Physical Sciences and Mathematics Commons^™

Evaluation Of An Alternative Natural Surfactant For Non Aqueous Phase Liquid Remediation, Brian A. Beach

Masters Theses

Applications of surfactant technology in the environmental remediation industry can greatly enhance the success of non-aqueous phase liquid (NAPL) remediation. Saponins derived from the bark of the Quillaja soapbark tree were evaluated as an alternative natural surfactant. Properties including the critical micelle concentration, emulsion kinetics and the solubilization enhancement of sixteen PAHs (polycyclic aromatic hydrocarbons) were measured. The critical micelle concentration (CMC) for Quillaja saponin was found to be 60 mg/L. Soil contaminated with NAPL from a former manufactured gas plant was used to evaluate saponin’s ability to enhance the solubilization of PAHs commonly found in NAPL. Although solubilization enhancement …

Geochemical And Petrological Studies On The Origin Of Nickel-Copper Sulfide Mineralization At The Eagle Lntrusion In Marquette County, Michigan, Benjamin Davis Hinks

Masters Theses

The Eagle magmatic intrusion is located in the Upper Peninsula of Michigan in Marquette County. It hosts a high grade magmatic nickel-copper sulfide ore deposit. Country rocks surrounding the Eagle intrusion are metamorphosed slate and greywacke of the Proterozoic Michigamme Formation and Archean granite-gneiss. The aim of this thesis is to characterize the magmatic sulfide mineral deposit at Eagle and to establish its relationship to the surrounding host rocks of the Baraga Basin area.

The Eagle East intrusion is located 600 meters east of the Eagle intrusion. These two intrusions are similar in composition and sulfide mineralization. Sulfide textural domains …

Stable Isotope Investigations Of Two Components Of The Cryosphere: Snow And Icicle Formation, Thomas C. Brubaker

Masters Theses

Understanding the processes that govern the cryosphere is necessary to understand the water budget within an area that receives significant winter precipitation. This research investigates two components of the cryosphere, namely snow and icicle formation, through the application of the stable isotopes of oxygen and hydrogen.

Stable isotope measurements from precipitation collected throughout the winter of 2013-2014 are presented. The measured isotope values are in discord with known isotope effects. This discrepancy hints at a previously unexplored atmospheric phenomenon, where the enriched oxygen isotope signature of atmospheric ozone was incorporated, via photochemical reactions, into water vapor which subsequently fell as …

Geochemical And Petrological Characterizations Of Peridotite And Related Rocks In Marquette County, Michigan, Andrew Lloyd Sasso

Masters Theses

This study characterizes the following rock units in Marquette County, Michigan in terms of geochemistry and petrology: (1) Presque Isle Peridotite, (2) Deer Lake Peridotite, (3) Yellowdog Peridotite, and (4) Black Rock Point Gabbro. Analyses were conducted to determine if any petrological or geochemical relationships exist between these units, and to assess the potential of these units to host magmatic sulfide deposits.

The generated data and chosen geotectonic proxies indicate that Black Rock Point Gabbro and Deer Lake Peridotite crystallized from unrelated magmas, probably during the formation of the Great Lakes Tectonic Zone (2.7-1.85 Ga). No evidence was found which …

Application Of Electrospray Ionization Mass Spectrometry For Ionic Liquids And Their Biodegradation Products, Sepideh Rahbarirad

Masters Theses

Ionic liquids (ILs) are organic salts with unique physico-chemical properties and are used as green alternatives to volatile organic solvents. ESI-MS is a sensitive technique to detect these stable, permanent ions. My research focused on (1) Identification of biodegradation products of ionic liquids and (2) Multiplexed tandem MS by modulation of ionization efficiency.

Studies, have demonstrated that ILs are toxic to the environment, which makes their biodegradability an important consideration. In this work, metabolites generated during the biodegradation of 1-butyl-3-methylimidazolium chloride (BMIM), a degradation resistant and commonly used ionic liquid, are identified using high performance liquid chromatography-mass spectrometry (LC-MS).

