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2009

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Articles 61 - 90 of 310

Full-Text Articles in Materials Science and Engineering

Implementation Of Six Sigma Method To Maintain The Quality Of Construction Projects, Yusuf Latief, Retyaning Puji Utami Nov 2009

Implementation Of Six Sigma Method To Maintain The Quality Of Construction Projects, Yusuf Latief, Retyaning Puji Utami

Makara Journal of Technology

Implementation of Six Sigma Method to Maintain The Quality of Construction Projects. Six sigma (6-sigma) is a method that widely developed in the world, especially in manufacturing industry to decrease failures in achieving good quality in construction projects. The objective of this research is to explore the existing condition of quality management and the aplication of 6-sigma method in maintaining quality of construction projects. Structured interviews to experienced experts and people who were recommended by their companies were conducted. Non-parametric analysis using frequencies distribution procedures were used for analysis. The result shows that existing condition in quality management of construction …


Simple Ml Detector For Multiple Antennas Communication System, Ahmad Taqwa, Soegijardjo Soegijoko, Sugihartono Sugihartono, Suhartono Tjondronegoro Nov 2009

Simple Ml Detector For Multiple Antennas Communication System, Ahmad Taqwa, Soegijardjo Soegijoko, Sugihartono Sugihartono, Suhartono Tjondronegoro

Makara Journal of Technology

Simple ML Detector for Multiple Antennas Communication System. In order to support providing broadband wireless communication services against limited and expensive frequency bandwidth, we have to develop a bandwidth efficient system. Therefore, in this paper we propose a closed-loop MIMO (Multiple-Input-Multiple-Output) system using ML (Maximum Likelihood) detector to optimize capacity and to increase system performance. What is especially exciting about the benefits offered by MIMO is that a high capacity and performance can be attained without additional frequency-spectral resource. The grand scenario of this concept is the attained advantages of transformation matrices having capability to allocate transmitted signals power suit …


Mechanical Properties Of Ramie Fiber Reinforced Epoxy Lamina Composite For Socket Prosthesis, Tresna P. Soemardi, Widjajalaksmi Kusumaningsih, Agustinus Purna Irawan Nov 2009

Mechanical Properties Of Ramie Fiber Reinforced Epoxy Lamina Composite For Socket Prosthesis, Tresna P. Soemardi, Widjajalaksmi Kusumaningsih, Agustinus Purna Irawan

Makara Journal of Technology

Mechanical properties of ramie fiber reinforced epoxy lamina composite for socket prosthesis. This paper presents an investigation into the application of natural fiber composite especially ramie fiber reinforced epoxy lamina composite for socket prosthesis. The research focuses on the tensile and shear strength from ramie fiber reinforced epoxy lamina composite which will be applied as alternative material for socket prosthesis. The research based on American Society for Testing Material (ASTM) standard D 3039/D 3039M for tensile strength and ASTM D 4255/D 4255M-83 for shear strength. The ramie fiber applied is a fiber continue 100 % Ne14'S with Epoxy Resin Bakelite …


Potency Of Thermoelectric Generator For Hybrid Vehicle, Nandy Putra, Raldi Artono Koestoer, Mohammad Adhitya, Ardian Roekettino, Bayu Trianto Nov 2009

Potency Of Thermoelectric Generator For Hybrid Vehicle, Nandy Putra, Raldi Artono Koestoer, Mohammad Adhitya, Ardian Roekettino, Bayu Trianto

Makara Journal of Technology

Potency of Thermoelectric Generator for Hybrid Vehicle. Thermoelectric Generator (TEG) has been known as electricity generation for many years. If the temperature difference occurred between two difference semi conductor materials, the current will flow in the material and produced difference voltage. This principle is known as Seebeck effect that is the opposite of Peltier effect Thermoelectric Cooling (TEC). This research was conducted to test the potential of electric source from twelve peltier modules. Then, these thermoelectric generators were applied in hybrid car by using waste heat from the combustion engine. The experiment has been conducted with variations of peltier module …


