Physical Sciences and Mathematics Commons^™

Absolute Soft X-Ray Dosimetry For Radiation Chemistry Studies, Howard Sajon Joyner

Masters Theses

"A homogeneous, variable plate separation ion chamber consisting of a polyethylene body and employing flowing ethylene as the cavity gas has been designed and tested for the specification soft x-ray (<75kV) energy deposition in typical hydrocarbons. The variable plate separation feature provided primary data on the differential specific ionization originating within the cavity gas occupying the effective collector volume which is independent of inherent chamber inhomogeneities associated with the electrically conducting films comprizing the chamber electrodes. These data demonstrated that charged particle equilibrium is established within the first few ten thousandths of an inch in typical solid hydrocarbons irradiated with this class of sources. Comparison of this type of chamber with a fixed plate separation, static cavity gas mode of operation showed that the latter may predict dose rates with inherent errors exceeding 100%. With the quality of electronic readout accessories presently available, the variable plate separation chamber yielded dose rate data exhibiting a probable error of 3.8 percent (plus the unknown uncertainty in the literature data on the energy required to form an ion pair), and an ultimate limiting error of less than 2 percent appears feasible"--Abstract, page ii.

Error Analysis Of Rational Approximations Of Functions With Emphasis On Minimax Techniques, Mary Frances Good

Masters Theses

"This study examines the various considerations which are made when a function is approximated by a rational function. None of the four approximations considered here gives both a rapidly calculated approximation and one in which the maximum magnitude of the error function over a given interval is a minimum.

The second algorithm of Remes produces a sequence of rational approximations which converge to the rational approximation that minimizes the maximum magnitude of the error function for a given number of parameters to be calculated if the initial approximation in the sequence is chosen properly. Several rational function approximations are investigated …

Geology Of The Acari Iron Mining District Arequipa, Peru, Raul Alejandro Zevallos

Masters Theses

"The Acari Iron Mining District, part of a tilted uplifted fault block, comprises an area about 300 square kilometers, in the southern part of the coastal belt of Peru. It is in the foothills of the western range of the Andes and it is dominantly formed by granodioritic and granitic intrusive rocks which belong to the Andean batholith of Cretaceous-Tertiary age. The intrusive rocks are overlain by a central, elongated, northwest trending band, of metasedimentary and volcanic rocks

The magnetite deposits of Acari district are long, dike-shaped bodies, which fill two systems of fractures in the granodiorite intrusive, located in …

Stable Predictor-Corrector Methods For First Order Ordinary Differential Equations, Terrell Lester Carlson

Masters Theses

"Because of the wide variety of differential equations, there seems to be no numerical method which will affect the solution best for all problems. Predictor-corrector methods have been developed which utilize more ordinates in the predictor and corrector equations in the search for a better method.

These methods are compared for stability and convergence with the well known methods of Milne, Adams, and Hamming"--Abstract, page ii.

Heat Flow In The Boss Deposit Of Missouri, Don Stainbrook

Masters Theses

"Values of heat flow through a Precambrian mineral deposit were determined in the Boss area of Missouri, where 350 meters of Paleozoic sedimentary rocks overlie a complex series of rhyolite flows which have been altered and contain a copper bearing magnetite deposit. Geothermal data were obtained from a closely spaced grid of 17 diamond drill holes penetrating to depths of 1000 meters below ground surface. Temperature measurements were made at 5 meter intervals in the Precambrian section of all holes. These and thermal conductivity measurements made on representative core samples from 300 to 400 meters below the top of the …

Plant-Derived Pigments And Dyes Used By Artists, Samuel C. Rizzetta

Masters Theses

History

Uses of Biologically-derived Products in Painting

Throughout history man has relied heavily on plant-derived materials in the production of paintings. Plant products have been used to fulfill each of the material requirements of painting. The ground or surface upon which an artist applies paint -is usually of plant origin, such as woven fabrics and paper. The ancient Egyptians painted on canvas (from Linum usitatissimum L.), papyrus, (from Cyperus papyrus L.), and wood (Lucas, 1934:149-150, 201-203; Laurie, 1910:17, 31-32).

