Physical Sciences and Mathematics Commons^™

Prescribed-Time Nash Equilibrium Seeking For Pursuit-Evasion Game, Lei Xue, Jianfeng Ye, Yongbao Wu, Jian Liu, D. C. Wunsch

Electrical and Computer Engineering Faculty Research & Creative Works

Dear Editor, this letter is concerned with prescribed-time Nash equilibrium (PTNE) seeking problem in a pursuit-evasion game (PEG) involving agents with second-order dynamics. In order to achieve the prior given and user-defined convergence time for the PEG, a PTNE seeking algorithm has been developed to facilitate collaboration among multiple pursuers for capturing the evader without the need for any global information. Then, it is theoretically proved that the prescribed-time convergence of the designed algorithm for achieving Nash equilibrium of PEG. Eventually, the effectiveness of the PTNE method was validated by numerical simulation results.

Visible-Light Photocatalytic C-H Amination Of Arenes Utilizing Acridine-Lewis Acid Complexes, Matthew R. Lasky, En Chih Liu, Matthew S. Remy, Melanie S. Sanford

Chemistry Faculty Research & Creative Works

This report describes the development of a visible-light photocatalytic system for C(sp²)-H amination that leverages in situ-generated photocatalysts. We demonstrate that the combination of acridine derivatives and Lewis acids form potent photooxidants that promote the C-H amination of electronically diverse arenes upon irradiation with visible-light (440 nm). A first-generation photocatalyst composed of Sc (OTf)₃ and acridine effects the C-H amination of substrates with oxidation potentials ≤ +2.5 V vs SCE with pyrazole, triazole, and pyridine nucleophiles. Furthermore, the simplicity and modularity of this system enable variation of both Lewis acid and acridine to tune reactivity. This enabled …

Prevention Of Web Scraping And Copy And Paste Of Content By Font Obfuscation, Mingkui Wei, Yao Liu, Zhuo Lu, Junjie Xiong

Computer Science Faculty Research & Creative Works

A method and system provide and utilize obfuscated fonts for displayable content. Responsive to a request for displayable content having text, a text portion of the requested displayable content to be obfuscated is determined. For that text portion, obfuscated fonts are provided, by retrieving obfuscated fonts or by generating obfuscated fonts from a set of obfuscated glyphs created from a plurality of glyphs representative of a plurality of characters of the text portion of the displayable content. The obfuscated fonts can be created by assigning obfuscated glyphs of the set into the obfuscated fonts in accordance with one or more …

Advancing Simultaneous Extraction And Sequential Single-Particle Icp-Ms Analysis For Metallic Nanoparticle Mixtures In Plant Tissues, Lei Xu, Xingmao Ma, John Yang, Joel G. Burken, Paul Ki-Souk Nam, Honglan Shi, Hu Yang

Civil, Architectural and Environmental Engineering Faculty Research & Creative Works

Engineered Nanoparticles (ENPs) Have Been Increasingly Used in Agricultural Operations, leading to an Urgent Need for Robust Methods to Analyze Co-Occurring ENPs in Plant Tissues. in Response, This Study Advanced the Simultaneous Extraction of Coexisting Silver, Cerium Oxide, and Copper Oxide ENPs in Lettuce Shoots and Roots using Macerozyme R-10 and Analyzed Them by Single-Particle Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). Additionally, the Standard Stock Suspensions of the ENPs Were Stabilized with Citrate, and the Long-Term Stability (Up to 5 Months) Was Examined for the First Time. the Method Performance Results Displayed Satisfactory Accuracies and Precisions and Achieved Low Particle Concentration …

Scalable Pythagorean Mean-Based Incident Detection In Smart Transportation Systems, Md Jaminur Islam, Jose Paolo Talusan, Shameek Bhattacharjee, Francis Tiausas, Abhishek Dubey, Keiichi Yasumoto, Sajal K. Das

