Physical Sciences and Mathematics Commons^™

Chm110 Principles Of Chemistry Lecture Slides, Leah S. Cohen

Open Educational Resources

These modified slides contain information from the first ten chapters from the General, Organic, and Biochemistry: connecting Chemistry to Your Life textbook by Blei & Odian.

Towards A New Role Of Mitochondrial Hydrogen Peroxide In Synaptic Function, Cliyahnelle Z. Alexander

Student Theses and Dissertations

Aerobic metabolism is known to generate damaging ROS, particularly hydrogen peroxide. Reactive oxygen species (ROS) are highly reactive molecules containing oxygen that have the potential to cause damage to cells and tissues in the body. ROS are highly reactive atoms or molecules that rapidly interact with other molecules within a cell. Intracellular accumulation can result in oxidative damage, dysfunction, and cell death. Due to the limitations of H₂O₂ (hydrogen peroxide) detectors, other impacts of ROS exposure may have been missed. HyPer7, a genetically encoded sensor, measures hydrogen peroxide emissions precisely and sensitively, even at sublethal levels, during …

Examining Galaxy Bulge Regions With The Sloan Digital Sky Survey, Sarah E. Draves, Ariyeh Maller

Publications and Research

Nearly all of the ordinary matter in the universe is located in galaxies, which are made up stars, gas, dust, and black holes, and range in size from a few thousand to a few hundred thousand light years across. Galaxies come in different shapes, but many of them are spiral shaped, and some of those have a central bulge region that is distinct from the rest of the galactic disk. This project used a large data set of galaxies that had their bulge and disk components separated to see what correlations those fractions of each galaxy have with other galaxy …

The Use Of Repurposed Whole Textiles To Modify The Mechanical And Hydrogeological Properties Of Green Roof Media And Granular Soils, Angelis Almanzar-Chevalie, Yehya Elfgeeh, Calvin O. Walters Jr.

Publications and Research

This study investigates using repurposed whole textiles to modify the mechanical and hydrogeological properties of lightweight Green Roof media and granular pavement soils.

Green Roof Media Green roofs aim to bring the advantages of suburban agriculture to urban environments while improving energy efficiency and enhancing stormwater management in public, commercial, and residential buildings. Previous studies by City Tech undergraduate research assistants demonstrated significant modification in hydrogeological properties when incorporating textile fabric up to 3% textile by weight (%Tex) at an aspect ratio of 1:1. The effects of mixing repurposed whole textile fiber with Green Roof media is evaluated with regards …

Machine Learning: Face Recognition, Mohammed E. Amin

Publications and Research

This project explores the cutting-edge intersection of machine learning (ML) and face recognition (FR) technology, utilizing the OpenCV library to pioneer innovative applications in real-time security and user interface enhancement. By processing live video feeds, our system encodes visual inputs and employs advanced face recognition algorithms to accurately identify individuals from a database of photos. This integration of machine learning with OpenCV not only showcases the potential for bolstering security systems but also enriches user experiences across various technological platforms. Through a meticulous examination of unique facial features and the application of sophisticated ML algorithms and neural networks, our project …

A Spatial Decision Support System For Rent Estimation Of Retail Spaces In Manhattan Using Geographically Weighted Regression And Spatial Regression, Andie M. Migden Miller

Theses and Dissertations

This report outlines an automated, three-phase Spatial Decision Support System that creates models to estimate rent of retail spaces across Manhattan. First, enrich data with predictors. Second, optimize spatially aware neighborhood-level models by combining GWR, spatial regression, and non-spatial regression. Finally, visualize results in an Esri-based WebApp.

Chm116 Principles Of Chemistry Ii Lecture Slides, Leah S. Cohen, Probal Banerjee

Open Educational Resources

This file contains the lecture slides that are used in CHM116, Principles of Chemistry II.

