solution to an engineering challenge.

A highlight of the year-long senior design project is the senior design competition. This competition, which usually takes place the week before finals each semester, helps focus the senior students on increasing the quality and potential for commercial application for their design projects.

Judges from local industry evaluate the projects on innovation, commercial …

Warning Based Browser Extension To Protect User Data Against Phishing Attacks, Sree Rama Konduri

Theses and Dissertations

There are currently many anti-phishing tools to combat against the phishing and web scams. Many of which are browser extensions that warn users when they are using suspected phishing websites. But most of the users are ignoring the warnings of the phishing site and providing their valuable credentials. Therefore, the focus of this research is to develop a browser extension, which manipulates the user credentials, whenever a user ignores anti-phishing tools warnings about malicious websites. This browser extension will protect user's information from being handed to attackers.

Creation Of Soil Liquefaction Susceptibility Maps For San Luis Obispo & Marin Counties Using Geographic Information Systems., Amelia M. Lowman

Earth and Soil Sciences

Liquefaction of soils in response to earthquake shaking is a pressing issue in the state of California. Using Geographic Information Systems, Geological and lithology layers, along with criteria in order to separate out the data into four risk categories, a liquefaction risk assessment map was created for San Luis Obispo and Marin Counties. The accuracy of these maps was then assessed using liquefaction occurrences for San Luis Obispo County, and it was determined that while the map is somewhat accurate, in order to obtain a greater amount of accuracy and increase the usefulness of these maps, more data would need …

Development Of Regional Hydraulic Geometry Curves For The Santa Cruz Mountains, Sarah Howell

Natural Resources Management and Environmental Sciences

This study was conducted to develop regional hydraulic geometry curves for the Santa Cruz Mountains that could be used in stream related and/or engineering projects. Data used to form these curves was collected from the USGS and by conducting stream geometry surveys. The resulting regional curves had high R² values ranging from .82 to .92. Compared to other regional curves in nearby areas, the Santa Cruz Mountains regional curve equations have higher exponents, meaning bankfull channel measurements increase at faster rates as drainage areas increases. Further measurements and analysis should be done before applying these curves to project sites.

2,5-Dichlorothiophene 1,1-Dioxide, Jonathan B. Briggs, Wenling Jia, Mikael D. Jazdzyk, Glen P. Miller

Chemistry

The complete molecule of the title compound, C(4)H(2)Cl(2)O(2)S, is generated by crystallographic twofold symmetry, with the S atom lying on the rotation axis. In the crystal, the molecules are linked by C-H center dot center dot center dot O hydrogen bonds..

Distribution And Diversity Of Archaeal And Bacterial Ammonia Oxidizers In Salt Marsh Sediments, Nicole S. Moin, Katelyn A. Nelson, Alexander Bush, Anne E. Bernhard

Biology Faculty Publications

Diversity and abundance of ammonia-oxidizing Betaproteobacteria (β-AOB) and archaea (AOA) were investigated in a New England salt marsh at sites dominated by short or tall Spartina alterniflora (SAS and SAT sites, respectively) or Spartina patens (SP site). AOA amoA gene richness was higher than β-AOB amoA richness at SAT and SP, but AOA and β-AOB richness were similar at SAS. β-AOB amoA clone libraries were composed exclusively of Nitrosospira-like amoA genes. AOA amoA genes at SAT and SP were equally distributed between the water column/sediment and soil/sediment clades, while AOA amoA sequences at SAS were primarily affiliated with the …

Partially Coherent Standard And Elegant Laguerre-Gaussian Beams Of All Orders, Fei Wang, Yangjian Cai, Olga Korotkova

Physics Articles and Papers

Partially coherent standard and elegant Laguerre-Gaussian (LG) beams of all orders are introduced as a natural extension of coherent standard and elegant LG beams to the stochastic domain. By expanding the LG modes into a finite sum of Hermite-Gaussian modes, the analytical formulae are obtained for the cross-spectral densities of partially coherent standard and elegant LG beams in the source plane and after passing through paraxial ABCD optical system, based on the generalized Collins integral formula. A comparative study of the propagation properties of the partially coherent standard and elegant LG beams in free space is carried out via a …

Sfa Weather Station-December 2009, Arthur Temple College Of Forestry And Agriculture, Stephen F. Austin State University

Weather Station Data

No abstract provided.

