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Full-Text Articles in Civil Engineering

Hazard Assessment Of Meteoroid Impact For The Design Of Lunar Habitats, Herta Paola Montoya, Shirley Dyke, Julio A. Ramirez, Antonio Bobet, H. Jay Melosh, Daniel Gomez Aug 2017

Hazard Assessment Of Meteoroid Impact For The Design Of Lunar Habitats, Herta Paola Montoya, Shirley Dyke, Julio A. Ramirez, Antonio Bobet, H. Jay Melosh, Daniel Gomez

The Summer Undergraduate Research Fellowship (SURF) Symposium

The design of self-sustaining lunar habitats is a challenge primarily due to the Moon’s lack of atmospheric protection and hazardous environment. To assure safe habitats that will lead to further lunar and space exploration, it is necessary to assess the different hazards faced on the Moon such as meteoroid impacts, extreme temperatures, and radiation. In particular, meteoroids pose a risk to lunar structures due to their high frequency of occurrence and hypervelocity impact. Continuous meteoroid impacts can harm structural elements and vital equipment compromising the well-being of lunar inhabitants. This study is focused on the hazard conceptualization and quantification of …


Buckling Of Cylindrical Shells Under Wind Loading, Tianlong Sun, Eyas Azzuni, Sukru Guzey Aug 2017

Buckling Of Cylindrical Shells Under Wind Loading, Tianlong Sun, Eyas Azzuni, Sukru Guzey

The Summer Undergraduate Research Fellowship (SURF) Symposium

Cylindrical shells such as aboveground steel storage tanks are widely used to store gases, chemicals and fuels. Stiffener rings are introduced to prevent cylindrical shells from buckling due to wind loads. The current top wind stiffener design rules used in the USA for such cylindrical storage tanks are specified in API 650. However, the design methodology of top stiffener rings is overly conservative. Therefore, relaxation of the design rules for the top stiffener is investigated in this study. The API 650 mandated top stiffener size was reduced to the same size as the mandated intermediate stiffener ring in this study. …


Spectroscopic Contrast Of Diarylethene Molecules On Octanethiol Monolayer, Arramel Arramel, Tibor Kudernac, Nathalie Katsonis, Bernard Lucas Feringa, Bart Jan Van Wees Aug 2017

Spectroscopic Contrast Of Diarylethene Molecules On Octanethiol Monolayer, Arramel Arramel, Tibor Kudernac, Nathalie Katsonis, Bernard Lucas Feringa, Bart Jan Van Wees

Makara Journal of Technology

We present a systematic scanning tunneling microscopy (STM) study of bias-dependent imaging of disulfur diarylethene (2S-DE) molecules on octanethiol (C8) monolayer at room temperature. In a rigid confinement of the C8 matrix, we did not observe any significant variation in the appearance of the 2S-DE. On the contrary, a reversal in the apparent height of the 2S-DE was present when the molecule was situated on a gold vacancy island. We attributed this finding to the presence of a new electronic state that became accessible for a tunneling event. In addition, the C8 surface structure underwent a reversible phase transformation from …


Residual Stress Measurements On The Tig Weld Joint Of 57fe15cr25ni Austenitic Steel For Structural Material Applications By Means X-Ray Diffraction Techniques, Parikin Parikin, Agus Hadi Ismoyo, Riza Iskandar, Arbi Dimyati Aug 2017

Residual Stress Measurements On The Tig Weld Joint Of 57fe15cr25ni Austenitic Steel For Structural Material Applications By Means X-Ray Diffraction Techniques, Parikin Parikin, Agus Hadi Ismoyo, Riza Iskandar, Arbi Dimyati

Makara Journal of Technology

Measurements of residual stress on the 57Fe25Cr15Ni steel plate with no-filler TIG-welding process were carried out. This work was conducted to determine the nature of weld ability in synthesized steel. The bulks were formed in a dimension of 30x20x7 mm3 to ease data retrieval. Results show that the largest residual stress occurred in the weld metal area, amounting to 82.40 MPa with lattice stretching of 0.18%. Conversely, the values decreased to 65.92 MPa and a stretch of 0.14% in the HAZ area. This residual stress is a tensile stress that can reduce the mechanical strength of the material since it …