At the time of Theophilus leather parchment, preferably of horsehide, was popular for painting (Bazzi, 1960:13). After parchment, walls and wooden …

The Calculation Of The Cross-Section Of The Interaction Between Two Yang-Mills Fields, Richard A. Starr

Masters Theses

The Problem and Its Background

This thesis presents a study of the interaction between two arbitrary fields, named Yang-Mills fields¹ for their originators. The basic equations for the calculations of the Yang-Mills interaction are due to modern quantum field theory and its specific application to quantum electrodynamics.²

Much useful information can be obtained from the formulation of the dynamical equations for a classical system: for example, the classical description of the electromagnetic field, based on Maxwell's equations, leads to wave concepts. Then using this formalism as a starting point, one can proceed to the quantum theory of free …

Phase Shift Analysis Of Protons Elastically Scattered By 016 Near EP = 8.3 Mev, Glenn D. Westin

Masters Theses

Chapter I

Introduction

The study of the resonances in the scattering cross section of the p + O¹⁶ reaction can reveal information regarding the energy levels of the compound nucleus F¹⁷. The analysis is simplified because of the zero spin of the O¹⁶ nucleus. Also, the low binding energy of the proton added to O¹⁶ allows examination of the low-lying energy levels in F¹⁷.¹ The reaction has been intensively investigated at the University of Wisconsin in a series of experiments using an electrostatic accelerator as a source of protons.

The Preparation Of 5-Arylazopyrimidines, Frederic Edwin Dutton

Masters Theses

Introduction

The synthesis of 5-arylazopyrimidines was undertaken in search of potential anticancer agents.

While many azo compounds have carcinogenic activity, it has been shown by several workers in this area that some 5-arylazopyrimidines have anticancer properties. S. Hibino(1) has shown that p-(2,4,6-triamino-5-pyrimidinylazo) benzene-sulfonic acid shows promise as an effective anticancer agent when used in conjunction with 6-mercaptopurine and adrenal steroidal hormones. When tested clinically, total remission of the leukemic process was achieved in 85.7% of the cases treated. In comparison, total remission was achieved in only 57.5% of the cases treated with a mixture of 6-MP and the hormone which …

The Reaction Of Metal Hydrides With Azoacetates, Thomas H. Althuis

Masters Theses

Introduction

The term aliphatic azo compound refers to those azo compounds in which at least one of the two nitrogen atoms is linked to a tetrahedral, that is, sp³ -hybridized carbon atom. Di-imides, RN=NH, however, are not being considered. Mixed aliphatic-aromatic azo compounds are those in which one nitrogen atom is linked to an sp³ -hybridized carbon atom and the other to an aromatic sp² -hybridized carbon atom. If present, a symmetry element (point or plane) is determined by the mid-point between the two nitrogen atoms.

Study Of The Stereochemistry Of A Carbanion Generated From An Azoacetate, Nguyen Thanh Buu

Masters Theses

Introduction

The reaction of lead tetraacetate with ketohydrazones to form azoacetates has been reported recently by Iffland, Salisbury and Schafer (13) and may be represented by the following equation:

R₂C=N-NH-R' + Pb(0Ac)₄ → R₂C-N=N-R' + Pb(OAc)₂ + HOAc OAc

Of principal interest has been the base-catalyzed decomposition of an azoacetate in a protonic solvent to give a ketone, a hydrocarbon, nitrogen and an acetate salt. The following sequence of steps has been proposed to account for these products (11).

Aminomethylation And Hydroxymethylation Of 6-Mercaptopurine And 6-Alkylthiopurines, Charles P. Bryant

Masters Theses

Introduction

The Mannich reaction and hydroxymethylation were used to prepare analogs of 6-mercaptopurine as possible antimetabolites. Physical and chemical methods were used to elucidate the structures of the compounds prepared.

Nuclear Magnetic Relaxation And Diffusion In Paraffin Oil, David E. Parker

Masters Theses

Introduction

Since the introduction of the spin echoes technique by E. L. Hahn¹ many studies have been made in the determination of the spin relaxation T₂, spin-lattice relaxation T₁, and the diffusion rates in gases, liquids^2-5, and solids^6-10. Hahn's methods were later improved by Carr and Purcell¹¹. The Carr-Purcell method serves as the basic technique for this study.

Several studies have been published on the relaxation and diffusion rates in hydrocarbons¹². These studies have shown:

1. The spin relaxation time T₂, is independent of the …

The Polarizing Effects Of Inhibitors Upon The Reaction Of Iron With Hydrochloric Acid, Duane L. Mickelson

Masters Theses

Introduction

Corrosion inhibitors have been widely studied. Electrical methods of study have been utilized (7) (10) (24) and polarization curves (2) (6) (18) (26) have been plotted by many observers in studying different aspects of corrosion. In this research the measured polarizing currents a.re used strictly in an effort to find out how the corrosion inhibitors affect the anodic and the cathodic reactions.

