Chemical Engineering Commons^™

Assessment Of Factors Contributing On Early Rotting Of Chromated Copper Arsenate Treated Utility Power Distribution Wood Poles In Tanzania, Innocent J. Macha

Tanzania Journal of Engineering and Technology (TJET)

The study aimed to assess the factors contributing to the premature decay of Chromated Copper Arsenate (CCA) treated utility power distribution wooden poles in Tanzania. Deteriorated poles samples from various regions in Tanzania were analyzed using handheld X-ray spectrometry to quantify the retention of CCA preservative chemicals. The ages of these poles were estimated based on annual growth rings. The findings indicated that premature failure of CCA treated wooden poles is attributed to an imbalance in the chemical composition of the preservative solution. The study found that CuO retention in most samples ranged between 10-18 kg/m3, significant lower that the …

Dust Analyses In Ventilation Ducts, Karolina Vyhlidalova, Petr Vlček, Olga Rubinová, Jiří Bernard

Journal of Sustainable Construction Materials and Technologies

The paper describes the importance of monitoring the dust in the atmosphere of human life. It deals with the issue of dust in air ducts, approaching the methods that can be used to detect the amount of dust. For conditions for buildings in the Czech Republic there is created the methodology of quantitative and qualitative evaluation of dust sediment for the needs of HVAC and other building surfaces. The scale for visual evaluation was created and it has been elaborated the assessment of kind of particles contained in dust.

Assessment Of Long Time Approximation Equation To Determine Thermal Conductivity Of High Porous Materials With Nss Probe, Hussein Humaish, Bastien Ruet, Laurent Marmoret, Hassen Beji

Journal of Sustainable Construction Materials and Technologies

Recent economic changes have increased the focus on energy conservation in buildings. Improve insulation represents one of the biggest challenge to save energy. The TP02 Huksefux® Non Steady State Probe (NSSP) has been used to determine the thermal conductivity of the building insulation materials. Usually, the long term approximation equation (linear form) is applied to determine the thermal conductivity when using hot wire techniques. Long term approximation has been successfully used to characterize glycerol: a fluid which doesn’t present contact resistance and porosity. But, an S-shaped appears for more porous materials. So to generalize the possibility of using this method, …

Biowaste Valorization: Integrating Circular Economy Principles With Artificial Intelligence-Driven Optimization For Sustainable Energy Solutions, Dina Aboelela Dr.

Biochemical Engineering

Biowaste, encompassing food waste and agricultural residues, poses significant environmental challenges while offering transformative opportunities. Traditionally relegated to landfills or incineration, biowaste is increasingly recognized as a renewable resource for producing biofuels, biochemicals, biomaterials, and animal feed. This review offers a systems-level analysis of biowaste characteristics, conversion processes, and derived bioenergy products such as biofuels, biogas, biodiesel, biohydrogen, bioelectricity, and other valuable chemicals. Diverse conversion methods are explored, including anaerobic digestion, fermentation, microbial fuel cells, pyrolysis, and gasification, alongside conventional practices like landfilling and incineration. Emerging analytical advancements are revolutionizing biowaste valorization. Artificial intelligence (AI) …

Approach Formula To Increase Energy Efficiency Of Internal Combustion Engines In The “Green Economy” And Impact On The Natural Ecosystem, Zakirjon Ergashevich Musabekov, Hilola Zokir Qizi Uralova, Sayyodbek Ilxomjon O‘G‘Li Abdullajonov

Technical science and innovation

This article discusses, analyzes, and proposes solutions for the role of internal combustion engines in forming a "green economy", as well as ways to replace or modernize them. The relationship between internal combustion engines and the "green economy," as well as their energy efficiency and impact on natural ecosystems, is a crucial and urgent issue. These engines primarily generate energy through the combustion of petroleum-based fuels such as gasoline and diesel. However, this process releases harmful gases into the atmosphere, contributing to environmental degradation. The green economy is an economic model designed to protect the environment, ensure the efficient management …

Biobased Acrylate Composites With Enhanced Strength For Additive Manufacturing, Nicole Wagner, Joseph Mcwherter