An Efficient Palladium-Thiourea Catalysed Heck Cross-Coupling Reaction For Molecular Electronic Interest, Wan M. Khairul, Mohd Shahrul Shahmi Md Shariff, Rafizah Rahamathullah, Adibah Izzati Daud, Mustaffa Shamsuddin, Siti Kamilah Che Soh Aug 2017

An Efficient Palladium-Thiourea Catalysed Heck Cross-Coupling Reaction For Molecular Electronic Interest, Wan M. Khairul, Mohd Shahrul Shahmi Md Shariff, Rafizah Rahamathullah, Adibah Izzati Daud, Mustaffa Shamsuddin, Siti Kamilah Che Soh

Makara Journal of Technology

The synthesis and utilization of C-C bonds formation are concerned about the key steps for the building of several conducting molecular electronics involving many asymmetric catalysts approached, which is an essential task that most researchers would ignore in preparing these materials to enhance the production yield of cross-coupling materials. Despite the enormous progress, there still remains a great demand for economic and practicable cross-coupling processes involving ultra-low catalyst loadings with high turnover numbers due to the employment of conventional metal catalyst. Thus, there has been an excessive interest to cultivate non-phosphine palladium catalysts for excellent achievement of activity, stability, and …


A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System, Nur Muhitul Jalilah Rasali, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin Aug 2017

A Study On Dielectric Properties Of The Cellulose Derivative-Nh4br-Glycerol- Based The Solid Polymer Electrolyte System, Nur Muhitul Jalilah Rasali, Saifful Kamaluddin Muzakir, Ahmad Salihin Samsudin

Makara Journal of Technology

The characterization of biopolymer-based solid polymer electrolytes (SPEs) has been carried out in this present work. Cellulose derivative was chosen due to its superior physical attributes. In this work, NH4Br-doped glycerol plasticized carboxyl methylcellulose-based SPEs were successfully prepared via the solution casting method. The conductivity and dielectric properties of the prepared films were investigated using the impedance analysis which presented ~1.91×10-3 Scm-1 (with addition of 6 wt% of glycerol). In addition, the studied SPE system shows a non-Debye behaviour without a single relaxation time. The findings of the research indicate that the complexes of NH4Br and glycerol in the cellulose …


Urban Drainage Management And Flood Control Improvement Using The Duflow Case Study: Aur Sub Catchment, Palembang, South Sumatra, Indonesia, Charlotte De Fraiture, Robiyanto Hendro Susanto, F.X. Suryadi, Harrini Mutiara Hapsari Wahyu Aug 2017

Urban Drainage Management And Flood Control Improvement Using The Duflow Case Study: Aur Sub Catchment, Palembang, South Sumatra, Indonesia, Charlotte De Fraiture, Robiyanto Hendro Susanto, F.X. Suryadi, Harrini Mutiara Hapsari Wahyu

Makara Journal of Technology

Urban flooding often times staggers the livelihood in an urban area, which most likely happens in the lowland urban area. Therefore, the existing urban drainage system should be improved in order to tackle the upcoming urban flooding events, which are more than likely to be more devastating than those in the previous years. The research location is in Palembang, Sumatra, Indonesia, where 30% of its urban part is a lowland area. The selected Aur Sub Catchment is located in Silaberanti. The main objective of this research is to improve the current drainage system in order to achieve the optimal design …


Ethanol Purification Using Activated Natural Zeolite, Chandra Wahyu Purnomo, Nelliza Putri, Indra Perdana, Hirofumi Hinode Aug 2017

Ethanol Purification Using Activated Natural Zeolite, Chandra Wahyu Purnomo, Nelliza Putri, Indra Perdana, Hirofumi Hinode