Performance Of Hollow Fiber Membrane Gas-Liquid Contactors To Absorb Co2 Using Diethanolamine (Dea) As A Solvent, Sutrasno Kartohardjono, Pan Ade Nata, Eko Prasetio, Yuliusman Yuliusman Nov 2009

Performance Of Hollow Fiber Membrane Gas-Liquid Contactors To Absorb Co2 Using Diethanolamine (Dea) As A Solvent, Sutrasno Kartohardjono, Pan Ade Nata, Eko Prasetio, Yuliusman Yuliusman

Makara Journal of Technology

This study uses DEA solution to absorb CO2 from the gas flow through the hollow fiber membrane contactors. This study aims to evaluate the performance of hollow fiber membrane contactors to absorb CO2 gas using DEA solution as solvent through mass transfer and hydrodynamics studies. The use of DEA solution is to reduce the mass transfer resistance in the liquid phase, and on the other side, the large contact area of the membrane surface can cover the disadvantage of membrane contactors; additional mass transfer resistance in the membrane phase. During experiments, CO2 feed flows through the fiber lumens, while the …


Effect Of Stress Ratio On The Fatigue Behavior Of A Friction Stir Processed Cast Al-Si-Mg Alloy, S. Jana, Rajiv S. Mishra, J. B. Baumann, G. Grant Nov 2009

Effect Of Stress Ratio On The Fatigue Behavior Of A Friction Stir Processed Cast Al-Si-Mg Alloy, S. Jana, Rajiv S. Mishra, J. B. Baumann, G. Grant

Materials Science and Engineering Faculty Research & Creative Works

The effect of friction stirs processing (FSP) on the fatigue life of a cast Al-7Si-0.6 Mg alloy at stress ratios of R = 0 and R = -1 was evaluated. Two types of specimen geometry were used for the FSPed condition, through thickness processed and partial thickness processed. at R = 0, the microstructural refinement enhanced the fatigue life by a factor of 15, whereas at R = -1 the improvement in fatigue life was 5-fold. in light of these observations, various closure mechanisms were examined. © 2009 Acta Materialia Inc.


Continuous Steel Production And Apparatus, Kent D. Peaslee, Jörg Peter, D. G. C. Robertson, Brian G. Thomas, Lifeng Zhang Nov 2009

Continuous Steel Production And Apparatus, Kent D. Peaslee, Jörg Peter, D. G. C. Robertson, Brian G. Thomas, Lifeng Zhang

Materials Science and Engineering Faculty Research & Creative Works

A process for continuous refining of steel via multiple distinct reaction vessels for melting, oxidation, reduction, and refining for delivery of steel continuously to, for example, a tundish of a continuous caster system, and associated apparatus.


On The Thermal Activation Of Negative Bias Temperature Instability, Richard G. Southwick Iii, William B. Knowlton, Ben Kaczer, Tibor Grasser Oct 2009

On The Thermal Activation Of Negative Bias Temperature Instability, Richard G. Southwick Iii, William B. Knowlton, Ben Kaczer, Tibor Grasser

Materials Science and Engineering Faculty Publications and Presentations

The temperature dependence of negative bias temperature instability (NBTI) is investigated on 2.0nm SiO2 devices from temperatures ranging from 300K down to 6K with a measurement window of ~12ms to 100s. Results indicate that classic NBTI degradation is observed down to ~200K and rarely observed at temperatures below 140K in the experimental window. Since experimental results show the charge trapping component contributing to NBTI is thermally activated, the results cannot be explained with the conventionally employed elastic tunneling theory. A new mechanism is observed at temperatures below 200K where device performance during stress conditions improves rather than degrades with …


Workshop - Feminist Engineering Education: Building A Community Of Practice, Alice L. Pawley, Donna Riley, Susan M. Lord, Trevor S. Harding Oct 2009

Workshop - Feminist Engineering Education: Building A Community Of Practice, Alice L. Pawley, Donna Riley, Susan M. Lord, Trevor S. Harding