Computer Science Faculty Research & Creative Works

Modern smart cities need smart transportation solutions to quickly detect various traffic emergencies and incidents in the city to avoid cascading traffic disruptions. to materialize this, roadside units and ambient transportation sensors are being deployed to collect speed data that enables the monitoring of traffic conditions on each road segment. in this article, we first propose a scalable data-driven anomaly-Based traffic incident detection framework for a city-scale smart transportation system. Specifically, we propose an incremental region growing approximation algorithm for optimal Spatio-temporal clustering of road segments and their data; such that road segments are strategically divided into highly correlated clusters. …

Excellent Bifunctional Oxygen Evolution And Reduction Electrocatalysts (5a1/5)Co2o4 And Their Tunability, Xin Wang, Harish Singh, Manashi Nath, Kurt Lagemann, Katharine Page

Chemistry Faculty Research & Creative Works

Hastening the Progress of Rechargeable Metal-Air Batteries and Hydrogen Fuel Cells Necessitates the Advancement of Economically Feasible, Earth-Abundant, Inexpensive, and Efficient Electrocatalysts Facilitating Both the Oxygen Evolution Reaction (OER) and Oxygen Reduction Reaction (ORR). Herein, a Recently Reported Family of Nano (5A1/5) Co2O4 (A = Combinations of Transition Metals, Mg, Mn, Fe, Ni, Cu, and Zn) Compositionally Complex Oxides (CCOs) [Wang Et Al., Chemistry of Materials, 2023, 35 (17), 7283-7291.] Are Studied as Bifunctional OER and ORR Electrocatalysts. among the Different Low-Temperature Soft-Templating Samples, Those Subjected to 600 °C Post annealing Heat Treatment Exhibit Superior Performance in Alkaline Media. One …

Hls Taking Flight: Toward Using High-Level Synthesis Techniques In A Space-Borne Instrument, Marion Sudvarg, Chenfeng Zhao, Ye Htet, Meagan Konst, Thomas Lang, Nick Song, Roger D. Chamberlain, Jeremy Buhler, James H. Buckley

Computer Science Faculty Research & Creative Works

FPGAs are widely deployed on high-energy astrophysics telescopes to preprocess and reduce sensor data read out by front-end electronics. Across instruments, these computational pipelines have similar semantics, sharing common stages such as pedestal subtraction, signal integration, zero-suppression, island detection, and centroiding. However, diverse telescope designs require unique implementations of these algorithms, and the logic is often rewritten from scratch for a new instrument. As an alternative, High-Level Synthesis (HLS) tools enable these algorithms to be implemented in a high-level language, which eases modifications and enables fast prototyping and deployment. Nonetheless, writing performant HLS code requires augmentation of the code with …

Statistical Modeling Of Right-Censored Spatial Data Using Gaussian Random Fields, Fathima Z. Sainul Abdeen, Akim Adekpedjou, Sophie Dabo Niang

Mathematics and Statistics Faculty Research & Creative Works

Consider a Fixed Number of Clustered Areas Identified by their Geographical Coordinates that Are Monitored for the Occurrences of an Event Such as a Pandemic, Epidemic, or Migration. Data Collected on Units at All Areas Include Covariates and Environmental Factors. We Apply a Probit Transformation to the Time to Event and Embed an Isotropic Spatial Correlation Function into Our Models for Better Modeling as Compared to Existing Methodologies that Use Frailty or Copula. Composite Likelihood Technique is Employed for the Construction of a Multivariate Gaussian Random Field that Preserves the Spatial Correlation Function. the Data Are Analyzed using Counting Process …

Dimensional Regularization And Two-Loop Vacuum Polarization Operator: Master Integrals, Analytic Results, And Energy Shifts, Stefano Laporta, Ulrich D. Jentschura

