Materials Science and Engineering Commons^™

Design, Fatigue, And Strength Analysis Of A Tie Rod Hydraulic Cylinder Bolt, Jacob Roemen, Donald Webber

The Journal of Undergraduate Research

This report illustrates strength and fatigue analysis completed on a tie rod hydraulic cylinder bolt from a Lion TX 2500 tie rod hydraulic cylinder. The goal was to: solve for total clamping force, damping force per bolt at 90% proof load strength, amount of force per bolt, find the required number of bolts to hold the hydraulic cylinder together, solve for bolt spacing requirements, estimate a safety factor based on proof load strength, nut shear strength, required nut thickness, the least number of threads that must be engaged, estimate R.R. Moore Bending Fatigue Strengths, estimate the maximum value of P …

A Three-Dimensional Quantitative Understanding Of Short Fatigue Crack Growth In High Strength Aluminum Alloys, Wei Wen

Theses and Dissertations--Chemical and Materials Engineering

The behaviors of short fatigue crack (SFC) propagation through grain boundaries (GBs) were monitored during high cycle fatigue in an Al-Li alloy AA8090. The growth behaviors of SFCs were found to be mainly controlled by the twist components (α) of crack plane deflection across each of up to first 20 GBs along the crack path. The crack plane twist at the GB can result in a resistance against SFC growth; therefore SFC propagation preferred to follow a path with minimum α at each GB. In addition to the grain orientation, the tilting of GB could also affect α.

An experiment …

Numerical Modeling And Characterization Of Vertically Aligned Carbon Nanotube Arrays, Johnson Joseph

Theses and Dissertations--Mechanical and Aerospace Engineering

Since their discoveries, carbon nanotubes have been widely studied, but mostly in the forms of 1D individual carbon nanotube (CNT). From practical application point of view, it is highly desirable to produce carbon nanotubes in large scales. This has resulted in a new class of carbon nanotube material, called the vertically aligned carbon nanotube arrays (VA-CNTs). To date, our ability to design and model this complex material is still limited. The classical molecular mechanics methods used to model individual CNTs are not applicable to the modeling of VA-CNT structures due to the significant computational efforts required. This research is to …

The Study Of Photo-Reduction Of Cerium Oxide Nanoparticles In Presence Of Dextran: An Attempt In Understanding The Functionality Of The System, Swetha Barkam

Electronic Theses and Dissertations

Malignant melanoma cancer is the sixth common cancer diagnosed in the United States. Surgery, chemotherapy and radiation are some of the successful techniques in killing tumor cells. However, in these techniques, it is not easy to distinguish tumor cells from the healthy once which inadvertently get exposed to chemical agent/radiation. Therefore it is required to develop an anticancer agent which selectively kills the cancer cells, while still protecting the normal tissues. In our preliminary work, we have shown that Dextran (1000Da) coated Cerium oxide nanoparticles (Dex-CNPs) selectively kills the cancer cells (50% killing at a concentration of 150μM) without inducing …

Tailoring The Properties Of Polyelectrolyte Coated Cerium Oxide Nanoparticles As A Function Of Molecular Weight, Shashank Saraf

Electronic Theses and Dissertations

The application of Cerium oxide nanoparticles (CNPs) for therapeutic purposes requires a stable dispersion of nanoparticles in biological environment. The objective of this study is to tailor the properties of polyelectrolyte coated CNPs as a function of molecular weight to achieve a stable and catalytic active dispersion. This was achieved by coating CNPs with polyacrylic acid (PAA) which increased the dispersion stability of CNPs and enhanced the catalytic ability. The stability of PAA coating was analysed using the change in the Gibbs free energy computed by Langmuir adsorption model. The adsorption isotherms were determined using soft particle electrokinetics which overcomes …

First Principle Studies Of Cu-Carbon Nanotube Hybrid Structures With Emphasis On The Electronic Structures And The Transport Properties, Chengyu Yang

Electronic Theses and Dissertations

Carbon nanotubes have been regarded as ideal building blocks for nanoelectronics and multifunctional nanocomposites due to their exceptional strength, stiffness, flexibility, as well as their excellent electrical properties. However, carbon nanotube itself has limitations to fulfill the practical application needs: 1) an individual carbon nanotube has a low density of states at the Fermi level, and thus its conductivity is only comparable to moderate metals but lower than that of copper. 2) Metallic and semiconducting nanotubes are inherently mixed together from the synthesis, and the selection/separation is very difficult with very low efficiency. 3) Carbon nanotubes alone cannot be used …