Materials Engineering

As a result of a series of papers and special sessions held at FIE between 2004 and 2008, a community of CSET educators interested in exploring feminist pedagogies has formed at FIE. Past participants in these sessions have expressed a desire to learn more about what makes a set of pedagogies "feminist." At the same time, there has been an increase in the number of research papers at FIE that draw on feminist research methods or topics. This workshop is designed to meet the needs of members of the FIE community who have some experience with feminist pedagogies or research …


A Systematic Study Of Atomic Layer Deposition Of Platinum Nano-Scale Metallization Films And Their Application To Electrical Contacts In Porous Alumina Templates, Ngoc H. Tran Oct 2009

A Systematic Study Of Atomic Layer Deposition Of Platinum Nano-Scale Metallization Films And Their Application To Electrical Contacts In Porous Alumina Templates, Ngoc H. Tran

Electrical & Computer Engineering Theses & Dissertations

ln this thesis a comprehensive analysis is presented on nano-scale thin films of platinum deposited with Angstrom resolution by Atomic Layer Deposition (ALD) technology utilizing the Cambridge Nanotech Savannah 100 ALD system. Physical characterizations of film thickness, film morphology, and surface roughness of the deposited platinum were all performed before and after rapid thermal annealing (RTA) and as a function of forming gas annealing (FGA). Noble metal thin films of platinum were deposited on four inch wafers of p-type boron doped &100& oriented silicon (Si) substrates. The ALD film thickness was measured with a novel method utilizing the linear dependence …


Focusing Electromagnetic Radiation In Dielectric Media, Mark A. Migliaccio Jr. Oct 2009

Focusing Electromagnetic Radiation In Dielectric Media, Mark A. Migliaccio Jr.

Electrical & Computer Engineering Theses & Dissertations

Bioelectrics and microwave imaging requires an ultra-wideband (UWB) antenna to deliver intense, short electromagnetic pulses into biological targets for the purpose of therapy and imaging. Two antennas with different focal distances, predicted by a two­ dimensional model, have been designed for focusing electromagnetic radiation in the near field.

Focusing is achieved through the use of prolate spheroidal reflector antennas with a conical wave launcher submerged in water. For an ultra-wideband feed signal, with a rise time of 200 picoseconds, the maximum electric field was found to be close to the edge of the reflector, a result that differs from the …


Nanoscale Domain Patterns In Ultrathin Polymer Ferroelectric Films, Pankaj Sharma, Timothy J. Reece, Daniel W. Wu, Vladimir M. Fridkin, Stephen Ducharme, Alexei Gruverman Oct 2009

Nanoscale Domain Patterns In Ultrathin Polymer Ferroelectric Films, Pankaj Sharma, Timothy J. Reece, Daniel W. Wu, Vladimir M. Fridkin, Stephen Ducharme, Alexei Gruverman

Stephen Ducharme Publications

High-resolution studies of domain configurations in Langmuir–Blodgett films of ferroelectric polymer poly(vinylidene fluoride-trifluoroethylene), P(VDF-TrFE), have been carried out by means of piezoresponse force microscopy (PFM). Changes in film thickness and morphology cause significant variations in polarization patterns. In continuous films and nanomesas with relatively low thickness/grain aspect ratio (<1/10), the relationship between the average domain size and thickness follows the Kittel law. Nanomesas with high aspect ratio (>1/5) exhibit significant deviations from this law, suggesting additional surface-energy-related mechanisms affecting the domain patterns. Polarization reversal within a single crystallite has been demonstrated and local switching parameters (coercive voltage and remnant piezoresponse) have been measured by monitoring the local hysteresis loops. Reliable control of polarization at the sub-grain level demonstrates …


Technical Research Needs For Sustainable Buildings: Results From A Multidisciplinary Nsf Workshop, Leidy Klotz, Vivien Loftness, Gregor Henze, David J. Sailor, David Riley Oct 2009

Technical Research Needs For Sustainable Buildings: Results From A Multidisciplinary Nsf Workshop, Leidy Klotz, Vivien Loftness, Gregor Henze, David J. Sailor, David Riley

