Physical Sciences and Mathematics Commons^™

Temporal Changes Of Nutrients Within The Lower Grand River Watershed And Selected Sites, Weston Scott Duley

Masters Theses

"This report presents the results of a study carried out in collaboration with the U.S. Geological Survey (USGS) and the Missouri Department of Natural Resources (MDNR) to estimate total nitrogen (TN) and total phosphorus (TP) at five USGS monitoring sites within Lower Grand River Watershed (LGRW) and two monitoring sites on the Missouri River. The objective of this study was to quantify temporal changes in TN and TP concentrations and compare those to best management practices (BMPs).

In this study, the approach to the analysis of long-term surface water-quality data by using Weighted Regressions on Time, Discharge and Seasons models …

Geophysical Imaging Beneath Lake Chesterfield, Missouri, James Daniell Hayes

Masters Theses

"Lake Chesterfield in Wildwood, Missouri, has been leaking since construction of the earth-fill dam was completed in 1986, despite numerous mitigation efforts. The mitigation efforts, including the injection of grouting and the emplacement of clay liners, has not solve the leakage problem.

In the current study, geophysical (subsurface imaging) data was acquired across the drained and dry lake bed and along the base of the earth-fill dam to 1) map variable depth to top of bedrock, 2) determine the variable quality of the bedrock to depths on the order of 80 ft., 3) identify any significant karst features beneath the …

Design And Implementation Of Applications Over Delay Tolerant Networks For Disaster And Battlefield Environment, Karthikeyan Sachidanandam

Masters Theses

"In disaster/battlefield applications, there may not be any centralized network that provides a mechanism for different nodes to connect with each other to share important data. In such cases, we can take advantage of an opportunistic network involving a substantial number of mobile devices that can communicate with each other using Bluetooth and Google Nearby Connections API(it uses Bluetooth, Bluetooth Low Energy (BLE), and Wi-Fi hotspots) when they are close to each other. These devices referred to as nodes form a Delay Tolerant Network (DTN), also known as an opportunistic network. As suggested by its name, DTN can tolerate delays …

Controlled Switching In Kalman Filtering And Iterative Learning Controls, He Li

Masters Theses

“Switching is not an uncommon phenomenon in practical systems and processes, for examples, power switches opening and closing, transmissions lifting from low gear to high gear, and air planes crossing different layers in air. Switching can be a disaster to a system since frequent switching between two asymptotically stable subsystems may result in unstable dynamics. On the contrary, switching can be a benefit to a system since controlled switching is sometimes imposed by the designers to achieve desired performance. This encourages the study of system dynamics and performance when undesired switching occurs or controlled switching is imposed. In this research, …

Exploration For Alteration Halos Around The Ag-W Deposits In Southeastern Missouri, Usa, Daniel Joseph Warbritton

Masters Theses

"The St. Francois Mountains in SE Missouri are an extensive terrane of granitic ring complexes and associated rhyolites. They were an important source of Ag, W, and Sn and mined intermittently from the 1800s until the 1950s. The Ag-W ores occur in the Silvermine Granite and rhyolite roof rocks. The deposits are classified as a xenothermal ore system with mineralization occurring in quartz veins and surrounding greisen (up to 2.5 m). Exploration for hydrothermal ore deposits often focuses on the identification of alteration halos in the surrounding host rocks. In the vast majority of xenothermal ore deposits, such as in …

Solvation Properites Of Supercritical Carbon Dioxide Using Chirped-Pulse Fourier-Transform Microwave Spectra Of Carbon Dioxide / 1, 1-Difluoroethene (Dfe) Mixtures, Tulana Ariyaratne Subasinghe Arachchige

Masters Theses

Supercritical carbon dioxide (sc-C0₂) is a highly utilized industrial substance identified as an excellent solvent and a surfactant, which is cheaper and less hazardous than other typical solvents. The higher solubility of fluorinated hydrocarbons than their hydrocarbon (HC) analogs is not well understood and the theory behind the microsolvation of sc-C0₂ cannot be fully explained with the existing chemical information. Microwave spectroscopy is a good method of identifying the structural arrangement of clusters made from fluorinated HCs and C0₂. I n this project, microwave scans of the four different mixtures of 1 , 1-difluoroethene (DFE) …