Determination Of Common Drugs Of Abuse And Metabolites In Oral Fluid: Comparison Of Different Extraction Procedures, Melissa Koffer

Student Theses

Oral fluid has been gaining importance in forensic and clinical toxicology for many different drug testing scenarios. Oral fluid is composed of saliva, along with gingival fluid, bacteria, and food residues. Drug testing using oral fluid has many advantages over other matrices (blood, urine) such as the non-invasive collection, reduced risk of tampering, and shorter detection windows which show recent drug use. The purpose of this study was to develop an analytical method for the determination of 19 drugs of abuse and metabolites in oral fluid by liquid chromatography tandem mass spectrometry (LC-MS/MS) and compare three different extraction methods: liquid-liquid …

Cloud Computing Integration Into Mixed-Reality: Physical To Abstraction, Yassine Chahid, Patrick Slattery

Publications and Research

This research evaluates the progression of cloud computing and mixed-reality technologies, and to identify how these technologies influence advancements in the latter. Both cloud computing and mixed reality have significantly impacted the IT field and the services available to the public and various institutions. Cloud computing provides a valuable way to process information or allocate computational resources on otherwise limited hardware. Augmented or virtual reality hardware would greatly benefit from this by offloading resource-intensive tasks to other machines. The research methodology involves analyzing essential components of both innovations, divided into multiple categories. These components range from physical, hardware-based elements to …

Performance Outcomes In Introductory Statistics: R Vs. Spss Usage At A Community College, Venessa Singhroy Ph.D., Bianca Sosnovski

Publications and Research

This dataset corresponds to a study investigating the performance outcomes of students enrolled in two sections of an introductory statistics course at a community college in New York. The study, titled "Examining Differences in Performance Outcomes between Statistics Classes using High-coding vs. Low-coding Statistical Software Packages," explores the impact of utilizing different statistical software packages (R and SPSS) on student performance and motivation. The dataset comprises assessments administered to participants, including the Mathematics Motivation Questionnaire, Reading Comprehension Assessment, Algebra Assessment, Statistics Assessment, and Coding Assessment. Participants were divided into two sections: one utilizing R and the other utilizing SPSS for …

Syllabus For Oer Version Of Math 20100, Thea Pignataro

Open Educational Resources

Syllabus for OER version of first semester calculus with analytic geometry for physical sciences and engineering.

A Causal Inference Approach For Spike Train Interactions, Zach Saccomano

Dissertations, Theses, and Capstone Projects

Since the 1960s, neuroscientists have worked on the problem of estimating synaptic properties, such as connectivity and strength, from simultaneously recorded spike trains. Recent years have seen renewed interest in the problem coinciding with rapid advances in experimental technologies, including an approximate exponential increase in the number of neurons that can be recorded in parallel and perturbation techniques such as optogenetics that can be used to calibrate and validate causal hypotheses about functional connectivity. This thesis presents a mathematical examination of synaptic inference from two perspectives: (1) using in vivo data and biophysical models, we ask in what cases the …

Clustering Of Patients With Heart Disease, Mukadder Cinar

Dissertations, Theses, and Capstone Projects

Heart disease, a leading cause of mortality worldwide, presents complex challenges in public health due to its varied manifestations. Accurate diagnosis and patient stratification are essential for effective management and improved outcomes. In response, this study employed machine learning techniques to analyze heart disease data obtained from UCI Machine Learning Repository, aiming to enhance patient care through advanced data analysis.

The study began with the application of K-Nearest Neighbors (KNN) classification, which categorized patients into 'Disease' and 'No Disease' groups. This preliminary step provided initial insights into the structure of the dataset. Subsequently, K-means clustering was applied in two rounds, …

New Effective Transformational Computational Methods, Jun Zhang, Ruzong Fan, Fangyang Shen, Junyi Tu

Publications and Research

Mathematics serves as a fundamental intelligent theoretic basis for computation, and mathematical analysis is very useful to develop computational methods to solve various problems in science and engineering. Integral transforms such as Laplace Transform have been playing an important role in computational methods. In this paper, we will introduce Sumudu Transform in a new computational approach, in which effective computational methods will be developed and implemented. Such computational methods are straightforward to understand, but powerful to incorporate into computational science to solve different problems automatically. We will provide computational analysis and essentiality by surveying and summarizing some related recent works, …

