Civil and Environmental Engineering Commons^™

Analysis And Modeling Of Ultrasound To Decontaminate Heavy Metals In Dredged Sediments, Ruvini Perera

Theses

Sediments contaminated with heavy metals due to past disposal practices threatens the environment and requires remediation. This research is an attempt to develop a technology to decontaminate heavy metals in the dredged sediments with an integrated set of processes using ultrasound. Acoustic cavitation caused by ultrasound energy can be used to remove chromium from the sediments. Two coupled processes were used to treat both coarse (Process#1) and fine (Process#2) fractions of the sediments. Full factorial experimental designs were carried out to evaluate the treatment technique and to statistically model and optimize the processes. The model for Process#1 had four contributing …

Ultrasound To Decontaminate Organics In Dredged Sediments, Kanya Veerawat

Theses

In this research, it was attempted to decontaminate and separate dredged sediments contaminated with organic compounds by the application of ultrasound energy coupled with sub-atmospheric pressures. The decontamination and separation of contaminated sediments was achieved by integrated two processes. For Process 1, ultrasound energy was used to decontaminate the sandy fraction in dredged sediments, and sub-atmospheric pressure was used to separate and remove fines. For Process 2, ultrasound was again used to decontaminate fines with bulk fluid, and sub-atmospheric pressure was used to remove the contaminants with water. Process 1 was evaluated and found to have four variables contributing to …

Production Of Submicron Aerosols By Powder Depressurization, Amit Haryani

Theses

Disaggregation of dry powders in shear flow has limitations in producing submicron particles. This study explores a new method for the production of submicron particles by the depressurization of powder aerosols. The depressurization mechanism is based on the rapid depressurization of the aggregated powder through a specially designed nozzle. As the pressure suddenly decreases from very high values inside the aggregates (800 psi) to ambient at the surface of such aggregates, disaggregation takes place due to the force exerted by the gas escaping through their pore structure.

he effect of various process parameters, namely: nozzle diameter, pressure and pretreatment with …

Fluorescence Spectroscopy For The Characterization Of Humic And Fulvic Acids And Their Disinfection By-Products Formation Potential, Ishvinder H. Kochar

Theses

Natural Organic Matter (NOM) plays a major role in the formation of undesirable organic by-products following disinfection/oxidation of drinking water. It is suspected that most precursors to disinfection by-products (DBPs) are humic although non-humic substances have not been studied and are suspected of also contributing to DBPs. NOM reacts with many of the disinfectants used to treat drinking water, such as chlorine, chioramine, and ozone, to form a variety of DBPs. Many of these DBPs have adverse health effects in humans (i.e. carcinogenic or mutagenic effects). The primary DBPs of concern include the trihalomethanes (THMs), haloacetic acids (HAAs), and haloacetonitrile …

Container Arrivals Forecasting Practice And Experience At Marine Terminals, Alexios C. Sideris

Theses

The advent of the container traffic in maritime transportation has led during its 40-year long history to novel perceptions and operation planning requirements for the port container terminal. A major requirement in this respect refers to the efficiency of the operations in the container transfer between the different modes. The current study presents a methodology on the development of a forecasting tool to access the service demand patterns at a marine terminal on per day basis. A set of forecasting models was introduced and their implementation difficulties were explored. The main effort in this approach was to replicate the distribution …

Pneumatic Fracture Propagation And Particulate Transport In Geologic Formations, Suresh Puppala

Dissertations

Pneumatic fracturing is an in situ remediation enhancement technology developed to increase the permeability of contaminated geologic formations. This technology can also be used to deliver atomized liquid and particulate supplements to geologic formations, thereby enhancing in situ processes such as bioremediation and reactive dechlorination.

The main objective of this study was the development of a mathematical model that simulates the propagation of pneumatic fractures in soil and rock formations. Pneumatic fracture propagation differs from other fluid fracturing phenomena in the propagation velocity (1-3 m/sec) and the viscosity of the fracturing fluid (1.9E-05 Pa•sec). For the purposes of model development, …

Reuse Of Cold Top Ex-Situ Vitrified Chromium Contaminated Soils In Hot Mix Asphalt Concrete, Gerald Charleston

Theses

This research investigated the pilot scale feasibility of the remediation of chromium contaminated soil through cold top ex-situ vitrification and the reuse of the vitrified products as highway construction aggregates. There are more than two million tons of chromite ore residues from the chromate extraction manufacturing leftover in Hudson County, New Jersey. They contained both un-leached hexavalent and unoxidized trivalent chromium. Hexavalent chromium is well known as a group A human carcinogen. It is also considered an environmental and health hazard. Of the many ex- situ and in-situ physical, chemical, and biological treatment technologies for chromate production waste, the ability …

The Determination Of 2-Methylisoborneol And Geosmin In Water Using Fluorescence Spectroscopy, Ramesh Chandra Sharma

Theses

Geosmin and 2-Methylisoborneol are responsible for imparting earthy, musty taste and odor qualities to water. The human threshold odor concentrations (TOCs) for 2-MIB and Geosmin vary over a wide range. TOCs of 10ng/1 for Geosmin and 30ng/1 for 2-MIB have been reported.