Synthesis Of Potential Anti-Tumor Agents Related To Ethanolamine. I. Phenoxyacetic Acid Derivatives, Kenneth Wayne Rodarmer

Masters Theses

Introduction

Derivatives of phenoxyacetic acid (PAA), because of their activity as synthetic auxins, have long been of interest in the botanical sciences. PAA itself was noted (29) to have some auxin activity. However, real interest in PAA derivatives awaited the establishment of 2,4-dichlorophenoxyacetic acid (2,4-D) as a powerful, selective herbicide (12). An enormous number of PAA analogs and homologs have been investigated for their potential in the herbicide industry, and the statistical evidence from these investigations has been used as the basis for several interesting and sometimes conflicting theories of auxin mechanisms (17, 26, 23, 27).

Physiological effects of PAA …

Helianthus Annuus - The Separation And Identification Of A New Fatty Acid, Donald C. Gruber

Masters Theses

Introduction

The term "fatty acids" was first applied principally to saturated, monobasic carboxylic acids and especially to long chain acids derived from animal and vegetable oils. As time passed and the knowledge of natural fats increased, polyunsaturated, hydroxy, keto and branched chain acids were also found as constituents of these fats and oils and these also came under the heading of fatty acids. Even acids containing alicyclic substituents were found.

More recently the term 11 fatty acid" has been applied to include saturated and unsaturated monobasic carboxylic acids and several other series of substituted acids having carbon skeletons similar to …

Reaction Of Dihydropyran With Substituted Benzenesulfonyl Azides, Douglas L. Rector

Masters Theses

Introduction

The intent of this investigation was to study the addition of arylsulfonyl azides to vinyl ethers, specifically 2,3-dihydro-4H-pyran, and to establish by chemical and physical methods the structure of the adduct.

The Resource Base For Water-Oriented Recreational Areas In Coles And Cumberland Counties, Roger J. Barry

Masters Theses

No abstract provided.

Studies On The Conversion Of Indole Acetic Acid And Oxindole Acetic Acid By Hygrophorous Conicus, Barbara Ruth Patterson

Masters Theses

"The fungus, Hygrophorous conicus, produces the enzyme, indole acetic acid oxidase, when grown in the presence of indole acetic acid (IAA) or tryptamine. The IAA acts both as an inducer and a substrate for this intracellular enzyme. The product of the oxidation catalyzed by the IAA oxidase is oxindole acetic acid (OIAA). Since the IAA and OIAA absorb maximally at two different wavelengths the use of spectrophotometric analysis was possible for assaying for the IAA oxidase activity. Paper chromatography was used for qualitative identification of the IAA and OIAA. The rate of growth and the rate of formation of the …

Stereochemistry Of Chlorinated Diels-Alder Adducts, Harry R. Musser

Masters Theses

"Hexachlorocyclopentadiene and related compounds have been studied extensively in connection with Diels-Alder reactions. Many of the adducts formed are used as intermediates in insecticide syntheses. It is of interest to study the stereochemistry of the adducts of one of the hexachlorocyclopentadiene derivaites. 5,5-Dimethoxy-1,2,3,4-tetrachlorocyclopentadiene and various dienophiles, when allowed to react, yield compounds of the bridges bicyclo [2.2.1] hept-2-ene series. The study of the endo and/or exo configuration of various functional groups such as carboxyl, aldehyde, and hydroxymethyl can be related to the known exo-5-hydroxymethyl1-1,2,3,4-tetrachlorobicyclo-[2.2.1] help-2-ene-7-one"--Introduction, page [1].

An Instrument For The Measurement Of Anelastic Properties Of Glass, Thomas Frederick Miller

Masters Theses

"An inverted torsion pendulum for measuring the internal friction and dynamic shear modulus of glass fibers over an extended temperature range has been constructed and calibrated. The calibration consists of the determination of the moment of inertia. Extraneous damping losses were investigated and primary sources were found to be (1) the suspension thread, (2) the method of securing the fiber and (3) air damping. Anelastic measurements were made on an annealed vitreous silica fiber and a soda-lime-silica fiber"--Abstract, page ii.

Thermal Hydrolysis And Structure Studies On Cobalt (Ii) Acetate, Russell J. Hesch

Masters Theses

"The object of this study was to investigate the structure of cobalt (II) acetate, isolated from glacial acetic acid, without recourse to standard x-ray methods"--Introduction, page 1.