Multiplexed …

Slug Tests In Unconfined Aquifers, Rozkar Izzaddin Ismael

Masters Theses

This research presents a hydraulic conductivity (K) analysis of unconfined aquifers using slug tests. Slug tests are used to determine in situ aquifer hydraulic conductivity more quickly and economically than by a pump test. This study examines how to best conduct a slug test using a physical slug. Different common slug test analysis methods are compared, including Bouwer and Rice (1976), Hvorslev (1951), Dagan (1978) and Kansas Geological Survey (KGS, 1994). Questions that motivated this study include: Which methods are better for performing and analyzing slug tests? Does the size of the physical slug affect the results? Do large initial …

Extent Of Capillary Rise In Sands And Silts, Rachel Lynn Salim

Masters Theses

The values reported in literature for the height of capillary rise in fine sands, silts, and clays are contradictory. Most of the values were based on mathematical models, which used estimated rather than measured input data. This work measured capillary rise values in laboratory experiments in fine-grained sands and silts.

Two uniform sands with grains 0.35--0.7 mm in diameter and 0.3-0.6 mm in diameter, silt with an average grain size below 40 microns, and 0.35--0.7 mm sand coated with a water-repellant spray were carefully packed into two-inch diameter glass columns. These columns were placed into clear plastic tanks with water …

Environmental Applications Of Chromatography-Mass Spectrometry, Wisam Abdulabbas Flayyih Al Isawi

Masters Theses

Gas chromatography-mass spectrometry (GC-MS) and liquid chromatographymass spectrometry (LC-MS) are powerful analytical techniques that combine the separation power in a stationary phase with the detection power of mass spectrometry. GCMS and LC-MS have gained dominant positions in identifying and quantifying different analyte species due to their high selectivity, high sensitivity, and high reproducibility.

My research utilizes the analytical power of LC-MS and GC-MS to address two environmental issues: 1) Identification of biodegradation products of the ionic liquid 1- butyl-3-methylimidazolium chloride (BMIMCl) by an activated sludge microbial community using LC-MS and 2) identification and quantification of polycyclic aromatic hydrocarbons (PAHs) in …

Lnfluence Of Persulfate On Solidification/Stabilization Characteristics Of Iss Treatment, Jeffrey M. Hudson

Masters Theses

Two environmental remediation technologies that lend themselves well to being combined in a single application are In Situ Chemical Oxidation (ISCO) using activated persulfate (PS), and In Situ Stabilization (ISS). Persulfate can be activated by increasing the pH to 10.5 and/or increasing temperatures to 30ºC. Many common ISS amendments increase temperature to 30°C and/or pH to 10.5 when in contact with soil water. Laboratory experiments were conducted with various soils to determine the ability of eight ISS amendments to activate persulfate. All eight ISS amendments activated persulfate. This work also showed that the relative contribution of heat vs. alkaline activation …

Differentiating Saginaw From Huron-Erie Lce Lobe Meltwater Deposits In South Central Michigan Using Longitudinal Profiles, Grain Size Analysis, And Lithology, Nathan R. Erber

Masters Theses

The Saginaw and Huron-Erie lobes of the Laurentide Ice Sheet had a significant impact on the landscape of south-central Michigan after the Late Glacial Maximum. During the advances and retreats of these lobes, a complicated network of meltwater channels developed. Two goals of this study are: 1) to use sand-grain lithology, grain-size analysis, and longitudinal profiles to determine if a difference exists between Saginaw lobe and Huron-Erie lobe meltwater deposits; and 2) to determine if a large meltwater sluiceway containing the modern St. Joseph River had a source of meltwater and outwash from the Huron-Erie lobe. Two cores from drumlinized …

Structures And Nuclear Quadrupole Coupling Tensors Of 1,2-Dichloroethane, 1-Chloro-2-Fluoroethane And 2,3-Dichloropropene Studied Using Microwave Spectroscopy And Computational Chemistry, Asela Sampath Dikkumbura

Masters Theses

The Fourier-transform microwave (FTMW) spectra of 1,2-dichloroethane (12DCE), 1-chloro-2-fluoroethane (1C2FE) and 2,3-dichloropropene (23DCP) have been studied in the 6 to 18 GHz range to determine experimental rotational constants, nuclear quadrupole coupling constants (NQCC) and quartic centrifugal distortions constants. These three molecules have different spatial arrangements (anti and gauche) resulting from different relative orientations of chlorine and/or fluorine atoms about the C-C single bond. The lowest energy anti conformer of 12DCE is non-polar and it is not detectable by microwave spectroscopy, but rotational spectra of gauche-12DCE with three isotopologues, gauche-1C2FE with three isotopologues, and both anti- …

White-Rot Fungi As Pretreatment Agents For Wood Destined For Biofuel Applications, Ryan M. Kalinoski

