Physical Sciences and Mathematics Commons^™

Exciton Dynamics, Interaction, And Transport In Monolayers Of Transition Metal Dichalcogenides, Saroj Chand

Dissertations, Theses, and Capstone Projects

Monolayers Transition metal dichalcogenides (TMDs) have attracted much attention in recent years due to their promising optical and electronic properties for applications in optoelectronic devices. The rich multivalley band structure and sizable spin-orbit coupling in monolayer TMDs result in several optically bright and dark excitonic states with different spin and valley configurations. In the proposed works, we have developed experimental techniques and theoretical models to study the dynamics, interactions, and transport of both dark and bright excitons.

In W-based monolayers of TMDs, the momentum dark exciton cannot typically recombine optically, but they represent the lowest excitonic state of the system …

Synthesis And Characterization Of Donor-Acceptor Fluorescent Conjugated Polymers By Acyclic Diene Metathesis (Admet) And Suzuki Polycondensation (Spc), Hamid Ardolic Jr.

Dissertations, Theses, and Capstone Projects

Conjugated polymers are useful in a wide variety of applications including production of Light Emitting Diodes (LEDs), Field Effect Transistors (FETs) and organic photovoltaics. Our work in the lab focuses on the development of materials for use in Polymer Solar Cells (PSCs) using various electron donating and electron accepting units to individually tune the Highest Occupied Molecular Orbital (HOMO) and Lowest Unoccupied Molecular Orbital (LUMO) respectively and produce a small but controlled band gap. This is accomplished through the synthesis of several precursors and their subsequent polymerization using Acyclic Diene Metathesis (ADMET) and Suzuki Polycondensation (SPC). Moderately strong electron donors, …

Low Elevation Coastal Zone (Lecz) Population Social Vulnerability And Risk: A Spatial Analysis Based On The 2015-16 National Family Health Survey (Nfhs-4) Of India, Paradorn Wongchanapai

Dissertations, Theses, and Capstone Projects

Background & Problem Statement:

This study assessed social vulnerability and risk to hydroclimate hazards of Indian urban and rural populations in the Low Elevation Coastal Zone (LECZ), a contiguous coastal area with elevations less than 10 meters. The LECZ is considered an at-risk area as hydroclimate hazards tend to be heightened. Moreover, being the most populous country in the world, any hydroclimate hazards that hit the LECZ would disproportionately impact a large number of Indian populations. Understanding the social vulnerability and risk of the LECZ populations can help mitigate and prevent potential adverse outcomes for the populations.

Importantly, this study …

Analyzing The Effects Of Data Variability & Volume On Predicting Particulate Matter (Pm2.5): Insights From A Machine Learning Approach, Jada A. Macharie

Theses and Dissertations

Accurately predicting PM_2.5 concentrations are imperative to the future of public health and environmental policies. Machine learning models incorporating spatial and temporal datasets to predict PM_2.5 are often limited by data availability constraints and poor resolution satellite imagery.

Ai-Enhanced Detection Of Clinically Relevant Structural And Functional Anomalies In Mri: Traversing The Landscape Of Conventional To Explainable Approaches, Pegah Khosravi, Saber Mohammadi, Fatemeh Zahiri, Masoud Khodarahmi, Javad Zahiri

Publications and Research

Anomaly detection in medical imaging, particularly within the realm of magnetic resonance imaging (MRI), stands as a vital area of research with far-reaching implications across various medical fields. This review meticulously examines the integration of artificial intelligence (AI) in anomaly detection for MR images, spotlighting its transformative impact on medical diagnostics. We delve into the forefront of AI applications in MRI, exploring advanced machine learning (ML) and deep learning (DL) methodologies that are pivotal in enhancing the precision of diagnostic processes. The review provides a detailed analysis of preprocessing, feature extraction, classification, and segmentation techniques, alongside a comprehensive evaluation of …