What Does One Billion Dollars Look Like?: Visualizing Extreme Wealth, William Mahoney Luckman

Dissertations, Theses, and Capstone Projects

The word “billion” is a mathematical abstraction related to “big,” but it is difficult to understand the vast difference in value between one million and one billion; even harder to understand the vast difference in purchasing power between one billion dollars, and the average U.S. yearly income. Perhaps most difficult to conceive of is what that purchasing power and huge mass of capital translates to in terms of power. This project blends design, text, facts, and figures into an interactive narrative website that helps the user better understand their position in relation to extreme wealth: https://whatdoesonebilliondollarslooklike.website/

The site incorporates …

Examining The Health Risks Of Particulate Matter 2.5 In New York City: How It Affects Marginalized Groups And The Steps Needed To Reduce Air Pollution, Freddy Castro

Dissertations, Theses, and Capstone Projects

The following examines the impact of particulate matter 2.5 (PM2.5) on public health, focusing on its sources and effects on vulnerable populations in New York City. PM2.5 is a particle that is 2.5 micrometers or less in diameter and, because of its size, can enter the bloodstream affecting the respiratory and cardiovascular systems and further complicating the health of the immunocompromised. Recent studies have shown that PM2.5 can come from various sources, including transportation and industrial emissions, as well as indoor sources like cigarettes and gas-operated stoves. Despite reduced levels of PM2.5 due to recent policy changes and initiatives taken …

Modeling Of Covid-19 Clinical Outcomes In Mexico: An Analysis Of Demographic, Clinical, And Chronic Disease Factors, Livia Clarete

Dissertations, Theses, and Capstone Projects

This study explores COVID-19 clinical outcomes in Mexico, focusing on demographic, clinical, and chronic disease variables to develop predictive models. In the binary classification task, the Ada Boost Classifier distinguishes survivors from non-survivors, with age, sex, ethnicity, and chronic medical conditions influencing outcomes. In multiclass classification, the Gradient Boosting Classifier categorizes patients into outcome groups.

Demographic variables, especially age, are crucial for predicting COVID-19 outcomes for both the binary and multiclass classification tasks. Clinical information about previous conditions, including chronic diseases, also holds relevance, especially diabetes, immunocompromise, and cardiovascular diseases. These insights inform public health measures and healthcare strategies, emphasizing …

Making Sense Of Making Parole In New York, Alexandra Mcglinchy

Dissertations, Theses, and Capstone Projects

For many individuals incarcerated in New York, the initial step toward freedom begins with an interview with the Board of Parole. This process, however, is frequently a complex and challenging one, characterized by repeated denials and extended incarcerations. The disparity in outcomes – where one individual may receive over 20 denials and another is granted parole on their first attempt – highlights the ambiguity and inconsistency in the parole decision-making process. This project aims to clarify the factors that influence parole decisions by concentrating on measurable variables. These include age, race, duration of sentence served, proportion of sentence served, type …

Towards Sociobiogeochemistry: Critical Perspectives On Anthropogenic Alterations To Soil Nitrogen Chemistry Via U.S. Urban And Suburban Development, Christopher D. Ryan

Dissertations, Theses, and Capstone Projects

The ecological impacts of changes to land use are relevant to concerns about climate change, eutrophication of waterbodies, and reductions in biodiversity. As a foundational component of ecosystem functioning, changes to soil biogeochemistry have significant effects on overall ecosystem health. With cities continuing to grow and develop in extent, the impacts of urbanization and suburbanization on soils are of particular concern. Despite a wide range of natural climatic and geologic conditions, several factors have driven similar patterns of land transformation and management across the United States. In particular, federal initiatives including the Home Owners Loan Corporation, the Federal Housing Administration, …

Integration Of Field- And Space-Based Observations Toward Assessing Drivers Of Biogeochemical Variability Across Vulnerable Coastal Ecosystems, Alana B. Menendez

