Physical Sciences and Mathematics Commons^™

Minimize End-To-End Delay Through Cross-Layer Optimization In Multi-Hop Wireless Sensor Networks, Yibo Xu

Masters Theses

"End-to-end delay plays a very important role in wireless sensor networks. It refers to the total time taken for a single packet to be transmitted across a network from source to destination. There are many factors could affect the end-to-end delay, among them the routing path and the interference level along the path are the two basic elements that could have significant influence on the result of the end-to-end delay. This thesis presents a transmission scheduling scheme that minimizes the end-to-end delay when the node topology is given. The transmission scheduling scheme is designed based on integer linear programming and …

Oxidative Stress, Calcium Homeostasis, And Altered Gene Expression In Human Lung Epithelial Cells Exposed To Zno Nanoparticles, Chuan-Chin Huang

Masters Theses

"The influence of 20 nm ZnO nanoparticles on oxidative stress, intracellular calcium homeostasis, and gene expression was studied in human bronchial epithelial cells (BEAS-2B). ZnO caused a concentration- and time-dependent cytotoxicity while elevating oxidative stress and causing membrane damage (cellular LDH release). There was a remarkably steep relationship between concentration and toxicity at concentrations from 5 to 10 μg/ml. Exposure to ZnO increased intracellular calcium levels in a concentration- and time-dependent manner. Treatment with the antioxidant N-acetylcysteine prevented cell loss and diminished the increase in intracellular calcium concentration, suggesting oxidative stress mediated cytotoxicity. Exposure to a sublethal concentration of ZnO …

Automated Offspring Sizing In Evolutionary Algorithms, André Chidi Nwamba

Masters Theses

"Evolutionary Algorithms (EAs) are a class of algorithms inspired by biological evolution. EAs are applicable to a wide range of problems; however, there are a number of parameters to set in order to use an EA. The performance of an EA is extremely sensitive to these parameter values; setting these parameters often requires expert knowledge of EAs. This prevents EAs from being more widely adopted by nonexperts. Parameter control, the automation of dynamic parameter value selection, has the potential to not only alleviate the burden of parameter tuning, but also to improve performance of EAs on a variety of problem …

Comparison Of Dashboard-Based And Balanced Scorecard-Based Corporate Performance Management System, Lin Zhu

Masters Theses

"Under current hypercompetitive and technology driven economic environment, more companies are using a corporate performance management (CPM) system to gain more accurate understandings of the company goals and strategies and to craft methods of achieving those goals and strategies. While CPM systems are generally implemented in two approaches: dashboard approach and scorecard approach, very few studies examine the effectiveness of each type of CPM systems implementation. Therefore, the main objective of this study is to assess the effectiveness of a dashboard based and a balanced scorecard based corporate performance management system. The effectiveness is examined through management effectiveness, degree of …

Environmental Geochemistry Of Metal Contaminated Sediments From The Big River System Of Southeastern Missouri, Helen Carrie Bender

Masters Theses

"Geochemical analysis of stream sediments from the Big River Watershed of southeastern Missouri indicates that they contain elevated concentrations of contaminant metals such as Pb. Zn, Cu. Co, Ni and Cd. The elevated concentrations are derived from natural exposures of metal enriched strata and the numerous mine tailings piles and water seeps created as a result of about 300 years of lead-zinc mining in the “Old Lead Belt”. Galena (PbS), sphalerite (ZnS), and pyrite (FeS₂) are the primary sulfides found in the tailings piles and Scanning Electron Microscopy analysis of individual metallic sediment particles collected at intervals downstream …

Nona-Arginine Peptides Facilitate Cellular Entry Of Semiconductor Nanocrystals: Mechanisms Of Uptake, Yi Xu

Masters Theses

"Luminescent semiconductor quantum dots (QDs) have recently been used for delivering and monitoring biomolecules, such as drugs and proteins. However, QDs alone have a very low efficiency of transport across the plasma membrane. In order to increase the efficiency of QD delivery, synthetic nona-arginine (sR9) was used, a cell penetrating peptide, to facilitate uptake. Data demonstrated that sR9 could significantly increase the cellular uptake of QDs by noncovalent binding between QDs and sR9. Furthermore, the mechanisms of QD/sR9 cellular internalization were investigated. Low temperature and metabolic inhibitors markedly inhibited the uptake of QD/sR9, indicating that internalization is an energy-dependent process. …