Engineering Faculty Articles and Research

With the expanding use of polymers in additive manufacturing, sustainable resins for use in vat photopolymerization are required to reduce their environmental impact. One promising approach to achieve this is to incorporate biobased fillers that replace the acrylates in photopolymer resins as ‘green’ alternatives. In this study, photopolymer composites consisting of a methacrylate resin with varying calcium carbonate powder content between 0 and 50 wt.% were investigated. A digital light processing technique was used to fabricate tensile test specimens for mechanical testing. Good printability, dimensional accuracy, and good interlayer adhesion were observed for composite resin formulations that incorporated calcium carbonate …

Optimization And Dft Study For Boosted Electooxidation Of Formic Acid At Niox Modified Pt Using Urea Derivatives As Blending Fuels, Aya Saada

Biochemical Engineering

This paper addresses the enhancement of formic acid electrooxidation (FAO) at Pt and Pt-NiOx nanoparticles based-catalysts assisted with urea derivatives as blending fuels. Blending formic acid with various ratios of urea derivatives showed noticeable enhancements of FAO as demonstrated by a favorable negative shift of its onset potential (Eonset) and increase of its peak current density concurrently with suppression of the amount of CO poisoning reaction intermediate. Among all the used derivatives, phenyl urea (PU) showed superior enhancing effect towards the direct FAO with a minimal CO formation together with a favorable negative shift of Eonset by 150 mV. The …

Polymorphism And Mechanical Behavior In Hot-Pressed 3d-Printed Polyamide Composite: Effects Of Pressure And Temperature, John Barber, Patricia Revolinsky, Jimesh Bhagatji, Diego Pedrazzoli, Sergii Kravchenko, Oleksandr Kravchenko

Mechanical & Aerospace Engineering Faculty Publications

The aim of this work is to study the effect of high-temperature compaction (HTC) upon the polymorphism and the mechanical behavior of an additively manufactured (AM) carbon fiber-reinforced polyamide (PA6). Different pressure and temperature levels during HTC were tested to determine the overall effect on the mechanical behavior and material crystalline composition. Treated, carbon fiber-reinforced PA6 samples were analyzed using differential scanning calorimetry, X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, and three-point bending testing. When considered with respect to as-printed samples, an HTC temperature of 190 °C combined with 80 psi pressure resulted in an increased flexural modulus and strength …

A Comprehensive Review Of Piezoelectric Pvdf Polymer Fabrications And Characteristics, Nadia Ahbab, Sidra Naz, Tian-Bing Xu, Shihai Zhang

Mechanical & Aerospace Engineering Faculty Publications

Polyvinylidene fluoride (PVDF) polymer films, renowned for their exceptional piezoelectric, pyroelectric, and ferroelectric properties, offer a versatile platform for the development of cutting-edge micro-scale functional devices, enabling innovative applications ranging from energy harvesting and sensing to medical diagnostics and actuation. This paper presents an in-depth review of the material properties, fabrication methodologies, and characterization of PVDF films. Initially, a comprehensive description of the physical, mechanical, chemical, thermal, electrical, and electromechanical properties is provided. The unique combination of piezoelectric, pyroelectric, and ferroelectric properties, coupled with its excellent chemical resistance and mechanical strength, makes PVDF a highly valuable material for a wide …

Fluid Pathways For Enhanced Mass Transfer In The Micro Regime: Applications In Novel Pumpless Redox Flow Cell And Zinc Finger Protein-Based Dna Detection, Shaikh Al Mahmud Bhuiyan

Theses and Dissertations--Mechanical and Aerospace Engineering

Precise fluid transport through microscale geometries can help optimize electrochemical and biochemical processes by maximizing the mass transfer rate of reactants. By introducing intricate structural features inside microchannels, it is possible to manipulate the fluid motion and direct the flow towards any surface of interest. In this study, we have demonstrated that rationally designed fluid pathways can improve the performance of electrochemical and biochemical systems.

