Physical Sciences and Mathematics Commons^™

A Model Of An Environmental Advisory Committee For City Government, Henry Barrett Baker

Masters Theses

No abstract provided.

Imbedding Cayley Graphs, Brian L. Garman

Masters Theses

No abstract provided.

A Generalized Dirac Equation With Spin I, Tilahun Eneyew

Masters Theses

No abstract provided.

Operation And Maintenance Of An Accelerator For Neutral Bombardment Level-Crossing Spectroscopy, James Vincent Morford

Masters Theses

The accelerator is equipped with a charge exchange canal so that a well collimated energetic neutral hydrogen beam is produced This beam will be used to produce excited states of atoms which will be studied by level-crossing spectroscopy. Both theoretical and—experimental predictions of the beam composition and focus ar presented.

Ortho-Substituent Effects On Reactivities Of Benzohydroxamic Acids, Irl E. Ward

Masters Theses

No abstract provided.

An Algorithm For Minimizing The Riding Time Of Students On School Buses., Dennis Ray Morgan

Masters Theses

"This thesis presents an algorithm which selects from a given set of stops a subset of stops corresponding to a given bus which minimize the riding time of students in going to and from school. The time required in picking up students at their stops and delivering them to school is analyzed. An example is given which illustrates the formulation of a problem and the results obtained from the solution. Finally, the program which was used in the solution of the problem is given along with its implementation"-- Abstract, p. ii

Barometric And Pump Test Determination Of The Characteristics Of A Carbonate Aquifer In The Vicinity Of Norman Creek, Phelps County, Missouri., Somchai Wongsawat

Masters Theses

"Carbonate rock aquifers underlie many parts of Missouri. As population and water use increase, these aquifers will increase in importance as sources of water supply. The purpose of this study is to investigate the applicability of barometric calculations and a variety of pump test evaluation equations to a shallow confined doloii mite aquifer. The aquifer is the upper Gasconade Formation of Lower Ordovician age in the vicinity of Norman Creek, south central Phelps County, Missouri.

The response of water level to atmospheric pressure showed that the carbonate aquifer in this study site has a rather high barometric efficiency (B_{av …}

Linear Geometry, Phyllis L. Thomas

Masters Theses

"This paper contains material suitable for a one semester course in linear geometry where the student has had a one semester course in linear algebra previously. It compiles information in the areas of affine sets, affine geometry, convex sets, and a few applications. Also included are Caratheodory's theorem and the well-known theorem by Helly as proved by Radon"--Abstract, page ii.

A Study Of The Subsurface Stratigraphy Of The Upper Cambrian In Western Missouri, Joseph L. Thacker Jr.

Masters Theses

"Megascopic examination of diamond-drill cores supplemented by insoluble residue data provides a usable means of studying the lithologic characteristic of Upper Cambrian strata in the subsurface of western Missouri.

The stratigraphic relationships within each Cambrian formation and the relationships of each Cambrian unit to formations above and below are discussed.

The relationship of Upper Cambrian strata to the Precambrian surface in western Missouri and easternmost Kansas is illustrated. The Lamotte Sandstone is overlapped by the Reagan Sandstone against Precambrian topographic highs and the Bonneterre and lower Davis are replaced by sandstones similar to the Reagan in southwest Missouri and southeast …

Metal Salt Catalyzed Carbenoids The Catalysts In Trialkyl Phosphite Copper (I) Complex Catalyzed Decomposition Of Diazo Compounds, Nguyen Van Thinh

Masters Theses

"Partial rate data, asymmetric induction studies, interrupted experiments and additives studies indicate that copper(I) salt-phosphite complexes are destroyed during the course of reactions with dimethyl diazomalonate (1) and ethyl diazoacetate (2). All evidence is consistent with the copper(I) being oxidized to copper(II) and copper(0) being oxidized by impurities in the olefin which most probably are hydroperoxides.

Several new copper(I) salt-phosphite complexes were prepared and examined but none proved as effective for decomposing (1) as copper(II) bis acetylacetonate.