Interdiffusion Reaction Between Uranium-Zirconium And Iron, Young Joo Park

Electronic Theses and Dissertations

U-Zr metallic fuels cladded in Fe-alloys are being considered for application in an advanced Sodium-Cooled Fast Reactor (SFR) that can recycle the U-Zr fuels and minimize the long-lived actinide waste. To understand the complex fuel-cladding chemical interaction of the U-Zr metallic fuel with Fe-alloys, a systematic multicomponent diffusion study was carried out using solid-to-solid diffusion couples. The U-10 wt.% Zr vs. pure Fe diffusion couples were assembled and annealed at temperatures, 630, 650 and 680°C for 96 hours. Development of microstructure, phase constituents, and compositions developed during the thermal anneals were examined by scanning electron microscopy, transmission electron microscopy and …

High Volume Fraction Mg-Based Nanocomposites: Processing, Microstructure And Mechanical Behavior, Jinling Liu

Electronic Theses and Dissertations

Mg-based metal matrix nanocomposites (MMNCs) with mechanical properties, superior to those of coarse-grained composites, are promising structural materials for applications in the automotive and aerospace industries. The research in this area was primarily focused earlier on either micro-scaled reinforcements or nano-scaled reinforcements with very low volume fractions. MMNCs with high volume fractions have not been explored yet. In this research, we study the processing, microstructures and properties of MMNCs containing ceramic nanoparticles up to 30 vol.%. We first investigated the mechanical alloying of Al2O3 nanoparticles and pure Mg under high-energy ball milling conditions. The phase evolution and their distribution were …

Corrosion Behaviour Of Aisi 304 Stainless Steel In Contact With Eutectic Salt For Concentrated Solar Power Plant Applications, Omar Ahmed

Electronic Theses and Dissertations

In response to the extensive energy demands on national and global levels, concentrated solar power (CSP) plants are designed to harness and convert solar energy to electricity. For such green energy application, robust, reliable and durable materials for CSP constructions are required. The corrosion resistance is among many parameters to consider in these thermalelectrical stations such as for pipes and storage tanks in CSP. In this investigation, the corrosion behavior of AISI 304 stainless steel (18 wt. % Cr, 8 wt. % Ni) with the heat transfer fluid, also known as solar salt, has been examined. The ternary eutectic salt …

Interdiffusion And Impurity Diffusion In Magnesium Solid Solutions, Catherine Kammerer

Electronic Theses and Dissertations

Magnesium, being lightweight, offers potential to be developed into extensive structural applications. The transportation segment has particular interest in Mg and Mg alloy for applications where reduced vehicle weight is proportional to increased fuel efficiency. Aluminum and zinc are two of the most common alloying elements in commercial Mg alloys. They improve the physical properties of Mg through solid solution strengthening and precipitation hardening. Diffusion plays a key role in the kinetics of and microstructural development during solidification and heat treatment. However, there is limited diffusion data available for Mg and Mg alloys. In particular, because Al is monoisotopic, tracer …

Development Of Nitrogen Concentration During Cryomilling Of Aluminum Composites, Clara Hofmeister

Electronic Theses and Dissertations

The ideal properties of a structural material are light weight with extensive strength and ductility. A composite with high strength and tailorable ductility was developed consisting of nanocrystalline AA5083, boron carbide and coarser grained AA5083. The microstructure was determined through optical microscopy and transmission electron microscopy. A technique was developed to determine the nitrogen concentration of an AA5083 composite from secondary ion mass spectrometry utilizing a nitrogen ionimplanted standard. Aluminum nitride and amorphous nitrogen-rich dispersoids were found in the nanocrystalline aluminum grain boundaries. Nitrogen concentration increased as a function of cryomilling time up to 72hours. A greater nitrogen concentration resulted …

Nano-Morphology Of Polymer Bulk Herojunctions Studied By Time-Resolved Synchrotron X-Ray Scattering, Soo Kim

Material Science and Engineering Dissertations - Archive

This study investigates the phase transformation of an active layer in organic photovoltaics (OPV) during film deposition and post thermal treatment as well as effects of phase transformation on OPV performance. For this purpose, small - and wide angle X-ray scattering technique (SAXS and WAXS) was applied to examine the phase separation mechanism at relevant fabrication condition of the highest OPV device performance. The poly(3-alkylthiophene)/[6,6]-phenyl-C61 butyric acid methylester (P3AT/PCBM) blend sample was employed in order to study phase transformation of the active layer systemically.Our exploration with SAXS and WAXS technique found that the polarity of the substrate, a solubility, and …