The emergence of additive manufacturing has enabled rapid fabrication of robust structures with intricate features to guide fluid motion. However, their application in nonaqueous electrochemical systems has been limited due to their interaction with organic …

Numerical Modelling And Co-Optimization Of Gasoline Fuels For Gasoline Compression Ignition Using Multi Component Approach, Ashwin Karthik Purushothaman

Dissertations, Master's Theses and Master's Reports

Future mobility is expected to rely on a broad spectrum of powertrain technologies, including battery electric vehicles (BEVs), hybrid electric vehicles (HEVs), fuel cell electric vehicles (FCEVs) and traditional internal combustion engine (ICE) vehicles. Despite the shift toward electrification, internal combustion engines are projected to remain a key component of future powertrains, either as the primary power source or as range extenders to generate electricity in hybrid systems. As such, significant research efforts continue to focus on enhancing the efficiency and reducing the emissions of ICEs to meet increasingly stringent regulatory and environmental targets. Gasoline compression ignition (GCI) has been …

Thermo-Rheological And Tribological Properties Of Low- And High-Oleic Vegetable Oils As Sustainable Bio-Based Lubricants, Abiodun Saka, Tobechukwu K. Abor, Anthony C. Okafor, Monday U. Okoronkwo

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Vegetable oil-based lubricants have attracted increased research attention in recent decades as sustainable alternatives to conventional petroleum-based lubricants in metal machining. However, more studies are required to fully elucidate the thermo-rheological and tribological properties. This study presents an investigation of the thermo-rheological and tribological properties of different vegetable oils, including low- and high-oleic soybean oil, high-oleic sunflower, safflower, and canola oils. The lubricity, and evolution of viscosity and thermodynamic properties as a function of temperature were investigated to obtain important parameters including the viscosity index, flow behavior index, flow activation energy, specific heat capacity, thermal conductivity, coefficient of friction, contact …

Microwave-Assisted Reduction Of Critical Metal Oxides From E-Waste Mixture, Kurundu Shavinka Jayasekera

Graduate Theses, Dissertations, and Problem Reports (ETD)

The efficient recovery of critical metals such as tantalum (Ta), manganese (Mn), gallium (Ga), and indium (In) from electronic waste (e-waste) is essential for resource sustainability and environmental protection. This research uses microwave-assisted treatment to investigate the carbothermal reduction of these four specific metals from their oxides in a simulated e-waste mixture, with carbon black serving as both a microwave coupling and reduction agent. Microwave processing is used specifically because it offers a rapid and energy-efficient alternative to conventional thermal methods, with the benefits of intrinsic heating and selective heating of materials. The first experiments centered on understanding the effects …

Integrating Medical Plastic Waste Pyrolysis And Circular Economy For Environmental Sustainability, Attia Attia, Mohamed Bassyouni Prof., Reem Nasser Eng., Moataz El-Bagoury Eng., Islam Shaker Eng., Yasser Elhenawy Prof., Dina Aboelela Dr.

Biochemical Engineering

A critical assessment of pyrolysis technologies and reactor designs was discussed, highlighting various reactor configurations. This study explored the influence of catalysts, temperature, heating rate, and residence time on the pyrolysis process, and addressed their effects on product distribution and composition. Safety considerations and strategies for mitigating the potential environmental impacts of pyrolysis were presented. Comparative analyses of the environmental impacts of traditional waste disposal methods versus pyrolysis-based approaches provided insights into the potential reduction of greenhouse gas emissions and other pollutants. The circular economy approach was explored in the context of medical plastic waste pyrolysis. The potential for closing …

Enhancing The Mechanical Properties Of Sla 3d-Printed Bio-Resin From Linseed Oil Using Cellulose And Lignin Biopolymers, Chukwunonso A. Ikedionu

College of Graduate Studies: Theses & Dissertations

Abstract

This research explores the development of bio resin from linseed oil by the process of epoxidation and acrylation to produce acrylated epoxidized linseed oil (AELO). Lignin and cellulose biopolymers were added as reinforcement at varying weight fractions of 1 wt.%, 2.5 wt.%, and 5 wt.%, and their mechanical performance was compared against pure AELO. The formulations were printed using an Elegoo SLA 3D printer to create standardized test specimens like tensile bars, compression cylinders, and hardness blocks, which were all prepared according to the ASTM testing standard.