The utility of the copper (I) chloride-trimethyl phosphite complex for decomposing (1) is a function of the means of preparation. The three general …

Rate Of Growth As A Method Of Assessing Water Quality, George L. Johnston

Masters Theses

A study of the Embarras River basin was conducted to determine if rate of growth could be used as an indicator of water quality. Six species of sucker were collected from five locations using hand seines and electrofishing gear from December 1970 to December 1971. Tests of eighteen water quality parameters were conducted from November 1970 to November 1971.

The fish were measured and scale samples taken. The rate of growth of the fish taken at the five stations was analyzed and compared using the single classification analysis of variance. Condition factors were also compared.

Although there was some difference …

A Numerical Study Of Ordinary Differential Equations With Periodic Coefficients, Richard Bruce Schuessler

Masters Theses

"In this thesis a method for solving ordinary differential equations with periodic coefficients is derived. In addition, by utilization of Floquet theory, a theorem is given by which it is possible to determine the stability of the zero solution. Error bounds are given for the method and for the two dimensional case bounds are given for the error in the eigenvalues. Several numerical examples are given to illustrate the method"--Abstract, page ii.

A Computational Method For Determining The Growth Rates Of Saline Water Drops., Robert Alexander Fletcher

Masters Theses

"A phenomenologica1 theory is presented which describes the growth or evaporation of cloud droplets containing dissolved NaCl. The main interest is in the early stages of growth. The Maxwell-Fuchs equation is employed with refinements to account for the high sa1t concentration in small droplets. A computer program is presented that ca1culates the growth time as a function of radius for cloud droplets nucleated with NaCl.

The growth times obtainable from the Maxwe11-Fuchs equation differ significantly from the growth times ca1culated using the refined Maxwell-Fuche equation for ambient relative humidities less than or equal to 100%. Growth times for droplets nucleated …

A Kinetic Study Of The Cerium (Iv)-Oxalic Acid System In Acidic Sulfate Media., Robert Richard Kessler

Masters Theses

"The kinetics of the cerium (IV) oxidation of oxalic acid was studied by a stopped-flow spectrophotometric technique in acidic sulfate media. The media consisted of perchloric acid, sodium sulfate and sodium perchlorate which allowed for the determination and control of the various sulfate and hydroxo species of cerium (IV) at prescribed hydrogen ion concentrations. The rate of reaction decreases rapidly with increasing sulfate concentration which yields evidence against previous reports indicating Ce (SO₄)₂ and Ce (SO₄)^2-₃ as the reactive cerium (IV) species. The results indicate that Ce (SO₄)²⁺ is the …

Metal Promoted Reactions Of Enamino Ketones, Suhas Satchidanand Joshi

Masters Theses

The reaction of 4-amino-3-allyl-3-penten-2-one (7) with mercuric acetate in acetic acid was found to produce 4-amino-1-pentene (12) in 70% yield. The scope of this unusual cleavage reaction was investigated by systematic variation of substituents on the enamino ketone framework, the metal salt and the solvent. The presence of the allyl group was necessary for the reaction to produce compound 12.

Under a variety of conditions there was no evidence for cyclization of 7 to give heterocyclic compounds. Neither was there evidence for cyclization in reactions of 4-amino-3-penten-2-one with vinyl acetate in the presence of mercury (II) or thallium (III) salts …

Pesticide Effects In A Simulated Soil Ecosystem, Raymond J. Samp

Masters Theses

The screening of pesticides to determine which were most inhibitory to bacteria was accomplished by testing the effects of 10 pesticides on 9 different organisms using the disk assay method. Results showed that Gram positive bacteria were more sensitive to all pesticides tested than were the Gram negative bacteria. In addition, the hormone herbicides were found to be the most inhibitory to these bacteria and 2,4-D (2,4-dichlorophenoxyacetic acid), a hormone herbicide, was chosen for subsequent in vivo studies.

A soil perfusion apparatus was used to determine the effects of 2,4-D in a typical soil ecosystem. Bacterial plate counts and nutrient …

A Survey Of The Water Quality And Fishes Of Rocky Branch Nature Preserve, Clark County, Illinois, Larry J. Decker

Masters Theses

No abstract provided.