Masters Theses

Efficient and economical conversion of lignocellulosic biomass to biofuels is often hampered by the chemical recalcitrance of the material. Inexpensive and environmentally-friendly pretreatment processes are therefore desirable in order to lower the cost of biofuel production and minimize negative environmental impacts. To that end, we have explored the use of a naturally occurring white-rot fungus, Trametes versicolor, as a direct pretreatment agent for hardwood destined for biofuel applications. Specifically, we examined the pretreatment effects on the hardwood mixture after treatment with the wild-type strain of T. versicolor (52J) compared with those from a cellobiose dehydrogenase (CDH)-deficient strain (m4D) , …

Theoretical Investigations Of Difluorobenzene Interacting With Ne And Infrared Analysis Of 1,1-Dichloroethylene From Synchrotron Data, Seri P. Kamari

Masters Theses

The intermolecular interactions between two molecules are of great importance in proteins, polypeptides, DNA binding, and drug binding interactions. Dimers of chemical rings such as difluorobenzene with hydrogen containing molecules such as acetylene (HCCH) and atoms such as neon are classic systems for investigating weak interactions; however, the microwave spectrum of 1,2-difluorobenzene...Ne does not behave as expected. Possible explanation of this phenomenon is that there is some large amplitude motion perturbing the spectrum.

A computational study was performed to analyze the potential energy surface (PES) of Ne or Ar with ortho, meta, and para difluorobenzene, and reveal the …

Understanding The Management Of Sustainability On One Public Midwestern College Campus, Eric Swinehart

Masters Theses

Environmental sustainability is a substantial issue within our world today that is on the forefront of policy makers' minds. Implementation of sustainability initiatives on a college campus comes in many forms and different scales, which falls upon the question of who manages all the moving pieces to make these initiatives successful. This study was designed to gain an understanding of how administrators are defining and implementing environmental sustainability initiatives on their campus, to understand their role in managing these tasks. Using a qualitative approach, the researcher interviewed a purposeful sample of four higher education administrators from one public Midwestern university. …

Synthesis And Characterization Of Dicopper(Ii) Complexes With Biological Relevance, Ashley E. Hall

Masters Theses

The research discussed in this study focused on the design, synthesis, and characterization of new model complexes that mimic the type-3 enzyme, catechol oxidase, which oxidizes catechols to their corresponding quinones. Our approach focused on the design and synthesis new model complexes that contain a dicopper(II) center that can be fine-tuned in a variety of ways, such as sterics and exogeneous bridging molecules. This method allows a multitude of complexes to be created and compared to determine how the overall structure affects the catecholase activity of the complexes.

Two ligands were synthesized; they contain a phenolate body, two amide groups, …

Oxidative Dehydrogenation Of Light Alkanes With Carbon Dioxide, Marktus A. Atanga

Masters Theses

”Most experts studying the global ecosystem and climate suggest that rising anthropogenic CO₂ emissions have contributed to significant global climate change in the last half-century. The development of effective strategies that convert CO₂ into energy, fuels, and chemicals are greatly preferable to oceanic or geologic sequestration options because they offer the potential to create new commercially-viable products from renewable carbon feedstock. On the other hand, the selective oxidative dehydrogenation of light alkanes (C₂-C₄) to corresponding olefins, methane reforming, and methane coupling are the major challenges for producing valuable and versatile feedstocks. The oxidative dehydrogenation …

Gravity And Magnetic Investigations Of The North-Eastern Kansas Section Of The Midcontinent Rift System, Ozgun Kamil Sahin

Masters Theses

"The Midcontinent Rift System (MRS) is a major Precambrian magmatic province on the North American continent. It formed when the North American craton began to split apart during the Mesoproterozoic era (1,100 Ma). As a result of the extension and possibly the effects of a rising mantle plume, a thick layer of basalt and numerous reverse and normal faults were formed. The basalt layer is buried below sedimentary formations and makes it difficult for seismic techniques to image. On the other hand, gravity and magnetic methods can be utilized for focused depths, and the basalt layer of the system can …

2d Seismic Data And Gas Chimney Interpretation In The South Taranaki Graben, New Zealand, Taqi Talib Alzaki

Masters Theses

"The Taranaki Basin is one of the major oil and gas producing basins offshore New Zealand. The study area covers an area of 10,000 km² in the basin, and includes 171 2D seismic lines and six wells, which are provided by the New Zealand Petroleum & Minerals. Some previous studies refer to the study area as the South Taranaki Graben.