On Neutral Absorption And Spectral Evolution In X-Ray Binaries, J. M. Miller, E. M. Cackett, R. C. Reis

Physics and Astronomy Faculty Research Publications

Current X-ray observatories make it possible to follow the evolution of transient and variable X-ray binaries across a broad range in luminosity and source behavior. In such studies, it can be unclear whether evolution in the low-energy portion of the spectrum should be attributed to evolution in the source, or instead to evolution in neutral photoelectric absorption. Dispersive spectrometers make it possible to address this problem. We have analyzed a small but diverse set of X-ray binaries observed with the Chandra High Energy Transmission Grating Spectrometer across a range in luminosity and different spectral states. The column density in individual …

Well-Posedness Of Minimal Time Problem With Constant Dynamics In Banach Spaces, Giovanni Colombo, Vladimir V. Goncharov, Boris S. Mordukhovich

Mathematics Research Reports

This paper concerns the study of a general minimal time problem with a convex constant dynamic and a closed target set in Banach spaces. We pay the main attention to deriving efficient conditions for the major well-posedness properties that include the existence and uniqueness of optimal solutions as well as certain regularity of the optimal value function with respect to state variables. Most of the results obtained are new even in finite-dimensional spaces. Our approach is based on advanced tools of variational analysis and generalized differentiation.

Synthesis And Cytotoxic Analysis Of Some Disodium 3Β,6Β-Dihydroxysterol Disulfates, Jianguo Cui, Hui Wang, Yi Xin, Aimin Zhou

Chemistry Faculty Publications

Disodium 3β,6β-dihydroxy-5α-cholestane disulfate (1) was synthesized in 4 steps with a high overall yield from cholesterol. First, cholesterol (4a) was converted to cholest-4-en-3,6-dione (5a) via oxidation with pyridinium chlorochromate (PCC) and then 5a was reduced by NaBH4 in the presence of NiCl2 to produce cholest-3β,6β-diol (6a). The reaction of 6a with the triethylamine-sulfur trioxide complex generated diammonium 3β,6β-dihydroxy-5α-cholestane disulfate (7a) and the treatment of 7a by cation exchange resin 732 (sodium form)(Na+) yielded the target steroid 1. Disodium 24-ethyl-3β,6β-dihydroxycholest-22-ene disulfate (2) and disodium 24-ethyl-3β,6β-dihydroxycholestane disulfate (3) were synthesized using a similar method. The cytotoxicity of these compounds against Sk-Hep-1 (human …

Water Resources Year In Review - Winter 2009 Vol 21. No 2, Annis Water Resources Institute

AWRI Reviews

No abstract provided.

Are Periodic Solar Wind Number Density Structures Formed In The Solar Corona?, N. M. Viall, Harlan E. Spence, J. Kasper

Physics & Astronomy

[1] We present an analysis of the alpha to proton solar wind abundance ratio (AHe) during a period characterized by significant large size scale density fluctuations, focusing on an event in which the proton and alpha enhancements are anti-correlated. In a recent study using 11 years (1995–2005) of solar wind observations from the Wind spacecraft, N. M. Viall et al. [2008] showed that periodic proton density structures occurred at particular radial length-scales more often than others. The source of these periodic density structures is a significant and outstanding question. Are they generated in the interplanetary medium, or are they a …