Currently available methods are time consuming and require use of sophisticated technique and expensive equipment.

Fluorescence spectroscopy has been successfully used in the identification of many organic compounds. Geosmin and 2-MIB have organic origin. This research explores the possibility of using the technique of fluorescence spectroscopy in the determination of Geosmin and 2-MIB. The excitation and emission wavelengths …

Composite Columns, Magnar Berge

Theses

The purpose of this thesis is to provide an introduction in the design of composite columns. The design methods according to AISC and Eurocode 4 are summarized and provide a procedure to design a composite column. In addition, equation are derived to determine the nominal flexural strength of typical composite cross-sections.

Stabilization Of Water Treatment Plant (Wtp) Residuals Using Sorbond, Rituraj Sinha

Theses

Disposal of water treatment plant (WTP) residuals has always been an important consideration for the water industry. Stringent water quality standards, environmental regulations, and unavailability of land for ultimate disposal affect disposal of large amounts of this residual. The search for alternate economical disposal options and beneficial use are probably the next most logical and economical step to take.

This study was performed to explore the possibility of stabilization of water treatment plant (WTP) residuals using additives. Three water treatment plant (WTP) residuals from treatment plants in New Jersey were used for the analysis. The objective of this research is …

A Combined Simulated Annealing And Tabu Search Strategy To Solve Network Design Problem With Two Classes Of Users, Qifeng Zeng

Dissertations

A methodology to solve a transportation network design problem (TCNDP) with two classes of users (passenger cars and trucks) is developed. Given an existing highway system, with a capital investment budget constraint, the methodology selects the best links to be expanded by an extra lane by considering one of three types of traffic operations: exclusive for passenger cars, exclusive for trucks, and for both passenger cars and trucks such that the network total user equilibrium (UE) travel time is minimized.

The problem is formulated as an NP-hard combinatorial nonlinear integer programming problem. The classical branch and bound methodology for the …

Fluorescence Spectroscopy For The Characterization Of Total Organic Carbon And Disinfection By-Product Formation, Matthew Brendan Washington

Theses

One of the concerns facing the drinking water industry is the formation of disinfection by-products (DBPs) during the disinfection stage of treatment. Organic DBPs form during the oxidation of the natural organic matter (NOM) found in natural waters by the application of a disinfectant, such as chlorine.

NOM is composed of two aggregate materials, humic and non-humic substances. It is unknown which portions of NOM react with the oxidant to form DBPs. Methods used to predict the formation of DBPs include total organic carbon (TOC) analysis and Trihalomethane Formation Potential (THMFP), which are time consuming and do not give specific …

A Model For Travel Mode Switching, Lei Cao

Dissertations

Transportation policy research assesses the effect of policy changes such as the imposition of a parking charge or the augmentation of passenger rail service, on individual travel behavior. Over the last few decades, Conditional Lo it Model has been strongly advocated among discrete choice models for transportation policy study due to its ease of estimation and realistic outcomes.

This dissertation analyzes the necessity of the entry of constraints in the indirect utility function. These functions are used in discrete choice models and form the basis for travel demand modeling. This dissertation proposes a hypothesis that the explicit entry of constraints …

Impact Of Access Points On Multilane Highway Accidents, Tao Qu

Theses

This thesis presents an analysis of reported accidents on multilane highways and regression models that identify the primary explanatory variables that have a significant effect on accident rates midblock to signalized intersections. The analysis was based on traffic and reported accident data provided by New Jersey DOT. The access points per mile and the accident rates per million-vehicle-miles-traveled were analyzed based on a large number of roadway sections which were selected from five NJ State routes. Comparative accident analysis related with traffic and roadway geometric characteristics were performed. The analysis showed that approximately 30% of accidents occurred between intersections, which …

Analysis Of Safe Separation Distances From Natural Gas Transmission Pipelines, James Stephen Haklar

Dissertations

Accidental rupture of natural gas transmission pipelines with subsequent ignition of the escaping gas can result in the loss of life and property. In the United States, current means of protecting both the pipeline and the public include the establishment of class locations, in which specific pipeline design, construction and operation requirements must be attained. In addition, distances at which the pipelines can be safely set back from the community, called safe separation distances, have been developed in some European countries (e.g., Great Britain, the Netherlands) through use of risk assessment principles. However, to date there has been no simple, …

Characteristics Of Recycled Plastics And Applications For Highway Appurtenances, Keith Macbain