Mechanical and Materials Engineering Faculty Publications and Presentations

This article describes research needs for sustainable buildings as defined in a July 2009 National Science Foundation-sponsored workshop. This workshop brought together building researchers with researchers in the areas of distributed renewable energy and multifunctional materials to engage their expertise and identify overlapping research needs and opportunities. An overview of sustainable building design provided the broad context for discussion. This overview was followed by focused presentations in building control systems, advanced building envelopes, and systems and process integration. In addition, presentations on distributed renewable energy and multi-functional materials supported the participants in outlining and generating research needs that connect the …


Methods For Cancer Detection, Kimberly W. Anderson, Kimberly M.L. May, Leonidas G. Bachas Sep 2009

Methods For Cancer Detection, Kimberly W. Anderson, Kimberly M.L. May, Leonidas G. Bachas

Chemical and Materials Engineering Faculty Patents

A method is provided for detecting an analyte indicative of a cancer or a metastatic disease condition, which utilizes the ability of the analyte to induce permeability in a barrier. The method includes providing a biosensor having a barrier which is substantially impermeable to an ion, a permeable membrane which is selective for the ion, and a detector capable of detecting the ion. The biosensor is contacted with a sample including at least one of the ion and the analyte, wherein the analyte causes at least a portion of the ion to pass through the barrier and the membrane. Passage …


Shear Rate Threshold For The Boundary Slip In Dense Polymer Films, Nikolai V. Priezjev Sep 2009

Shear Rate Threshold For The Boundary Slip In Dense Polymer Films, Nikolai V. Priezjev

Mechanical and Materials Engineering Faculty Publications

The shear rate dependence of the slip length in thin polymer films confined between atomically flat surfaces is investigated by molecular dynamics simulations. The polymer melt is described by the bead-spring model of linear flexible chains. We found that at low shear rates the velocity profiles acquire a pronounced curvature near the wall and the absolute value of the negative slip length is approximately equal to thickness of the viscous interfacial layer. At higher shear rates, the velocity profiles become linear and the slip length increases rapidly as a function of shear rate. The gradual transition from no-slip to steady-state …


Work In Progress - A Mixed-Methods Approach To Developing An Instrument Measuring Engineering Students' Positive Ethical Behavior, Mathew A. Holsapple, Cynthia J. Finelli, Donald D. Carpenter, Trevor S. Harding, Janel A. Sutkus Sep 2009

Work In Progress - A Mixed-Methods Approach To Developing An Instrument Measuring Engineering Students' Positive Ethical Behavior, Mathew A. Holsapple, Cynthia J. Finelli, Donald D. Carpenter, Trevor S. Harding, Janel A. Sutkus

Materials Engineering

Ethics education and the drive to produce ethical professional engineers is an important focus of one body of research on engineering education. This research often defines the positive outcome of ethics education as students and professional engineers choosing not to engage in unethical behavior. This paper discusses a portion of a larger research project and details efforts to identify and validate a definition of ethical behavior that includes the decision to engage in a positive behavior, defined as a service to a larger community. Through a series of interviews and focus groups with engineering administrators, faculty, and students, the authors …


Thermo-Mechanical Characterization Of Silicon Carbide-Silicon Carbide Composites At Elevated Temperatures Using A Unique Combustion Facility, Ted T. Kim Sep 2009

Thermo-Mechanical Characterization Of Silicon Carbide-Silicon Carbide Composites At Elevated Temperatures Using A Unique Combustion Facility, Ted T. Kim

Theses and Dissertations

This research investigated four different types of CMCs in a simulated gas turbine engine hot section condition that involved the simultaneous application of a combustion environment and mechanical fatigue loading using a unique burner rig facility developed for this study at AFIT. Three of the materials were woven Melt-Infiltrated (MI) BN/SiC reinforced by Hi-Nicalon Type S (Hi-Nic-S), Sylramic (Syl) and Sylramic with insitu BN coating (Syl-iBN) fibers, respectively. They were made by the slurry cast method. The other CMC was MI Hi-Nic-S/BN/SiC made using the prepreg MI processing. Prepreg MI CMC and Sylramic-iBN fiber reinforced CMC showed better resistance to …


Feasibility Of Ellipsometric Sensor Development For Use During Pecvd Siox Coated Polymer Product Manufacturing, Daniel Lynn Helms Sep 2009