Impacts Of Plant-Microbe Interactions On Seedling Performance In A Riparian Forest Invaded By Lonicera Maackii, Taylor E. K. Strehl

Masters Theses

Soil microbes have profound impacts on plant growth and survival and can either promote or inhibit plant dominance. Exotic plants are often strongly invasive because they have escaped their natural enemies, potentially including antagonistic soil microbes. I examined how the invasive shrub Lonicera maackii and a common native tree, Acer negundo, responded to soil microbial communities to determine the role of soil microbes in regulating invasion success. This was done by growing both species with microbes from invaded (L. maackii) and uninvaded (A. negundo) soils collected from three locations within a riparian forest. Seedlings were …

Identifying Priority Conservation Areas And Strategies For Myotis Sodalis (Chiroptera: Vespertilionidae) Via Habitat And Connectivity Modeling, Ashleigh B. Cable

Masters Theses

Myotis sodalis, the Indiana bat, is a federally endangered bat species in the United States of America (USA). Conservation efforts are typically focused at identified maternity sites at local scales, however, the species is a regional migrant that interacts with its environment at multiple spatial scales. We are limited in our knowledge of landscape-level requirements of this species, especially in large areas such as Illinois, USA, where a wide range of environmental and landscape conditions exist. Many previous M. sodalis habitat studies have limited their focus to smaller spatial scales. Due to limitations in funding, personnel, and time, it …

Synthesis Toward A Molecular Container Based On P-Tert-Butylcalix[4]Arene With Gate Features, Balasooriya Appuhamilage Dinesh Madushan Balasooriya

Masters Theses

Nowadays molecular and supramolecular chemistry have endless examples for the development of smart devices. Among those applications, nano-baskets of calixarenes play vital roles in host-guest chemistry. One of the main appealing concepts of this field is the development of host molecules with gate features. These hosts are designed and constructed for the delivery of chemical or biochemical species that are volatile, or reactive, or sensitive to normal solution environment and they are mainly functioned by predefined groups that are responsive toward stimuli such as concentration, temperature, pH and so on. In our previous study, we found that benzyl bromides can …

Complex Varieties As Minima, Richard Koss

Masters Theses

We will explore various numeric methods of finding roots of an analytic function over some open set of the complex plane. We will discuss a method of visually observing the roots, a gradient descent method for finding the roots of an analytic function, a gradient descent method for solving systems of analytic functions, and finally a method of descent that uses osculating circles to find roots of an analytic function. Of particular interest to this thesis are roots of complex polynomials. There will be examples, code snippets, and outputs of programs to illustrate all of these methods.

The Impact Of Dutch Disease: The Case Of Nigeria, Halimat Atinuke Laguda

Masters Theses

Nigeria, over the years, has been showing a rapid appreciation of the domestic currency, a rise in real wages and the service sector and a slow-down in the industrial production which are all signs of presence of Dutch disease which predicts that a country with large natural resource rents may experience a de-industrialization and a lower long term economic growth. This paper analyses the impact of Dutch disease in Nigeria Ordinary Least square method, Two-Stage Least Square and Autoregressive Distributed Lag with a system of equation from 1981 to 2017 and found that the real wage rate emphasizes on the …

Exploring The Impact Of Pretrained Bidirectional Language Models On Protein Secondary Structure Prediction, Dillon G. Daudert

Masters Theses

Protein secondary structure prediction (PSSP) involves determining the local conformations of the peptide backbone in a folded protein, and is often the first step in resolving a protein's global folded structure. Accurate structure prediction has important implications for understanding protein function and de novo protein design, with progress in recent years being driven by the application of deep learning methods such as convolutional and recurrent neural networks. Language models pretrained on large text corpora have been shown to learn useful representations for feature extraction and transfer learning across problem domains in natural language processing, most notably in instances where the …

Regional Sulfur Isotope Study Of The Vms Deposits In The Penokean Volcanic Belt, Nicholas M. Moleski

Masters Theses

The Penokean Volcanic Belt (PVB), located in northern Wisconsin and Upper Peninsula, Michigan hosts several volcanogenic massive sulfide deposits (VMS) including the well-known deposits of Flambeau and Crandon. The host rocks of the VMS deposits are Paleoproterozoic in age overlying Archean age basement rocks. This study provides δ³⁴S (VCDT) values for the following deposits within the PVB; (1) Eisenbrey, (2) Schoolhouse, (3) Bend, (4) Flambeau, (5) Reef, (6) Horseshoe, and (7) Back Forty, and explains the distribution of δ³⁴S values in the region.