Electricity Generation And Ethanol Production Using Iron-Reducing, Haloalkaliphilic Bacteria, Varun Paul

Masters Theses

"Microbial life in extreme environments has been studied primarily for their metabolic activities. Very few commercial or industrial applications have been known from these systems. In this study, the metabolic pathways and properties of bacteria from a haloalkaliphilic environment of Soap Lake, Washington were employed in two research applications related to energy production. In the first study, the bacterial cultures that were known to reduce iron (III) were used in a Microbial Fuel Cell (MFC) reactor. Iron reducing bacteria have shown to shunt their electrons on to the surface of a carbon electrode of an MFC, and the electrons can …

Exploring The Use Of A Commercial Game Engine For The Development Of Educational Software, Hussain Alafaireet

Masters Theses

"Three-dimensional visualization and simulation environments are becoming increasingly important in both industrial and educational environments. However, developing these simulations can be a difficult and expensive task. Herein we explore the use of a commercial game engine to develop a 3-D, interactive computer game designed to teach players about the anatomy of a frog. The goal of this project is threefold: 1) to develop high-fidelity virtual reality educational software with a limited budget and limited personnel, 2) to define a software development process by which similar simulations can be developed, and 3) to explore the benefits that these simulations provide to …

Information Flow Properties For Cyber-Physical Systems, Rav Akella

Masters Theses

"In cyber-physical systems, which are the integrations of computational and physical processes, security properties are difficult to enforce. Fundamentally, physically observable behavior leads to violations of confidentiality. This work analyzes certain noninterference based security properties to ensure that interactions between the cyber and physical processes preserve confidentiality. A considerable barrier to this analysis is the representation of physical system interactions at the cyber-level. This thesis presents encoding of these physical system properties into a discrete event system and represents the cyber-physical system using Security Process Algebra (SPA). The model checker, Checker of Persistent Security (CoPS) shows Bisimulation based NonDeducibility on …

Integration Of A Gis Learning System Into Civil Engineering Curricula: An Evaluation, Basanta Tandon

Masters Theses

"An evaluation of a web-based e-learning system to facilitate integration of Geographical Information Systems (GIS) into the Civil Engineering curriculum was conducted. The principal goals of the evaluation were to examine the effectiveness of the learning system and to develop a preliminary model to describe how students interact with the learning system. Quantitative and qualitative data were collected from 80 students who participated in a geotechnical engineering laboratory session, which covered soil borrow sites. Students rated the laboratory session as significantly more effective for learning, a nd more motivational than the class text. They also rated the lab significantly more …

Cloning, Overexpression, Purification And Characterization Of Gcp Ii Homologous Metalloprotein From Caulobacter Crescentus, Dilani Nilushika Gigiriwala Gamage

Masters Theses

A novel zinc metalloprotease gene isolated from Caulobacter crescentus (CCM) was cloned and overexpressed in Escherichia coli. A protease database search using MEROPS predicted this protein is a homolog of Glutamate Carboxypeptidase II (GCP II), a zinc metalloprotease found in humans and many other organisms. GCP II is considered as a suitable target for treating stroke, neurological disorders and a biomarker for prostate cancer. Chromatographic purification of CCM produced pure protein in milligram quantities. Molecular weight detern1ination using MALDI-TOF showed 51,582 Da and the extinction coefficient was found to be 33,007 M"1cm·1. Metal analysis and substrate profiling showed neither sufficient …

Stability Of Heme Proteins: Cytochrome C And Horseradish Peroxidase, Mini Gupta

Masters Theses

A heme protein is a metalloprotein containing the heme prosthetic group. This prosthetic group is responsible for the wide range of biological functions found in heme proteins, from oxygen transport to electron transport. Moreover, heme proteins show a fascinating range of folding architectures, leading to their interest in research on structure-function relationships. The objective of this research in bioinorganic chemistry is to study the structural stability of two heme proteins, iron cytochrome c (Fecyt) and horseradish peroxidase (HRP). Absorbance spectroscopy is used to monitor the structural changes in the protein environment around the heme prosthetic group.