Fabrication And Characterization Of Barium Titanate Thin Film On Polycrystalline Nickel Substrate, Parisa Sahebi

Material Science and Engineering Theses - Archive

Ferroelectric BaTiO₃(BTO) thin films were deposited on polycrystalline nickel disks and silicon wafer substrates by rf magnetron sputtering. Nickel oxide (NiO) and nanocrystalline nickel (nc-Ni) layers were used as interfacial buffer layers. Microstructural studies with X-ray diffraction and transmission electron microscopy reveal that the BTO films deposited at temperatures lower than 700℃ have an amorphous structure. However, the BTO films sputtered at temperatures higher than 700℃ are partially crystalline. BTO films have a good and continuous interface with both interfacial layers with no interdiffusion or reaction with the substrates. In the case of BTO deposition with nc-Ni interlayer at higher …

Effect Of Microwave Heating On The Migration Of Additives From Ps, Pp And Pet Container Into Food Simulants, Ruoyin Cai

Theses

Microwave food packaging has become a tremendous element in the food manufacturing process. The purpose of any food packaging regulations concerned with the safety of the food is to control and limit the migration of substances from the packaging into the food. The main objective of this thesis is to test three different microwaving packaging materials that are the most common material in the market, viz. polystyrene (PS), polypropylene (PP), and polyethylene terephthalate (PET), migrated into four food simulant solutions. Four different simulant solutions were used based on the food type and FDA recommendations and regulations. These food simulants include …

Effect Of Thermal Annealing And Carbon Implantation On The Functional Properties Of Nanocomposite Tisin Coatings On Steel, Mohammad Shoeb Ahmed

Theses: Doctorates and Masters

This PhD research contributes to the part of advanced materials technology. The machining industry currently faces tremendous pressures with the need for durable cutting tools suitable for eco-friendly high speed machining operations becoming acute. In this thesis innovative design and synthesis strategies are explored to tailor the properties of nanocomposite coatings. Advanced characterisation techniques are applied to identify the mechanisms that control the mechanical, tribological, and corrosion behaviours of these coatings. Cutting tools protected by these coatings are anticipated to exhibit a unique combination of superior toughness and greater resistance to wear and corrosion, providing significant economic and environmental benefits. …

Surface Plasmons For Enhanced Metal-Semiconductor-Metal Photodetectors, Ayman A. Karar

Theses: Doctorates and Masters

Surface Plasmon Polaritons (SPPs) are quantized charge density oscillations that occur when a photon couples to the free electron gas of the metal at the interface between a metal and a dielectric. The extraordinary properties of SPP allow for sub-diffraction limit waveguiding and localized field enhancement. The emerging field of surface plasmonics has applied SPP coupling to a number of new and interesting applications, such as: Surface Enhanced Raman Spectroscopy (SERS), super lenses, nano-scale optical circuits, optical filters and SPP enhanced photodetectors. In the past decade, there have been several experimental and theoretical research and development activities which reported on …

Processing, Microstructural Evolution And Electrochemical Performance Relationships In Solid Oxide Fuel Cells, Ayhan Sarikaya

Doctoral Dissertations

"The relationships between the processing parameters, microstructures and electrochemical performance of solid oxide fuel cell (SOFC) components were investigated. The operating regimes (i.e., reducing vs. oxidizing) as well as the elevated temperatures (e.g. 800°C) for their operation introduce several material challenges. Therefore, composite materials are employed to withstand operating conditions while providing sufficient electrochemical performance for fuel cell operation. Analyses on lanthanum-strontium manganite (LSM) - yttria stabilized zirconia (YSZ) compositions (45 vol%-55 vol%) by impedance spectroscopy demonstrated that two competing polarization mechanisms (i.e. charge-exchange and surface adsorption-diffusion of oxygen) limit performance. Optimization of microstructures resulted in total resistances as low …

Liquid Phase Sintering Of 20bi(Zn₀.₅Ti₀.₅)O₃-80batio₃ Dielectrics With Bismuth-Zinc-Borate And Bismuth Borosilicate Glasses, David I. Shahin

Masters Theses

"Dielectrics in the Bi(Zn₀.₅Ti₀.₅O₃-BaTiO₃ system (specifically 20BZT-80BT, in mol%) are promising candidates for high energy density capacitor applications due to broad temperature-dependent dielectric constant maxima and a relatively field-independent permittivity. Bulk samples require sintering temperatures of greater than 1180ºC to reach useful densities. Due to incompatibility of Bi with low-pO₂ processing, BZT-BT-based multilayer capacitors must utilize noble metal electrodes that resist oxidation during sintering. Sintering temperatures must be reduced to allow use of less expensive electrode materials (Cu, etc.). This work studies the reduced temperature sintering behavior and dielectric properties of BZT-BT sintered with 30 Bi₂O₃-30ZnO-40B₂O₃ and 50Bi₂O₃-25B₂O₃-25SiO₂ (mol%) liquid …