The study reveals tight ranges of δ³⁴S values for each deposit …

A Structural And Stratigraphic Study Of The A-2 Carbonate In Southwest Michigan And Reservoir Characterization Of An A-2 Carbonate Gas Storage Field, Clayton Joupperi

Masters Theses

The Overisel and Salem gas storage fields of southwest Michigan annually store 34 Bcf of natural working gas in the upper dolomitized portion of the Silurian A-2 Carbonate. Porosity and permeability in these fields is thought to be enhanced by fracturing and dolomitization associated with the dissolution and collapse of underlying salt units. This study utilizes wire-line logs from 383 wells to explore the structural and stratigraphic controls on the deposition and diagenesis of the A-2 Carbonate in southwest Michigan. Core and thin sections from 4 wells serve as the primary data for investigating the depositional and diagenetic history of …

Agent Based Terrain Generator: Cruthú, Lawrence L. O'Boyle

Masters Theses

Terrain generation models are applied in different industries and fields of study. Current techniques assist in planning transportation networks, visualizing population migrations, conducting epidemiology research, and training self-driving cars and drones. Many current applications and research models generate complex realistic artifacts, e.g., trees, rivers, coastlines, populations, and even cities. Unfortunately, most of these techniques are described and implemented separately. Techniques do not work together to generate a complete holistic view. This thesis proposes a model, Cruthú (Gaelic for "creation"), that provides a novel platform allowing for complete world generation by integrating existing research and algorithms. The model is inspired by …

Use Of Fluorescein Dye For Characterizing Water And Solute Flux Across The Groundwater – Surface Water Interface, Ryan Nicholas Cascarano

Masters Theses

Quantifying groundwater discharge across the sediment—surface water interface remains a challenge due to streambed heterogeneity and the integration of disparate measurements over a continuum of spatial and temporal scales. In this study, mini-piezometers are first used to identify areas of groundwater discharge in lakes and streams, and micro-pulses of fluorescein dye are released at precisely known shallow depths as a conservative tracer. The use of fluorescein dye allows for visual dye detection regardless of light conditions, and measurements of dye concentrations over time using a fluorometer are used to generate high resolution breakthrough curves. Accurate determination of groundwater velocity and …

Computational Study Of The Nature Of Tetrel Bond, Yama Aman

Masters Theses

For more than a hundred years, the type of a chemical bond has been distinguished according to the relative electronegativities of chemical units at the ends of a bond. Whereas, the bond of unequally electronegative on both ends is called a polar covalent or even ionic bond or a non-polar covalent bond in case of both equal. Regardless the type of bonded elements, the whole idea for the bond was believed to be electron driven only. In the 20th century the development of the idea, that not just the electronic relation but specific elements are also able to characterize the …

An Investigation Of Sub-Meter Skill In Stem And Non-Stem Undergraduate Students, Laura A. Tingin

Masters Theses

This study designed a nationally-relevant, valid, and reliable survey that measures STEM and Non-STEM undergraduate student familiarity with sub-meter metric scale and common sub-meter sized science objects. The instrument assesses scalar relationship and scalar magnitude, as explained by Cheek, LaDue, and Shipley (2017). The instrument development was based on an existing Scale of Objects Questionnaire (SOQ) instrument created by Tretter, Jones, Andre, Negishi, & Minogue (2006a) which was modified to be nationally relevant and in an electronic format in two phases: online survey development and undergraduate pilot testing. Online survey development was framed in the tailored design method described by …

Deep Reinforcement Learning For Autonomous Search And Rescue, Juan Gonzalo Cárcamo Zuluaga

Masters Theses

Unmanned Aerial Vehicles (UAVs) are becoming more prevalent every day. In addition, advances in battery life and electronic sensors have enabled the development of diverse UAV applications outside their original military domain. For example, Search and Rescue (SAR) operations can benefit greatly from modern UAVs since even the simplest commercial models are equipped with high-resolution cameras and the ability to stream video to a computer or portable device. As a result, autonomous unmanned systems (ground, aquatic, and aerial) have recently been employed for such typical SAR tasks as terrain mapping, task observation, and early supply delivery. However, these systems were …