Theses

Recycling is gaining widespread support in many communities as an environmentally acceptable solution to the management of solid waste. The success of these recycling programs depends largely on the development of high-value end use for the recycled products. This research involves an experimental and analytical study on the development of high-value, high-volume end uses for recycled plastic shapes. The experimental part includes material tests to determine mechanical properties of various recycled plastics. A constitutive model is proposed and verified that can be used in characterization of recycled plastics. Bending tests of recycled plastic beams were performed to assess strength, stiffness …

Distribution Of Velocities And Velocity Gradients In Mixing And Flocculation Vessels : Comparison Between Ldv Data And Cfd Predictions, Changgen Luo

Dissertations

Flocculation is an operation of significant industrial relevance commonly encountered in many processes, including water and wastewater treatment. The physico-chemical phenomena of this process is strongly affected by the magnitude of the velocity gradients generated, typically through agitation, in rapid mix devices and flocculation vessels.

In this work the fluid dynamic characteristics of mechanically agitated systems, namely three different types of stirred tanks, which can be used as flocculation vessels, were studied. Both the mean and fluctuating velocities in all three directions were measured by using a Laser-Doppler Velocimeter (LDV). The velocity distribution, fluctuating velocities, power consumption and local velocity …

The Study Of Permeability In Concrete, Jie Yuan

Theses

In this study, samples of regular, high performance, expansive and the polymer concrete and mortar were prepared for test of permeability and mechanical property. In the permeability measurement, water and an aqueous chemical solution were employed as the permeant.

The test results of the samples, ranging from 5.7 x 10-9 cm/sec to 1.0 x cm/sec for the permeability and 3800 psi to 10600 psi for compression strength, indicated that the polymer coated concrete has the lowest permeability among the concretes and high performance concrete has the highest compression strength . The finding leads to the possibility that a high strength …

An Analytical Approach To Toxic Substance Replacement In Support Of Pollution Prevention, Ithan B. Zimmer

Theses

In support of pollution prevention and in accordance with Executive Order 12356 concerning pollution prevention, all federal agencies must comply with the Toxic Release Inventory (TRI) chemical release reduction and pollution prevention planning. The inventory lists hundreds of chemicals and choosing those to replace and finding actual replacement chemicals or procedures is not always clear. This study focuses on an analytical approach to this problem by understanding the application of two substances. The representative chemicals are two volatile organic compounds (VOC), ethyl ether and ethanol, used as solvents in ammunition manufacturing.

Thirteen military specifications provide the cases involving ether. Ethanol's …

Analysis And Modeling Of Ultrasound Enhanced Soil Washing Process, Kamalavathany Rajaratnam

Theses

In this research, statistical analysis of data from ultrasound enhanced soil washing process was performed. The process was optimized using a statistical model. The model had four factors namely power, solvent:soil, surfactant, and dwell time as process variables. The percentage of removal efficiency was considered as the dependent variable. The results from two full and one partial factorial designs were analysed. Interactions up to third order were considered in the analysis, but the results from full factorial design showed that those of order higher than second had insignificant contributions to the removal of contaminants. Since the higher order interactions of …

Enhancing The Bioavailability Of Sorbed Pollutants From Sediments Using Ultrasound, Rachel Mathew

Theses

Many organic compounds, that enter aquatic systems have a strong tendency to sorb onto particulate matter which may be present in suspension or as sediment. Numerous studies have shown that the sediment in aquatic systems concentrate contaminants several orders of magnitude greater than the concentration in the aqueous phase. Particulate associated contaminants in sediments are not easily bioavailable. Hence the efficacy of any treatment technology would be strongly undermined if the contaminants are not made available for microbial utilization. Sediment associated contaminants can be made biologically available to various microorganisms under certain conditions.

In this study, desorption studies were conducted …

Evaluation Of Environmental Characteristics Of Wtp Residuals For Disposal In Monofills, Ping Tian

Dissertations

Disposal of water treatment plant (WTP) have raised great concerns due to the stringent water quality standards and environmental regulations, and limited availability of land for ultimate disposal. The ultimate disposal of water treatment plant residuals by using monofill may be one of the most economical, and feasible options. Design and operation of such a monofill will be simple because of the uniformity of the characteristics of WTP residuals.

The objectives of this project were to determine the environmental characteristics of WTP residuals and to apply these characteristics for the design of monofills and development of the metal leaching model …

Non-Linear Evaluation Of Concrete-Filled Steel Tubular Columns, Mohammad Hassan Shams

Dissertations

Concrete-filled steel tubular (CFT) columns have become increasingly popular in structural applications due to their high strength, high ductility, and large energy absorption capacity. These structural properties are the result of integral behavior of the concrete core and the steel tube. This research provides an analysis of the interaction of the concrete core and the steel tube in CFT columns.