The Use Of Elemental Powder Mixes In Laser-Based Additive Manufacturing, Rodney Michael Clayton

Masters Theses

"This study examines the use and functionality of laser depositing alloys from mixes of elemental metallic powders. Through the use of laser-based additive manufacturing (LAM), near net-shaped 3-Dimensional metallic parts can be produced in a layer-by-layer fashion. It is customary for pre-alloyed powders to be used in this process. However, mixes of elemental powders can be used to produce alloys that are formed during the deposition process. This alternative technique requires that the elemental powders adequately mix during deposition for a homogeneous deposit to be produced. Cost savings and versatility are among several of the advantages to using elemental powder …

Effects Of Material Variables And Process Parameters On Properties Of Investment Casting Shells, Priyatham Tumurugoti

Masters Theses

"Manufacture of investment casting shells is a complex process. The choice of raw materials - refractory powders or grains, binders and additives - affects the properties of investment casting shells. In this study, different systems of shells were prepared, according to a design of experiments, with commercially available raw materials that differ in chemistry, particle size or particle size distribution. Shell strength was measured in green, fired and cooled, and hot conditions and the results were analyzed for strength-material property relation. Various microstructures of polished cross sections of these shells were characterized using scanning electron microscope. It was determined that …

Processing And Properties Of Zrb₂-Zrsi₂ Matrix Composites Reinforced With Continuous Sic Fiber, Benjamin John Bowin Lai

Masters Theses

"The research presented in this thesis focuses on the processing, microstructure, and mechanical properties of ZrB₂-based composites. The main goal was to develop a process that incorporates high strength continuous SiC fiber in a ZrB₂-based matrix. In order to achieve this, the densification, microstructure, and mechanical properties of ZrB₂-ZrSi₂ monolithic ceramics were characterized along with various SiC fiber reinforced ceramic matrix composites (CMCs) utilizing the same matrix.

There were two main areas of study in this thesis. The initial study demonstrated that additions of ZrSi₂ into a ZrB₂ ceramic increases densification at significantly reduced processing temperatures ≤1600ºC). This study revealed …

Mse Annual Report 2013, Department Of Materials Science And Engineering, Michigan Technological University

Department of Materials Science and Engineering Annual Reports

Table of Contents

• Paul Sanders, Project-Oriented Learning
• A New Way to Prevent Deadly Infections
• 3D Printers for Peace and Progress
• Faculty and Staff News
• Graduate Student Update
• Outreach
• Undergraduate Student News
• Alumni at a Glance

Faulted Structures In Li Ion Exchanged Namo2 (M=Ni(0.25)Mn(0.75)), Aaron M. Dewahl

Dissertations, Master's Theses and Master's Reports - Open

A family of LiMO2 materials (M=Ni_0.25Mn_0.75) was prepared from Na_1.2-xLi_xMO_∂ precursors (0≤x≤0.6) via ion exchange. The resulting IE products were examined via XRD and compared to simulated XRD patterns produced using DIFFax to determine the defect structures resulting from the IE process. For the 0.1≤x≤0.6 materials, it is observed that there are 3 LiMO₂ sub-phases with different Li contents present. As the amount of Li in the precursor increases, the amount of each phase changes resulting in a net shift to higher 2-theta; corresponding to an overall decrease in lattice …

An Investigation Of Waste Glass-Based Geopolymers Supplemented With Alumina, Mary U. Christiansen

Dissertations, Master's Theses and Master's Reports - Open

An increased consideration of sustainability throughout society has resulted in a surge of research investigating sustainable alternatives to existing construction materials. A new binder system, called a geopolymer, is being investigated to supplement ordinary portland cement (OPC) concrete, which has come under scrutiny because of the CO2 emissions inherent in its production.