With just a change …

Electrochemical And Spectroscopic Characterization Of A Polypyridyl Ru(Ii) Complex Containing A Fused Alloxazine, Waynie Wilson Olaprath

Masters Theses

Phenanthroline pteridinedione (pptd) is an alloxazine derivative capable of 2e/ 2H+ transfer reactions. Coordination of pptd to a Ru(II) metal center allows for the synthesis of water-soluble metal complexes capable of being reduced by as many as 6 Hatoms making them candidates to be electrochemical mediators. This thesis describes the synthesis and characterization of pptd and [Ru(bpy)2(pptd)](PF6)2(b py = 2,2-bipyridine). The dipyrido[3,2-a: 1' ,2' -c] phenazine (d ppz) and [Ru(bpy)2(d ppz) ](PF6)2 are also synthesized and studied in order to distinguish the properties of the free and coordinated pteridinedione-based pptd ligand from the well-characterized phenazine based ligand.

Detailed cyclic voltammetry, …

Molecular Structures And Pulsed Discharge Emission Studies Of Volatile Organic Compound Derivatives, Ashley Osthoff

Masters Theses

Understanding the structure and reactivity of volatile organic compounds (VOCs), hydrochlorofluorocarbons (HCFCs) and their derivatives is a fundamental concern in the study of atmospheric chemistry. Recently, a series of studies were done aimed at constructing and optimizing a rapid-scan, midinfrared spectrometer in order to study the structure and intermolecular interactions of these compounds. Visible emission spectroscopy was used to optimize the pulsed discharge nozzle that would be used within the infrared spectrometer. The emission spectra of toluene and xylene were used to characterize production of free radical compounds. In addition, control programs were written in the Lab VIEW programming language …

In Vitro Evaluation Of Bioactive Glass Scaffolds And Modified Bioactive Glasses With An Osteogenic Cell Line, Vernon C. Modglin

Masters Theses

"This investigation consisted of two parts focused on bioactive glasses and scaffolds for in vitro growth of bone cells for tissue engineering and bone repair. The first part involved evaluation of the ability of two new types of porous 13-93 bioactive glass scaffolds to support the growth and differentiation of mouse MLO-AS cells, an established osteogenic cell line used as a model of developing bone tissue. The two scaffold types tested included 13-93 glass fiber and trabecular-like scaffolds seeded with MLO-AS cells and cultured for intervals of 2 to 12 days. Collectively, in vitro results indicate that the 13-93 glass …

Satellite Photography: Instrumental, Rhetorical, Affective?, Irangi Kaushalya Egodapitiya

Masters Theses

"This study examines how tsunami satellite images operate and could provoke various interpretations. The goal of this research project is to study whether the interpretation of tsunami satellite images could extend beyond scientific features to affective messages. Primarily based on the satellite images of Sri Lanka taken before and during the 2004 tsunami, this study analyses: How could mechanical satellite images, taken automatically by a machine in orbit, become an object of profound emotional meaning?; How do viewer's experiences, knowledge, and discourse affect their interpretations of mechanical artifacts?; How are tsunami satellite images connected to affective responses by viewers?; How …

Formation Of Iron-Rimmed Sandstone Nodules On Earth; Terrestrial Analogue For The Formation Of Martian Blueberries?, Katherine Charlotte Muller

Masters Theses

"NASA's twin Mars Exploration Rovers, MER, Spirit and Opportunity, have identified numerous geologic features that hint at a watery past on Mars noted in Malik, 2004. Prominent among these features are the "Martian Blueberries" that occur as spherical hematite (Fe₂O₃) nodules. Hematite formation is facilitated by the presence of water, although there are presently no known sources of free liquid water on Mars. Chan et al., 2004 states that these "blueberries" are also similar to nodules found in the Jurassic aged Navajo Sandstone in Utah. An understanding of the processes controlling the formation of the Utah nodules may thus be …

The Effects Of Technology On Literacy(S), Thomas Glen Petersen

Masters Theses

"One of the challenges when measuring the effects of technology on literacy(s) is finding a control group where technology; does not play a major role in the culture. The Amish successfully live in a Technocracy where mechanical/electronic tools are used only when absolutely necessary; the Amish are not dependent on them for survival. The crux of the Amish philosophy is humility, serving the community and serving God. Ironically, they have suffered tremendous repercussions for adopting a wholesome, selfless lifestyle which is contrary to most popular world views, regardless of religious or spiritual views"--Purpose, page 40.