Dissertations, Theses, and Capstone Projects

This thesis uses new field datasets and satellite ocean color products to quantify biogeochemical variability in three coastal regions: Long Island Sound estuary, the coastline of the Bay of Bengal extending east to the Mekong Delta, and the Yukon River Delta. These three study regions have vastly different size domains, climates, populations, and economies, but all require enhanced coastal water monitoring in the face of climate change. These regions are all naturally dynamic and experience strong seasonal phenomena but are also subject to changing hydrological forcings and direct anthropogenic perturbations. This leaves these coastal areas vulnerable to altered biogeochemical cycling, …

Studies Of Oxidopyrylium Ylide Dimers And Their Utility In The Synthesis Of Densely Functionalized Troponoids, Daniel V. Schiavone

Dissertations, Theses, and Capstone Projects

Herein, we describe our efforts to investigate mechanistic considerations of oxidopyrylium ylides and their use in cycloadditions to form complex bicyclic structures and the advancement of these cycloadducts to the synthesis of densely functionalized tropolones. This work also describes applications of tropolones as biologically relevant structures and dynamic fluorophores.

In Chapter 1, we expand upon previous studies done in the Murelli Lab describing the ability of 3-hydroxy-4-pyrone derived oxidopyrylium dimers to revert back to ylides in situ and as result can be used as a clean oxidopyrylium ylide source in accessing oxabicyclic compounds. Intermolecular cycloadditions of these ylides can be …

New Algorithmic Support For The Fundamental Theorem Of Algebra, Vitaly Zaderman

Dissertations, Theses, and Capstone Projects

Univariate polynomial root-finding is a venerated subjects of Mathematics and Computational Mathematics studied for four millenia. In 1924 Herman Weyl published a seminal root-finder and called it an algorithmic proof of the Fundamental Theorem of Algebra. Steve Smale in 1981 and Arnold Schonhage in 1982 proposed to classify such algorithmic proofs in terms of their computational complexity. This prompted extensive research in 1980s and 1990s, culminated in a divide-and-conquer polynomial root-finder by Victor Pan at ACM STOC 1995, which used a near optimal number of bit-operations. The algorithm approximates all roots of a polynomial p almost as fast as one …

The Early Late Miocene Cessation Of Deep And Intermediate Water Circulation Through The Central American Seaway, Benjamin Stanley Kwiatkowski

Dissertations, Theses, and Capstone Projects

The state of the middle late Miocene global ocean circulations which regulated climate and affected deep ocean chemical environments were impacted by geographic changes. During the Miocene, cirum-equatorial circulations slowly decreased, which included through the seaway between the Americas called the Central American Seaway (CAS). Its shoaling and ultimate closing led to the onset of modern day oceanic circulation as characterized by the global thermohaline circulation. However, this seaway has a long hotly debated history concerning the timing of its restriction and shallowing owing in part to the shifting of tectonic plates.

The goal of this research focuses on investigating …

Trees In Urban Environments: How Soil Quality Impacts Tree Performance, Saidan Qi

Dissertations, Theses, and Capstone Projects

Cities around the world are increasingly investing in reforestation and afforestation efforts to mitigate impacts from climate change and population growth. However, urban soil conditions can be unfavorable for tree growth. Street trees are widely known to suffer from poor soil quality, but there has been no comprehensive review of this topic so far. Clean soils can be transported from nonurban areas to support cities’ green projects, but this approach is not sustainable. Artificial (constructed) soils can be created from various materials and have been proposed as an alternative medium for urban tree growth, but no research has been done …

Containerization Of Seafarers In The International Shipping Industry: Contemporary Seamanship, Maritime Social Infrastructures, And Mobility Politics Of Global Logistics, Liang Wu