Feasibility Of Ellipsometric Sensor Development For Use During Pecvd Siox Coated Polymer Product Manufacturing, Daniel Lynn Helms

Master's Theses

Polymeric materials have provided pathways to products that could not be manufactured otherwise. A new technology which merges the benefits of ceramics into these polymer products has created materials ideally suited to many different industries, like food packaging. Nano Scale Surface Systems, Inc. (NS3), a company which coats polymers with ceramic oxides like SiO2 through a process known as plasma enhanced chemical vapor deposition (PECVD), was interested in the feasibility of an in line measurement system for monitoring the deposited films on various polymer products. This project examined two different coated polymer products, polyethylene terephthalate (PET) beverage containers and biaxially …


Emerging Nonequilibrium Bound State In Spin-Current-Local-Spin Scattering, Fatih Dogan, Lucian Covaci, Wonkee Kim, Frank Marsiglio Sep 2009

Emerging Nonequilibrium Bound State In Spin-Current-Local-Spin Scattering, Fatih Dogan, Lucian Covaci, Wonkee Kim, Frank Marsiglio

Materials Science and Engineering Faculty Research & Creative Works

Magnetization reversal is a well-studied problem with obvious applicability in computer hard drives. One can accomplish a magnetization reversal in at least one of two ways: application of a magnetic field or through a spin current. The latter is more amenable to a fully quantum-mechanical analysis. We formulate and solve the problem whereby a spin current interacts with a ferromagnetic Heisenberg spin chain, to eventually reverse the magnetization of the chain. Spin flips are accomplished through both elastic and inelastic scattering. A consequence of the inelastic-scattering channel, when it is no longer energetically possible, is the occurrence of a nonequilibrium …


Assessment Of Electrospinning As An In-House Fabrication Technique For Blood Vessel Mimic Cellular Scaffolding, Colby M. James Sep 2009

Assessment Of Electrospinning As An In-House Fabrication Technique For Blood Vessel Mimic Cellular Scaffolding, Colby M. James

Master's Theses

Intravascular devices, such as stents, must be rigorously tested before they can be approved by the FDA. This includes bench top in vitro testing to determine biocompatibility, and animal model testing to ensure safety and efficacy. As an intermediate step, a blood vessel mimic (BVM) testing method has been developed that mimics the three dimensional structure of blood vessels using a perfusion bioreactor system, human derived endothelial cells, and a biocompatible polymer scaffold used to support growth of the blood vessel cells. The focus of this thesis was to find an in-house fabrication method capable of making cellular scaffolding for …


A Novel Approach To Predicting The Lifetime Of Elastomers Undergoing Stress Relaxation, Stephen Ronan Sep 2009

A Novel Approach To Predicting The Lifetime Of Elastomers Undergoing Stress Relaxation, Stephen Ronan

Doctoral

his work opens with a broad overview of several factors influencing the behaviour of elastomeric materials under constant deformation. Following this, an evaluation of the common difficulties surrounding industry-standard lifetime prediction methods is presented. Subsequently, a novel method for the lifetime prediction of stress relaxation in elastomeric materials under constant deformation is introduced. Experimental testing to determine the influence of filler type and content was conducted on several natural rubber materials. The effect of altering the vulcanising agent, crosslink density and mixing time was also examined. Chemiluminescence was used to determine the influence that oxidation has on the overall life …


Dielectric Nanocomposites: An Inside-Out Approach To Storing Electrostatic Energy, Stephen Ducharme Sep 2009

Dielectric Nanocomposites: An Inside-Out Approach To Storing Electrostatic Energy, Stephen Ducharme

Stephen Ducharme Publications

The ability to achieve high-energy densities is the central challenge in energy storage and recovery. A promising strategy for increasing energy storage is to use highperformance dielectric materials, such as highly polarizable nanoparticles or polymers, or nanocomposites of the two. In this issue, Kim et al. use a molecular coating and clever chemistry to combine oxide nanoparticles with a polymer matrix, thereby producing an improved nanocomposite dielectric. Some advantages and challenges of using nanocomposites as improved dielectric materials are presented in this Perspective.