The Analogue Of The Iterated Logarithm For Quantum Difference Equations, Karl Friedrich Ulrich

Masters Theses

"In this thesis, we consider oscillation and nonoscillation of q-difference equations, i.e., equations that arise while studying q-calculus. In particular, we prove an extension of Kneser’s theorem on q-calculus to cases in which no conclusion can be drawn by applying Kneser’s theorem. In order to accomplish this, we establish a change of variables which yields, when applied iteratively, a sequence of comparison functions. We use these comparison functions to establish our main result. Finally, we consider an analogue result for time scales which are unbounded from above"--Abstract, page iii.

Influence Of Bioirrigation On Metal Distribution Within Burrows, Terri Shattuck

Masters Theses

Bioirrigation is the increase of solute transport resulting from introduction of oxygenated water from the surface into the more reduced environment deep within the burrow. Fe and Mn hydr-(oxides) accumulate on burrow margins in response to the oxygen flux into suboxic porewaters. This has been shown to trap trace metals (Harding and Risk, 1986; Tessier and Campbell, 1988; Tessier et al., 1979, 1982). The diagenesis, mobility, and transport of metals contribute to the bioavailability of metals in the environment possibly to the extent of harming ecosystems; especially in coastal areas with buried waste. This study assesses Fe and trace metal …

Origin Of Tunnel Valley And Esker Assemblages In The Saginaw Lobe, Barry County, Michigan, Caleb J. Woolever

Masters Theses

Surficial mapping, borehole analysis, and ground penetrating radar surveys are used to reconstruct conditions leading to the formation of tunnel valley and esker networks within the Dowling 7 .5 minute quadrangle. The relationship between tunnel valleys and eskers has important implications on the subglacial hydrology beneath the Saginaw Lobe of the Laurentide Ice Sheet.

Surficial mapping reveals northeast-southwest trending tunnel valleys, some containing eskers of the same orientation, in hummocky topography mapped as the Saginaw Kalamazoo Moraine. A borehole hole drilled through one such tunnel valley and esker pair reveals sand and gravel fining upwards to fine sand. Stratigraphy suggests …

Characterization Of P62, Hah1 And Their Interaction With The Wilson Disease Protein, Paul Sifuna Oshule

Masters Theses

Wilson disease is an autosomal recessive disorder resulting in the accumulation of copper in the body primarily in the liver and brain. In order to understand the pathogenesis of Wilson disease, our laboratory is studying several different proteins. Wilson disease protein (ATP7B) is a P-type ATPase which acts to remove excess copper from the cells. The p62 subunit of the dynactin complex is a protein whose function is still unknown but it has been proposed to have a copperdependent interaction with ATP7B. HAH1 is a human metallochaperone that binds copper as it comes into the cells from CTR1, a permease. …

Origin Of Size-Dependent Energy Transfer From Photoexcited Cdse Quantum Dots And Fluorescent Dyes To Gold Nanoparticles, Mariana Kondon

Masters Theses

The photoluminescence quenching of CdSe quantum dots (QD) and fluorescent dyes by hexanethiolate Mono layer Protected Clusters (MPCs) with core diameters of 1.1- 4 .9 nm is described.

The CdSe QD investigated had the following core diameters of 2.0, 2.6, 3.4 and 6.9 nm. The florescent dyes used were: Coumarin 440 (CM440), Fluorescein 548 (F548), Rhodamine 6G (R6G), Pyromethene 597 (PM597) and Lyssamine Dye (LD700). Experimental evidence suggests that the photoluminescence quenching of both CdSe QD and the fluorescent dyes occurs through energy transfer and that the AuMPCs are efficient quenchers in both cases. The larger MPCs are more efficient …

Optical And Electrochemical Molecular And Nanoscale Sensors For The Selective Detection Of Organophosphorus Based Pesticides, Chandrima De

Masters Theses

Organophosphorus based pesticides are highly toxic and represent serious environmental concerns. These compounds tend to easily enter ground water and cause drastic pollution. The toxicity levels of the organophosphorus pesticides however are based on their structures, and hence methods for their selective detection are in high demand. The creation of new materials for sensing and actuation requires careful manipulation of the responsive units required to control analyte selectivity. We have successfully designed and synthesized a molecular sensor based on the family of stilbenes that not only can detect organophosphorus pesticides, but also distinguish between them. Four different pesticides have been …

The Physics Of Electron Degenerate Matter In White Dwarf Stars, Subramanian Vilayur Ganapathy

