Physical Sciences and Mathematics Commons^™

Phase Shift Analysis Of Protons Elastically Scattered By 016 Near EP = 8.3 Mev, Glenn D. Westin

Masters Theses

Chapter I

Introduction

The study of the resonances in the scattering cross section of the p + O¹⁶ reaction can reveal information regarding the energy levels of the compound nucleus F¹⁷. The analysis is simplified because of the zero spin of the O¹⁶ nucleus. Also, the low binding energy of the proton added to O¹⁶ allows examination of the low-lying energy levels in F¹⁷.¹ The reaction has been intensively investigated at the University of Wisconsin in a series of experiments using an electrostatic accelerator as a source of protons.

The Preparation Of 5-Arylazopyrimidines, Frederic Edwin Dutton

Masters Theses

Introduction

The synthesis of 5-arylazopyrimidines was undertaken in search of potential anticancer agents.

While many azo compounds have carcinogenic activity, it has been shown by several workers in this area that some 5-arylazopyrimidines have anticancer properties. S. Hibino(1) has shown that p-(2,4,6-triamino-5-pyrimidinylazo) benzene-sulfonic acid shows promise as an effective anticancer agent when used in conjunction with 6-mercaptopurine and adrenal steroidal hormones. When tested clinically, total remission of the leukemic process was achieved in 85.7% of the cases treated. In comparison, total remission was achieved in only 57.5% of the cases treated with a mixture of 6-MP and the hormone which …

The Reaction Of Metal Hydrides With Azoacetates, Thomas H. Althuis

Masters Theses

Introduction

The term aliphatic azo compound refers to those azo compounds in which at least one of the two nitrogen atoms is linked to a tetrahedral, that is, sp³ -hybridized carbon atom. Di-imides, RN=NH, however, are not being considered. Mixed aliphatic-aromatic azo compounds are those in which one nitrogen atom is linked to an sp³ -hybridized carbon atom and the other to an aromatic sp² -hybridized carbon atom. If present, a symmetry element (point or plane) is determined by the mid-point between the two nitrogen atoms.

Study Of The Stereochemistry Of A Carbanion Generated From An Azoacetate, Nguyen Thanh Buu

Masters Theses

Introduction

The reaction of lead tetraacetate with ketohydrazones to form azoacetates has been reported recently by Iffland, Salisbury and Schafer (13) and may be represented by the following equation:

R₂C=N-NH-R' + Pb(0Ac)₄ → R₂C-N=N-R' + Pb(OAc)₂ + HOAc OAc

Of principal interest has been the base-catalyzed decomposition of an azoacetate in a protonic solvent to give a ketone, a hydrocarbon, nitrogen and an acetate salt. The following sequence of steps has been proposed to account for these products (11).

Aminomethylation And Hydroxymethylation Of 6-Mercaptopurine And 6-Alkylthiopurines, Charles P. Bryant

Masters Theses

Introduction

The Mannich reaction and hydroxymethylation were used to prepare analogs of 6-mercaptopurine as possible antimetabolites. Physical and chemical methods were used to elucidate the structures of the compounds prepared.

Nuclear Magnetic Relaxation And Diffusion In Paraffin Oil, David E. Parker

Masters Theses

Introduction

Since the introduction of the spin echoes technique by E. L. Hahn¹ many studies have been made in the determination of the spin relaxation T₂, spin-lattice relaxation T₁, and the diffusion rates in gases, liquids^2-5, and solids^6-10. Hahn's methods were later improved by Carr and Purcell¹¹. The Carr-Purcell method serves as the basic technique for this study.

Several studies have been published on the relaxation and diffusion rates in hydrocarbons¹². These studies have shown:

1. The spin relaxation time T₂, is independent of the …

The Polarizing Effects Of Inhibitors Upon The Reaction Of Iron With Hydrochloric Acid, Duane L. Mickelson

Masters Theses

Introduction

Corrosion inhibitors have been widely studied. Electrical methods of study have been utilized (7) (10) (24) and polarization curves (2) (6) (18) (26) have been plotted by many observers in studying different aspects of corrosion. In this research the measured polarizing currents a.re used strictly in an effort to find out how the corrosion inhibitors affect the anodic and the cathodic reactions.

Reaction Of Dihydropyran With Substituted Benzenesulfonyl Azides, Douglas L. Rector

Masters Theses

Introduction

The intent of this investigation was to study the addition of arylsulfonyl azides to vinyl ethers, specifically 2,3-dihydro-4H-pyran, and to establish by chemical and physical methods the structure of the adduct.