Physics Faculty Research & Creative Works

We Present a Complete Reevaluation of the Irreducible Two-Loop Vacuum-Polarization Correction to the Photon Propagator in Quantum Electrodynamics, i.e. with an Electron-Positron Pair in the Fermion Propagators. the Integration is Carried Out by Reducing the Integrations to a Limited Set of Master Integrals, Which Are Calculated using Integration-By-Parts Identities. Dimensional Regularization is Used in D=4-2ϵ Dimensions, and On-Mass Shell Renormalization is Employed. the One-Loop Effect is Given to Order ϵ, to Be Combined with the 1/ϵ Divergence of the Two-Loop Amplitude. Master Integrals Are Given. Final Evaluations of Two-Loop Energy Shifts for 1S, 2S, and 2P States Are Done Analytically, …

Crystallographic Defects In Weyl Semimetal Laalge, Inseo Kim, Byungkyun Kang, Hyunsoo Kim, Minseok Choi

Physics Faculty Research & Creative Works

Crystallographic Defects in a Topological Semimetal Can Result in Charge Doping and Scattering Centers Which May Mask the Exotic Spectroscopic and Transport Properties, respectively. Here, We Investigate the Possible Crystallographic Defects Including Vacancy and Antisite in Weyl Semimetal LaAlGe using Hybrid-Density-Functional Theory Calculations. We Show that a Considerable Concentration of Al- and Ge-Related Defects Naturally Form during Growth Due to their Low Formation Enthalpy. Specifically, Al Can Be Easily Replaced by Ge in the I41md Phase of LaAlGe, Forming the Ge-On-Al Antisite, GeAl. the Counterpart, Al-On-Ge (AlGe), is Also Probable. the Most Abundant Defect GeAl is Donorlike, Effectively Electron Doping, …

Scalar Susceptibility Of A Diluted Classical Xy Model, Reece Beattie-Hauser, Thomas Vojta

Physics Faculty Research & Creative Works

We Analyze the Amplitude Fluctuations in a Diluted 3D Classical XY Model Near the Magnetic Phase Transition, motivated by the Unusual Localization Properties of the Amplitude (Higgs) Mode Recently Found at the Disordered Superfluid-Mott Glass Quantum Phase Transition. We Calculate the Amplitude Correlation Function and the Corresponding Scalar Susceptibility by Means of Monte Carlo Simulations. in Contrast to the Quantum Case, in Which the Scalar Susceptibility Was Found to Violate Naive Scaling, We Find that the Scalar Susceptibility of the Classical System Fulfills Naive Scaling (Employing the Clean Critical Exponents, as Expected from the Harris Criterion) as the Temperature is …

Exploring The Coronal Magnetic Field With Galactic Cosmic Rays: The Sun Shadow Observed By Hawc, R. Alfaro, C. Alvarez, J. C. Arteaga-Velázquez, K. P. Arunbabu, D. Avila Rojas, R. Babu, E. Belmont-Moreno, K. S. Caballero-Mora, T. Capistrán, A. Carramiñana, S. Casanova, P. Colín-Farias, U. Cotti, J. Cotzomi, S. Coutiño De León, E. De La Fuente, C. De León, D. Depaoli, R. Diaz Hernandez, J. C. Diaz-Velez, M. Durocher, M. A. Duvernois, K. Engel, C. Espinoza, K. L. Fan, N. Fraija, J. A. Garcia-Gonzalez, F. Garfias, A. Gonzalez Munoz, M. M. Gonzalez, J. A. Goodman, J. P. Harding, D. Huang, F. Hueyoyl-Zahuantitla, A. Iriarte, S. Kaufmann, A. Lara, J. Lee, H. Leon Vargas, A. L. Longinotti, G. Luis-Raya, K. Malone, O. Martinez, J. Martinez-Castro, J. A. Matthews, P. Miranda-Romagnoli, E. Moreno, M. Mostafa, A. Nayerhoda, L. Nellen, T. Niembro, R. Noriega-Papaqui, N. Omodei, E. G. Perez-Perez, C. D. Rho, D. Rosa-Gonzalez, E. Ruiz-Velasco, J. Ryan, H. Salazar, D. Salazar-Gallegos, A. Sandoval, J. Serna-Franco, A. J. Smith, Y. Son, R. W. Springer, O. Tibolla, K. Tollefson, I. Torres, R. Turner, F. Urena-Mena, E. Varela, L. Villasenor, Xiaojie Wang, I. J. Watson, E. Willox, S. Yun-Carcamo, H. Zhou