The results indicate that reinforcement effects depend on both filler type and …

Ground Testing Of A Magnetic-Electrostatic Separation System For Lunar Regolith Beneficiation, Peter Bachle, Charles Wood, Jeffrey Smith, Fateme Rezaei, David Bayless, William Schonberg, Daoru Han

Materials Science and Engineering Faculty Research & Creative Works

The separation of lunar regolith by mineral composition and size category is useful forin-situ resource utilization (ISRU). The research presented herein discusses the designing and development of equipment that has the potential to separate lunar regolith into aluminum, iron-titanium, and magnesium-iron ores. Along with the metal ore separation, this equipment shows the potential to separate regolith by size categories. The combined effect of these separation methods generates output that is valuable to subsequent use in metal and oxygen extraction, additive manufacturing, and regolith sintering processes. The designed equipment uses a dual-strength magnet system with N42 and N52 neodymium magnets for …

Gas-Generating Reactive Materials: Design, Evaluation And Effect Of Morphology On Their Ignition And Combustion, Purvam Mehulkumar Gandhi

Dissertations

This work investigates optimizing gas-generating reactive materials, focusing on particle morphology's effect on ignition and combustion behavior. Metal-based gas-generating energetic materials (EMs) are promising alternatives to replace traditional CHNO compounds. Design of advanced metal-based EMs requires consistent ways of evaluating how their characteristics affect their ignition and combustion. Many relevant evaluation approaches exist; however, the results may be difficult to compare directly across different studies. Commonly, experimentalists ignite metal-based EMs in enclosed chambers and report pressures, P. However, direct comparison of these pressures is hindered by variations in the chamber volume, V, and the EM mass, m. To standardize the …

Effect Of Alkyd And Polyester Resin Compositions On Corrosion Resistance, Blistering, And Adhesion In Utilization Of Oily Sludge As Anti-Rust Coating Material, Gerets Land Kakalang, Yohanes David Kristianto, Johny Wahyuadi Mudaryoto

Journal of Materials Exploration and Findings

Oil sludge is a waste derived from upstream and downstream activities of the oil and gas industry which is estimated at 10,000 tonnes generated from all PERTAMINA downstream activities spread across various fields, processing units and depots throughout Indonesia. Oil sludge has the same characteristics as asphalt, where asphalt in previous studies can be used as an anti-rust coating, so that the handling of oily sludge can be topped up by reusing and having its own added value. The purpose of this research is to utilise waste oily sludge as an alternative anti-rust coating material and compare alkyd resin and …

Capacity Of Self Compact Concrete Walls Using Attapulgite As A Partial Replacement Of Cement Under One Way And Two Way Action Restriction, Wissam Kadhim Alsaraj, Luma Abdul Ghani Zghair, Akhlas Hashem Mohammed

Al-Esraa University College Journal for Engineering Sciences

This investigation about the structural performance of sustainable self-compact concrete walls exposed to eccentric axial regularly dispersed loading, including the effect of aspect ratio (AR) and slenderness ratio (λ) by one-way and two-way action. The experimental program includes testing ten wall panels, the eccentricity of the loading system equivalent to one-sixth of depth. These wall panels are separated into four groups, each one consisting of three specimens. first and second groups clarify the aspect ratio (H/L) effect. The results indicated for decreasing AR from (0.75 to 0.625), (0.625 to 0.5), and (0.75 to 0.5), the increase of final load is …

Exploring The Benefits Of Feature Selection Based On Bat Algorithm And Deep Learning In Brain Cancer Diagnosis, Noor Fawzi Shafiq

Al-Esraa University College Journal for Engineering Sciences

Brain cancer is considered one of the most dangerous types that must be treated as soon as possible. Therefore, it is necessary to detect brain cancer in its early stages to enhance the diagnosis of the condition. This study proposes to combine the bat algorithm (BA) with deep learning methods to identify and classify brain tumors in medical images accurately.