Dissertations, Theses, and Capstone Projects

This dissertation discusses the mobility politics of container shipping and argues that technological development, political-economic order, and social infrastructure co-produce one another. Containerization, the use of standardized containers to carry cargo across modes of transportation that is said to have revolutionized and globalized international trade since the late 1950s, has served to expand and extend the power of international coalitions of states and corporations to control the movements of commodities (shipments) and labor (seafarers). The advent and development of containerization was driven by a sociotechnical imaginary and international social contract of seamless shipping and cargo flows. In practice, this liberal, …

Evaluating The Reliability And Accuracy Of Alchemical Binding Free Energy Methods And Calculations, Fnu Sheenam

Dissertations, Theses, and Capstone Projects

Molecular recognition plays a crucial role in various biological processes, such as enzymatic reactions, signal transduction, and genetic information processing. Investigating how proteins selectively bind to their partners is an active research area, but there is a lack of experimental details on protein structures and interactions in molecular complexes. Computational techniques based on macromolecular structures offer a way to predict protein-ligand interactions and explore their recognition mechanisms. Estimating binding affinities, particularly through alchemical binding free energy calculations, has become valuable in supporting drug discovery. This work introduces new methodologies, utilizing the Alchemical Transfer Method, to address issues like poor convergence …

Deep Learning-Based Human Action Understanding In Videos, Elahe Vahdani

Dissertations, Theses, and Capstone Projects

The understanding of human actions in videos holds immense potential for technological advancement and societal betterment. This thesis explores fundamental aspects of this field, including action recognition in trimmed clips and action localization in untrimmed videos. Trimmed videos contain only one action instance, with moments before or after the action excluded from the video. However, the majority of videos captured in unconstrained environments, often referred to as untrimmed videos, are naturally unsegmented. Untrimmed videos are typically lengthy and may encompass multiple action instances, along with the moments preceding or following each action, as well as transitions between actions. In the …

Rational Design Of Peptide-Based Materials Informed By Multiscale Molecular Dynamics Simulations, Dhwanit Rahul Dave

Dissertations, Theses, and Capstone Projects

The challenge of establishing a sustainable and circular economy for materials in medicine and technology necessitates bioinspired design. Nature's intricate machinery, forged through evolution, relies on a finite set of biomolecular building blocks with through-bond and through-space interactions. Repurposing these molecular building blocks requires a seamless integration of computational modeling, design, and experimental validation. The tools and concepts developed in this thesis pioneer new directions in peptide-materials design, grounded in fundamental principles of physical chemistry. We present a synergistic approach that integrates experimental designs and computational methods, specifically molecular dynamics simulations, to gain in-depth molecular insights crucial for advancing the …

Stereospecific Cross-Coupling Reactions Of Vinyl Triflates And An Investigation Of The Synthesis And Reactivity Of Activated Alkyltricyclohexylstannanes, Pejman Ghaemimohammadi

Dissertations, Theses, and Capstone Projects

Organic chemistry exists in all aspects of everyday life from polymers to pharmaceutics. Formation of carbon-carbon bonds is essential for the synthesis of complex organic compounds. This goal can be achieved by using transition metal catalysts. Second-row transition metals such as Pd, Pt, Rh, and Ir have shown remarkable efficacy in these reactions. Metal-catalyzed cross-coupling reactions form carbon-carbon bonds between electrophiles and nucleophiles using transition metal catalysts. Pd is mainly used in this reaction.

Transition metal-catalyzed cross-coupling reactions that form a bond between two C(sp²) carbons have been widely studied over the past decades. C(sp²)-C(sp^{3 …}

Biomolecular Crystals As Functional Materials, Fahmeed Khan Sheehan

Dissertations, Theses, and Capstone Projects

The field of supramolecular chemistry has undergone significant evolution over the last few decades, progressing from fundamental studies of self-assembling systems to the rational design of functional materials with exceptional properties. Among these materials, short peptides have emerged as a chemically simple yet highly versatile class of biomimetic compounds. Initially, short peptides were used as model systems to understand larger protein interactions. As the field progressed, short peptides were found to have exceptional functionality, and are now explored as functional nanomaterials for diverse applications. In many cases, short peptide materials have displayed properties not found in biology, in some cases …