Physics 100 Level Laboratory Data Collection Tables, Kalani Hettiarachchilage

Open Educational Resources

The physics 100-level laboratory part demonstrates and applies the material learned from related classes. This document shows guidelines for collecting data and analyzing them by using Microsoft Excel. Laboratory components of PHY 114/ PHY 206/SLS 261 (Introduction to Physics and Nature of Physical Processes), PHY116/PHY 121 (Physics I and General Physics I), and PHY 156/PHY 161 (Physics II and General Physics II) at College of Staten Island are in-person mandatory sessions for students and it is required to pass to receive a passing grade for that class. This part is taught by different instructors. Although everyone is supposed to follow …

Radiation Pressure Induced Oscillations Of An Optically Levitating Mirror, Satyam Shekhar Jha, Tal Carmon, Fan Cheng, Lev Deych

Publications and Research

Optical Fabry–Perot cavity with a movable mirror is a paradigmatic optomechanical system. While usually the mirror is supported by a mechanical spring, it has been shown that it is possible to keep one of the mirrors in a stable equilibrium purely by optical levitation without any mechanical support. In this work, we expand previous studies of the nonlinear dynamics of such a system by demonstrating a possibility for mechanical parametric instability and the emergence of the “phonon laser” phenomenon.

Structural And Magnetic Properties Of Molecular Beam Epitaxy (Mnsb2te4)X(Sb2te3)1−X Topological Materials With Exceedingly High Curie Temperature, Candice R. Forrester, Christophe Testelin, Kaushini Wickramasinghe, Ido Levy, Dominique Demaille, David Hrabovsky, Xiaxin Ding, Lisa Krusin-Elbaum, Gustavo Lopez, Maria C. Tamargo

Publications and Research

Tuning the properties of magnetic topological materials is of interest to realize exotic physical phenomena, new quantum phases and quasiparticles, and topological spintronic devices. However, current topological materials exhibit Curie temperature (T_C) values far below those needed for practical applications. In recent years, significant progress has been made to control and optimize T_C, particularly through defect-engineering of these structures. Most recently, we reported T_C values up to 80 K for (MnSb₂Te₄)_x(Sb₂Te₃)_1−x when 0.7 ≤ x ≤ 0.85 by controlling the composition x and the …

It Is Normal: The Probability Distribution Of Temperature Extremes, Nir Y. Krakauer

Publications and Research

The probability of heat extremes is often estimated using the non-stationary generalized extreme value distribution (GEVD) applied to time series of annual maximum temperature. Here, this practice was assessed using a global sample of temperature time series, from reanalysis (both at the grid point and the region scale) as well as station observations. This assessment used forecast negative log-likelihood as the main performance measure, which is particularly sensitive to the most extreme heat waves. It was found that the computationally simpler normal distribution outperforms the GEVD in providing probabilistic year-ahead forecasts of temperature extremes. Given these findings, it is suggested …

Quotients Of The Curve Complex, Joseph Maher, Hidetoshi Masai, Saul Schleimer

Publications and Research

We consider three kinds of quotients of the curve complex, which are obtained by coning off uniformly quasiconvex subspaces: symmetric curve sets, non-maximal train track sets, and compression body disc sets. We show that the actions of the mapping class group on those quotients are strongly weakly properly discontinuously (WPD), which implies that the actions are non-elementary and those quotients are of infinite diameter.

Time-Efficient Filtering Of Imaging Polarimetric Data By Checking Physical Realizability Of Experimental Mueller Matrices, Tatiana Novikova, Alexey Ovchinnikov, Gleb Pogudin, Jessica C. Ramella-Roman

Publications and Research

Motivation: Imaging Mueller polarimetry has already proved its potential for biomedicine, remote sensing, and metrology. The real-time applications of this modality require both video rate image acquisition and fast data post-processing algorithms. First, one must check the physical realizability of the experimental Mueller matrices in order to filter out non-physical data, i.e. to test the positive semi-definiteness of the 4 × 4 Hermitian coherency matrix calculated from the elements of corresponding Mueller matrix pixel-wise. For this purpose, we compared the execution time for the calculations of (i) eigenvalues, (ii) Cholesky decomposition, (iii) Sylvester’s criterion, and (iv) coefficients of the characteristic …

Effective Size Of A Parity-Time-Symmetric Dimer, Li Ge

Publications and Research

Parity-time (PT)-symmetric dimers were introduced to highlight the unusual properties of non-Hermitian systems that are invariant after a combined parity and time reversal operation. They are also the building blocks of a variety of symmetry and topologically protected structures, especially on integrated photonic platforms. As the name suggests, it consists of two coupled oscillators, which can be optical, mechanical, electronic, and so on in nature. In this article, we show that its effective size, defined by the number of lattice sites inversely proportional to the lattice momentum, is surprisingly three instead of two from the perspective of energy quantization. More …

General Physics Ii - Lab Manual, David Goldberg, Peter Glass

Open Educational Resources

No abstract provided.