Spatio-Temporal Variability Of Precipitation And Drought In The State Of Arizona, Usa, Samuel Nimako Nyarkoh

Masters Theses

As a result of climate change, several dry regions continue to get drier as precipitation amounts decline. This decline impact water resources and hinder economic development. Understanding the variability of precipitation and drought through climatic, agricultural and hydrological studies is therefore critical to decision makers and stakeholders in developing proactive measures that promotes economic development.

This study therefore uses dataset from 55 Meteorological stations containing 110-year (1900-2010) monthly precipitation data and a series of spatial and temporal tests to investigate the spatial and temporal patterns of precipitation and drought as well as the effects of local factors such as topography …

Application Of Handheld Ed-Xrf For High-Resolution Chemostratigraphy In Texturally Homogeneous Carbonate Mudstones: Salina A-1 Carbonate (Silurian), Michigan Basin, Matthew A. Hemenway

Masters Theses

Handheld energy dispersive x-ray fluorescence spectrometry (ED-XRF) is routinely used to observe elemental variability in fine-grained siliciclastics but has been applied rarely in fine-grained carbonates. Here, ED-XRF chemostratigraphy is utilized in the texturally homogenous, mudstones of the Silurian A-1 Carbonate (A-1C), Michigan Basin. Previous studies on the A-1C focused on the stratigraphic relationship with the underlying Niagaran reefs, so little is known about the geological variability in the basin center. In this study, high-resolution elemental data from nine cores were integrated with petrographic and mineralogical observations to evaluate two hypotheses: (1) Texturally homogeneous, basin-center mudstones in the A-1C have spatially …

Synthesis And Characterization Of Fluorescent Nanojars, Vageesha Warnajith Liyana Gunawardana

Masters Theses

Self-assembly is a powerful tool utilized by synthetic chemists to create large, intricate structures for a variety of applications such as drug delivery, adaptable materials and electronics. In contrast to stepwise synthesis, this process allows the formation of intricate molecular architectures starting from synthetically rudimentary building blocks. Nanojars are class of self-assembling, cyclic copper(II) pyrazolate coordination compounds that encapsulate oxoanions with negative two or three charge. The strong anion binding characteristics of nanojars have potential towards developing novel tools for detecting biologically and environmentally relevant anions such as carbonate, sulfate and phosphate.

This work addresses the design and synthesis of …

A Survey Of Security And Privacy In Mobile Cloud Computing, Bhuvaneswari Rayapuri

Masters Theses

Cloud Computing is an emerging technology that provides shared processing resources and data to computers and other devices on demand. On the other hand, Mobile Computing allows transmission of data, voice and video. From these two there emerges a new concept Mobile Cloud Computing which not only overcomes the problems of Mobile Computing but also integrates Cloud Computing into Mobile Environments to overcome obstacles related to Performance, Security and Environment. This paper also provides a decent description on Security and Privacy, its related problems, threats and challenges. This paper first provides details on survey of Mobile Cloud Computing, then it …

Interannual Variations Of Snowfall In The Lower Peninsula Of Michigan And Impacts Of Local And Remote Meteorological Conditions, Nirjala Koirala

Masters Theses

Inter-annual variation of snowfall and its relation to climate indices will help clarify and improve the prediction of total snowfall in the Lower Peninsula of Michigan (LPM). This study examines the trend and variability of annual snowfall (November- March) using 8 homogeneous weather stations in the LPM. The statistical relationship between snowfall and air temperature, Sea Surface Temperature (SST), North Atlantic Oscillation (NAO), Pacific Decadal Oscillation (PDO) and Maximum Ice Coverage(MIC) of Lake Michigan is calculated. The long-term trend in the snowfall data set from 1950 to 2015 is removed before any statistical correlation analysis is conducted. My analysis suggests …

Determinants Of Household Water Use In The City Of Kalamazoo, Michigan: The Role Of Climate And Socioeconomic Factors, Danielle Molenaar