The Geology Of The Interstate Highway 244 And 44 Exchange, Kirkwood, Missouri, John Neil Thomas

Masters Theses

"During the summer of 1964, construction was completed on the intersection of Interstate Highways 244, 44 and U.S. Highway 66, one mile southwest of Kirkwood, Missouri. during the construction of the interchange, numerous artificial exposures of rocks of the middle Mississippian Meramecian Series were exposed. This provided an excellent opportunity for examining fresh exposures near the type Meramecian Series. The formations of the area were studied, and startigraphic [sic] sections were prepared from three of the more complete sections that were measured and described. The highway cuts expose complete sections of the Warsaw and Salem formations, and the lower part …

Transformations Of Tryptamine And Tryptophan By Basidiomycetes, Hsaio-Lung Cheng

Masters Theses

"The product formed from tryptamine by Trichloloma nudum was identified as indoleacetic acid (IAA) and from tryptophan by Cantharellus cibrarius as indolelactic acid (ILA). The products were extracted from the spent media with organic solvents. Purification and identification of the crystalline transformation products were accomplished by means of paper chromatography, spectrophotometry and thin layer chromatography.

The conversion of tryptamine and tryptophan was also studied in cultures of Lencopaxillus paradoxus, Pluteus granularis and Pleuatus ostreatus. Only Pluteus granularis was found to transform tryptamine into IAA. Lencopaxillus paradoxus transformed tryptamine into oxindoleacetic acid (OIAA).

Paper chromatography proved to be useful …

A Study Of Certain Conservative Sets For Parameters In The Linear Statistical Model, Roger Alan Chapin

Masters Theses

"In the case of the linear statistical model, it has been shown that under certain conditions the confidence intervals obtained by considering the parameters one at a time are conservative when used as a joint confidence region, using the product of confidences as the confidence. However, nothing had been known of how conservative they are. This research provides accurate estimates of the true confidence for these cases.

Also, it has not yet been proved that they are indeed conservative for all cases. It is thought that they are, and the results of this research support this conjecture"--Abstract, page ii.

Zinc And Copper Content Of Stream Sediment In South-Central Missouri, Shih-Cheang Cheng

Masters Theses

"Thirty samples of stream sediment from the North Fork River, Bryant Creek and related tributaries in south-central Missouri have been analyzed for cold-extractable copper, cold-extractable heavy metal, total copper and total zinc.

Cold-extractable copper varies from 0 to 10 ppm and averages less than 1 ppm; cold-extractable heavy metal varies from 3 to 30 ppm and averages 12 ppm; total copper varies from 50 to 200 ppm and averages 88 ppm; total zinc varies from 20 to 300 ppm and averages 86 ppm.

The pH of the stream water appears to have no affect on the metal content of the …

A Graphical Method Of Estimating Heat Capacities Of Hydrocarbons, Pu-Ying Liu

Masters Theses

"Heat capacity arises because the individual particles comprising a substance are able to move and thus take up kinetic energy and usually also potential energy as the temperature rises. In many substances electrons do not absorb energy until very high temperatures are reached. Thus most heat capacity effects are interpreted in terms of the motion of the atoms neglecting electronic transitions. The total internal energy of a material is, therefore, equal to the sum of the energies due to translational and rotational motion of the molecules and to the vibrational motion of the atoms making up the molecules...The objective of …

Drop Growth In A Supersaturated Vapor, Roger Buecher

Masters Theses

"Using kinetic theory and the thermodynamics of phase transitions, a method is derived for finding the growth rate and temperature increase of a droplet in water vapor which has been supersaturated by the expansion of a cloud chamber. Calculations are performed for a specific numerical example and compared to other work in this field"--Abstract, page [2].

A Terrain Study Of The Bloodland Quadrangle, Pulaski County, Missouri, Lawrence E. Mullins

Masters Theses

"This study is an investigation of the environmental conditions which affect cross country movement for tracked military vehicles on a major portion of the Fort Leonard Wood Military Reservation.

The terrain has been mapped from the trafficability standpoint by an investigation of the geology, topography, pedology and restrictive vegetation characteristics of the Bloodland seven and one-half minute quadrangle. The terrain analysis was accomplished by a combination of map study, laboratory investigation, photo interpretation, and direct field study of representative soil and vegetation types. The conclusions of this analysis are presented in the form of a cross country movement map"--Abstract, page …

An X-Ray Study Of The Lead Zirconate-Bismuth Ferrate System, Pen-Chu Chou

Masters Theses

"The lead zirconate-bismuth ferrate system was studied employing x-ray and microscopic analysis. Samples were prepared by sintering stoichiometric mixtures of the corresponding oxides followed by air quenching. The results of the analyses show the system to be probably solid solutions over the entire compositional range, although small amounts of other phases are present in some regions.

X-ray data indicate a multiple cell, orthorhombic phase, to exist over the range 100-30 mole percent PbZrO₃ . From 100-82 mole percent PbZrO₃ , the addition of BiFeO₃ reduces the distortion of the phase such that a nearly cubic x-ray pattern is obtained at …