On Cyclically 4-Connected Cubic Graphs, R. J. Kingan, S. R. Kingan

Publications and Research

A 3-connected cubic graph is cyclically 4-connected if it has at least n ≥ 8 vertices and when removal of a set of three edges results in a disconnected graph, only one component has cycles. By introducing the notion of cycle spread to quantify the distance between pairs of edges, we get a new characterization of cyclically 4-connected graphs. Let Q_n and V_n denote the ladder and Möbius ladder on n ≥ 8 vertices, respectively. We prove that a 3-connected cubic graph G is cyclically 4-connected if and only if G is either the Petersen graph, Q …

Photo-Induced Charge State Dynamics Of The Neutral And Negatively Charged Silicon Vacancy Centers In Room-Temperature Diamond, G. Garcia-Arellano, G. I. López-Morales, N. B. Manson, J. Flick, A. A. Wood, C. A. Meriles

Publications and Research

The silicon vacancy (SiV) center in diamond is drawing much attention due to its optical and spin properties, attractive for quantum information processing and sensing. Comparatively little is known, however, about the dynamics governing SiV charge state interconversion mainly due to challenges associated with generating, stabilizing, and characterizing all possible charge states, particularly at room temperature. Here, multi-color confocal microscopy and density functional theory are used to examine photo-induced SiV recombination — from neutral, to single-, to double-negatively charged — over a broad spectral window in chemical-vapor-deposition (CVD) diamond under ambient conditions. For the SiV⁰ to SiV^‒ transition, …

Enhance Students’ Learning Outcomes By Redesigning Individual Learning Activities Into Group Activities For Introductory Level Physics Courses, Kalani Hettiarachchilage, Neel Haldolaarachchige

Publications and Research

The evolution of science education is a dynamic process driven by advances in pedagogy, technology, and especially, our understanding of how students learn. Educators are exploring innovative teaching and learning methodologies such as active learning, incorporated technology, interdisciplinary approaches, flipped classrooms, personalized teaching, and many more. The goal of all these evolving methodologies is to empower students with not only a strong foundation in scientific knowledge but also with the skills and mindset required to thrive in the future world. By adopting these innovative approaches, educators can help students become effective problem solvers, critical thinkers, and life-learning citizens. Our focus …

Investigating Efficiency Of Free-For-All Models In A Matchmaking Context, Emil Gensby, Bryan S. Weber, Anders H. Christiansen

Publications and Research

We explore several popular (and unpopular) systems for matchmaking and ranking in free-for-all (FFA) environments. The commonplace existing methods involve the reinterpretation of established two-player ranking systems (ie. Elo/Glicko) and decomposing multiplayer games into a set of multiple one-vs-one pairings. This decomposition, while commonplace, is not part of the intended use-case of these two-player ranking systems. We are the first to formally explore this ad-hoc usage and reassuringly find evidence that it converges to correct values. Second, we identify a method that appears to dominate what appears to be the most common publicly used method. At the same time, this …

Change Of Metal Oxidation State At High Temperature, Impact Of Temperature And Reactive Gases, Yegor Nikitin

Dissertations and Theses

The fundamental understanding of gas-solid reactions enables a wide range of applications to be developed and improved. Specifically, the use of metal-based materials is critical to ensuring robust, safe, and long-term operations. For example, in power systems where boilers are used to generate steam for heat or electricity generation the use of stainless metal alloys is critical to allow high quality steam to be produced in a very harsh environment. Alternatively, in catalysis, the use of metal doped heterogeneous catalysts are essential in achieving selectivity and conversion performance for chemical synthesis to emissions abatement. Typically, these metal alloys must withstand …