In this paper, the bat algorithm was used to select distinctive features from the input brain images. The Bat Algorithm (BA) is a metaheuristic optimization algorithm that mimics the echolocation behavior of bats. It efficiently explores the feature space to …

Unveiling The Hidden Threat: How Wireless Networks Fuel Serious Cyber Attacks, Ibtesam Jomaa Hawi

Al-Esraa University College Journal for Engineering Sciences

The spread of wireless networks has led to an increase in serious cyber attacks due to their weak architecture. This article focuses on reevaluating cybersecurity in wireless network technology by integrating statistical information detection methods and artificial intelligence (AI) algorithms. To construct a wireless networking scenario that accurately reflects real-life conditions, we created a data fabrication that included four pre-existing anomalies as well as four newly introduced anomalies. The synthetic dataset created from these generation processes contains 20 thousand distinguishable values, which are later divided into training and validation sets. Using the strategy described before, we began to analyze the …

A Study On Improving The Accuracy And Effectiveness Of Similarity Detection Processes In Text Files Using Nlp Techniques, Noor Abdulmuttaleb Jaafar

Al-Esraa University College Journal for Engineering Sciences

The rapid expansion of the Internet has revolutionized access to information, especially in the area of unstructured data, most of which consists of textual content. While instant access to information brings many advantages, it has also given rise to a prevalent problem – plagiarism. Copying and reusing materials without proper permission poses a significant threat to academic integrity and integrity. Rates of plagiarism, especially in academic and scientific publications, have risen with the advent of the Internet, reaching alarming levels, such as 60% in student projects. This study examines the proposed model that includes computation of similarity using cosine coefficients, …

An Intelligent System Using Deep Learning For Healthcare Monitoring In Light Of The Covid-19 And Future Pandemics Based On Iot, Sara Salman Qasim, Rajaa J. Khanjar, Jamal Nasir Hasoon, Baesher Abdullateff Abad, Ali Hussein Fadil, Shajan.M. Alsowaidi

Al-Esraa University College Journal for Engineering Sciences

Recently, the Internet of Things has become a compelling research field as a new topic of research in various disciplines, particularly in the field of healthcare, because the Internet of Things is rebuilding modern healthcare systems by integrating technology, economics, and social perspectives. The development of healthcare systems from traditional to more personalized systems in which patients can be easily diagnosed, monitored and treated and many people can be helped. People are treated and cared for remotely and this is what some people need in the crisis the world has been through like COVID-19. This epidemic is caused by the …

Speech Coding Based On A Hybrid Approach: Dct, Huffman And Run-Length Coding, Sundos Abdulameer Alazawi, Esraa Jaffar Baker, Shahbaa Mohammed Abdulmaged

Al-Esraa University College Journal for Engineering Sciences

The exponential expansion of data in the digital world necessitates the development of effective methods for data transmission and storage. Data compression (DC) strategies are suggested to reduce the quantity of data stored or conveyed due to constrained resources. As a result of DC ideas' ability to efficiently use existing storage space and transmission capacity, different methods have been developed in various areas. Speech coding is a lossy method of coding; therefore, the output signal differs slightly from the input signal. Speech coding is useful for message encryption, communication over long distances and speech quality. In the fields of digital …

The Evolution Of The University Of Al-Anbar Urban Planning Based On The Mental Picture's Diversity And The Contemporary Planning Spaces Filling, Ali Abdulsamea Hameed

Al-Esraa University College Journal for Engineering Sciences

This research concentrated on the role of environmental graphic design (EGD) and the place-making idea in the interior environment of Al-Anbar University. To develop an identity being visual for the University of Al-Anbar internal environment (IE) is this goal of project. The search sought to create and enhance the shape of the internal University of Al-Anbar vacuum by reviving the idea of place building. In order to build and filling the internal emptiness of the campus, the identity being visual must also be strengthened. The descriptive analytical approach was chosen since it was best suited to achieve the goal of …

Optimization Of Tps Films Using An Adaptive Design Of Experiments Approach In A Bayesian Optimization Framework, Theresa Marks, Gracie White, Scott Lohman, Mayank Malhotra