Synthesis And Characterization For A New Organic Cathode Material Of Lithium-Ion Batteries——Poly Sulfurized Chloranilic Acid(Psca), Kai Liu, Jian-Ming Zheng, Gui-Ming Zhong, Yong Yang Aug 2009

Synthesis And Characterization For A New Organic Cathode Material Of Lithium-Ion Batteries——Poly Sulfurized Chloranilic Acid(Psca), Kai Liu, Jian-Ming Zheng, Gui-Ming Zhong, Yong Yang

Journal of Electrochemistry

A new organic cathode material,poly sulfurized chloranilic acid(PSCA),has been successfully synthesized for lithium-ion batteries. 13C solid state NMR and FTIR results indicated that the chorine in chronailic acid was substituted by sulfur after sulfurization. The electrochemical measurements showed that the initial discharge capacity of PSCA was up to 287.6 mAh/g,and 169.9 mAh/g still remained after 100 cycles when cycled between 1.5~3.6 V at the current density of 15 mA/g.


Silicon Silver Composite Materials For Li-Ion Batteries, Lian-Bang Wang, Xiao-Bo Dai, Xin-Yan Zhu, Xin-Biao Mao, Chun-An Ma Aug 2009

Silicon Silver Composite Materials For Li-Ion Batteries, Lian-Bang Wang, Xiao-Bo Dai, Xin-Yan Zhu, Xin-Biao Mao, Chun-An Ma

Journal of Electrochemistry

properties of the composites were determined by charge-discharge tests and cyclic voltammetry. The composite composed of Si∶Ag with an atomic ratio of 1∶1 (sample 1#) showed good cyclic stability and charge-discharge reversibility. The reversible capacity of the composite (sample 1#) was remained over 300 mAh·g-1 after 50 cycles. Experimental results showed that controlling the potential range of charge-discharge processes could enhance the cyclic performance of alloy materials.


Synergism Of Complex Additives Of Dtab+Ktl For Zinc Corrosion Inhibition In Koh Solutions, Sheng-Zhou Lin, Zeng-Xin Cai, Gui-Sheng Wang, He-Bing Zhou, Wei-Shan Li Aug 2009

Synergism Of Complex Additives Of Dtab+Ktl For Zinc Corrosion Inhibition In Koh Solutions, Sheng-Zhou Lin, Zeng-Xin Cai, Gui-Sheng Wang, He-Bing Zhou, Wei-Shan Li

Journal of Electrochemistry

The electrochemical behaviors of Zn in 3mol/L KOH solution containing several kinds of inhibitors were investigated by weight-loss,electrochemical methods and SEM. The results showed that both the single ad-ditive and the mixed additives can suppress the corrosion of zinc in 3 mol/LKOH solution. And the inhibition ef-feciency of the mixed additives is higher than that of any single additive because of the synergistic effect between KTL and DTAB. The adsorption of DTAB on the surface of zinc has been enhanced in the presence of KTL.


A Study On The Lifepo4/Mwcnts Cathode Materials For Li-Ion Batteries, You-Yi Peng, Hai-Yan Zhang, Chun-Hua He, Wei Xie, Zhi-Feng Zeng Aug 2009

A Study On The Lifepo4/Mwcnts Cathode Materials For Li-Ion Batteries, You-Yi Peng, Hai-Yan Zhang, Chun-Hua He, Wei Xie, Zhi-Feng Zeng

Journal of Electrochemistry

The LiFePO4/MWCNTs composite was synthesized by ball milling,then the composite electrode was assembled into button lithium-ion batteries.The structure and morphology of the samples,the electrochemical performance of the electrodes were investigated by ways of X-ray diffraction,scanning electron microscopy,cyclic voltammetry and charge-discharge capacity tests. The electrochemical performance of the composite electrodes with different MWNTs contents were studied. The results indicated that the composite electrode containing 10% MWCNTs(by mass)exhibited the most excellent electrochemical performance with the initial charge-discharge capacities of 139 mAh·g-1,128.5 mAh·g-1,respectively,and a Kulun efficiency of 92.4% at 0.1C rate under room temperature.Compared to the electrodes …