On The Understanding Of The Coastal-Urban Nexus Of Weather, Air Quality And Energy, Harold Gamarro

Dissertations and Theses

Urban environments exhibit complex interactions between atmospheric processes, building energy consumption, and air quality, particularly during periods of seasonal extremes such as summer ozone peaks and winter heating. Accurate representation of these interactions in urban modeling is crucial for understanding and addressing air pollution and energy management challenges in cities. This research presents a comprehensive study that advances urban atmosphere simulations by integrating building energy dynamics, air quality, and robust multi-source observational evaluation. Leveraging the Weather Research and Forecasting (WRF) model, coupled with a multilayer building environment parameterization (BEP) and a building energy model (BEM), with an improved boundary layer …

Orbital And Spin Angular Momentum Light Generation, Interactions, Special Photons, And Applications In Liquids, Solids, Vapors And Biological Tissue Media, Sandra Mamani Reyes

Dissertations and Theses

Photons possess many characteristics such as wavelength, coherence, speed, polarization and wavefront. The aim of this thesis is the study of two salient properties of light exploring light carrying polarization and space degree of freedom of the wavefront. The wavefront of light is complex with different states of polarization. Special light beams are generated and characterized for interaction with liquids, solids, vapors, and bio- materials to understand fundamental processes such as Transmission, Raman scattering, and Optical Kerr Effect in steady state and temporal domains.

It has been more than hundred years since it is known that light can carry other …

Hydrodynamics Of Drops And Particles Driven By Marangoni And Diffusiophoretic Forces, Subramaniam Chembai Ganesh

Dissertations and Theses

This study investigates the hydrodynamics of particles and drops driven by forces generated by an asymmetrical physical and chemical surrounding environment. In the first part, a novel colloidal motor design driven by surface tension forces is proposed, utilizing an active Janus particle encapsulated in an immiscible liquid drop to form a compound drop/particle. Marangoni forces induced by asymmetric solute adsorption at the liquid-liquid interface of the drop propels the compound system. The propulsion speeds of the motor are analyzed for various relative sizes and configurations of the Janus particle and the encapsulating drop and the effects of varying the transport …

Hyperspectral And Polarimetric Imaging Of The Ocean For The Characterization Of The Surface Effects And Measurement Uncertainties, Mateusz Malinowski

Dissertations and Theses

Ocean and coastal waters are monitored by Ocean Color satellite sensors to determine concentrations of chlorophyll and water properties and identify areas of algal blooms and other events. The light radiance from the ocean is weak in comparison with the sky radiance, which requires very accurate atmospheric correction of the radiance measured at the top of the atmosphere (TOA) on the satellite and heavy validation of the derived water leaving radiance by field measurements from the ships and ocean platforms. For TOA and especially above water radiance the skylight reflected from the ocean surface represents one of the main sources …

Synthesis Of Novel 5-Aryl 2’-Deoxyuridine And 2’-Deoxycytidine Analogues, Kevin E. Persaud

Dissertations and Theses

Briefly, the following report details a synthetic route to prepare 5-phenyl-2’-deoxycytidine analogues. This multistep synthesis began with silyl protection of the 3’- and 5’-hydroxyl groups of 5-iodo-2’-deoxyuridine. Next, the installation of a phenyl ring at the C5 position of the nucleobase via a Suzuki-Miyaura cross-coupling reaction, yielding 5-phenyl-2’-deoxyuridine (5-PdU). After that, modification of the obtained 5-PdU at the C4 position was performed with benzotriazole-1-yl-oxy-tris-(dimethylamino)-phosphonium hexafluorophosphate (BOP, a peptide-coupling agent) and a base (cesium carbonate) to activate the amide group of the uridine nucleobase for subsequent displacement with a variety of amines. Modification of the C4 position resulted in protected 5-phenyl-2’-deoxycytidine …

Review Of Slow Down: The Degrowth Manifesto, Michael Kirby

Publications and Research

No abstract provided.