Makara Journal of Technology

Bio ethanol is one of the potential fuels in the future. However, ethanol in water mixture has an azeotropic concentration of 95.6 wt. %, which makes it difficult to purify further. The common method of purification is by using an azeotropic distillation column, which requires an intensive energy and an addition of specific solvent. In this study, ethanol purification is done using an adsorption column packed with zeolite Raschig rings. The natural zeolite ring was modified beforehand using the NaOH solution to enhance the material’s water adsorption performance. The ethanol purity can reach more than 99% with the modified zeolite …


Physical And Mechanical Properties Of Palm Kernel Oil-Based Polyester Polyurethane/Multi-Walled Carbon Nanotube Composites, Khairul Anuar Mat Amin, Muhammad Alif Zailani, Nurul Nabilah Zulkifli, Khairiah Haji Badri Aug 2017

Physical And Mechanical Properties Of Palm Kernel Oil-Based Polyester Polyurethane/Multi-Walled Carbon Nanotube Composites, Khairul Anuar Mat Amin, Muhammad Alif Zailani, Nurul Nabilah Zulkifli, Khairiah Haji Badri

Makara Journal of Technology

In this study, polyurethane (PU) films from palm kernel oil-based polyester (PKO-p) incorporated multi-walled carbon nanotubes (MWNTs) are prepared via a evaporative casting method. Nanoparticle fluid dispersions containing 0.02%, 0.03%, and 0.05% wt. of MWNTs are added into PKO-p based resin and mixed by digital probe sonicator for 30 min followed by mixing with isocyanate to produce PU-MWNTs composite films. The mechanical properties, swelling, water vapour transmission rate (WVTR) and conductivity of the PU-MWNTs composite films are examined. Results show that the toughness (T) or flexibility, the tensile strength (TS), and Young’s modulus (YM) values of PU-MWNTs composite films increase …


Personality Trait Based Intervention For Workplace Accident Prevention, Yassierli Yassierli, Nurhayati Nurhayati, Marisa Anatasia, Shamsul Bahri Aug 2017

Personality Trait Based Intervention For Workplace Accident Prevention, Yassierli Yassierli, Nurhayati Nurhayati, Marisa Anatasia, Shamsul Bahri

Makara Journal of Technology

Previous research has suggested that some traits may be useful as the predictors of risk behaviours behaviors. Therefore, personality traits seem to play a role in accident involvement. The purpose of this study is was to explore the relationship between the personality traits based on the Big Five Inventory (BFI) and worker accident experiences in order to elaborate personality traits based intervention for workplace accident prevention. A cross cross-sectional study was conducted among 173 workers in a cement company using a set of questionnaires consisting of respondents’ characteristics, BFI, and self-reported accident experience. The correlations were computed using Goodman Kruskal’s …


Characterization Of Unknown Bridge Foundations, Saman Rashidyan Jul 2017

Characterization Of Unknown Bridge Foundations, Saman Rashidyan

Civil Engineering ETDs

The National Bridge Inventory (NBI) recognized 86,133 bridges in the United States have no foundation data on record in 2003. It is evident that an unknown percentage of the 86,133 bridges identified by NBI with missing foundation data could also be highly vulnerable to scouring induced by water flow coupled with erodible soils. Conventional excavation, coring and boring excavations to identify unknown bridge foundation depths and types are deemed to be expensive, destructive, and limited in their application to the unknown foundation problem. Many surface and borehole nondestructive testing (NDT) technologies have been developed for this purpose. Three economical proven …


Effect Of Austempering Time On The Microstructure And Carbon Partitioning Of Ultrahigh Strength Steel 56nicrmov7, Quanshun Luo, Matthew Kitchen, Shahriar Abubakri Jul 2017

Effect Of Austempering Time On The Microstructure And Carbon Partitioning Of Ultrahigh Strength Steel 56nicrmov7, Quanshun Luo, Matthew Kitchen, Shahriar Abubakri

Henry M. Rowan College of Engineering Departmental Research

Ultrahigh strength steel 56NiCrMoV7 was austempered at 270 °C for different durations in order to investigate the microstructure evolution, carbon partitioning behaviour and hardness property. Detailed microstructure has been characterised using optical microscopy and field emission gun scanning electron microscopy. A newly developed X-ray diffraction method has been employed to dissolve the bainitic/martensitic ferrite phase as two sub-phases of different tetragonal ratios, which provides quantitative analyses of the carbon partitioning between the resultant ferrites and the retained austenite. The results show that, a short-term austempering treatment was in the incubation period of the bainite transformation, which resulted in maximum hardness …