The Water Quality And Benthic Macroinvertebrate Fauna Of Lake Charleston, Coles County, Illinois, Paul Barding

Masters Theses

The benthic macroinvertebrate fauna and 15 water quality parameters for five sites on Lake Charleston, Coles County, Illinois were examined for 26 weeks from March 14 through September 5, 1974. None of the water quality parameters studied showed sufficient deviations at any particular area on the lake to merit demarcated water quality zonation. The lake, with its continuous mixing and shallow depth, represented a fairly stable and continuous environment. The benthic macroinvertebrate fauna was determined as fairly diverse and some indication of seasonal variation was apparent. No significant compositional variation over different areas of the lake was found, also indicating …

Conodonts Of The Mecca Quarry Shale, Timothy Charles O'Neill

Masters Theses

Conodonts were found to be abundant in the Middle Pennsylvanian, Mecca Quarry Shale, Parke County, Indiana. Nine forms were identified in this black fissile shale from a locality along Montgomery Creek near the town of Mecca. These elements are: Hindeodella parva, Idiognathodus delacatus, Gondolella sp. a, Ozarkodina delacatula, Lonchodina clarki, Ligonodina typa, Lonchodus simplex, Metalonchodina bidentata, and Neoprioniodus conjunctus.

Ratios of elements to each other were determined and used to arrive at an idea of what conodont assemblages were present. At least three asemblages are presented; Scottognathus, Duboisella, and Illinella …

Mechanism Of Solvolysis Of 3-Methyl-2-Butyl Brosylates., Luu Le Nghi

Masters Theses

"The brosylates of 3-methyl-2-butanol and it's a-d₁-, ß-d₁-, B-d₃-, and S-d₄- analogs have been synthesized. The solvolytic rate data for these compounds were determined. The solvolytic products in 70% (vol.) ethanol-water have been identified by flame ionization gas chromatography using a Carbowax 20M column. The amount of each product was measured by integrating the peak areas from the chromatograms. By analyzing the isotope effect data, the rate determining step is shown to be the formation of the hydrogen bridged ion pair intermediate. By evaluating the GC-mass spectral analysis of the isopentenes, a …

The Completions Of Local Rings And Their Modules., Christopher Scott Taber

Masters Theses

"This paper gives a generally self-contained introduction to the completions of local rings and their modules. The '.Fbrmal Power Series, the Ideal-adic, and the Projective Limit completions are established, and the conditions under which they are equivalent are also given. In addition, two methods of obtaining the completion of an R-module from the completion of the ring Rare supplied. As an ideal of R may also be taken as an R-module, a discussion of obtaining its completion from the completed ring is also provided. Two well-known examples are furnished in this paper"--- Abstract, p. ii

Models For Molecular Vibration, Allan Bruce Capps

Masters Theses

“The purpose of the investigation is to determine if a classical model can be used to characterize molecular vibrational and librational (restricted rotation) frequencies. In general, the model treats a molecule as asymmetrical and rigid and simulates the intermolecular forces by springs along the bonds. Molecules constrained to a plane and molecules free to move in three dimensions are analyzed. The frequencies of water molecules are investigated, in particular. The model and analytic components are found to function well. Within the limits set for the model, the water molecule simulation is not successful as the motion becomes anharmonic for energy …

Comparison Of Scatter Storage Techniques Using An Analysis Of Variance Model, Robert Lee Kitsch

Masters Theses

"An analysis of variance model is developed to determine if a significant difference exists between various scatter storage techniques. The model is a two-factor hierarchical mixed design with each combination of transformation and search method considered as a treatment. The data used in the analysis is obtained from a computer program which provides statistics on the number of probes needed to load the (k+l)st item into a table for the different treatments. An ANOVA table was then computed for various load factors.

A significant difference among the treatments was detected for load factors above .4. Comparison of individual treatments using …

A Study On Two Iodine Containing Peptides Isolated From Porcine Thyroglobulin, Frederick E. Bishop Jr.