Physics Faculty Research & Creative Works

Galactic cosmic rays (GCRs) are charged particles that reach the heliosphere almost isotropically in a wide energy range. In the inner heliosphere, the GCR flux is modulated by solar activity so that only energetic GCRs reach the lower layers of the solar atmosphere. In this work, we propose that high-energy GCRs can be used to explore the solar magnetic fields at low coronal altitudes. We used GCR data collected by the High-Altitude Water Cherenkov observatory to construct maps of GCR flux coming from the Sun's sky direction and studied the observed GCR deficit, known as Sun shadow (SS), over a …

Russian Verbs Of Sound’S Web-Scraping Results From The A.A. Zalizniak Grammatical Dictionary And The Russian National Corpus. Multi-Dimensional Scaling Techniques And Visualization Strategies, John Simmons, Irina V. Ivliyeva

Graduate Student Research & Creative Works

This project aims to enhance web extraction techniques pertaining to a specific lexical-semantic group of Russian verbs of sounds, which undergo semantic modifications at the word-formation level (affixation). Additionally, it seeks to organize search results in a manner conducive to linguistic research using Multi-Dimensional Scaling (MDS) techniques and novel visualization strategies.

The primary objective in this phase of the research was to gather, consolidate, analyze, and present a comprehensive index of all forms of verbs of sound sourced from the A.A. Zalizniak Grammatical Dictionary of the Russian language, hyperlink each verbal form in this index with the Russian National Corpus …

Rotational Spectrum, Structure, And Quadrupole Coupling Of Cyclopropylchloromethyldifluorosilane, Alexander R. Davies, Abanob G. Hanna, Alma Lutas, Gamil A. Guirgis, Garry S. Grubbs

Chemistry Faculty Research & Creative Works

Cyclopropylchloromethyldifluorosilane, C-C3H5SiF2CH2Cl, Has Been Synthesized, and its Rotational Spectrum Has Been Recorded by Chirped-Pulse Fourier Transform Microwave Spectroscopy. the Spectral Analysis of Several Isotopologues Indicates the Presence of Two Distinct Conformations in the Free-Jet Expansion, Which Are Interconvertible through a Rotation of the Chloromethyl Group. a Partial Substitution Structure is Presented for the Lower Energy Conformation and is Compared to the Equilibrium Structure Obtained from Quantum Chemical Calculations. Additionally, the Presence of the Chlorine Nucleus Leads to the Rotational Transitions Splitting into Multiple Hyperfine Components and Χaa, a Measure of the Electric Field Gradient Along the a Axis, is Unusually …

Rainbowcake: Mitigating Cold-Starts In Serverless With Layer-Wise Container Caching And Sharing, Hanfei Yu, Rohan Basu Roy, Christian Fontenot, Devesh Tiwari, Jian Li, Hong Zhang, Hao Wang, Seung Jong Park

Computer Science Faculty Research & Creative Works

Serverless Computing Has Grown Rapidly as a New Cloud Computing Paradigm that Promises Ease-Of-Management, Cost-Efficiency, and Auto-Scaling by Shipping Functions Via Self-Contained Virtualized Containers. Unfortunately, Serverless Computing Suffers from Severe Cold-Start Problems - -Starting Containers Incurs Non-Trivial Latency. Full Container Caching is Widely Applied to Mitigate Cold-Starts Yet Has Recently Been Outperformed by Two Lines of Research: Partial Container Caching and Container Sharing. However, Either Partial Container Caching or Container Sharing Techniques Exhibit their Drawbacks. Partial Container Caching Effectively Deals with Burstiness While Leaving Cold-Start Mitigation Halfway; Container Sharing Reduces Cold-Starts by Enabling Containers to Serve Multiple Functions While Suffering …