This thesis provides detailed mapping and interpreted subsurface stratigraphy and structure of five horizons, i.e. basement top, Pakawau Group top, Kapuni Group top, Wai-iti Group top, and seafloor. It undertakes studies of the relation between the basin evolution, faults, …

Tracking Silver, Gold, And Titanium Dioxide Nanoparticles Through Drinking Water Systems By Single Particle - Inductively Coupled Plasma - Mass Spectrometry, Ariel Renee Donovan

Masters Theses

"Single particle (SP)-ICP-MS methods were developed to characterize and quantify Ti-containing, titanium dioxide, silver, and gold NP concentration, size, size distribution and dissolved metal element concentration in surface water and treated drinking water. The effectiveness of conventional drinking water treatments (including lime softening, alum coagulation, filtration, and disinfection) to remove NPs from surface water was evaluated using six-gang stirrer jar test simulations. Six-gang stirrers were used to simulate drinking water treatments including lime softening, alum coagulation, powdered activated carbon sorption, filtration, and disinfection by free chlorine. Lime softening effectively removed most nanoparticles added. Source and drinking waters from three large …

Phytoforensics Tools: The Degradation And Detection Of Chlorinated Solvents In Integrated Systems, Tommy J. Goodwin Jr.

Masters Theses

"Due to decades of mismanaged pollutants entering groundwater, subsurface pollution of various compounds has become a widespread challenge. Chlorinated solvents are the most common groundwater contaminants that persist in aquifers, and remediation of these wide-spread plumes is difficult. Bioremediation, permeable reactive barriers, and phytoremediation are remedial technologies that have been developed and applied to chlorinated solvents in groundwater systems. This study integrates these technologies in different combinations to demonstrate the remediation potential of this approach. Zerovalent iron (ZVI) and bioaugmentation with a Dehalococcoides sp. (DHC) culture were applied separately and in combination for degradation of perchloroethene (PCE). Salix pentandra were …

The Mantle Transition Zone Beneath South America From Stacking Of P-To-S Receiver Functions, B. A. Goetze

Masters Theses

"The Mantle Transition Zone (MTZ) beneath South America is investigated with stacking of Receiver Functions (RFs) of converted P-to-S phases from the velocity discontinuities at 410 km (d410) and 660 km (d660). A total of 785 seismic stations provided 22,235 high quality RFs, allowing 1,717 MTZ thickness measurements in circular bins of 2⁰ radius. An apparent MTZ structure is derived using the IASP91 reference model, where the d410 mean depth is 409.1 km and the d660 is 661.5 km, and the mean MTZ thickness is 251.8 km. This model presents coherent depressions and uplifts of the discontinuities matching well known …

Imaging Reinforced Concrete: A Comparative Study Of Ground Penetration Radar And Rebarscope, Abhishek Kodi

Masters Theses

"Geophysical techniques have been playing a very vital role in subsurface imaging in the recent past. Technology has been making it both reliable and convenient to utilize non-destructive geophysics techniques like Ground Penetration Radar, Induction current based Rebarscope, Seismic methods, ERT, etc. The applications range from shallow subsurface investigation of Bridge decks to old tunnels, mapping of rabars in a pre-existing construction and analyzing the concrete strength.

The thesis constitutes of a comparative study and analysis of a Ground Penetration Radar system and a Rebarscope. Individual parameters obtained directly from the study and obtained indirectly from the study shall be …

Care-Chair: Opportunistic Health Assessment With Smart Sensing On Chair Backrest, Rakesh Kumar

Masters Theses

"A vast majority of the population spend most of their time in a sedentary position, which potentially makes a chair a huge source of information about a person's daily activity. This information, which often gets ignored, can reveal important health data but the overhead and the time consumption needed to track the daily activity of a person is a major hurdle. Considering this, a simple and cost-efficient sensory system, named Care-Chair, with four square force sensitive resistors on the backrest of a chair has been designed to collect the activity details and breathing rate of the users. The Care-Chair system …

Assessing Downstream Stormwater Impacts For Urban Watershed Planning, Johanna Meyer Pavlowsky

Masters Theses

"The urbanization of watersheds has caused debilitating effects to downstream aquatic ecosystems in catchments and streams. The implementation of green infrastructure (GI), such as permeable pavements and bioretention facilities, has been shown to alleviate these effects by both reducing runoff and mitigating pollutants; however, the implements are often not designed with a specific goal of water improvement. This study targets understanding a small, impaired urban watershed, and the benefits green infrastructure may have to provide environmental, social, and economic improvement to the watershed.