Masters Theses

"Two iodopeptides were isolated from thyroglobulin that had been digested with trypsin by paper electrophoresis and paper chromatography. The amino acid analysis demonstrated that the amino acid compositions were similar. The N-terminal amino acid of both iodopeptides was shown to be leucine. The amino acid sequence of one of the iodopeptides was determined by the Edman degradation method and digestion with the enzyme Carboxypeptidase A. The sequence was shown to be: NH₂-Leu-Asn-Ala-Ser-Glu-MIT-Gly-Thr-Ser-Gly-COOH. Other workers have shown that synthetic tyrosyl peptides with the sequence Glu-Tyr are iodinated by the thyroid peroxidase enzyme with a greater specificity than other tyrosyl peptides. This …

Interpretation Of Imagery Lineations, Logan Creek Area, Southeast Missouri, Gregory Paul Smith

Masters Theses

"Depletion of ore in Missouri's old lead districts and the opening of the state's new lead district adds impetus to understanding and delineating geologic structure in and adjacent to the new lead district. Image and geomorphic analysis, hydrologic data, and subsurface structural contour mapping are used in interpretation of geologic structure in Dent, Shannon, Reynolds, and Carter counties, Missouri. Unlike the time consuming surface geologic mapping, the modes of investigation used in this study enabled the writer to make a larger, regional-scale study with results comparable to those attainable by surface mapping. The area is covered by thick residual soils …

An Analysis Of The Bourbeuse River As A Source Of Concrete Aggregate., David John Lexa

Masters Theses

"This thesis represents a study made to evaluate the sand and gravel deposits of the Bourbeuse River as a source of concrete aggregate. The Meramec River has long been a major source of aggregate in Missouri; however, proposed dam construction will limit the quantity available for exploitation. The Bourbeuse River, a tributary of the Meramec, was chosen for evaluation as an alternate source.

The study was conducted in two parts: an estimation of available quantity; a determination of the quality of the material. Quantity of material was estimated through an analysis of drill logs, correlated with the results of basic …

Heavy And Alkali Metal Content Of Surface And Ground Waters In The Joplin Area, Missouri., Edwin Joseph Garrison

Masters Theses

"Over 50 water samples were collected in the fall and spring from springs, streams, lakes and selected water wells within a radius of six miles from the population center of Joplin, Missouri, which lies within the formerly active Tri-State mining district. The samples were analyzed for Ca, Mg, Na, K, Cu, Pb, Zn, Cd, Fe and Hg. Water well samples represent deep (Cambrian-Ordovician) and shallow (Mississippian) rock sources. Statistical evaluations of the data were conducted to help delineate the patterns and causes of metal variations.

The Ca, Mg, Na, K, Zn and Fe concentrations, listed in descending order of abundance, …

Charge Transfer Between H ˉIons And O₂ Molecules And D ˉIons And O₂ Molecules In The Ground State., Paul Edgar Chaplin

Masters Theses

"This thesis has been prepared in the style utilized by the Physical Review A. Pages 1-17 will be presented for publication in that journal. Appendices I, II, III, and IV have been added for purposes normal to thesis writing"-- Abstract, p. ii

Mercury Distribution In A Massive Sulfide Ore Deposit At Balmat, New York, David Ray Jessey

Masters Theses

"Ore samples consisting of diamond drill core and mine samples, collected from several Balmat ore bodies, were analyzed for their mercury content. The average contents in these ore bodies were found, in ppb, to be: Upper Gleason, 829; Middle and Lower Gleason, 504; Loomis, 546; Fowler, 195; No. 1 Zone, 37; Sylvia Lake, 59; No. 2 Mine, 5. If all of the mercury in these pyrite-sphalerite-galena ores occurs in the sphalerite, then the average sphalerite mercury contents, in ppb, are the following: Upper Gleason, 2490; Middle and Lower Gleason, 2516; Loomis, 2701; Fowler, 1376; No.1 Zone, 384; Sylvia Lake, 408; …

Campground Usage And User Attitudes In The Allegan State Game Area, Allegan County, Michigan, Gregg R. Squire

Masters Theses

No abstract provided.