Vt-Nmr Analysis Of Rotation-Inversion Of N-(4-Hydroxybutyl)-N-(2,2,2-Trifluoroethyl) Tert-Butyl Carbamate: Utilizing The −Ch2cf3 Appendage As A Reporter On E/Z-Isomerization, Brian Jameson, Rainer Glaser

Chemistry Faculty Research & Creative Works

The rotational barrier about the CN carbamate bond of N-(4-hydroxybutyl)-N-(2,2,2-trifluoroethyl) tert-butyl carbamate 1 was determined by variable temperature (VT) 13C and 19F NMR spectroscopy. The −CH2CF3 appendage reports on rotational isomerism and allows for the observation of separate signals for the E- and Z-ensembles at low temperature. The activation barrier for E/Z-isomerization was quantified using Eyring-Polanyi theory which requires the measurements of the maximum difference in Larmor frequency Δνmax and the convergence temperature Tc. Both Δνmax and Tc were interpolated by analyzing sigmoidal functions fitted to data describing signal separation and the quality of the superposition of the E- and …

Drone-Based Bug Detection In Orchards With Nets: A Novel Orienteering Approach, Francesco Betti Sorbelli, Federico Coró, Sajal K. Das, Lorenzo Palazzetti, Cristina M. Pinotti

Computer Science Faculty Research & Creative Works

The Use of Drones for Collecting Information and Detecting Bugs in Orchards Covered by Nets is a Challenging Problem. the Nets Help in Reducing Pest Damage, But They Also Constrain the Drone's Flight Path, Making It Longer and More Complex. to Address This Issue, We Model the Orchard as an Aisle-Graph, a Regular Data Structure that Represents Consecutive Aisles Where Trees Are Arranged in Straight Lines. the Drone Flies Close to the Trees and Takes Pictures at Specific Positions for Monitoring the Presence of Bugs, But its Energy is Limited, So It Can Only Visit a Subset of Positions. to …

Li2mp2s6: Building-Block Approach To A Family Of 2d Non-Van Der Waals-Layered Materials And Their Water, Ammonia, And Ion Intercalation Properties, Santhoshkumar Sundaramoorthy, Nikolay Gerasimchuk, Kartik Ghosh, Steven P. Kelley, Amitava Choudhury

Chemistry Faculty Research & Creative Works

A Series of Non-Van Der Waals 2D Quaternary Thiophosphates with Nominal Composition, Li2MP2S6 (M = V, Mn, Fe, Co, Ni, and Zn), Has Been Successfully Synthesized through Solid-State Metathesis Reactions by a Building Block Approach as Well as Starting with a Stoichiometric Combination of Elements. Li4-NxMxn+P2S6 (M = V, Fe, Ni, Co, and Zn; X = 0.5-1, N = 2 or 3) Crystallize in the P3̅1m Space Group, While Li2MnP2S6 Crystallizes in R3̅. All the Compounds Form a 2D Layered Structure through Edge Sharing MS6 Octahedra and P2S6 Units with Li Atoms Occupying the Interlayer Spaces. X-Ray Diffraction and Thermogravimetric …

Li2mp2s6: Building-Block Approach To A Family Of 2d Non-Van Der Waals-Layered Materials And Their Water, Ammonia, And Ion Intercalation Properties, Santhoshkumar Sundaramoorthy, Nikolay Gerasimchuk, Kartik Ghosh, Steven P. Kelley, Amitava Choudhury

Chemistry Faculty Research & Creative Works

A series of non-van der Waals 2D quaternary thiophosphates with nominal composition, Li₂MP₂S₆ (M = V, Mn, Fe, Co, Ni, and Zn), has been successfully synthesized through solid-state metathesis reactions by a building block approach as well as starting with a stoichiometric combination of elements. Li4-nxMxn+P2S6 (M = V, Fe, Ni, Co, and Zn; x = 0.5-1, n = 2 or 3) crystallize in the P3̅1m space group, while Li₂MnP₂S₆ crystallizes in R3̅. All the compounds form a 2D layered structure through edge sharing MS6 octahedra and P₂S …