Approximating Stationary Statistical Properties, Xiaoming Wang

Mathematics and Statistics Faculty Research & Creative Works

It is well-known that physical laws for large chaotic dynamical systems are revealed statistically. Many times these statistical properties of the system must be approximated numerically. the main contribution of this manuscript is to provide simple and natural criterions on numerical methods (temporal and spatial discretization) that are able to capture the stationary statistical properties of the underlying dissipative chaotic dynamical systems asymptotically. the result on temporal approximation is a recent finding of the author, and the result on spatial approximation is a new one. Applications to the infinite Prandtl number model for convection and the barotropic quasi-geostrophic model are …

Event Coverage In Sparse Mobile Sensor Networks, Mark Snyder, Sriram Chellappan

Computer Science Faculty Research & Creative Works

Autonomous mobile sensors are employed with ever-increasing frequency, in applications ranging from search and rescue, detection of forest fires, and battlefield surveillance. in this paper, we consider a representative surveillance problem wherein a sparse number of mobile sensors are expected to cover events of interest in a deployment field. Each event appears for a certain time and then disappears. Furthermore, the location of each event and its duration is unknown. in this paper, we design a sensor movement strategy based on efficient traversal in the network to fulfill two objectives: maximizing event detection and minimizing detection delay. Analysis and simulations …

What Does Security Culture Look Like For Small Organizations?, Patricia A. Williams

Australian Information Security Management Conference

The human component is a significant factor in information security, with a large numbers of breaches occurring due to unintentional user error. Technical solutions can only protect information so far and thus the human aspect of security has become a major focus for discussion. Therefore, it is important for organisations to create a security conscious culture. However, currently there is no established representation of security culture from which to assess how it can be manoeuvred to improve the overall information security of an organization. This is of particular importance for small organizations who lack the resources in information security and …

Modeling Of Metal-Ferroelectric-Insulator-Semiconductor Structures Based On Langmuir–Blodgett Copolymer Films, Timothy J. Reece, Stephen Ducharme

Stephen Ducharme Publications

Among the ferroelectric thin films used in field-effect transistor devices; the ferroelectric copolymer of polyvinylidene fluoride PVDF –CH2–CF2–, with trifluoroethylene TrFE –CHF–CF2–, has distinct advantages, including low dielectric constant, low processing temperature, low cost, and compatibility with organic semiconductors. The operation of a metal-ferroelectric insulatorsemiconductor structure with PVDF-TrFE as the ferroelectric layer was analyzed and optimized by numerical solution of the Miller and McWhorter model. A model device consisting of 20 nm PVDF/TrFE on a 10-nm-thick high-k dielectric buffer exhibits a memory window of 5 V with an operating voltage of 15 V. The operating voltage can be reduced to …

Mortality Of Cranes (Gruidae) Associated With Powerlines Over A Major Roost On The Platte River, Nebraska, Gregory D. Wright, Timothy J. Smith, Robert K. Murphy, Jeffery T. Runge, Robert R. Harms

The Prairie Naturalist

Two 69-kilovolt powerlines spanning the Platte River in south central Nebraska are suspected to cause substantial mortality to sandhill cranes (Grus canadensis) and pose a threat to endangered whooping cranes (G. americana) that roost overnight on the river during spring and fall migrations. Most studies of crane collisions with powerlines in the region have focused on counts of carcasses away from night roosts on the river and none have accounted for potential biases in detecting carcasses. We found 61 carcasses of sandhill cranes below over-river segments of the two powerlines during 4 March to 7 April …

Investigation Of Novel Thiol "Click" Reactions, Justin William Chan

Dissertations

The thio-Michael addition reaction is traditionally considered a base catalyzed reaction which involves high catalyst concentrations and long reaction times. This reaction utilizes potent, simple nucleophiles to catalyze the reaction, decreases the catalyst concentration and greatly increases the reaction times. The free radical mediated thiol-ene click reaction uses light or heat and an initiator to catalyze the rapid and quantitative addition of thiols to most electron rich enes without the formation of side products and in the absence of solvent. Recently, the thiol-ene click reaction has been exploited for these reasons in materials science and organic synthesis. The research herein …

Investigation Of The Relationship Between Polymer Structures And Thermal, Mechanical, Viscoelastic Properties, Ethem Kaya

Dissertations

The research presented in this dissertation involves four distinct areas: physical crosslinking systems, UV curable coatings for enhanced oxygen and carbon dioxide barrier properties, synthesis, and investigation of melting behavior/crystallinity relations of linear polyamides with long alkyl chains, and synthesis and characterization of cyclic diamides as precursors to linear polyamides 6 4.