While there have been many experimental studies of CFT columns, there has been no analytical work modeling the confining effect of the steel tube on the concrete core. Furthermore, current design procedures tend to underestimate the ultimate strengths of CFTs …

Potential Effects Of Pneumatic Fracturing On Existing Structures And Utilities, Michael C. Canino

Theses

This thesis develops a mathematical design model for predicting ground deformations resulting from pneumatic fracturing. Pneumatic fracturing is a patented process developed for the purpose of enhancing the in situ treatment and removal of hazardous contaminants from geologic formations. During pneumatic injections, measurable ground deformations are experienced both during and after the process. Safe application of pneumatic fracturing to contaminated plumes occurring beneath existing structures and utilities requires that the elastic deformation behavior of the geologic formation and overlying structures be quantified.

Data from five pneumatic fracturing sites were regressed to establish the characteristic polynomial describing the curvature of ground …

A Methodology For The Design Of An Integrated Air Stripping/Biofiltration Process To Clean Contaminated Aquifers, Pothitos Ioannis Stamatiadis

Theses

This thesis deals with the conceptual design of an integrated air stripping/biofiltration process for cleaning aquifers contaminated with volatile organic pollutants. In this technology, the pollutant is transferred from the aquifer to an air stream which is subsequently treated in a biofilter. The work presented here is an effort to develop a design methodology for the integrated process and suggests a general, quantitative approach which can be used in preliminary technology evaluation. This methodology involves relatively simple equations for the stripping process and detailed (oftentimes complex) models for biofiltration under conditions of continuous variation of the properties of the polluted …

Fracture Mechanics Of High Strength Concrete Members, Rajendra K. Navalurkar

Dissertations

This study investigates the behavior of High Strength Concrete (HSC) under uniaxial state of stresses. Emphasis is placed on experimental evaluation of important mechanical and fracture properties. Owing to high brittleness of HSC, experimental results especially on tensile behavior have been largely limited and scarce. In this research, direct uniaxial tension tests are employed for determination of the post-peak tensile softening characteristics of HSC. The softening characteristics of high strength concrete is found to be considerably different than that of normal strength concrete (NSC). Fracture energies evaluated form the descending branch of the stress softening reveal significant drop in the …

Biodegradation And Landfill Settlement, Shailesh Pisolkar

Theses

The most widely used method for the final disposal of solid waste is landfilling, which is also economical and simpler than most other disposal systems. Long term settlement in a landfill occurs mainly due to biodegradation of the refuse which is a very slow microbiological process. However, if the rate of biodegradation is enhanced, it may be possible to achieve early stabilization, faster settlement, consequently more capacity of the landfill to handle waste.

The objective of this research is to study the effects of enhanced biodegradation on settlement and to compare these results to other models used for predicting landfill …

Solidification/Stabilization Of Petroleum Contaminated Soils With Cold Mix Asphalt Concrete, Nazhat Aboobaker

Theses

In this research Petroleum Contaminated Soils (PCSs) are recycled in Cold Mix Asphalt (CMA), to produce a useful product that can control potential environmental threats. The stability, durability, and hydraulic conductivity are three important engineering parameters that need to be considered when using petroleum contaminated soils (PCSs) in cold mix asphalt (CMA). In this research, stability, durability, and hydraulic conductivity due to the addition of six different PCSs into CMA is investigated. The stability test were performed to determine if cold mix asphalt made with petroleum contaminated soil can withstand heavy traffic. The freeze-thaw, and wet-dry tests were performed to …

Relationship Between Precipitation, Surface Runoff, And Shallow Water-Table, Manoj Patel

Theses

In this study, a model was developed to describe the relationship between precipitation, surface runoff, and shallow groundwater table in a watershed that is subjected to groundwater extraction and urbanization. Regression analysis of fourteen years (1976-1989) of time series data for precipitation, stream discharge, ground water elevation, and groundwater extraction yielded good correlation between these parameters.

Analysis of the data associated with groundwater recharge and discharge events that occurred in the watershed from 1976 to 1989 yielded a high correlation between the above cited parameters. Regression analysis utilized to predict monthly variations in groundwater elevations showed a fair correlation between …

The Constant Fracture Angle Model For Cementitious Materials, Suk Ki Kim

Dissertations

Fracture mechanics of concrete has been investigated for the past two decades using linear elastic and nonlinear fracture mechanics concepts. The models proposed so far remain questionable largely due to specimen dependency of the proposed fracture parameters.

In this study, a new approach for modeling the fracture characteristics of concrete and fiber reinforced concrete is proposed. The model depends on the load CMOD relationship rather than the traditional load-deflection principle. Although energy consumed during fracture is definitely a direct function of the load displacement response, it was observed that traditional displacement measurement included an extraneous and erratic portion due to …