Scanning Electrochemical Microscopy Reveals That Model Silicon Anodes Demonstrate Global Solid Electrolyte Interphase Passivation Degradation During Calendar Aging, Josefine D. Mcbrayer, Noah B. Schorr, Mila Nhu Lam, Melissa L. Meyerson, Katharine L. Harrison, Shelley D. Minteer

Chemistry Faculty Research & Creative Works

Silicon is a promising next-generation anode to increase energy density over commercial graphite anodes, but calendar life remains problematic. In this work, scanning electrochemical microscopy was used to track the site-specific reactivity of a silicon thin film surface over time to determine if undesirable Faradaic reactions were occurring at the formed solid electrolyte interphase (SEI) during calendar aging in four case scenarios: formation between 1.5 V and 100 mV with subsequent rest starting at (1) 1.5 V and (2) 100 mV and formation between 0.75 V and 100 mV with subsequent rest starting at (3) 0.75 V and (4) 100 …

2023 Rising Stars In Measurement Science, Shelley Minteer

Chemistry Faculty Research & Creative Works

No abstract provided.

A Reputation System For Provably-Robust Decision Making In Iot Blockchain Networks, Charles C. Rawlins, Sarangapani Jagannathan, Venkata Sriram Siddhardh Nadendla

Electrical and Computer Engineering Faculty Research & Creative Works

Blockchain systems have been successful in discerning truthful information from interagent interaction amidst possible attackers or conflicts, which is crucial for the completion of nontrivial tasks in distributed networking. However, the state-of-the-art blockchain protocols are limited to resource-rich applications where reliably connected nodes within the network are equipped with significant computing power to run lottery-based proof-of-work (pow) consensus. The purpose of this work is to address these challenges for implementation in a severely resource-constrained distributed network with internet of things (iot) devices. The contribution of this work is a novel lightweight alternative, called weight-based reputation (wbr) scheme, to classify new …

Seeding Effects Of Submicron Caal-No3 Ldh Particles On The Hydration And Properties Of Portland Cement And Sulfoaluminate Cement Pastes, Sukanta K. Mondal, Monday Uchenna Okoronkwo

Chemical and Biochemical Engineering Faculty Research & Creative Works

Layered double hydroxide (LDH) is reported to improve the durability of concretes, primarily due to its ability to exchange anionic species, including chloride, which is implicated in corrosion-driven durability issues. However, there is no comprehensive study investigating the effect of LDH on the properties of different cement systems at both early and mature ages. in this study, the early age and mature age properties of Portland cement (OPC) and calcium sulfoaluminate (CSA) cement pastes seeded with submicron-sized calcium aluminum-NO3 LDH (CaAl-NO3 LDH) were investigated. the effects of the 1–5%mass dosage of LDH on the hydration of both cement systems were …

Enhancing Galaxy Surveys With Machine Learning, Steven Karst

Undergraduate Research Conference at Missouri S&T

Applications of machine learning (ML) or artificial intelligence (AI) to problems in astrophysics and cosmology have recently entered a golden era. In response, we have updated two of our recent ML/ AI efforts that contribute to galaxy surveys whose main scientific target is to reveal the nature of the Cosmic Acceleration or Dark Energy. We first revised our effort to infer cosmological information beyond the survey geometry using Graph Neural Networks (GNN) to take advantage of supercomputing resources on campus. We then updated our reinforcement learning methods for galaxy target selection in the Subaru Prime Focus Spectrograph (PFS) survey with …

Visualization Of Ultracold Atomic Samples, Samuel Schrader

Undergraduate Research Conference at Missouri S&T

Laser cooling techniques have evolved into a powerful experimental tool to perform precision spectroscopy (for instance, atomic clocks), study fundamental few-body dynamics, and create well-controlled systems for quantum information applications. When the atoms are captured, it is critical to analyze the laser-cooled atomic samples carefully and characterize their properties, such as density, temperature, population distribution, etc., in order to perform these advanced tasks. A straightforward way to measure these properties is detecting the visible optical photons emitted from the sample with a camera. Throughout this project, I have written and developed a computer application that controls a camera and extracts …