Geopolymers are produced from the alkali activation of a powdered aluminosilicate source by an alkaline solution, which results in a dense three-dimensional matrix of tetrahedrally linked aluminosilicates. Geopolymers have shown great potential as a building construction material, offering similar mechanical and durability properties to OPC. Additionally, geopolymers have …

Molecular Modeling Of Pmr-15 Polyimide, Fnu Pruthul Kokkada Ravindranath

Dissertations, Master's Theses and Master's Reports - Open

PMR-15 polyimide is a polymer that is used as a matrix in composites. These composites with PMR-15 matrices are called advanced polymer matrix composite that is abundantly used in the aerospace and electronics industries because of its high temperature resistivity. Apart from having high temperature sustainability, PMR-15 composites also display good thermal-oxidative stability, mechanical properties, processability and low costs, which makes it a suitable material for manufacturing aircraft structures. PMR-15 uses the reverse Diels-Alder (RDA) method for crosslinking which provides it with the groundwork for its distinctive thermal stability and a range of 280-300 degree Centigrade use temperature. Regardless of …

Dysprosium Transport In Nd-Fe-B Pellets, Parawee Pumwongpitak

Dissertations, Master's Theses and Master's Reports - Open

The addition of heavy rare earth (RE) elements to Nd2Fe14B based magnets to form (Nd,Dy)₂Fe₁₄B is known to increase the coercivity and high temperature performance required for hybrid vehicle electric motors and other extreme temperature applications. Attempts to conserve heavy rare earth elements for high temperature (RE)₂Fe₁₄B based magnets have led to the development of a grain boundary diffusion process for bulk magnets. This process relies on transport of a heavy rare earth, such as Dy, into a bulk Nd₂Fe₁₄B magnet along pores, a low volume fraction of …

Parametric Study Of Reaxff Simulation Parameters For Molecular Dynamics Modeling Of Reactive Carbon Gases, Benjamin David Jensen

Dissertations, Master's Theses and Master's Reports - Open

Abstract

Intergranular Corrosion And Stress Corrosion Cracking Of Extruded Aa6005a, David James Seguin

Dissertations, Master's Theses and Master's Reports - Open

A research program focused on understanding the intergranular corrosion (IGC) and stress corrosion cracking (SCC) behavior of AA6005A aluminum extrusions is presented in this dissertation. The relationship between IGC and SCC susceptibility and the mechanisms of SCC in AA6005A extrusions were studied by examining two primary hypotheses.

IGC susceptibility of the elongated grain structure in AA6005A exposed to low pH saltwater was found to depend primarily on the morphology of Cu-containing precipitates adjacent to the grain boundaries in the elongated grain structure. IGC susceptibility was observed when a continuous (or semi-continuous) film of Cu-containing phase was present along the grain …

Reducing Metal Alloy Powder Costs For Use In Powder Bed Fusion Additive Manufacturing: Improving The Economics For Production, Fransisco Medina

Open Access Theses & Dissertations

Titanium and its associated alloys have been used in industry for over 50 years and have become more popular in the recent decades. Titanium has been most successful in areas where the high strength to weight ratio provides an advantage over aluminum and steels. Other advantages of titanium include biocompatibility and corrosion resistance. Electron Beam Melting (EBM) is an additive manufacturing (AM) technology that has been successfully applied in the manufacturing of titanium components for the aerospace and medical industry with equivalent or better mechanical properties as parts fabricated via more traditional casting and machining methods. As the demand for …

Crystal Structure, Phase, And Optical Properties Of Yttrium-Doped Hafnium Oxide Nanocrystalline Thin Films, Alejandro Ortega

Open Access Theses & Dissertations

Yttrium-doped hafnium oxide (YDH) nanocrystalline films were produced by sputter-deposition at various substrate times and temperatures, to produce YDH films in a wide range of thicknesses, dYDH∼25 to 1100 nm. The deposition was made onto optical grade quartz and sapphire substrates. Samples deposited on sapphire were subject to post-deposition annealing (PDA) at various times (3-24 hr) and temperatures (1100 - 1500 °C). The effect of d[special characters omitted]YDH on the crystal structure, surface/interface morphology and optical properties of YDH films was investigated. X-ray diffraction analyses revealed the formation of monoclinic phase for relatively thin films (<150nm). The evolution towards stabilized cubic phase with increasing dYDH [special characters omitted]is observed. The scanning electron microscopy results indicate the dense, columnar structure of YDH films as a function of dYDH. Spectrophotometry analyses indicate that the grown YDH films are transparent and exhibit interference fringes. The band gap was found to be ∼ 5.60 eV for monoclinic YDH films while distinct separation and an increase in band gap to 6.03 eV is evident with increasing dYDH and formation cubic YDH films. The PDA films band gaps were found to be between 5.31 and 5.72 eV, all of which exhibit secondary gaps. A correlation between growth conditions, annealing, phase evolution, and optical properties of the YDH nanocrystalline thin films is established.