The Journal of Purdue Undergraduate Research

Plastic pollution, amounting to 12 million tons annually, necessitates sustainable alternatives to single-use plastics. Compostable thermoplastic starch (TPS) films show promise but lack strength and durability compared to traditional plastics. This study employs an adaptive design of experiments (DoE) approach to enhance TPS films by optimizing testing points. The research focuses on varying concentrations of plasticizers (acetic acid and glycerol) in a water and potato starch mixture, aiming to identify the optimal ratio maximizing tensile strength and % elongation at break. Gaussian process regression (GPR) with uncertainty estimation and Bayesian optimization (BO) utilizing an acquisition function (AF) are employed. The …

Zeolite 13x Particles With Porous Tio2 Coating And Ag2o Nanoparticles As Multi-Functional Filler Materials For Face Masks, Wei Su, Kaiying Wang, Han Yu, Fateme Fayyazbakhsh, Jeremy Watts, Yue-Wern Huang, Jee-Ching Wang, Xinhua Liang

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Adsorbent components in face masks are crucial for protecting individuals exposed to dangerous situations. In this study, one porous TiO₂ layer was deposited on zeolite 13X particles by coating hybrid organic/inorganic titanium alkoxide film via molecular layer deposition (MLD), followed by heat treatment to remove organic components in the MLD film. Various concentrations of Ag₂O nanoparticles were impregnated on the TiO₂-coated 13X particles, offering a wide range of antibacterial, antifungal, and antiviral characteristics. The obtained composite particles were characterized using X-ray photoelectron spectroscopy and thermal gravimetric analysis to study the composition and mass loading of …

Application Of Digital Rock Physics And Machine Learning To Improve The Understanding Of Fluid Flow Behavior Through Porous Media, Md Irfan Khan

Mechanical Engineering Theses

Accurately estimating reservoir rock properties and understanding capillary trapping mechanisms are crucial for fluid storage and flow modeling in porous media, particularly for applications such as carbon dioxide sequestration (CCS) and underground hydrogen storage (UHS). This thesis presents a comprehensive workflow that combines machine learning techniques and pore-network modeling approach to predict petrophysical properties and assess the impact of microscopic pore structures on capillary trapping. In the first part, a convolutional neural network (CNN) framework is used to predict rock properties—such as porosity, throat area, and pore surface area—from micro-computed tomography (micro-CT) X-ray images. It has been observed that incorporating …

Predictive Modeling And Sustainability Assessment Of Hydrothermal Liquefaction Of Seaweeds: A Techno-Economic And Life Cycle Analysis Approach, Micheal O. Asama

Mechanical Engineering Theses

This study presents comprehensive predictive models and an economic and environmental assessment of HTL for converting macroalgae into biofuels and valuable co-products. Predictive models were developed based on experimental kinetic data to simulate batch HTL of brown seaweed, capturing the yields of biocrude, gas, biochar, and water-soluble compounds as functions of key process variables, including temperature, time, pressure, and water-to-biomass ratio. Analysis of Variance (ANOVA) confirmed that temperature and residence time significantly affect biocrude yield, with an optimal yield of 23% achieved at 283°C, 200 bar, 54 minutes, and a 10:1 water-to-biomass ratio. The model’s predictive accuracy was validated with …

Deciphering Mechanochemical Influences Of Emergent Actomyosin Crosstalk Using Qcm‑D, Emily M. Kerivan, Victoria N. Amari, William B. Weeks, Leigh H. Hardin, Lyle Tobin, Omayma Y. Al Azzam, Dana N. Reinemann

Faculty and Student Publications

Purpose: Cytoskeletal protein ensembles exhibit emergent mechanics where behavior in teams is not necessarily the sum of the components’ single molecule properties. In addition, filaments may act as force sensors that distribute feedback and influence motor protein behavior. To understand the design principles of such emergent mechanics, we developed an approach utilizing QCM-D to measure how actomyosin bundles respond mechanically to environmental variables that alter constituent myosin II motor behavior.

Methods: QCM-D is used for the first time to probe alterations in actin-myosin bundle viscoelasticity due to changes in skeletal myosin II concentration and motor nucleotide state. Actomyosin bundles were …