Restoration Of Historic Buildings In Zanzibar, John K. Makunza Jkm Jun 2017

Restoration Of Historic Buildings In Zanzibar, John K. Makunza Jkm

Tanzania Journal of Engineering and Technology (TJET)

Looking at current state of most repaired historic buildings in Stone Town of Zanzibar, it is quite clear that the repair attempts made have not been very successful. Modern materials and techniques introduced in the repair works have often proven to be incompatible with the original materials causing accelerated deterioration of buildings fabric. This shows that, there is no comprehensive study undertaken so far on identifying the appropriate materials and restoration techniques. To solve this problem, a study has been made with the main objective of developing the means of restoring historic buildings by using materials existing in Stone Town …


Building Information Modelling In Ireland 2017, Barry Mcauley, Alan Hore, Roger West Jun 2017

Building Information Modelling In Ireland 2017, Barry Mcauley, Alan Hore, Roger West

Reports

BIM is perhaps the most topical issue in construction throughout the world at present, as it is associated with solving so many of the present concerns in our industry.

Our lack of housing, shortage of skilled workers, poor document management, overrunning project budgets and sustainability challenges are just a few of the challenges that BIM promises to assist in solving.

The increasing importance of “digitisation” to modern construction and engineering businesses is becoming more apparent as more and more clients are explicitly asking for BIM in the design and delivery of new facilities and infrastructure.

This report provides a snapshot …


Shrinkage Cracking In Concrete Tilt-Up Construction, Stewart Hooks, Jack Robinson Jun 2017

Shrinkage Cracking In Concrete Tilt-Up Construction, Stewart Hooks, Jack Robinson

Architectural Engineering

The purpose of this project is to investigate a particular, undesirable cracking pattern in concrete tilt-up panels that, until now, did not have a known definite cause. The cause of this cracking pattern is hypothesized to be due to shrinkage restraint of the concrete panels. The cracking under investigation occurs at the bottom corners of the Tilt-Up panels, suggesting that the base of the panel is restrained from shrinkage. This project models various components of Tilt-Up Construction that have potential for restraining the panels from shrinking. This project consists of the following main components.

The first aspect of this project …


Schedule And Cost Performance Analysis And Prediction In Louisiana Dotd, Mahmoud Hamide May 2017

Schedule And Cost Performance Analysis And Prediction In Louisiana Dotd, Mahmoud Hamide

LSU New Orleans Theses and Dissertations

Many construction projects in the United States are facing the risk of cost overrun and schedule delays. This is also happening here in the State of Louisiana. When these things happen, it causes cost overrun which can then be passed on to the tax payers and may also cause the state to take on less projects than they normal. Many researchers have studied the reasons behind both the cost overrun and the delays resulting in private firms, developing project management tools and best practices to prevent this risk. In this research, I aim to study the historical trend in 2912 …


Effect Of Column Axial Load On Skewed Smf Rbs Connection Demands, Clovis Desrochers May 2017

Effect Of Column Axial Load On Skewed Smf Rbs Connection Demands, Clovis Desrochers

Graduate Theses and Dissertations

Steel buildings in high seismic areas often require special structural systems to transfer large lateral forces induced by earthquake accelerations. The selection of an appropriate seismic steel system (braced frame, moment frame, shear wall, etc.) is often influenced by architectural considerations. Moment frame configurations offer the most architectural flexibility, but are limited by code prequalification requirements that limit the use of non-orthogonal (skewed) beam-column connection geometries. A recent study has investigated laterally skewed moment frame connections, indicating that skew increases the potential for column twist and column flange yielding; however, it is unclear how realistic column axial loads will affect …


A Comparison Of Force And Pressure Coefficients On Dome, Cube And Prism Shaped Buildings Due To Straight And Tornadic Wind Using Three Dimensional Computational Fluids Dynamics, Majdi A. A. Yousef May 2017