Helianthus Annuus - The Separation And Identification Of A New Fatty Acid, Donald C. Gruber

Masters Theses

Introduction

The term "fatty acids" was first applied principally to saturated, monobasic carboxylic acids and especially to long chain acids derived from animal and vegetable oils. As time passed and the knowledge of natural fats increased, polyunsaturated, hydroxy, keto and branched chain acids were also found as constituents of these fats and oils and these also came under the heading of fatty acids. Even acids containing alicyclic substituents were found.

More recently the term 11 fatty acid" has been applied to include saturated and unsaturated monobasic carboxylic acids and several other series of substituted acids having carbon skeletons similar to …

Synthesis Of Potential Anti-Tumor Agents Related To Ethanolamine. I. Phenoxyacetic Acid Derivatives, Kenneth Wayne Rodarmer

Masters Theses

Introduction

Derivatives of phenoxyacetic acid (PAA), because of their activity as synthetic auxins, have long been of interest in the botanical sciences. PAA itself was noted (29) to have some auxin activity. However, real interest in PAA derivatives awaited the establishment of 2,4-dichlorophenoxyacetic acid (2,4-D) as a powerful, selective herbicide (12). An enormous number of PAA analogs and homologs have been investigated for their potential in the herbicide industry, and the statistical evidence from these investigations has been used as the basis for several interesting and sometimes conflicting theories of auxin mechanisms (17, 26, 23, 27).

Physiological effects of PAA …

Operating Characteristics Of A Cloud Chamber Suited For Condensation Measurements, Donald L. Packwood

Masters Theses

"It is the main purpose of this research to investigate the validity of using the adiabatic laws to determine the temperature from the pressure ratio. Some of the effects which might invalidate the use of the adiabatic laws will be studied. Special consideration will be given to the accurate calculation of [gamma]. Carstens' approximate calculation of the heat flow into the chamber due to conduction will be checked. A measurement will be made of how long the chamber remains adiabatic after an expansion when the continuing expansion technique is used. The static temperature gradient throughout the chamber will be measured …

A Study Of The Piezometric Surface Of The Grand Falls Formation In The Duenweg-Oronogo Mining Belt East Of Joplin, Missouri, Renny Roger Nichols

Masters Theses

"The Joplin area of Missouri, which includes the Duenweg-Oronogo belt, was a famous zinc and lead mining district. Many mines were abandoned after World War I and filled with water. These provide a large potential supply of ground water. Expansion of industries and population in the area since World War II has caused a demand for water. In 1964, the Ground Water Branch, Water Resources Division, of the United States Geological Survey began a project to study the surface and ground water resources of the area. As part of his work on this project, the author measured the piezometric level …

A Study Of Certain Conservative Sets For Parameters In The Linear Statistical Model, Roger Alan Chapin

Masters Theses

"In the case of the linear statistical model, it has been shown that under certain conditions the confidence intervals obtained by considering the parameters one at a time are conservative when used as a joint confidence region, using the product of confidences as the confidence. However, nothing had been known of how conservative they are. This research provides accurate estimates of the true confidence for these cases.

Also, it has not yet been proved that they are indeed conservative for all cases. It is thought that they are, and the results of this research support this conjecture"--Abstract, page ii.

Transformations Of Tryptamine And Tryptophan By Basidiomycetes, Hsaio-Lung Cheng

Masters Theses

"The product formed from tryptamine by Trichloloma nudum was identified as indoleacetic acid (IAA) and from tryptophan by Cantharellus cibrarius as indolelactic acid (ILA). The products were extracted from the spent media with organic solvents. Purification and identification of the crystalline transformation products were accomplished by means of paper chromatography, spectrophotometry and thin layer chromatography.

The conversion of tryptamine and tryptophan was also studied in cultures of Lencopaxillus paradoxus, Pluteus granularis and Pleuatus ostreatus. Only Pluteus granularis was found to transform tryptamine into IAA. Lencopaxillus paradoxus transformed tryptamine into oxindoleacetic acid (OIAA).

Paper chromatography proved to be useful …

The Resource Base For Water-Oriented Recreational Areas In Coles And Cumberland Counties, Roger J. Barry

Masters Theses

No abstract provided.

Carcinostatic Sulfonic Acid Esters Of Selected 1,4-Diols, Robert A. Earl

Masters Theses

Introduction

The purpose of this research was to prepare the bisarylsulfonic acid esters of 1,4-butanediol and 1,4-but-2-ynediol.