The physical crosslinking section involves synthesis of monomers and polymers bearing cyclodextrin and adamantane pendent groups, and investigation of non-covalent interactions between these polymers (Chapter II). Two methacrylate monomers bearing cyclodextrin and adamantane were synthesized, and copolymerized with poly(ethylene glycol) methyl ether methacrylate. The specific interaction between copolymers …

Random And Block Copolymers Of Poly(Dodecamethyleneterephthalamide), Theodore Frank Novitsky Jr.

Dissertations

The following dissertation focuses on the synthesis and characterization of poly(dodecamethylene terephthalamide) (PA-12,T) and novel copolymers. Chapter I details the synthesis of PA-12,T homopolymer by melt condensation polymerization. A series of homopolymers with different molecular weights were obtained by adjusting the stoichiometry of the polymerization using 1,12-diaminododecane, terephthalic acid and benzoic acid. End group 13C NMR spectroscopy resonances were obtained by correlating peak intensities with intrinsic viscosity values. From the NMR data, total end group concentrations and molecular weights were determined for each sample. The data exhibited a linear trend when plotting log (IV) versus log (Mn), and previously unknown …

Preparation And Characterization Of Thiol Based Polymeric Materials, Junghwan Shin

Dissertations

The thiol click-type reaction is one of the most efficient chemical processes that can undergo at room temperature in the benign organic solvent providing excellent opportunity in the fabrication of new materials as well as development of new manufacturing processes. Moreover, the versatility of thiol click-type reactions with many different functional groups such as ene, yne, epoxy, isocyanate, and alkyl halide is the important aspect that should be differentiated from the classic azide-alkyne click chemistry. Although, there are tremendous studies on many areas using thiol click-type reactions, the efficiency and utilities for the material applications have been barely explored. Especially, …

Climate Change, Coral Reef Ecosystems, And Management Options For Marine Protected Areas, Brian D. Keller, Daniel F. Gleason, Elizabeth Mcleod, Christa M. Woodley, Satie Airame, Billy D. Causey, Alan M. Friedlander, Rikki Grober-Dunsmore, Johanna E. Johnson, Steven Miller, Robert S. Steneck

Marine & Environmental Sciences Faculty Articles

Marine protected areas (MPAs) provide place-based management of marine ecosystems through various degrees and types of protective actions. Habitats such as coral reefs are especially susceptible to degradation resulting from climate change, as evidenced by mass bleaching events over the past two decades. Marine ecosystems are being altered by direct effects of climate change including ocean warming, ocean acidification, rising sea level, changing circulation patterns, increasing severity of storms, and changing freshwater influxes. As impacts of climate change strengthen they may exacerbate effects of existing stressors and require new or modified management approaches; MPA networks are generally accepted as an …

Playing Safe: A Prototype Game For Raising Awareness Of Social Engineering, Michael Newbould, Stephen Furnell

Australian Information Security Management Conference

Social engineering is now a major threat to users and systems in the online context, and it is therefore vital to educate potential victims in order to reduce their susceptibility to the related attacks. However, as with other aspects of security education, this firstly requires a means of getting the user’s attention. This paper presents details of an awarenessraising game that was developed in order to educate users in a more interactive way. A board game approach, combining reference material with themed multiple-choice questions, was implemented as an initial prototype, and evaluated with 21 users. The results suggested that the …