Masters Theses

Located in the Great Lakes Watershed, the City of Kalamazoo can be considered “water rich”. Therefore, the area has been absent from water use studies. Water use studies are beneficial in all locations; as they can aid city planners, water resource managers, and utility companies. This study examines how household monthly water use in the City of Kalamazoo is impacted by both climate and socioeconomic variables over the period 2006-2016. Household level data were aggregated into census tracts to obtain monthly tract averages for the eleven-year period. Ordinary least squares regression (OLS) was used to determine which variables impact the …

Geochemical And Petrological Investigation Of The Prospective Ni-Cu-Pge Mineralization At The Echo Lake Intrusion In The Upper Peninsula Of Michigan, Usa, Alexander J. Koerber

Masters Theses

The Echo Lake Intrusion is located in Houghton and Ontonagon counties in the Upper Peninsula (UP) of Michigan. The intrusion is approximately 200 m below the surface and covers approximately 18 km2 in lateral extent. It is associated with the magmatic activities of a 1.1 Ga geologic event called the Midcontinent Rift. The rift is responsible for the formation of Ni-Cu ± PGE deposits in the Lake Superior Region. Based on its association with the Midcontinent Rift and a Cu and PGE enriched layer, the Echo Lake intrusion is identified as a prospect for an economic magmatic sulfide deposit.

The …

Geologic Mapping Of The Bronson North And Bronson South 7.5-Minute Quadrangles, Branch County, Michigan, Karl John Backhaus

Masters Theses

This study contributes to a better understanding of the glacial history of southwest Michigan through detailed surficial geologic and bedrock topography mapping within the Bronson North and Bronson South Quadrangles in Branch County, Michigan. This project was supported during the summer of 2017 by the USGS EDMAP program in conjunction with the Michigan Geological Survey. Hand-auger borings, grain size analysis tests, passive seismic depth-to-bedrock measurements, and ground penetrating radar transects were collected for this study. There are 350 feet of bedrock relief from west to east across the quadrangles, including a bedrock cuesta of Mississippian Coldwater Shale. This cuesta underlies …

Mapping Bedrock Topography Of The Portage And Schoolcraft Nw 7.5’ Quadrangles, Kalamazoo Co. Mi, Using The Hvsr Passive Seismic Method, Benjamin B. Seiderman

Masters Theses

This study utilizes the Horizontal to Vertical Spectral Ratio (HVSR) technique to map bedrock topography in the Portage and Schoolcraft NW quadrangles, Kalamazoo Co., MI, looking for buried bedrock valleys. Glacial sediment-landform assemblages dominate the study area, due to multiple advances of the Laurentide Ice Sheet (LIS). Tunnel valleys, which are one type of buried valley, are eroded by subglacial meltwater and commonly filled with the coarser varieties of glacial outwash, making them potential aquifers. The HVSR technique measures the ratio of horizontal to vertical ground motion, excited by ambient seismic noise, resulting in a peak at the resonance frequency. …

Organocatalyzed Synthesis Of Epoxides From Chalcones Utilizing Amino Acids, Sabrina N. Kegeler

Masters Theses

The epoxide functional group is important throughout the chemical and pharmaceutical industries, as well as in nature. In the chemical industry, epoxides are present in resins and fragrances. In the pharmaceutical industry, epoxide-containing compounds are used as intermediates in the manufacturing of drugs. In nature, many natural products contain epoxide groups and are used for medicinal purposes, and for models to create synthetic molecules.

One approach to epoxide synthesis involves the use of an alkene precursor, a base, and an oxidizing agent. This is where my investigations began. The first step was to optimize the epoxidation reaction, examining substrate scope, …

Mixed-Criticality Real-Time Task Scheduling With Graceful Degradation, Samsil Arefin

Masters Theses

”The mixed-criticality real-time systems implement functionalities of different degrees of importance (or criticalities) upon a shared platform. In traditional mixed-criticality systems, under a hi mode switch, no guaranteed service is provided to lo-criticality tasks. After a mode switch, only hi-criticality tasks are considered for execution while no guarantee is made to the lo-criticality tasks. However, with careful optimistic design, a certain degree of service guarantee can be provided to lo-criticality tasks upon a mode switch. This concept is broadly known as graceful degradation. Guaranteed graceful degradation provides a better quality of service as well as it utilizes the system resource …