A Comparison Of Force And Pressure Coefficients On Dome, Cube And Prism Shaped Buildings Due To Straight And Tornadic Wind Using Three Dimensional Computational Fluids Dynamics, Majdi A. A. Yousef

Graduate Theses and Dissertations

Tornadoes induce very different wind forces than a straight-line (SL) wind. A suitably designed building for a SL wind may fail when exposed to a tornado-wind of the same wind speed. It is necessary to design buildings that are more resistant to tornadoes. Most studies have been conducted to investigate tornado forces on cubic, gable-roof and cylinder buildings. However, little attention has been paid to investigate tornado force on dome buildings; hence, further research is conducted in this study. The forces on a dome, cube and prisms were analyzed and compared using Computational Fluid Dynamics (CFD) for tornadic and SL …


Fatigue Analysis Of The Greenup Lock Gate On The Ohio River, Maggie Langston May 2017

Fatigue Analysis Of The Greenup Lock Gate On The Ohio River, Maggie Langston

Civil Engineering Undergraduate Honors Theses

This thesis analyzes damage due to fatigue of a typical lock gate on the United States waterway transportation system. Functioning lock gates are essential for this mode of transportation because they control water levels and provide access through dams for ships. Fatigue cracking is caused by cyclic loading and corrosion. Cyclic loading on a lock gate was imitated using a finite element model. This model was used to calculate stress ranges for a cycle so that the number of cycles to failure could be calculated. The proportion of cycles to cycles to failure is known as the fatigue capacity. A …


Predicted Vs Measured Initial Camber In Precast Prestressed Concrete Girders, Luke T. Freedle May 2017

Predicted Vs Measured Initial Camber In Precast Prestressed Concrete Girders, Luke T. Freedle

Civil Engineering Undergraduate Honors Theses

Prestressing of concrete is the introduction of permanent internal stresses in a structure or system in order to improve its performance. Concrete is strong in compression but weak in tension. The tensile strength of concrete is approximately 10% of the concrete’s compressive strength. Prestressing strands helps counteract this by introducing compressive stress in the area that will experience tensile stress because of the service load. In precast prestressed concrete girders, strands are placed in the bottom flange of the girder. These strands are tensioned to approximately 75% of their ultimate tensile capacity. After placing the concrete and after the required …


Effectiveness Of Small Strain Shear Wave Velocity As A Property For Assessing Damage Associated With Alkali-Silica Reaction In Concrete, Dillon K. Self May 2017

Effectiveness Of Small Strain Shear Wave Velocity As A Property For Assessing Damage Associated With Alkali-Silica Reaction In Concrete, Dillon K. Self

Civil Engineering Undergraduate Honors Theses

This research paper details the monitoring of expansion and shear wave velocity for fifteen concrete prisms cast in accordance with ASTM C1293 utilizing five mix designs with varying levels of ASR reactivity. Jobe sand and sodium hydroxide pellets were added in various quantities to increase the reactivity of the prisms. Strain measurements of the prisms were taken according to ASTM C129 and the shear wave velocity of the prisms was measured using ASTM C215. These measurements were taken weekly, then monthly for over a year. It was determined that shear wave velocity of the prisms decrease linearly as strain in …


Effects Of Wash Water On The Compressive Strength Of Concrete, Gabriel W. Cook May 2017

Effects Of Wash Water On The Compressive Strength Of Concrete, Gabriel W. Cook

Civil Engineering Undergraduate Honors Theses

Due to the scale of concrete production throughout the world, there is potential for implementing methodologies that reduce the environmental impact of concrete processes. One intriguing solution is utilizing concrete wash water as mixing water. Concrete wash water is the water created by concrete production. If wash water can be reused, this would provide a safe disposal of the water and save millions of gallons of potable water per year (Indiana, 2014). For this to become a realistic option for concrete plants, it is important that the wash water does not decrease the compressive strength of concrete, otherwise the cost …


A Plastic Design Method For Rc Moment Frame Buildings Against Progressive Collapse, Hadi Faghihmaleki Apr 2017