This series of compounds is of interest because of the antitumor activity exhibited by the bismethanesulfonates of 1,4-butanediol and 1,4-but-2-ynediol. The compounds which were prepared were submitted to Cancer Chemotherapy National Service Center for evaluation in their anticancer program.

It was hoped that the compounds synthesized would be of pharmacological value. It was further hoped that the biological test data of these compounds would demonstrate a correlation between types of substituents on the aromatic nucleus and the degree of activity of the compounds. …

Geology Of Pride Mine And New Standard Mine Area, Northwestern Yuma County, Arizona, Henry E. Fernandez

Masters Theses

"A thick section of presumably Precambrian gneiss with thin intercalated bands of marble and schist has been mapped. There is structural continuity within these rock types as they are mutually intercalated, conformable, have gradational relations and show equal participation in the same individual fold. The layers of schist and marble in the gneiss can be followed over long distances. These rocks have undergone intense regional metamorphism, primarily dynamic, with a possible regional compressive force generated from NW-SE giving rise to sets of folds and faults in the area. From structural, petrographic and field evidence, it is concluded that the metamorphic …

A Graphical Method Of Estimating Heat Capacities Of Hydrocarbons, Pu-Ying Liu

Masters Theses

"Heat capacity arises because the individual particles comprising a substance are able to move and thus take up kinetic energy and usually also potential energy as the temperature rises. In many substances electrons do not absorb energy until very high temperatures are reached. Thus most heat capacity effects are interpreted in terms of the motion of the atoms neglecting electronic transitions. The total internal energy of a material is, therefore, equal to the sum of the energies due to translational and rotational motion of the molecules and to the vibrational motion of the atoms making up the molecules...The objective of …

Drop Growth In A Supersaturated Vapor, Roger Buecher

Masters Theses

"Using kinetic theory and the thermodynamics of phase transitions, a method is derived for finding the growth rate and temperature increase of a droplet in water vapor which has been supersaturated by the expansion of a cloud chamber. Calculations are performed for a specific numerical example and compared to other work in this field"--Abstract, page [2].

An X-Ray Study Of The Lead Zirconate-Bismuth Ferrate System, Pen-Chu Chou

Masters Theses

"The lead zirconate-bismuth ferrate system was studied employing x-ray and microscopic analysis. Samples were prepared by sintering stoichiometric mixtures of the corresponding oxides followed by air quenching. The results of the analyses show the system to be probably solid solutions over the entire compositional range, although small amounts of other phases are present in some regions.

X-ray data indicate a multiple cell, orthorhombic phase, to exist over the range 100-30 mole percent PbZrO₃ . From 100-82 mole percent PbZrO₃ , the addition of BiFeO₃ reduces the distortion of the phase such that a nearly cubic x-ray pattern is obtained at …

A Study Of Re-Evaporation Nuclei, Ronald Dawbarn

Masters Theses

"Classical considerations of the evaporation of a homogeneously nucleated droplet in an atmosphere of low humidity, indicates complete evaporation of the drop. Experimental results however, show that there is left behind a residual nucleus that is quite stable. Condensation occurs on these nuclei at comparatively low supersaturations. Using a specially instrumented cloud chamber, experimental procedures are described which attempt to investigate some of the properties of these nuclei. Various possibilities causing this stability are examined and compared to the experimental results obtained"--page [ii].

Latent Class Analysis And Information Retrieval, George Loyd Jensen

Masters Theses

"Information retrieval may be defined roughly as a procedure to either locate or physically retrieve a document or documents containing information on a given topic with a high degree of reliability. Information retrieval is one of the newest fields in computing science. Being so new there are many unexplored areas. The research that has been done has not been standardized beyond the point of the effort which has been slanted toward solving the "Library Problem" ... Several different information retrieval methods have been suggested and some research done on them to try and solve the "Library Problem". Of these methods …

A Measurement Of Dead Space And Its Effect On The Homogeneous Nucleation Rate Of Water Vapor In Helium, Michael A. Grayson

Masters Theses

"The existence of a "dead space" surrounding each nucleated water droplet is demonstrated and measurements of its rate of development are made. The effects of this "dead space" are considered to be due to both the removal of vapor from the helium-water vapor mixture and the evolution of heat about the drop due to its growth. The results confirm the usefulness of the concept of a "dead space" and provide a means for its measurement with respect to time. Recommendations for further study and a method of correcting for dead space effects is given"--page [i].