Learning To Code With Github Copilot: A Resource For New Student Developers, Sarah Zelikovitz

Open Educational Resources

This resource provides a step-by-step guide for new student developers on using GitHub Copilot. It covers the process of signing up for GitHub's Educa􀀁on program, integra􀀁ng Copilot into two popular integrated development environments (IDEs), and using Copilot to generate, document, debug, and optimize code through prompt-based interactions. This guide empowers students to leverage AI-driven assistance in solving coding challenges. It also gives students an understanding of the limitations of AI, and how to use it safely and effectively.

New York State Climate Impacts Assessment: 04 Buildings, Nicholas B. Rajkovich, Carrie Brown, Ilya Azaroff, Erik Backus, Shannon Clarke, Jared Enriquez, Bethany Greenaway, Meghan T. Holtan, Jamal Lewis, Ozgem Ornektekin, Laurie Schoeman

Publications and Research

New York State has nearly 5.3 million buildings, and all of them are vulnerable in some way to the impacts of climate change. Understanding these impacts is critical, because risks to buildings not only threaten individual lives but also pose threats to community-level resilience. This chapter examines the impacts of climate change on buildings and, by extension, the people and communities they shelter and support. It also highlights building types and populations that are at particular risk and presents adaptation strategies to protect the state’s existing and future building stock from climate impacts.

Compton Scattering Of Mammographic Soft X-Ray Beams By Alkali And Transition Metal Salt Filters Produce X-Ray Interference Zones That May Have Treatment Potential For Localized Cancer Lesions, Subhendra N. Sarkar, Eric Lobel, Sabina Rakhmatova, Derbie Desir, Somdat Kissoon, Daler Djuraev, Katie Tam

Publications and Research

In breast x-ray imaging scattered radiation adds 50% of harmful radiation dose from anisotropic Compton scattering mechanism. We have been working with double layered inorganic salt materials that can induce Compton scattering to the incident mammographic x ray beams (in 20-30 kVp range) with adequate isotropy (angular control). Typically metal nitrates and alkali halide salt layers are shown here to cause low energy radiation interference zones with high and low photon intensities and local flux heterogeneity in terms of flux covariance. Spatial variation of low energy photon flux creates concentrated and sparse radiation zones that may be used to induce …

Momentech - Modern Explorations Of The Impulse-Momentum Theorem, Todd Gelbord

Publications and Research

Herein we outline the design and construction of an instructional laboratory demonstration of the conservation of linear momentum, by way of the Impulse-Momentum Theorem, utilizing small, commercially available accelerometers attached to microcontrollers. The set-up is equipped with small, OLED screens which are able to display real-time acceleration graphs. Furthermore, a template for an experiment involving this set-up is provided. We also explore various data analysis options for different levels of student sophistication.

Circular Economy: The 4rs Reduce-Reuse-Recycle-Recover, Kevin Hom

Publications and Research

This article summarizes the lecture presented at the Net Built 2024 conference. The lecture addresses the unsustainability of the current linear economy, characterized by the "take, make, dispose" model, in light of environmental challenges. The inefficiencies of this system lead to increased energy consumption, elevated CO2 emissions, and the exacerbation of climate change. It examines the current state of design and construction with respect to climate change and sustainable resource management. Additionally, the lecture introduces a methodology that integrates technologies and design philosophies capable of driving significant positive change. By advocating for a transformative approach to the expected lifetime of …

Threading Unity Throughout Itaa: A Collaboration Of Fashion Academics Across Content Threading Unity: Apparel, Marketing, Beauty And Interior Design Within The Fashion Industry, Alyssa Dana Adomaitis, Carter Gabriel Averbeck, Kendel Bolton, Denise Sutton

Publications and Research

Sustainability has been an academic research topic of late that impacts more than just the fashion industry for apparel. Besides the apparel industry, marketing, beauty, and interior design are aware of the promise of sustainability for both the environment and consumers. Sustainability reduces its environmental impacts of pollutants such as carbon footprints and unsold inventory, protecting workers who create garments, and animal welfare (Biela-Weyenberg, 2023) which can impact the supply chain. “The United Nations established the UN Alliance for Sustainable Fashion in 2019 to hold fashion brands to a higher standard to create environmentally friendly apparel” (2023, p.1). Through modern …