Gender And The Billboard Top 40 Charts Between 1958 And 2023, Brileigh Cates, Justin W. Pope

Undergraduate Research Conference at Missouri S&T

Is there an inherent bias towards male artists in the music industry? Evidence has been shown in previous studies, the most recent being from 2017, that there may be bias towards male artists appearing in Billboard Magazine s Hot 100 list. This study not only updates previous data to include 2017 through 2023, but also looks at the top 40 charts on a week-by-week bias as opposed to the year-end charts that other studies used for their data. We coded each song so as to indicate the gender of the artist(s) as well as whether or not the artists appeared …

Ta Theoretical Framework For Comparing Rlhf Method, Matthew Dominicis

Undergraduate Research Conference at Missouri S&T

Reinforcement Learning from Human Feedback (RLHF) can be used as a means to align Al agents and Large Language Models (LLM) to better represent human expectations. There is a myriad of RLHF methods that exist, however it is difficult to benchmark and compare such methods in terms of alignment, training cost, data collection cost, and other metrics. This project aims to create a robust classification for different RLHF methods from a theoretical point of view. Additionally, this project will attempt to propose bounds for the degree of influence on LLMs that stems from human feedback. Open source LLMs will be …

Heat's Effect On Asphalt Binders Using Nmr, Kaitlin Miles

Undergraduate Research Conference at Missouri S&T

Nuclear Magnetic Resonance (NMR) spectroscopy is a well-known analytical technique that uses the excitation of nuclear spins for solving chemical structures and conformations. Relaxometry is a special field of NMR spectroscopy where information is gained about interactions of 100 nuclear spins with their molecular surroundings. The deterioration of asphalt is a major infrastructure problem, and its rejuvenation back toward its original virgin state is an important field of research and development. The current asphalt industry relies on visual inspection on site and invasive or destructive physical methods to assess emerging asphalt failures. This study examines the chemical changes environmental factors …

Amorphous Transparent Oxide P-Type Semiconductors, Joshua Santy

Undergraduate Research Conference at Missouri S&T

For decades, n-type transparent conducting oxides (TCOs) have been extensively studied and applied in various energy and optoelectronic devices. However, the search for high-performance p-type TCOs, crucial for transparent p-n junctions and next-generation microelectronics - remains uncertain. The most studied p-type TCOs (e.g ., Cu2O-based delafossite family) exhibit the carrier mobilities (<1 cm2Ns) that are much smaller than those in typical n-type TCOs (10-100 cm2Ns). In contrast to the Cu-based layered materials with a relatively flat Cu d10 valence band (resulting in the hole effective mass of 2.5me), Sn2+ in SnO has s2 electronic configuration giving rise to a significantly more dispersed valence band (the hole effective mass is 0.5me) and, hence, to higher hole mobility. Currently, the practical use of SnO is limited due to (i) stability issues of SnO associated with tin preference for valence 4 (as in SnO2, a well-known n-type TCO); (ii) small band gap ~0.7 eV; and (iii) anisotropic hole effective mass in the crystalline phase. Further search for p-type TCOs should involve amorphous phases of SnO-based multi-cation materials where metal composition helps stabilize Sn2+ and open the band gap, whereas the disordered structure is expected to result in uniform isotropic electronic properties and low scattering due to absence of grain boundaries.

Effects Of Reproduction On Senescence In Local Species, Nathan Smith

Undergraduate Research Conference at Missouri S&T

Understanding the impact of reproduction on the aging process within species populations remains an ongoing challenge in ecological and evolutionary research. In this study, we aim to clarify the relationship between reproduction and senescence using agent-based modeling using wild species data sets. Our objectives include investigating how variations in reproductive rates influence the lifespan and aging trajectories of individuals within populations, as well as identifying potential mechanisms underlying these effects. We will employ agent-based modeling to simulate populations and explore the dynamics of reproduction and senescence using publicly available datasets of local wild species. By manipulating parameters related to reproductive …