Masters Theses

White dwarfs are the remnant cores of medium and low mass stars with initial mass less than 8 times the mass of our sun. As the aging giant star expels its surface layers as planetary nebulae, the core is exposed as a white dwarf progenitor. The density of matter in white dwarfs is so high that thermal or radiation pressure no longer supports the star against the relentless pull of gravity. The white dwarf is supported by a new kind of pressure known as the degeneracy pressure, which is forced on the electrons by the laws of quantum mechanics. The …

Analysis Of Pore Architecture And Correlation To Sonic Velocity Values In Silurian (Niagaran) Reefs Of The Michigan Basin, Amy Kathryn Noack

Masters Theses

Recent work has shown that there is a complex relationship among porosity, permeability, and rock fabric in carbonate rocks. Porosity/permeability transforms are of limited value when evaluating carbonate reservoirs because permeability is controlled by pore type. Vuggy, moldic, or fenestral pore types have high porosity but poor permeability; in contrast, intergranular and intercrystalline pore networks have high porosity and high permeability. Visible pore types of key facies in five Middle Silurian (Niagaran) Reef reservoirs of the Michigan Basin were evaluated to better understand related permeability. Image analysis was performed on key facies to understand pore geometries and pore connectivity. Facies …

Blocked Localized Wavefunction Analysis Of Π And Σ Bonds In The Metal Carbonyl, Kazuhito Nakashima

Masters Theses

The bonding features in group 10 and 11 metal carbonyls Ni(CO), Pd(CO), Pt(CO), [Cu(CO)]+, [Ag(CO)]+, and [Au(CO)]+ have been studied with BLW method. The carbon monoxide is well known as both a π acceptor and a σ donor. The π back bonding and o bonding are synergistic in these metal carbonyl complexes, because the π donation from the metals polarizes the metals and creates a negative force field as an additional driving force on the σ donation from the carbon end of CO vice versa. The synergistic effect in the metal-carbonyl bonds can be described by decomposing the binding energy …

Morphological Analysis Of The Charlevoix-Antrim And Northport Drumlin Fields, Michigan Using Digital Elevation Models, Alan M. Lefever

Masters Theses

The Charlevoix-Antrim and Northport drumlin fields, located in northwest Lower Michigan, lie on opposite sides of Grand Traverse Bay. Morphological measurements were derived from topographic maps and Digital Elevation Models (DEMs), combined with grain size analyses performed on collected drumlin sediments. Comparison of the morphological results demonstrates that statistical analysis of equal or better accuracy can be performed on drumlins using high resolution DEMs. The grain size analysis determined that the drumlins contain more gravel near the coast and become sandier to the south and east.

Spindle drumlins are the dominant drumlin form in both the Charlevoix-Antrim and Northport fields. …

N-(Deoxyadenosine-8-Yl)-4-Aminobiphenyl Adduct Formation In Vitro On Tp53 Exon7 Genome: Quantitation By Lc-Esi-Ms/Ms, Paul René Knoll

Masters Theses

The p53 protein has been documented to be mutated in more than 50% of late stage bladder cancers and tobacco causes 50% of all bladder tumors. The 4- arninobiphenyl (ABP) carcinogen comprises 5 ng per cigarette in the smoke and is a known bladder carcinogen. The research goal in the present study was to compare the reactivity of rat liver S-9 fraction activated 4-arninobiphenyl with the 45-mer sense strand of the TP53 exon7 gene to the respective anti-sense strand. The specific and sensitive technique of LC-tandem mass spectrometry (LC-MS/MS) was used for quantitation. The authentic standard of N-(adenine-8yl-)-4-arninobiphenyl (A-ABP) …

Improving Query Efficiency Of Multiresolution Data Aggregation For Analytical Exploration Of Large Relational Dataset, Yu-Ting Huang

Masters Theses

Tree structures are developed to organize the data more efficiently by using fewer resources for searching records. This thesis investigates the tree's actual structure on the hard disk to see the influence of different kinds of structures on the tree building time and query execution time. In order to improve efficiency, one multi-file structure and two reorganization structures, BFS and DFS, are examined to achieve this goal. The results indicate that two reorganization structures on KDB-tree structure can significantly improve the query execution time in large data sets and multi-file structure can slightly improve the TPIE lover level building time.