A Plastic Design Method For Rc Moment Frame Buildings Against Progressive Collapse, Hadi Faghihmaleki

Makara Journal of Technology

In this study, progressive collapse potential of generic 3-, 8- and 12-storey RC moment frame buildings designed based on IBC-2006 code was investigated by performing non-linear static and dynamic analyses. It was observed that the model structures had high potential for progressive collapse when the second floor column was suddenly removed. Then, the size of beams required to satisfy the failure criteria for progressive collapse was obtained by using the virtual work method; i.e., using the equilibrium of the external work done by gravity load due to loss of a column and the internal work done by plastic rotation of …


In Vitro Toxicity Evaluation Of Caffeine Imprinted Polymer (Caf-Mip) For Decaffeination Method On Normal Chang Liver Cells, Fatimah Hashim, Faizatul Shimal Mehamod, Naizatul Akmal Nawi Apr 2017

In Vitro Toxicity Evaluation Of Caffeine Imprinted Polymer (Caf-Mip) For Decaffeination Method On Normal Chang Liver Cells, Fatimah Hashim, Faizatul Shimal Mehamod, Naizatul Akmal Nawi

Makara Journal of Technology

Over consuming of caffeine is one of the factors to a few health problems such as insomnia, hypertension and cardiovascular disease. This preliminary study was conducted to evaluate the Caffeine-Imprinted Polymer (CAF-MIP) toxicity that was synthesized for a new alternative method for decaffeination. It is crucial to evaluate the toxicity of CAF-MIPas this product is potential to be used as complimentary with any drinks containing caffeine. In this study, the CAF-MIP toxicity potential was confirmed on Normal Chang Liver cell (NCLC) based on its IC50 value andacridine orange and propidium iodide (AO/PI) staining for mode of cell death observation.Proliferation assay …


Sorption And Ion Exchange Behaviour Of Natural Zeolite Packing, Chandra Wahyu Purnomo, Bernice Lenora, Wiratni Budhijanto, Hirofumi Hinode Apr 2017

Sorption And Ion Exchange Behaviour Of Natural Zeolite Packing, Chandra Wahyu Purnomo, Bernice Lenora, Wiratni Budhijanto, Hirofumi Hinode

Makara Journal of Technology

It is well known that zeolite is an efficient metal ions adsorbent. The excess charge of the zeolite building blocks i.e. (AlO4)-5 and (SiO4)-4 creating a negative surface charge that attract metal cations. Beside the surface charge, zeolite also has three dimensional pore structure and reasonably large surface area which also can be used as adsorption sites. Ease of cation uptake make it suitable for many process with adsorption and desorption application. This study was conducted to observe the sorption and ion exchange behaviour of zeolite-betonite rings toward iron and cobalt cations. The results shows that the adsorption patterns follow …


Encapsulation Process Of Propolis Extract By Casein Micelle Improves Sunscreen Activity, Muhamad Sahlan, Dara Dienayati, Darul Hamdi, Soraya Zahra, Heri Hermansyah, Malyn Chulasiri Apr 2017

Encapsulation Process Of Propolis Extract By Casein Micelle Improves Sunscreen Activity, Muhamad Sahlan, Dara Dienayati, Darul Hamdi, Soraya Zahra, Heri Hermansyah, Malyn Chulasiri

Makara Journal of Technology

Propolis, a wax bee glue, have antioxidant activity and effective as broad spectrum UVB and UVA photoprotection sunscreens agent. To improve photoprotection activity in sunscreen cream, the propolis was encapsulated by casein micelle. The Indonesian propolis was extracted by ethanol and separated the wax by freeze precipitation. The extract was encapsulated by casein and reduced their size by ball mill homogenizer with the encapsulation efficiency about 80% and size of particles about 80 nm. The particles was applied in sunscreen cream, evaluate their stabillity and photoprotection activity Sun Protection Factor (SPF) spectrophotometer (Optometric 290s). The results shows that the selected …