Portions of Rolla including much of the S&T campus drain into the impaired urban waterbody Frisco Lake, …

Numerical Analysis Of Flexural Slip During Viscoelastic Buckle Folding, Davi Rodrigues Damasceno

Masters Theses

"Flexural slip is considered to be an important folding mechanism contributing in the development of different folds such as chevron, and kink-band buckle folds. Various filed studies have provided a general conceptual and qualitative understanding of flexural slip. However, quantitative evidence of the importance of the flexural slip mechanism during fold evolution is sparse, as the actual amount of surface parallel displacement, and timing, is difficult to measure accurately, due to the lack of suitable strain markers.

In this study 2D finite element analysis is used to overcome these disadvantages and to simulate flexural slip during viscoelastic buckle folding. Variations …

A Feasibility Study Of A Nuclear Power Plant With No Moving Parts, Jonathan Mark Schattke

Masters Theses

"In a nuclear reactor design, every moving part in a system is considered a failure point. In this study, a proposal is made for designing a nuclear reactor that has no moving parts by coupling an accelerator driven core (removing control system moving parts) to a magnetohydrodynamic generator (removing power generation moving parts) using mercury coolant (removing pumping system moving parts). Further safety is realized by using a subcritical core, where the core is never able to sustain a chain reaction on its own, obviating many safety systems. The design is verified with a Monte Carlo simulation "--Abstract, page iii.

On The Double Chain Ladder For Reserve Estimation With Bootstrap Applications, Larissa Schoepf

Masters Theses

"To avoid insolvency, insurance companies must have enough reserves to fulfill their present and future commitment-refer to in this thesis as outstanding claims towards policyholders. This entails having an accurate and reliable estimate of funds necessary to cover those claims as they are presented. One of the major techniques used by practitioners and researchers is the single chain ladder method. However, though most popular and widely used, the method does not offer a good understanding of the distributional properties of the way claims evolve. In a series of recent papers, researchers have focused on two potential components of outstanding claims, …

Reprocessing And Structural Interpretation Of Multichannel Seismic Reflection Data From Penobscot, Nova Scotia, Fulya Gizem Yagci

Masters Theses

"Penobscot area is located in the Scotian Basin, which was occurred as a result of extension in the eastern North America border. 2-D data set that was utilized for the study consists of three multichannel seismic profiles that were collected from Penobscot Parcel 8. The main purpose of the study was to enhance signal-to-noise ratio of the seismic reflection sections suppressing high frequency noise and multiples, and removing diffractions. In addition, while the resolution of the sections were enhanced, determining the correct processing techniques and parameters for better results was the another important criteria.

The processing steps included deconvolution, minimum …

3d Seismic Structural And Stratigraphic Interpretation Of The Tui-3d Field, Taranaki Basin, New Zealand, Gorkem Yagci

Masters Theses

"Identifying seismic structures and stratigraphy are important for exploration of hydrocarbons. The purpose of this study is to discover seismic structural and stratigraphic features and to utilize the results for interpreting depositional environments. A 3D seismic dataset from the Tui-3D Field, the Taranaki Basin, New Zealand with well data were used to visualize structures, to detect stratigraphic features, to identify main lithology, to understand depositional environment, and to describe seismic facies and reflection patterns of the target horizons. The major formations are in the Kapuni Group.

Seismic structural interpretation indicates thirty-two minor faults, which may play an important role in …

Variable Stress Orientations In The Offshore Nile Delta: The Role Of Salt As A Mechanical Detachment Horizon, Weicheng Zhang

Masters Theses

"The offshore Nile Delta is characterized by variations of the maximum horizontal stress orientation in subsalt and supra-salt sequences. Margin-parallel SH, typical for tertiary deltas, is observed for regions that are below or do not contain evaporites. In sequences underlain by evaporates pre-dominantly margin-normal SH is observed. This observation yielded the first conclusive in situ evidence that salt acts as a mechanical detachment layer. In this study, 3D finite element analysis (FEA) is used to simulate the total stress distribution in the offshore Nile Delta featuring evaporate sequences. Several parameters such as different salt sequence geometries, friction coefficient on faults, …