Coprecipitation Of Metal Salts With Organic Coprecipitants, Omar E. El-Arini

Masters Theses

"Coprecipitation studies were carried out for the more insoluble salts of six common metals and five anion systems. Three metal sulfides, namely, CuS, CdS and NiS, were the only metal salts studied that indicated nearly complete coprecipitation with phenolphthalein as carrier precipitate. The same salts showed almost no coprecipitation with B-naphthol as carrier precipitate. Solvent extraction of CuS with chloroform showed no significant amount of extraction had taken place. The data obtained in this work did not disclose any relationship between the extent of coprecipitation and the solubility product constant of the salt present. The main difficulty encountered at this …

Geochemical Prospecting For Copper In The Northern Part Of Yuma County, Arizona, Abdul Razak Kasim Al-Hashimi

Masters Theses

"Geochemical prospecting for copper has been carried out in two selected areas in the northern part of Yuma County, Arizona. These areas have a few old copper mines and some other zones of mineralization. The rocks of the area range in age from Precambrian to Quaternary and consist of complex gneiss, lava flows, schists, marble, sandstone, conglomerates and some intrusive dikes. A cold-extractible [sic] field method was used to study the relation between the copper content of stream sediments in washes and the geology, mineralization, and topography of the areas. A few total copper tests were also carried out. Another …

A Parameter Perturbation Technique Applied To Multipoint Iteration Functions For The Solution Of Systems Of Nonlinear Equations, Robert N. Delozier

Masters Theses

"The convergence of classical iterative procedures, when applied to a system of nonlinear algebraic or transcendental equations, is highly dependent upon a good initial approximation to the desired roots. Most of the classical iterative schemes have convergence factors between one and two. In this paper iterative schemes of order two and greater are studied in connection with a parameter perturbation process. The parameter perturbation process relaxes the restrictions on the choice of initial values. The procedure divides each problem into a number of subsidiary problems. Each subsidiary system of equations is then solved until a solution is found to the …

Near Optimal Sequencing :N Jobs And M Machines; All Jobs To Be Processed Through The Same Order Of Machines, Larry Glen Clark

Masters Theses

"There is a need, in industry, for an efficient method of determining an optimal sequence for processing a number of jobs through two or more machines. A method which requires a minimum amount of time would be most beneficial. The purpose of this study has been to define such a method. Tests on the method described indicate that although an optimal solution is not always obtained, the solutions obtained are quite good and due to the time factor the method would be beneficial to industry"--Abstract, page ii.

Comparison Of Methods To Select A Probability Model, Howard Lyndal Colburn

Masters Theses

"A comparison is made between the estimates of the parameters in a gamma distribution obtained by the method of moments with those obtained by a numerical approximation to the maximum likelihood estimates. The estimates obtained by the numerical approximation had a smaller mean squared error from the true value than the estimates obtained by the method of moments. Modifications to tests of fit are made in order to develop methods to select a distribution from a set of possible distributions for a population with an unknown distribution. These selection methods are compared in their ability to make correct selections. Although …

Taxonomic Study Of Fossil And Recent Otoliths Of Certain Cuskeels, Gary Neal Pointer

Masters Theses

"Otoliths are calcareous structures occurring in the auditory labyrinths of teleost (bony) fishes. Three pairs of these earstones normally are found: the sagitta, in the sacculus; the asteriscus, in the lagena; and the lapillus in the utriculus. In fishes other than the Order cypriniformes (carp, catfishes, and related forms), the sagitta is the largest otolith, and it may be used in taxonomic and other studies. Fossil earstones of cuskeels (Family Ophidiiae-Brotulidae), constituting the Preophidion complex, occur in relative abundance at various levels in the Claiborne, Jackson, and Vicksburg groups of the Lower Tertiary on the Gulf Coast. The present study …

An Instrument For The Measurement Of Anelastic Properties Of Glass, Thomas Frederick Miller

Masters Theses

"An inverted torsion pendulum for measuring the internal friction and dynamic shear modulus of glass fibers over an extended temperature range has been constructed and calibrated. The calibration consists of the determination of the moment of inertia. Extraneous damping losses were investigated and primary sources were found to be (1) the suspension thread, (2) the method of securing the fiber and (3) air damping. Anelastic measurements were made on an annealed vitreous silica fiber and a soda-lime-silica fiber"--Abstract, page ii.