Nano-Channels Early Formation Investigation On Stainless Steel 316ti After Immersion In Molten Pb-Bi, Abu Khalid Rivai, Mardiyanto Mardiyanto, Annette Heinzel Apr 2017

Nano-Channels Early Formation Investigation On Stainless Steel 316ti After Immersion In Molten Pb-Bi, Abu Khalid Rivai, Mardiyanto Mardiyanto, Annette Heinzel

Makara Journal of Technology

Development of fuel cladding and structural materials in Pb-Bi environment, especially at high temperature, is a critical issue for the deployment of LFR (Lead alloy-cooled Fast Reactor) and ADS (Accelerator Driven Transmutation System). This is because of the corrosive characteristic of Pb-Bi to metals as constituent materials of fuel cladding and structural of the reactors. Corrosion test of a high-chromium austenitic stainless steel i.e. SS316Ti in molten Pb-Bi at 550 ºC has been carried out for about 300 hours continuously. The characterization using SEM-EDS (Scanning Electron Microscopy - Energy Dispersive X-ray Spectroscopy) showed that an iron oxide as the outer …


Synthesis Of Libob Fine Powder To Increase Solubility, Etty Marti Wigayati, Titik Lestariningsih, Christin Rina Ratri, Ibrahim Purawiardi, Bambang Prihandoko Apr 2017

Synthesis Of Libob Fine Powder To Increase Solubility, Etty Marti Wigayati, Titik Lestariningsih, Christin Rina Ratri, Ibrahim Purawiardi, Bambang Prihandoko

Makara Journal of Technology

Lithium bis (oxalate) borate or LiBOB compound has captured interest of researchers, because it is potentially viable to be used as electrolyte salt in lithium-ion battery system. This compound is easy to synthesize and considered to be more environmentally friendly compared to conventional electrolyte salt because LiBOB does not contain halogen element. This research focused on the synthesis of LiBOB fine powder, which main purpose is improving LiBOB salt solubility in liquid electrolyte solution. This will aid the ion transfer between electrodes which in turn will increase the electrolyte performance. Solid state reaction was employed in this experiment. Synthesis of …


Influence Of Polyethylene Glycol (Peg) In Cmc-Nh4br Based Polymer Electrolytes: Conductivity And Electrical Study, Nur Khalidah Zainuddin, Ahmad Salihin Samsudin Apr 2017

Influence Of Polyethylene Glycol (Peg) In Cmc-Nh4br Based Polymer Electrolytes: Conductivity And Electrical Study, Nur Khalidah Zainuddin, Ahmad Salihin Samsudin

Makara Journal of Technology

The present work was carried with new type and promising polymer electrolytes system by development of carboxyl methylcellulose (CMC) doped NH4Br and plasticized with polyethylene glycol (PEG). The sample was successfully prepared via solution casting with no separation phase and good mechanical properties. The electrical conductivity and thermal conductivity of CMC-NH4Br-PEG based PEs system have been measured by the electrical impedance spectroscopy method in the temperature range of 303–373 K. The highest ionic conductivity gained is 2.48 x 10-3 Scm-1 at ambient temperature for sample contain with 8 wt. % PEG. It can be concluded that the plasticized is accountable …


Purification Simulation With Vapor Permeation And Distillation-Adsorption In Bioethanol Plant, Misri Gozan, Mia Sari Setiawan, Kenny Lischer Apr 2017

Purification Simulation With Vapor Permeation And Distillation-Adsorption In Bioethanol Plant, Misri Gozan, Mia Sari Setiawan, Kenny Lischer

Makara Journal of Technology

High purity of Bioethanol is required in biofuel mixing with gasoline (EXX). In bioethanol production line, the azeotropic property of ethanol-water becomes the barrier for purification process. This study examined two bioethanol separation processes by support of simulation tools, Superpro Designer 9.0 software. Ethanol purity and a low costeconomical process were the major considerations. Purification method of vapor permeation membrane technology was compared with distillation-adsorption method. Data from previous lab experiments and some literatures were used. The results showed that distillation-adsorption method is more economical compared to vapor permeation technology. Payback period of the simulation is 3.9 years and 4.3 …