A Direct Borohydride Fuel Cell With Fecopc2-Catalysed Cathode, Jin-Fu Ma, Yan Liu, Jun-Hua Lai, Yong-Ning Liu Aug 2009

A Direct Borohydride Fuel Cell With Fecopc2-Catalysed Cathode, Jin-Fu Ma, Yan Liu, Jun-Hua Lai, Yong-Ning Liu

Journal of Electrochemistry

In this paper,a membraneless direct borohydride fuel cell was investigated. Cyclic voltammograms of FeCoPc2-modified glassy carbon electrode in the alkaline solution show that FeCoPc2 was active for oxygen reduction reaction. In addition, the steady-state polarization curve tests indicate that FeCoPc2 had better activity than FePc,CoPc or FePc+CoPc, which is due to its conjugated effect and synergistic effect of Fe and Co. Finally, a maximum power density of 110 mW/cm2 was attained, and the 25-day life test shows that the direct borohydride fuel cell had a good stability.


Simultaneous Determination Of Uric Acid(Ua) And Ascorbic Acid(Aa) At Pca/Gc Electrode, Ren Wang, Ying Zhang, Jie Ding Aug 2009

Simultaneous Determination Of Uric Acid(Ua) And Ascorbic Acid(Aa) At Pca/Gc Electrode, Ren Wang, Ying Zhang, Jie Ding

Journal of Electrochemistry

Poly(cinnamic acid)-modified electrode (PCA /GC) was prepared by potentiostatic technique and was used for determination of uric acid (UA),ascorbic acid (AA),and their mixture by cyclic voltammetry. This modified electrode exhibited a potent and persistent electron-mediating behavior followed by well-separated oxidation peaks toward UA and AA at a scan rate of 50 mV·s-1 with a potential difference of 280 mV,which is large enough to determine UA and AA individually and simultaneously. The catalytic peak current obtained was linearly dependent on the UA and AA concentrations in the range of 2.0×10-6~1.0×10-4 mol·L-1,2.0×10-5~6.0×10-4 mol·L …


The Electrochemical Behavior Of Daunorubicin Hydrochloride On Galactic Disk Electrode And Its Reaction With Bsa, Hong-Fen Cheng, Yong Zhang, Jie Liu, Yan-Mei Liu Aug 2009

The Electrochemical Behavior Of Daunorubicin Hydrochloride On Galactic Disk Electrode And Its Reaction With Bsa, Hong-Fen Cheng, Yong Zhang, Jie Liu, Yan-Mei Liu

Journal of Electrochemistry

This article used the linear sweep voltammetry and the circulation voltammetry to study the electrochemical behavior of daunorubicin hydrochloride on galactic disk electrode and its electrode reaction with BSA.Also it studied the interaction of daunorubicin hydrochloride with BSA.The results showed that daunorubicin hydrochloride has a sensitive reduction peak at -0.64 V(vs. SCE) in pH 6.50 Britton-Robinson buffer.The valus of reductions peak current reduced by the addition of BSA to the above mentioned solution.A new electrochemical determination method of bovine serum albumin was developed based on the interaction of daunorubicin hydrochloride with BSA.Furthermore,under the optimized condition,the decrease of the reduction peak …


Redox State Of Polyaniline Nanodot And Its Coulomb Staircase Effect, Jian-Zhang Zhou, Shao-Huang Weng, Zhong-Hua Lin Aug 2009

Redox State Of Polyaniline Nanodot And Its Coulomb Staircase Effect, Jian-Zhang Zhou, Shao-Huang Weng, Zhong-Hua Lin

Journal of Electrochemistry

Polyaniline nanodot array had been fabricated in AAO template with potentiostatic method and the I~V characteristics of nanodots with different redox states were measured by conducting atomic force microscope (C-AFM) in atmosphere at room temperature. We found that only nanodots in partial oxidation state exhibit coulomb staircase in the I~V curves,while those in the full oxidation state and reduced state do not. The above phenomena were discussed preliminarily.